Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size

2019
Authors
Taleb, KhaledMarkovski, Jasmina
Velicković, Zlate

Rusmirović, Jelena D.

Rancić, Milica

Pavlović, Vladimir

Marinković, Aleksandar

Article (Published version)
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Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g(-1)) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg(-1) min(-1)). Lower capacity of arsenite, As(III), removal, 68.3 mg g(-1) for NC-MA/L-MG and 17.8 mg g(-1) for MC-O/L-MG, were obt...ained. Calculated activation energies, 13.28 and 10.87 kJ mol(-1) for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption.
Keywords:
Sorption / Nanocellulose / Microcellulose / Arsenic / MagnetiteSource:
Arabian Journal of Chemistry, 2019, 12, 8, 4675-4693Publisher:
- Elsevier, Amsterdam
Funding / projects:
- Directed synthesis, structure and properties of multifunctional materials (RS-172057)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
DOI: 10.1016/j.arabjc.2016.08.006
ISSN: 1878-5352
WoS: 000504900300272
Scopus: 2-s2.0-84992436135
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Poljoprivredni fakultetTY - JOUR AU - Taleb, Khaled AU - Markovski, Jasmina AU - Velicković, Zlate AU - Rusmirović, Jelena D. AU - Rancić, Milica AU - Pavlović, Vladimir AU - Marinković, Aleksandar PY - 2019 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4987 AB - Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g(-1)) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg(-1) min(-1)). Lower capacity of arsenite, As(III), removal, 68.3 mg g(-1) for NC-MA/L-MG and 17.8 mg g(-1) for MC-O/L-MG, were obtained. Calculated activation energies, 13.28 and 10.87 kJ mol(-1) for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption. PB - Elsevier, Amsterdam T2 - Arabian Journal of Chemistry T1 - Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size EP - 4693 IS - 8 SP - 4675 VL - 12 DO - 10.1016/j.arabjc.2016.08.006 ER -
@article{ author = "Taleb, Khaled and Markovski, Jasmina and Velicković, Zlate and Rusmirović, Jelena D. and Rancić, Milica and Pavlović, Vladimir and Marinković, Aleksandar", year = "2019", abstract = "Comparative adsorption study related to benefits of parent media size, i.e. microfibrillated cellulose (MC) versus nanocellulose (NC) support, for the preparation of magnetite (MG) based high performance adsorbent for arsenic removal was conducted. Precipitation of MG on amino terminal branched organic structure, L, either linked by maleic acid residue on NC surface (NC-MA/L) or linked by oxalyl bridge on MC surface (MC-O/L) produced NC-MA/L-MG and MC-O/L-MG adsorbents, respectively. Precipitation of nanosized MG on amino functionalized NC-MA/L and MC-O/L, performed according to optimized procedure, contributed to improved textural properties and adsorptive/kinetic performances of novel adsorbents. Adsorption capacity of arsenate, As(V), was in favor of NC-MA/L-MG (85.3 versus 18.5 mg g(-1)) while MC-O/L-MG exhibited faster kinetics (0.541 versus 0.189 g mg(-1) min(-1)). Lower capacity of arsenite, As(III), removal, 68.3 mg g(-1) for NC-MA/L-MG and 17.8 mg g(-1) for MC-O/L-MG, were obtained. Calculated activation energies, 13.28 and 10.87 kJ mol(-1) for NC-MA/L-MG and MC-O/L-MG with respect to As(V), respectively, suggest, in accordance with results of Weber-Morris fitting, that internal mass transfer controls adsorption process. Model free adsorption kinetics confirmed beneficial uses of MC-O/L-MG due to low activation energy dependence on the extent of adsorption.", publisher = "Elsevier, Amsterdam", journal = "Arabian Journal of Chemistry", title = "Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size", pages = "4693-4675", number = "8", volume = "12", doi = "10.1016/j.arabjc.2016.08.006" }
Taleb, K., Markovski, J., Velicković, Z., Rusmirović, J. D., Rancić, M., Pavlović, V.,& Marinković, A.. (2019). Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size. in Arabian Journal of Chemistry Elsevier, Amsterdam., 12(8), 4675-4693. https://doi.org/10.1016/j.arabjc.2016.08.006
Taleb K, Markovski J, Velicković Z, Rusmirović JD, Rancić M, Pavlović V, Marinković A. Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size. in Arabian Journal of Chemistry. 2019;12(8):4675-4693. doi:10.1016/j.arabjc.2016.08.006 .
Taleb, Khaled, Markovski, Jasmina, Velicković, Zlate, Rusmirović, Jelena D., Rancić, Milica, Pavlović, Vladimir, Marinković, Aleksandar, "Arsenic removal by magnetite-loaded amino modified nano/microcellulose adsorbents: Effect of functionalization and media size" in Arabian Journal of Chemistry, 12, no. 8 (2019):4675-4693, https://doi.org/10.1016/j.arabjc.2016.08.006 . .