Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)
2019
Аутори
Kljajević, Ljiljana M.Melichova, Z.
Stojmenović, M.D.
Todorović, B.Z.
Pavlović, Vladimir
Čitaković, N.M.
Nenadović, Snežana S.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Geopolymers (GP) were successfully synthesized from metabentonite (MB), metadiatomite (MD) and metakaolinite (MK). Characterization of their phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. A SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel, and it is significantly different from the micrographs of the other two geopolymer samples, GPMB and GPMK. A considerable amount of unreacted particles, as well as the presence of pores in the geopolymer matrix of GPMK and GPMD, indicate an incomplete reaction in the system. Aluminosilicate inorganic polymers, geopolymers, are quasi solid electrolytes which possess a high electrical conductivity at room temperature in relation to materials of similar chemical composi-tion. The highest conductivity was found for the sample obtained from GPMK, amounting to 2.14 x 10-2 Ω-1cm-1 at 700 oC. The corresponding activation energies of conductivity for this sample amounted to 0.33 eV ...in the temperature range of 500-700 oC. The geopolymer synthesized from metakaolin has good ionic conductivity values, which recommends it for use as an alternative material for an SOFC (Solid Ox-ide Fuel Cell).
Кључне речи:
Electrical conductivity / Geopolymer / Metabentonite / Metadiatomite / MetakaolinИзвор:
Macedonian Journal of Chemistry and Chemical Engineering, 2019, 38, 2, 283-292Издавач:
- Macedonian Journal of Chemistry and Chemical Engineering
Финансирање / пројекти:
- Синтеза, процесирање и карактеризација наноструктурних материјала за примену у области енергије, механичког инжењерства, заштите животне стредине и биомедицине (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45012)
- Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
DOI: 10.20450/mjcce.2019.1678
ISSN: 1857-5552
WoS: 000508000900012
Scopus: 2-s2.0-85079366520
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Kljajević, Ljiljana M. AU - Melichova, Z. AU - Stojmenović, M.D. AU - Todorović, B.Z. AU - Pavlović, Vladimir AU - Čitaković, N.M. AU - Nenadović, Snežana S. PY - 2019 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5148 AB - Geopolymers (GP) were successfully synthesized from metabentonite (MB), metadiatomite (MD) and metakaolinite (MK). Characterization of their phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. A SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel, and it is significantly different from the micrographs of the other two geopolymer samples, GPMB and GPMK. A considerable amount of unreacted particles, as well as the presence of pores in the geopolymer matrix of GPMK and GPMD, indicate an incomplete reaction in the system. Aluminosilicate inorganic polymers, geopolymers, are quasi solid electrolytes which possess a high electrical conductivity at room temperature in relation to materials of similar chemical composi-tion. The highest conductivity was found for the sample obtained from GPMK, amounting to 2.14 x 10-2 Ω-1cm-1 at 700 oC. The corresponding activation energies of conductivity for this sample amounted to 0.33 eV in the temperature range of 500-700 oC. The geopolymer synthesized from metakaolin has good ionic conductivity values, which recommends it for use as an alternative material for an SOFC (Solid Ox-ide Fuel Cell). PB - Macedonian Journal of Chemistry and Chemical Engineering T2 - Macedonian Journal of Chemistry and Chemical Engineering T1 - Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite) EP - 292 IS - 2 SP - 283 VL - 38 DO - 10.20450/mjcce.2019.1678 ER -
@article{ author = "Kljajević, Ljiljana M. and Melichova, Z. and Stojmenović, M.D. and Todorović, B.Z. and Pavlović, Vladimir and Čitaković, N.M. and Nenadović, Snežana S.", year = "2019", abstract = "Geopolymers (GP) were successfully synthesized from metabentonite (MB), metadiatomite (MD) and metakaolinite (MK). Characterization of their phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. A SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel, and it is significantly different from the micrographs of the other two geopolymer samples, GPMB and GPMK. A considerable amount of unreacted particles, as well as the presence of pores in the geopolymer matrix of GPMK and GPMD, indicate an incomplete reaction in the system. Aluminosilicate inorganic polymers, geopolymers, are quasi solid electrolytes which possess a high electrical conductivity at room temperature in relation to materials of similar chemical composi-tion. The highest conductivity was found for the sample obtained from GPMK, amounting to 2.14 x 10-2 Ω-1cm-1 at 700 oC. The corresponding activation energies of conductivity for this sample amounted to 0.33 eV in the temperature range of 500-700 oC. The geopolymer synthesized from metakaolin has good ionic conductivity values, which recommends it for use as an alternative material for an SOFC (Solid Ox-ide Fuel Cell).", publisher = "Macedonian Journal of Chemistry and Chemical Engineering", journal = "Macedonian Journal of Chemistry and Chemical Engineering", title = "Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)", pages = "292-283", number = "2", volume = "38", doi = "10.20450/mjcce.2019.1678" }
Kljajević, L. M., Melichova, Z., Stojmenović, M.D., Todorović, B.Z., Pavlović, V., Čitaković, N.M.,& Nenadović, S. S.. (2019). Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite). in Macedonian Journal of Chemistry and Chemical Engineering Macedonian Journal of Chemistry and Chemical Engineering., 38(2), 283-292. https://doi.org/10.20450/mjcce.2019.1678
Kljajević LM, Melichova Z, Stojmenović M, Todorović B, Pavlović V, Čitaković N, Nenadović SS. Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite). in Macedonian Journal of Chemistry and Chemical Engineering. 2019;38(2):283-292. doi:10.20450/mjcce.2019.1678 .
Kljajević, Ljiljana M., Melichova, Z., Stojmenović, M.D., Todorović, B.Z., Pavlović, Vladimir, Čitaković, N.M., Nenadović, Snežana S., "Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)" in Macedonian Journal of Chemistry and Chemical Engineering, 38, no. 2 (2019):283-292, https://doi.org/10.20450/mjcce.2019.1678 . .