Vulić, Predrag J.

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Authority KeyName Variants
0d1d43f7-7bea-4bee-884f-7230304dc982
  • Vulić, Predrag J. (7)
  • Vulić, Predrag (2)
Projects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry) Directed synthesis, structure and properties of multifunctional materials
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) DGI(-MEC)/FEDEREuropean Union (EU)Spanish Government [CTQ2016-75816-C02-02-P]
Molecular properties and modifications of some respiratory and nutritional allergens Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring
Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)
This investigation was supported by the Serbian Ministry of Education, Science and Technological Development of the Republic of Serbia, and it was conducted under the following projects: OI 172057, and III 45007. The authors would like to thank Dr. Miodra

Author's Bibliography

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag; Jeremić, Dejan; Pavlović, Vladimir; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/9515
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5759
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
SP  - 111117
VL  - 134
DO  - 10.1016/j.materresbull.2020.111117
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag and Jeremić, Dejan and Pavlović, Vladimir and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
pages = "111117",
volume = "134",
doi = "10.1016/j.materresbull.2020.111117"
}
Šuljagić, M., Vulić, P., Jeremić, D., Pavlović, V., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M., Nikolić, A. S.,& Anđelković, L.. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
Šuljagić M, Vulić P, Jeremić D, Pavlović V, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković M, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117 .
Šuljagić, Marija, Vulić, Predrag, Jeremić, Dejan, Pavlović, Vladimir, Filipović, Suzana, Kilanski, Lukasz, Lewinska, Sabina, Slawska-Waniewska, Anna, Milenković, Milica, Nikolić, Aleksandar S., Anđelković, Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" in Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 . .
19
5
18

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag; Jeremić, Dejan; Pavlović, Vladimir; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/9514
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5758
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
SP  - 111117
VL  - 134
DO  - 10.1016/j.materresbull.2020.111117
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag and Jeremić, Dejan and Pavlović, Vladimir and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
pages = "111117",
volume = "134",
doi = "10.1016/j.materresbull.2020.111117"
}
Šuljagić, M., Vulić, P., Jeremić, D., Pavlović, V., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M., Nikolić, A. S.,& Anđelković, L.. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
Šuljagić M, Vulić P, Jeremić D, Pavlović V, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković M, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117 .
Šuljagić, Marija, Vulić, Predrag, Jeremić, Dejan, Pavlović, Vladimir, Filipović, Suzana, Kilanski, Lukasz, Lewinska, Sabina, Slawska-Waniewska, Anna, Milenković, Milica, Nikolić, Aleksandar S., Anđelković, Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" in Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 . .
19
5
18

Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis

Filipović, Suzana; Andjelković, Lj.; Jeremić, D.; Vulić, Predrag J.; Nikolić, A.S.; Marković, S.; Paunović, V; Lević, Steva; Pavlović, Vladimir

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2020)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Andjelković, Lj.
AU  - Jeremić, D.
AU  - Vulić, Predrag J.
AU  - Nikolić, A.S.
AU  - Marković, S.
AU  - Paunović, V
AU  - Lević, Steva
AU  - Pavlović, Vladimir
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5323
AB  - Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180 degrees C, and within a variety of frequencies. Curie temperature was detected at 130 degrees C.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis
EP  - 268
IS  - 3
SP  - 257
VL  - 52
DO  - 10.2298/SOS2003257F
ER  - 
@article{
author = "Filipović, Suzana and Andjelković, Lj. and Jeremić, D. and Vulić, Predrag J. and Nikolić, A.S. and Marković, S. and Paunović, V and Lević, Steva and Pavlović, Vladimir",
year = "2020",
abstract = "Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180 degrees C, and within a variety of frequencies. Curie temperature was detected at 130 degrees C.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis",
pages = "268-257",
number = "3",
volume = "52",
doi = "10.2298/SOS2003257F"
}
Filipović, S., Andjelković, Lj., Jeremić, D., Vulić, P. J., Nikolić, A.S., Marković, S., Paunović, V., Lević, S.,& Pavlović, V.. (2020). Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 52(3), 257-268.
https://doi.org/10.2298/SOS2003257F
Filipović S, Andjelković L, Jeremić D, Vulić PJ, Nikolić A, Marković S, Paunović V, Lević S, Pavlović V. Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis. in Science of Sintering. 2020;52(3):257-268.
doi:10.2298/SOS2003257F .
Filipović, Suzana, Andjelković, Lj., Jeremić, D., Vulić, Predrag J., Nikolić, A.S., Marković, S., Paunović, V, Lević, Steva, Pavlović, Vladimir, "Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis" in Science of Sintering, 52, no. 3 (2020):257-268,
https://doi.org/10.2298/SOS2003257F . .
4
1
5

