Приказ основних података о документу

dc.creatorBegović, Nebojša
dc.creatorVasić, Milica M.
dc.creatorBlagojević, Vladimir A.
dc.creatorFilipović, Nenad
dc.creatorMarinković, Aleksandar D.
dc.creatorMalesević, Aleksandar
dc.creatorMinić, Dragica M.
dc.date.accessioned2020-12-17T22:02:33Z
dc.date.available2020-12-17T22:02:33Z
dc.date.issued2017
dc.identifier.issn1388-6150
dc.identifier.urihttp://aspace.agrif.bg.ac.rs/handle/123456789/4483
dc.description.abstractThe structure of new cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex was determined using a combination of XRD and IR measurements and DFT calculations. Inherent flexibility of its structure is evident from the complexity of its IR spectrum, which could only be theoretically reproduced as a combination of several closely related structures, involving rotation around C-O bond and changes in hydrogen interactions of its -OH group. Its thermal stability and decomposition were studied non-isothermally, and the thermal decomposition mechanism was proposed using correlation with DFT calculations at the molecular level. It was determined that the initial degradation step consists of the release of Cl free radical, which then reacts with both the initial compound and the degradation products. Besides the endothermic steps, there are exothermic ones, contributing to the complex shape of the DSC curve, consisted of overlapping endothermic and exothermic peaks. Deconvolution of DTG curve allowed identification of primary fragments of the initial degradation process and, in conjunction with DFT calculations, construction of the most likely reaction mechanism.en
dc.publisherSpringer, Dordrecht
dc.rightsrestrictedAccess
dc.sourceJournal of Thermal Analysis and Calorimetry
dc.subjectThermal decompositionen
dc.subjectReaction mechanismen
dc.subjectDFT calculationen
dc.subjectReaction kineticsen
dc.subjectOrganometallic complexen
dc.subjectThermodynamicsen
dc.titleSynthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complexen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage711
dc.citation.issue2
dc.citation.other130(2): 701-711
dc.citation.rankM22
dc.citation.spage701
dc.citation.volume130
dc.identifier.doi10.1007/s10973-017-6458-2
dc.identifier.scopus2-s2.0-85020119946
dc.identifier.wos000413264100010
dc.type.versionpublishedVersion


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Приказ основних података о документу