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Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin
dc.creator | Filipović, Nenad | |
dc.creator | Bacchi, Alessia | |
dc.creator | Pelizzi, Giancarlo | |
dc.creator | Marković, R | |
dc.creator | Mitić, Dragana | |
dc.creator | Andjelković, Katarina | |
dc.date.accessioned | 2020-12-17T18:32:05Z | |
dc.date.available | 2020-12-17T18:32:05Z | |
dc.date.issued | 2005 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | http://aspace.agrif.bg.ac.rs/handle/123456789/1006 | |
dc.description.abstract | Four Co(III), Zn(II), Pd(II) and Cd(II) complexes with ligands derived in situ from acetylpyridine and ethyl hydrazinoacetate or hydrolysed ethyl hydrazinoacetate were prepared. An X-ray structural analysis showed that the Co(III) complex is octahedral with two tridentate (E)-2-[N'-(1-pyridin-2-yl-ethylidene) hydrazino] acetate (apha) ligands, each forming two five-membered rings with the metal ion. In the tetrahedral Zn(II) complex, only a single apha ligand was coordinated, in the same way as that in the Co(III) complex. In the case of the tetrahedral Cd(II) complex the non-hydrolysed form of (E)-2-[N'-(1-pyridin2-yl-ethylidene)hydrazino]acetic acid ethyl ester (aphaoet) coordinated as a bidentate and the two remaining coordination sites were occupied by Cl- and CH3COO- ions. In addition, the square-planar neutral Pd(II) complex was synthesized, having the same bidentate as in the Cd(II) complex and two Cl- ions in the remaining coordination sites. Due to their being diamagnetic, all four complexes were characterized by H-1-NMR and C-13-NMR spectroscopy. | en |
dc.publisher | Taylor & Francis Ltd, Abingdon | |
dc.rights | restrictedAccess | |
dc.source | Journal of Coordination Chemistry | |
dc.subject | cobalt(III) | en |
dc.subject | zinc(II) | en |
dc.subject | Cd(II) | en |
dc.subject | Pd(II) | en |
dc.subject | 2-acetylpyridine | en |
dc.subject | ethyl hydrazinoacetate | en |
dc.subject | crystal structure | en |
dc.subject | NMR | en |
dc.title | Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 1550 | |
dc.citation.issue | 17 | |
dc.citation.other | 58(17): 1541-1550 | |
dc.citation.rank | M23 | |
dc.citation.spage | 1541 | |
dc.citation.volume | 58 | |
dc.identifier.doi | 10.1080/00958970500240383 | |
dc.identifier.scopus | 2-s2.0-30944467489 | |
dc.identifier.wos | 000233130000003 | |
dc.type.version | publishedVersion |