1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study

Ristić, Predrag; Todorović, Tamara R.; Blagojević, Vladimir A.; Klisurić, Olivera; Marjanović, Ivana; Hollo, Berta Barta; Vulić, Predrag J.; Gulea, Mihaela; Donnard, Morgan; Monge, Miguel; Rodriguez-Castillo, Maria; Lopez-de-Luzuriaga, Jose M.; Filipović, Nenad

(Amer Chemical Soc, Washington, 2020)

TY  - JOUR
AU  - Ristić, Predrag
AU  - Todorović, Tamara R.
AU  - Blagojević, Vladimir A.
AU  - Klisurić, Olivera
AU  - Marjanović, Ivana
AU  - Hollo, Berta Barta
AU  - Vulić, Predrag J.
AU  - Gulea, Mihaela
AU  - Donnard, Morgan
AU  - Monge, Miguel
AU  - Rodriguez-Castillo, Maria
AU  - Lopez-de-Luzuriaga, Jose M.
AU  - Filipović, Nenad
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5281
AB  - Four silver-based coordination polymers, {[Ag(L)(2)](BF4)}(infinity) (1), {[Ag(H2BTC)(L)]center dot(H3BTC)}(infinity) (2), {[Ag-2(H2BTEC)(L)(2)]..3.33H(2)O}(infinity) (3), and [Ag(H(25)SSA)(L)](infinity) (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H(35)SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036-0.056 min(-1) range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet-singlet electronic excitations to the fluorescence, indicating that metal- intraligand transitions are responsible for luminescence in both complexes.
PB  - Amer Chemical Soc, Washington
T2  - Crystal Growth & Design
T1  - 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study
EP  - 4478
IS  - 7
SP  - 4461
VL  - 20
DO  - 10.1021/acs.cgd.0c00287
ER  - 
@article{
author = "Ristić, Predrag and Todorović, Tamara R. and Blagojević, Vladimir A. and Klisurić, Olivera and Marjanović, Ivana and Hollo, Berta Barta and Vulić, Predrag J. and Gulea, Mihaela and Donnard, Morgan and Monge, Miguel and Rodriguez-Castillo, Maria and Lopez-de-Luzuriaga, Jose M. and Filipović, Nenad",
year = "2020",
abstract = "Four silver-based coordination polymers, {[Ag(L)(2)](BF4)}(infinity) (1), {[Ag(H2BTC)(L)]center dot(H3BTC)}(infinity) (2), {[Ag-2(H2BTEC)(L)(2)]..3.33H(2)O}(infinity) (3), and [Ag(H(25)SSA)(L)](infinity) (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H(35)SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036-0.056 min(-1) range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet-singlet electronic excitations to the fluorescence, indicating that metal- intraligand transitions are responsible for luminescence in both complexes.",
publisher = "Amer Chemical Soc, Washington",
journal = "Crystal Growth & Design",
title = "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study",
pages = "4478-4461",
number = "7",
volume = "20",
doi = "10.1021/acs.cgd.0c00287"
}
Ristić, P., Todorović, T. R., Blagojević, V. A., Klisurić, O., Marjanović, I., Hollo, B. B., Vulić, P. J., Gulea, M., Donnard, M., Monge, M., Rodriguez-Castillo, M., Lopez-de-Luzuriaga, J. M.,& Filipović, N.. (2020). 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design
Amer Chemical Soc, Washington., 20(7), 4461-4478.
https://doi.org/10.1021/acs.cgd.0c00287
Ristić P, Todorović TR, Blagojević VA, Klisurić O, Marjanović I, Hollo BB, Vulić PJ, Gulea M, Donnard M, Monge M, Rodriguez-Castillo M, Lopez-de-Luzuriaga JM, Filipović N. 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design. 2020;20(7):4461-4478.
doi:10.1021/acs.cgd.0c00287 .
Ristić, Predrag, Todorović, Tamara R., Blagojević, Vladimir A., Klisurić, Olivera, Marjanović, Ivana, Hollo, Berta Barta, Vulić, Predrag J., Gulea, Mihaela, Donnard, Morgan, Monge, Miguel, Rodriguez-Castillo, Maria, Lopez-de-Luzuriaga, Jose M., Filipović, Nenad, "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study" in Crystal Growth & Design, 20, no. 7 (2020):4461-4478,
https://doi.org/10.1021/acs.cgd.0c00287 . .
3
12
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11

Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study

Ristić, Predrag; Blagojević, Vladimir A.; Janjić, Goran; Rodić, Marko; Vulić, Predrag J.; Donnard, Morgan; Gulea, Mihaela; Chylewska, Agnieszka; Makowski, Mariusz; Todorović, Tamara; Filipović, Nenad

(Amer Chemical Soc, Washington, 2020)

TY  - JOUR
AU  - Ristić, Predrag
AU  - Blagojević, Vladimir A.
AU  - Janjić, Goran
AU  - Rodić, Marko
AU  - Vulić, Predrag J.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Chylewska, Agnieszka
AU  - Makowski, Mariusz
AU  - Todorović, Tamara
AU  - Filipović, Nenad
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5373
AB  - Pt(II) and Pd(II) complexes (1 and 2, respectively) with thiomorpholine-4-carbonitrile (TM-CN), an N-substituted thiomorpholine derivative, were synthesized from tetrachlorido precursors in water. Structural analysis has shown that 1 represents the first monomeric metal complex with this ligand type with an axial M-S bond with respect to the TM-CN ring chair conformation, while in 2 a typical equatorial M-S bond position with respect to the ring chair conformation was observed. A detailed DFT investigation revealed that axial conformers are more stable for molecular forms of both metals, while intermolecular interactions in the crystals stabilize the axial conformer for Pt(II) and the equatorial conformer for Pd(II). The magnitude of this stabilization in the case of 2 is large enough to change the most stable axial conformer in the molecular form to the equatorial conformer in the crystal. Further investigation of the strength of individual intermolecular interactions revealed significant differences of some interactions between the two structures. The likely cause of the difference in the crystal structures of experimentally obtained complexes is the fact that 1 and 2 exhibit different dominant interactions: C-H/M and C-H/S are more dominant in 1 and C-H/Cl interactions are more dominant in 2. In addition, DFT calculations have shown that while the axial position of the Pt-S bond with respect to the ring chair conformation results in a significantly shorter C-H/Pt interaction distance than that in the hypothetical equatorial conformer, there is very little difference in C-H/Pd interaction distances in conformers with axial and equatorial positions of Pd-S bond with respect to the ring chair conformation.
PB  - Amer Chemical Soc, Washington
T2  - Crystal Growth & Design
T1  - Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study
EP  - 3033
IS  - 5
SP  - 3018
VL  - 20
DO  - 10.1021/acs.cgd.9b01661
ER  - 
@article{
author = "Ristić, Predrag and Blagojević, Vladimir A. and Janjić, Goran and Rodić, Marko and Vulić, Predrag J. and Donnard, Morgan and Gulea, Mihaela and Chylewska, Agnieszka and Makowski, Mariusz and Todorović, Tamara and Filipović, Nenad",
year = "2020",
abstract = "Pt(II) and Pd(II) complexes (1 and 2, respectively) with thiomorpholine-4-carbonitrile (TM-CN), an N-substituted thiomorpholine derivative, were synthesized from tetrachlorido precursors in water. Structural analysis has shown that 1 represents the first monomeric metal complex with this ligand type with an axial M-S bond with respect to the TM-CN ring chair conformation, while in 2 a typical equatorial M-S bond position with respect to the ring chair conformation was observed. A detailed DFT investigation revealed that axial conformers are more stable for molecular forms of both metals, while intermolecular interactions in the crystals stabilize the axial conformer for Pt(II) and the equatorial conformer for Pd(II). The magnitude of this stabilization in the case of 2 is large enough to change the most stable axial conformer in the molecular form to the equatorial conformer in the crystal. Further investigation of the strength of individual intermolecular interactions revealed significant differences of some interactions between the two structures. The likely cause of the difference in the crystal structures of experimentally obtained complexes is the fact that 1 and 2 exhibit different dominant interactions: C-H/M and C-H/S are more dominant in 1 and C-H/Cl interactions are more dominant in 2. In addition, DFT calculations have shown that while the axial position of the Pt-S bond with respect to the ring chair conformation results in a significantly shorter C-H/Pt interaction distance than that in the hypothetical equatorial conformer, there is very little difference in C-H/Pd interaction distances in conformers with axial and equatorial positions of Pd-S bond with respect to the ring chair conformation.",
publisher = "Amer Chemical Soc, Washington",
journal = "Crystal Growth & Design",
title = "Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study",
pages = "3033-3018",
number = "5",
volume = "20",
doi = "10.1021/acs.cgd.9b01661"
}
Ristić, P., Blagojević, V. A., Janjić, G., Rodić, M., Vulić, P. J., Donnard, M., Gulea, M., Chylewska, A., Makowski, M., Todorović, T.,& Filipović, N.. (2020). Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study. in Crystal Growth & Design
Amer Chemical Soc, Washington., 20(5), 3018-3033.
https://doi.org/10.1021/acs.cgd.9b01661
Ristić P, Blagojević VA, Janjić G, Rodić M, Vulić PJ, Donnard M, Gulea M, Chylewska A, Makowski M, Todorović T, Filipović N. Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study. in Crystal Growth & Design. 2020;20(5):3018-3033.
doi:10.1021/acs.cgd.9b01661 .
Ristić, Predrag, Blagojević, Vladimir A., Janjić, Goran, Rodić, Marko, Vulić, Predrag J., Donnard, Morgan, Gulea, Mihaela, Chylewska, Agnieszka, Makowski, Mariusz, Todorović, Tamara, Filipović, Nenad, "Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study" in Crystal Growth & Design, 20, no. 5 (2020):3018-3033,
https://doi.org/10.1021/acs.cgd.9b01661 . .
1
4
3
4

Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles

Andjelković, Ljubica; Jeremić, Dejan; Milenković, Milica R.; Radosavljević, Jelena; Vulić, Predrag J.; Pavlović, Vladimir; Manojlović, Dragan; Nikolić, Aleksandar S.

(Elsevier Sci Ltd, Oxford, 2020)

TY  - JOUR
AU  - Andjelković, Ljubica
AU  - Jeremić, Dejan
AU  - Milenković, Milica R.
AU  - Radosavljević, Jelena
AU  - Vulić, Predrag J.
AU  - Pavlović, Vladimir
AU  - Manojlović, Dragan
AU  - Nikolić, Aleksandar S.
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5327
AB  - A simple organic-phase synthesis process was used to produce bare NiFe2O4 and ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 ferrite nanoparticles. X-ray powder diffractograms for all investigated powders show characteristic peaks of a spinel cubic structure without a secondary phase. Transmission electron microscopy (TEM) indicated the presence of nanoparticles that are smaller than 20 nm. The release of divalent ions (Ni2+ and Zn2+) from synthesized nanoparticles that were dispersed in saline solution, phosphate-buffered saline (PBS) and human serum, as determined by the inductively coupled plasma mass spectrometry (ICP-MS) method, was lower than 2 wt %. These results demonstrate the stability of the investigated nanoparticles in biologically relevant media and exclude the toxicity of Ni2+ and Zn2+ due to metal ion release, thereby opening a broad range of (bio)medical applications.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles
EP  - 3533
IS  - 3
SP  - 3528
VL  - 46
DO  - 10.1016/j.ceramint.2019.10.068
ER  - 
@article{
author = "Andjelković, Ljubica and Jeremić, Dejan and Milenković, Milica R. and Radosavljević, Jelena and Vulić, Predrag J. and Pavlović, Vladimir and Manojlović, Dragan and Nikolić, Aleksandar S.",
year = "2020",
abstract = "A simple organic-phase synthesis process was used to produce bare NiFe2O4 and ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 ferrite nanoparticles. X-ray powder diffractograms for all investigated powders show characteristic peaks of a spinel cubic structure without a secondary phase. Transmission electron microscopy (TEM) indicated the presence of nanoparticles that are smaller than 20 nm. The release of divalent ions (Ni2+ and Zn2+) from synthesized nanoparticles that were dispersed in saline solution, phosphate-buffered saline (PBS) and human serum, as determined by the inductively coupled plasma mass spectrometry (ICP-MS) method, was lower than 2 wt %. These results demonstrate the stability of the investigated nanoparticles in biologically relevant media and exclude the toxicity of Ni2+ and Zn2+ due to metal ion release, thereby opening a broad range of (bio)medical applications.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles",
pages = "3533-3528",
number = "3",
volume = "46",
doi = "10.1016/j.ceramint.2019.10.068"
}
Andjelković, L., Jeremić, D., Milenković, M. R., Radosavljević, J., Vulić, P. J., Pavlović, V., Manojlović, D.,& Nikolić, A. S.. (2020). Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles. in Ceramics International
