Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting
Аутори
Aleksić, KatarinaStojković Simatović, Ivana
Stanković, Ana
Veselinović, Ljiljana
Stojadinović, Stevan
Rac, Vladislav
Radmilović, Nadežda
Rajić, Vladimir
Škapin, Srečo Davor
Mančić, Lidija
Marković, Smilja
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Catalytic materials are the greatest challenge for the commercial application of water electrolysis (WEs) and fuel cells (FCs) as clean energy technologies. There is a need to find an alternative to expensive and unavailable platinum group metal (PGM) catalysts. This study aimed to reduce the cost of PGM materials by replacing Ru with RuO2 and lowering the amount of RuO2 by adding abundant and multifunctional ZnO. A ZnO@RuO2 composite in a 10:1 molar ratio was synthesized by microwave processing of a precipitate as a green, low-cost, and fast method, and then annealed at 300°C and 600°C to improve the catalytic properties. The physicochemical properties of the ZnO@RuO2 composites were investigated by X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The electrochemical activity of the samples was investigate...d by linear sweep voltammetry in acidic and alkaline electrolytes. We observed good bifunctional catalytic activity of the ZnO@RuO2 composites toward HER and OER in both electrolytes. The improved bifunctional catalytic activity of the ZnO@RuO2 composite by annealing was discussed and attributed to the reduced number of bulk oxygen vacancies and the increased number of established heterojunctions. Copyright © 2023 Aleksić, Stojković Simatović, Stanković, Veselinović, Stojadinović, Rac, Radmilović, Rajić, Škapin, Mančić and Marković.
Кључне речи:
composites / photo-electro catalysis / RuO2 / water splitting / ZnOИзвор:
Frontiers in Chemistry, 2023, 11Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200175 (Институт техничких наука САНУ, Београд) (RS-MESTD-inst-2020-200175)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200146 (Универзитет у Београду, Факултет за физичку хемију) (RS-MESTD-inst-2020-200146)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200162 (Универзитет у Београду, Физички факултет) (RS-MESTD-inst-2020-200162)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
- Стварање сорти топола и врба за гајење у мултифункционалним засадима (RS-MESTD-MPN2006-2010-20001)
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Aleksić, Katarina AU - Stojković Simatović, Ivana AU - Stanković, Ana AU - Veselinović, Ljiljana AU - Stojadinović, Stevan AU - Rac, Vladislav AU - Radmilović, Nadežda AU - Rajić, Vladimir AU - Škapin, Srečo Davor AU - Mančić, Lidija AU - Marković, Smilja PY - 2023 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/6368 AB - Catalytic materials are the greatest challenge for the commercial application of water electrolysis (WEs) and fuel cells (FCs) as clean energy technologies. There is a need to find an alternative to expensive and unavailable platinum group metal (PGM) catalysts. This study aimed to reduce the cost of PGM materials by replacing Ru with RuO2 and lowering the amount of RuO2 by adding abundant and multifunctional ZnO. A ZnO@RuO2 composite in a 10:1 molar ratio was synthesized by microwave processing of a precipitate as a green, low-cost, and fast method, and then annealed at 300°C and 600°C to improve the catalytic properties. The physicochemical properties of the ZnO@RuO2 composites were investigated by X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The electrochemical activity of the samples was investigated by linear sweep voltammetry in acidic and alkaline electrolytes. We observed good bifunctional catalytic activity of the ZnO@RuO2 composites toward HER and OER in both electrolytes. The improved bifunctional catalytic activity of the ZnO@RuO2 composite by annealing was discussed and attributed to the reduced number of bulk oxygen vacancies and the increased number of established heterojunctions. Copyright © 2023 Aleksić, Stojković Simatović, Stanković, Veselinović, Stojadinović, Rac, Radmilović, Rajić, Škapin, Mančić and Marković. T2 - Frontiers in Chemistry T2 - Frontiers in Chemistry T1 - Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting VL - 11 DO - 10.3389/fchem.2023.1173910 ER -
@article{ author = "Aleksić, Katarina and Stojković Simatović, Ivana and Stanković, Ana and Veselinović, Ljiljana and Stojadinović, Stevan and Rac, Vladislav and Radmilović, Nadežda and Rajić, Vladimir and Škapin, Srečo Davor and Mančić, Lidija and Marković, Smilja", year = "2023", abstract = "Catalytic materials are the greatest challenge for the commercial application of water electrolysis (WEs) and fuel cells (FCs) as clean energy technologies. There is a need to find an alternative to expensive and unavailable platinum group metal (PGM) catalysts. This study aimed to reduce the cost of PGM materials by replacing Ru with RuO2 and lowering the amount of RuO2 by adding abundant and multifunctional ZnO. A ZnO@RuO2 composite in a 10:1 molar ratio was synthesized by microwave processing of a precipitate as a green, low-cost, and fast method, and then annealed at 300°C and 600°C to improve the catalytic properties. The physicochemical properties of the ZnO@RuO2 composites were investigated by X-ray powder diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), UV-Vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The electrochemical activity of the samples was investigated by linear sweep voltammetry in acidic and alkaline electrolytes. We observed good bifunctional catalytic activity of the ZnO@RuO2 composites toward HER and OER in both electrolytes. The improved bifunctional catalytic activity of the ZnO@RuO2 composite by annealing was discussed and attributed to the reduced number of bulk oxygen vacancies and the increased number of established heterojunctions. Copyright © 2023 Aleksić, Stojković Simatović, Stanković, Veselinović, Stojadinović, Rac, Radmilović, Rajić, Škapin, Mančić and Marković.", journal = "Frontiers in Chemistry, Frontiers in Chemistry", title = "Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting", volume = "11", doi = "10.3389/fchem.2023.1173910" }
Aleksić, K., Stojković Simatović, I., Stanković, A., Veselinović, L., Stojadinović, S., Rac, V., Radmilović, N., Rajić, V., Škapin, S. D., Mančić, L.,& Marković, S.. (2023). Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting. in Frontiers in Chemistry, 11. https://doi.org/10.3389/fchem.2023.1173910
Aleksić K, Stojković Simatović I, Stanković A, Veselinović L, Stojadinović S, Rac V, Radmilović N, Rajić V, Škapin SD, Mančić L, Marković S. Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting. in Frontiers in Chemistry. 2023;11. doi:10.3389/fchem.2023.1173910 .
Aleksić, Katarina, Stojković Simatović, Ivana, Stanković, Ana, Veselinović, Ljiljana, Stojadinović, Stevan, Rac, Vladislav, Radmilović, Nadežda, Rajić, Vladimir, Škapin, Srečo Davor, Mančić, Lidija, Marković, Smilja, "Enhancement of ZnO@RuO2 bifunctional photo-electro catalytic activity toward water splitting" in Frontiers in Chemistry, 11 (2023), https://doi.org/10.3389/fchem.2023.1173910 . .