Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
TY - JOUR
AU - Filipović, S.
AU - Obradović, N.
AU - Andjelković, Lj.
AU - Olćan, D.
AU - Petrović, J.
AU - Mirković, M.
AU - Pavlović, V.
AU - Jeremić, D.
AU - Vlahović, B.
AU - Đorđević, A.
PY - 2021
UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5835
AB - Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
PB - International Institute for the Science of Sintering (IISS)
T2 - Science of Sintering
T1 - Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction
EP - 8
IS - 1
SP - 1
VL - 53
DO - 10.2298/SOS2101001F
ER -
@article{
author = "Filipović, S. and Obradović, N. and Andjelković, Lj. and Olćan, D. and Petrović, J. and Mirković, M. and Pavlović, V. and Jeremić, D. and Vlahović, B. and Đorđević, A.",
year = "2021",
abstract = "Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.",
publisher = "International Institute for the Science of Sintering (IISS)",
journal = "Science of Sintering",
title = "Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction",
pages = "8-1",
number = "1",
volume = "53",
doi = "10.2298/SOS2101001F"
}
Filipović, S., Obradović, N., Andjelković, Lj., Olćan, D., Petrović, J., Mirković, M., Pavlović, V., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction. in Science of Sintering
International Institute for the Science of Sintering (IISS)., 53(1), 1-8.
https://doi.org/10.2298/SOS2101001F
Filipović S, Obradović N, Andjelković L, Olćan D, Petrović J, Mirković M, Pavlović V, Jeremić D, Vlahović B, Đorđević A. Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction. in Science of Sintering. 2021;53(1):1-8.
doi:10.2298/SOS2101001F .
Filipović, S., Obradović, N., Andjelković, Lj., Olćan, D., Petrović, J., Mirković, M., Pavlović, V., Jeremić, D., Vlahović, B., Đorđević, A., "Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction" in Science of Sintering, 53, no. 1 (2021):1-8,
https://doi.org/10.2298/SOS2101001F . .