Elsevier Sci Ltd, Oxford., 46(3), 3528-3533.
https://doi.org/10.1016/j.ceramint.2019.10.068
Andjelković L, Jeremić D, Milenković MR, Radosavljević J, Vulić PJ, Pavlović V, Manojlović D, Nikolić AS. Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles. in Ceramics International. 2020;46(3):3528-3533.
doi:10.1016/j.ceramint.2019.10.068 .
Andjelković, Ljubica, Jeremić, Dejan, Milenković, Milica R., Radosavljević, Jelena, Vulić, Predrag J., Pavlović, Vladimir, Manojlović, Dragan, Nikolić, Aleksandar S., "Synthesis, characterization and in vitro evaluation of divalent ion release from stable NiFe2O4, ZnFe2O4 and core-shell ZnFe2O4@NiFe2O4 nanoparticles" in Ceramics International, 46, no. 3 (2020):3528-3533,
https://doi.org/10.1016/j.ceramint.2019.10.068 . .
11
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11

Crystal structures and topological analysis of ag(i) complexes with 1,4-heterodisupstituted cyclohexanes

Marjanović, Ivana; Klisurić, Olivera; Filipović, Nenad; Todorović, Tamara; Vulić, Predrag J.; Ristić, Predrag; Gulea, Michaela; Donnard, Morgan

(Int Union Crystallography, Chester, 2019)

TY  - CONF
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera
AU  - Filipović, Nenad
AU  - Todorović, Tamara
AU  - Vulić, Predrag J.
AU  - Ristić, Predrag
AU  - Gulea, Michaela
AU  - Donnard, Morgan
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4966
PB  - Int Union Crystallography, Chester
C3  - Acta Crystallographica A-Foundation and Advances
T1  - Crystal structures and topological analysis of ag(i) complexes with 1,4-heterodisupstituted cyclohexanes
VL  - 75
DO  - 10.1107/S2053273319089861
ER  - 
@conference{
author = "Marjanović, Ivana and Klisurić, Olivera and Filipović, Nenad and Todorović, Tamara and Vulić, Predrag J. and Ristić, Predrag and Gulea, Michaela and Donnard, Morgan",
year = "2019",
publisher = "Int Union Crystallography, Chester",
journal = "Acta Crystallographica A-Foundation and Advances",
title = "Crystal structures and topological analysis of ag(i) complexes with 1,4-heterodisupstituted cyclohexanes",
volume = "75",
doi = "10.1107/S2053273319089861"
}
Marjanović, I., Klisurić, O., Filipović, N., Todorović, T., Vulić, P. J., Ristić, P., Gulea, M.,& Donnard, M.. (2019). Crystal structures and topological analysis of ag(i) complexes with 1,4-heterodisupstituted cyclohexanes. in Acta Crystallographica A-Foundation and Advances
Int Union Crystallography, Chester., 75.
https://doi.org/10.1107/S2053273319089861
Marjanović I, Klisurić O, Filipović N, Todorović T, Vulić PJ, Ristić P, Gulea M, Donnard M. Crystal structures and topological analysis of ag(i) complexes with 1,4-heterodisupstituted cyclohexanes. in Acta Crystallographica A-Foundation and Advances. 2019;75.
doi:10.1107/S2053273319089861 .
Marjanović, Ivana, Klisurić, Olivera, Filipović, Nenad, Todorović, Tamara, Vulić, Predrag J., Ristić, Predrag, Gulea, Michaela, Donnard, Morgan, "Crystal structures and topological analysis of ag(i) complexes with 1,4-heterodisupstituted cyclohexanes" in Acta Crystallographica A-Foundation and Advances, 75 (2019),
https://doi.org/10.1107/S2053273319089861 . .

