Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone
Authors
Ristić, Predrag G.Rodić, Marko V.
Filipović, Nenad R.
Mitić, Dragana M.
Andjelković, Katarina K.
Todorović, Tamara R.
Article (Published version)
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Show full item recordAbstract
Two square-planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.
Keywords:
Chelate complexes / N-heteroaromatic Schiff base / Non-covalent interactions / Single crystal X-ray diffractionSource:
Journal of the Serbian Chemical Society, 2021, 86, 4, 393-406Publisher:
- Serbian Chemical Society
Funding / projects:
DOI: 10.2298/JSC201126079R
ISSN: 0352-5139
WoS: 000646020100005
Scopus: 2-s2.0-85106476575
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Poljoprivredni fakultetTY - JOUR AU - Ristić, Predrag G. AU - Rodić, Marko V. AU - Filipović, Nenad R. AU - Mitić, Dragana M. AU - Andjelković, Katarina K. AU - Todorović, Tamara R. PY - 2021 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5860 AB - Two square-planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots. PB - Serbian Chemical Society T2 - Journal of the Serbian Chemical Society T1 - Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone EP - 406 IS - 4 SP - 393 VL - 86 DO - 10.2298/JSC201126079R ER -
@article{ author = "Ristić, Predrag G. and Rodić, Marko V. and Filipović, Nenad R. and Mitić, Dragana M. and Andjelković, Katarina K. and Todorović, Tamara R.", year = "2021", abstract = "Two square-planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.", publisher = "Serbian Chemical Society", journal = "Journal of the Serbian Chemical Society", title = "Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone", pages = "406-393", number = "4", volume = "86", doi = "10.2298/JSC201126079R" }
Ristić, P. G., Rodić, M. V., Filipović, N. R., Mitić, D. M., Andjelković, K. K.,& Todorović, T. R.. (2021). Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone. in Journal of the Serbian Chemical Society Serbian Chemical Society., 86(4), 393-406. https://doi.org/10.2298/JSC201126079R
Ristić PG, Rodić MV, Filipović NR, Mitić DM, Andjelković KK, Todorović TR. Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone. in Journal of the Serbian Chemical Society. 2021;86(4):393-406. doi:10.2298/JSC201126079R .
Ristić, Predrag G., Rodić, Marko V., Filipović, Nenad R., Mitić, Dragana M., Andjelković, Katarina K., Todorović, Tamara R., "Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone" in Journal of the Serbian Chemical Society, 86, no. 4 (2021):393-406, https://doi.org/10.2298/JSC201126079R . .