Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid
Authorized Users Only
2022
Authors
Šuljagić, M.Stanković, D.
Mirković, M.
Pavlović, V.

Petronijević, I.
Jeremić, D.
Andjelković, L.
Article

Metadata
Show full item recordAbstract
Abstract: Nickel ferrite nanoparticles were synthesized via thermal decomposition of β-diketonato complexes of nickel(II) and iron(III). The mechano-chemical activation of the complex precursors was used to ensure the increase in the reaction activity and consequently reduce thermal decomposition temperature. The prepared sample was thoroughly characterized by X-ray powder diffraction, FT-IR spectroscopy, scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). X-ray powder diffraction and FT-IR confirmed the spinel phase of the investigated powder. SEM and TEM revealed the ultrafine nature of nanosized polygonal particles, with a pronounced agglomeration effect. The capacity for electrocatalytic applications was examined using cyclic voltammetry (CV) and electrical impedance spectroscopy (EIS). Electrocatalytic measurements pointed out that the addition of 5% of nickel ferrite as a modifier to carbon paste elec...trode caused a current increase and a decrease of the EIS semicircle. Further increase in the amount of the modifier decreased heterogeneity of the electrode surface and served as excellent sensor for the detection of gallic acid in the concentration range from 1 to 10 µM with the detection limit of 0.27 µM. This unambiguously indicated the significant improvement in electrode transfer rate and better characteristics of the diffusion layer. © 2022, Pleiades Publishing, Ltd.
Keywords:
acetylacetone complexes / mechanochemical synthesis / nickel ferrite / sensors / spinelsSource:
Russian Journal of Inorganic Chemistry, 2022, 67, S13-S21Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200116 (University of Belgrade, Faculty of Agriculture) (RS-200116)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200168 (University of Belgrade, Faculty of Chemistry) (RS-200168)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (RS-200017)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200162 (University of Belgrade, Faculty of Physics) (RS-200162)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200288 (Innovation Center of the Faculty of Chemistry) (RS-200288)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200162 (University of Belgrade, Faculty of Physics) (RS-200162)
Collections
Institution/Community
Poljoprivredni fakultetTY - JOUR AU - Šuljagić, M. AU - Stanković, D. AU - Mirković, M. AU - Pavlović, V. AU - Petronijević, I. AU - Jeremić, D. AU - Andjelković, L. PY - 2022 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/6259 AB - Abstract: Nickel ferrite nanoparticles were synthesized via thermal decomposition of β-diketonato complexes of nickel(II) and iron(III). The mechano-chemical activation of the complex precursors was used to ensure the increase in the reaction activity and consequently reduce thermal decomposition temperature. The prepared sample was thoroughly characterized by X-ray powder diffraction, FT-IR spectroscopy, scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). X-ray powder diffraction and FT-IR confirmed the spinel phase of the investigated powder. SEM and TEM revealed the ultrafine nature of nanosized polygonal particles, with a pronounced agglomeration effect. The capacity for electrocatalytic applications was examined using cyclic voltammetry (CV) and electrical impedance spectroscopy (EIS). Electrocatalytic measurements pointed out that the addition of 5% of nickel ferrite as a modifier to carbon paste electrode caused a current increase and a decrease of the EIS semicircle. Further increase in the amount of the modifier decreased heterogeneity of the electrode surface and served as excellent sensor for the detection of gallic acid in the concentration range from 1 to 10 µM with the detection limit of 0.27 µM. This unambiguously indicated the significant improvement in electrode transfer rate and better characteristics of the diffusion layer. © 2022, Pleiades Publishing, Ltd. T2 - Russian Journal of Inorganic Chemistry T2 - Russian Journal of Inorganic Chemistry T1 - Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid EP - S21 SP - S13 VL - 67 DO - 10.1134/S003602362260201X ER -
@article{ author = "Šuljagić, M. and Stanković, D. and Mirković, M. and Pavlović, V. and Petronijević, I. and Jeremić, D. and Andjelković, L.", year = "2022", abstract = "Abstract: Nickel ferrite nanoparticles were synthesized via thermal decomposition of β-diketonato complexes of nickel(II) and iron(III). The mechano-chemical activation of the complex precursors was used to ensure the increase in the reaction activity and consequently reduce thermal decomposition temperature. The prepared sample was thoroughly characterized by X-ray powder diffraction, FT-IR spectroscopy, scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). X-ray powder diffraction and FT-IR confirmed the spinel phase of the investigated powder. SEM and TEM revealed the ultrafine nature of nanosized polygonal particles, with a pronounced agglomeration effect. The capacity for electrocatalytic applications was examined using cyclic voltammetry (CV) and electrical impedance spectroscopy (EIS). Electrocatalytic measurements pointed out that the addition of 5% of nickel ferrite as a modifier to carbon paste electrode caused a current increase and a decrease of the EIS semicircle. Further increase in the amount of the modifier decreased heterogeneity of the electrode surface and served as excellent sensor for the detection of gallic acid in the concentration range from 1 to 10 µM with the detection limit of 0.27 µM. This unambiguously indicated the significant improvement in electrode transfer rate and better characteristics of the diffusion layer. © 2022, Pleiades Publishing, Ltd.", journal = "Russian Journal of Inorganic Chemistry, Russian Journal of Inorganic Chemistry", title = "Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid", pages = "S21-S13", volume = "67", doi = "10.1134/S003602362260201X" }
Šuljagić, M., Stanković, D., Mirković, M., Pavlović, V., Petronijević, I., Jeremić, D.,& Andjelković, L.. (2022). Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid. in Russian Journal of Inorganic Chemistry, 67, S13-S21. https://doi.org/10.1134/S003602362260201X
Šuljagić M, Stanković D, Mirković M, Pavlović V, Petronijević I, Jeremić D, Andjelković L. Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid. in Russian Journal of Inorganic Chemistry. 2022;67:S13-S21. doi:10.1134/S003602362260201X .
Šuljagić, M., Stanković, D., Mirković, M., Pavlović, V., Petronijević, I., Jeremić, D., Andjelković, L., "Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid" in Russian Journal of Inorganic Chemistry, 67 (2022):S13-S21, https://doi.org/10.1134/S003602362260201X . .