Characterization of MgAl2O4 sintered ceramics

Obradović, Nina; Fahrenholtz, William G.; Filipović, Suzana; Đorđević, Pavle; Marković, Smilja; Rogan, Jelena; Vulić, Predrag J.; Pavlović, Vladimir

(Belgrade : Serbian Ceramic Society, 2019)

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Đorđević, Pavle
AU  - Marković, Smilja
AU  - Rogan, Jelena
AU  - Vulić, Predrag J.
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6980
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5748
AB  - Single crystalline phase MgAl2O4 is made from the predetermined composition of MgO-Al2O3 powder mixture by using ball-milling. Mixtures of MgO and Al2O3 are treated in planetary ball mill for 30, 60, 90 and 120 minutes, in air. The aim of this experiment was to examine phase composition, microstructure, and densification behavior of all sintered samples and to find out which sample has the best features for further use. After sintering in dilatometer at 1500 °C, XRD patterns and SEM images were recorded. The results show that mechanical activation is an efficient method to improve the densification behavior of MgAl2O4 sintered specimens. With the prolonged milling time, densities increased, reaching the maximum value of 2.8 g/cm3 for sample activated 120 minutes.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019
T1  - Characterization of MgAl2O4 sintered ceramics
EP  - 54
SP  - 54
UR  - https://hdl.handle.net/21.15107/rcub_dais_6980
ER  - 
@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Đorđević, Pavle and Marković, Smilja and Rogan, Jelena and Vulić, Predrag J. and Pavlović, Vladimir",
year = "2019",
abstract = "Single crystalline phase MgAl2O4 is made from the predetermined composition of MgO-Al2O3 powder mixture by using ball-milling. Mixtures of MgO and Al2O3 are treated in planetary ball mill for 30, 60, 90 and 120 minutes, in air. The aim of this experiment was to examine phase composition, microstructure, and densification behavior of all sintered samples and to find out which sample has the best features for further use. After sintering in dilatometer at 1500 °C, XRD patterns and SEM images were recorded. The results show that mechanical activation is an efficient method to improve the densification behavior of MgAl2O4 sintered specimens. With the prolonged milling time, densities increased, reaching the maximum value of 2.8 g/cm3 for sample activated 120 minutes.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019",
title = "Characterization of MgAl2O4 sintered ceramics",
pages = "54-54",
url = "https://hdl.handle.net/21.15107/rcub_dais_6980"
}
Obradović, N., Fahrenholtz, W. G., Filipović, S., Đorđević, P., Marković, S., Rogan, J., Vulić, P. J.,& Pavlović, V.. (2019). Characterization of MgAl2O4 sintered ceramics. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019
Belgrade : Serbian Ceramic Society., 54-54.
https://hdl.handle.net/21.15107/rcub_dais_6980
Obradović N, Fahrenholtz WG, Filipović S, Đorđević P, Marković S, Rogan J, Vulić PJ, Pavlović V. Characterization of MgAl2O4 sintered ceramics. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019. 2019;:54-54.
https://hdl.handle.net/21.15107/rcub_dais_6980 .
Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Đorđević, Pavle, Marković, Smilja, Rogan, Jelena, Vulić, Predrag J., Pavlović, Vladimir, "Characterization of MgAl2O4 sintered ceramics" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VIII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 23-25. September 2019 (2019):54-54,
https://hdl.handle.net/21.15107/rcub_dais_6980 .

