Characterization of glycidyl methacrylate based magnetic nanocomposites

Marković, Bojana M.; Spasojević, Vojislav V.; Dapcević, Aleksandra; Vuković, Zorica M.; Pavlović, Vladimir; Randjelović, Danijela, V; Nastasović, Aleksandra B.

doi:10.2298/HEMIND181113006M

2019

5026.pdf (1.521Mb)

Authors

Marković, Bojana M.
Spasojević, Vojislav V.

Dapcević, Aleksandra

Vuković, Zorica M.
Pavlović, Vladimir

Randjelović, Danijela, V
Nastasović, Aleksandra B.

Article (Published version)

Metadata

Show full item record

Abstract

Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the...

Keywords:

glycidyl methacrylate / trimethylolpropane trimethacrylate / magnetic nanocomposite / diethylenetriamine

Source:
HEMIJSKA INDUSTRIJA, 2019, 73, 1, 25-35

Publisher:

Savez hemijskih inženjera, Beograd

Funding / projects:

DOI: 10.2298/HEMIND181113006M

ISSN: 0367-598X

WoS: 000460129400003

Scopus: 2-s2.0-85064212602

[ Google Scholar ]


	3
	2

TY - JOUR
AU - Marković, Bojana M.
AU - Spasojević, Vojislav V.
AU - Dapcević, Aleksandra
AU - Vuković, Zorica M.
AU - Pavlović, Vladimir
AU - Randjelović, Danijela, V
AU - Nastasović, Aleksandra B.
PY - 2019
UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5029
AB - Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.
PB - Savez hemijskih inženjera, Beograd
T2 - HEMIJSKA INDUSTRIJA
T1 - Characterization of glycidyl methacrylate based magnetic nanocomposites
EP - 35
IS - 1
SP - 25
VL - 73
DO - 10.2298/HEMIND181113006M
ER -

@article{
author = "Marković, Bojana M. and Spasojević, Vojislav V. and Dapcević, Aleksandra and Vuković, Zorica M. and Pavlović, Vladimir and Randjelović, Danijela, V and Nastasović, Aleksandra B.",
year = "2019",
abstract = "Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "HEMIJSKA INDUSTRIJA",
title = "Characterization of glycidyl methacrylate based magnetic nanocomposites",
pages = "35-25",
number = "1",
volume = "73",
doi = "10.2298/HEMIND181113006M"
}

Marković, B. M., Spasojević, V. V., Dapcević, A., Vuković, Z. M., Pavlović, V., Randjelović, D. V.,& Nastasović, A. B.. (2019). Characterization of glycidyl methacrylate based magnetic nanocomposites. in HEMIJSKA INDUSTRIJA
Savez hemijskih inženjera, Beograd., 73(1), 25-35.
https://doi.org/10.2298/HEMIND181113006M

Marković BM, Spasojević VV, Dapcević A, Vuković ZM, Pavlović V, Randjelović DV, Nastasović AB. Characterization of glycidyl methacrylate based magnetic nanocomposites. in HEMIJSKA INDUSTRIJA. 2019;73(1):25-35.
doi:10.2298/HEMIND181113006M .

Marković, Bojana M., Spasojević, Vojislav V., Dapcević, Aleksandra, Vuković, Zorica M., Pavlović, Vladimir, Randjelović, Danijela, V, Nastasović, Aleksandra B., "Characterization of glycidyl methacrylate based magnetic nanocomposites" in HEMIJSKA INDUSTRIJA, 73, no. 1 (2019):25-35,
https://doi.org/10.2298/HEMIND181113006M . .