Two square-planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.
Keywords:
Chelate complexes / N-heteroaromatic Schiff base / Non-covalent interactions / Single crystal X-ray diffraction
Source:
Journal of the Serbian Chemical Society, 2021, 86, 4, 393-406
TY - JOUR
AU - Ristić, Predrag G.
AU - Rodić, Marko V.
AU - Filipović, Nenad R.
AU - Mitić, Dragana M.
AU - Andjelković, Katarina K.
AU - Todorović, Tamara R.
PY - 2021
UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5860
AB - Two square-planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.
PB - Serbian Chemical Society
T2 - Journal of the Serbian Chemical Society
T1 - Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone
EP - 406
IS - 4
SP - 393
VL - 86
DO - 10.2298/JSC201126079R
ER -
@article{
author = "Ristić, Predrag G. and Rodić, Marko V. and Filipović, Nenad R. and Mitić, Dragana M. and Andjelković, Katarina K. and Todorović, Tamara R.",
year = "2021",
abstract = "Two square-planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray diffraction analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-covalent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone",
pages = "406-393",
number = "4",
volume = "86",
doi = "10.2298/JSC201126079R"
}
Ristić, P. G., Rodić, M. V., Filipović, N. R., Mitić, D. M., Andjelković, K. K.,& Todorović, T. R.. (2021). Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 86(4), 393-406.
https://doi.org/10.2298/JSC201126079R
Ristić PG, Rodić MV, Filipović NR, Mitić DM, Andjelković KK, Todorović TR. Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone. in Journal of the Serbian Chemical Society. 2021;86(4):393-406.
doi:10.2298/JSC201126079R .
Ristić, Predrag G., Rodić, Marko V., Filipović, Nenad R., Mitić, Dragana M., Andjelković, Katarina K., Todorović, Tamara R., "Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone" in Journal of the Serbian Chemical Society, 86, no. 4 (2021):393-406,
https://doi.org/10.2298/JSC201126079R . .