Characterization of MgAl2O4 sintered ceramics

Obradović, N.; Fahrenholtz, W.G.; Filipović, Suzana; Corlett, C.; Djordjević, P.; Rogan, J.; Vulić, Predrag J.; Buljak, V.; Pavlović, Vladimir

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Obradović, N.
AU  - Fahrenholtz, W.G.
AU  - Filipović, Suzana
AU  - Corlett, C.
AU  - Djordjević, P.
AU  - Rogan, J.
AU  - Vulić, Predrag J.
AU  - Buljak, V.
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5150
AB  - Single phase MgAl2O4 was made from a one-to-one molar ratio of MgO and Al2O3 powders mixed using ball-milling. Mixtures of MgO and Al2O3 were subsequently treated in planetary ball mill for 30, 60, 90 and 120 minutes in air. The aim of this study was to examine phase composition, microstructure, and densification behavior of sintered specimens. After sintering in dilatometer at 1500 °C, the powder was converted to single phase MgAl2O4. The results show that mechanical activation improved the densification behavior of MgAl2O4 sintered specimens, and it reduced the onset temperature for sintering by approx. 100oC. Based on dilatometer data, powders were subsequently densified at 1450oC by hot pressing. Almost аll specimens exhibited full density, while sample activated for 30 minutes showed the fastest densification rate.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Characterization of MgAl2O4 sintered ceramics
EP  - 376
IS  - 4
SP  - 363
VL  - 51
DO  - 10.2298/SOS1904363O
ER  - 
@article{
author = "Obradović, N. and Fahrenholtz, W.G. and Filipović, Suzana and Corlett, C. and Djordjević, P. and Rogan, J. and Vulić, Predrag J. and Buljak, V. and Pavlović, Vladimir",
year = "2019",
abstract = "Single phase MgAl2O4 was made from a one-to-one molar ratio of MgO and Al2O3 powders mixed using ball-milling. Mixtures of MgO and Al2O3 were subsequently treated in planetary ball mill for 30, 60, 90 and 120 minutes in air. The aim of this study was to examine phase composition, microstructure, and densification behavior of sintered specimens. After sintering in dilatometer at 1500 °C, the powder was converted to single phase MgAl2O4. The results show that mechanical activation improved the densification behavior of MgAl2O4 sintered specimens, and it reduced the onset temperature for sintering by approx. 100oC. Based on dilatometer data, powders were subsequently densified at 1450oC by hot pressing. Almost аll specimens exhibited full density, while sample activated for 30 minutes showed the fastest densification rate.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Characterization of MgAl2O4 sintered ceramics",
pages = "376-363",
number = "4",
volume = "51",
doi = "10.2298/SOS1904363O"
}
Obradović, N., Fahrenholtz, W.G., Filipović, S., Corlett, C., Djordjević, P., Rogan, J., Vulić, P. J., Buljak, V.,& Pavlović, V.. (2019). Characterization of MgAl2O4 sintered ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(4), 363-376.
https://doi.org/10.2298/SOS1904363O
Obradović N, Fahrenholtz W, Filipović S, Corlett C, Djordjević P, Rogan J, Vulić PJ, Buljak V, Pavlović V. Characterization of MgAl2O4 sintered ceramics. in Science of Sintering. 2019;51(4):363-376.
doi:10.2298/SOS1904363O .
Obradović, N., Fahrenholtz, W.G., Filipović, Suzana, Corlett, C., Djordjević, P., Rogan, J., Vulić, Predrag J., Buljak, V., Pavlović, Vladimir, "Characterization of MgAl2O4 sintered ceramics" in Science of Sintering, 51, no. 4 (2019):363-376,
https://doi.org/10.2298/SOS1904363O . .
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