Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study
2017
Аутори
Djordjević, Ivana S.Vukasinović, Jelena
Todorović, Tamara R.
Filipović, Nenad
Rodić, Marko V.
Lolić, Aleksandar
Portalone, Gustavo
Zlatović, Mario
Grubisić, Sonja
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.
Кључне речи:
X-ray crystal structure / cobalt(III) / Schiff base / antioxidant activity / DFT / FukuiИзвор:
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2017, 82, 7-8, 825-839Издавач:
- Srpsko hemijsko društvo, Beograd
Финансирање / пројекти:
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-MESTD-Basic Research (BR or ON)-172035)
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-MESTD-Basic Research (BR or ON)-172055)
DOI: 10.2298/JSC170412062D
ISSN: 0352-5139
WoS: 000410203200005
Scopus: 2-s2.0-85029451534
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Djordjević, Ivana S. AU - Vukasinović, Jelena AU - Todorović, Tamara R. AU - Filipović, Nenad AU - Rodić, Marko V. AU - Lolić, Aleksandar AU - Portalone, Gustavo AU - Zlatović, Mario AU - Grubisić, Sonja PY - 2017 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4462 AB - Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated. PB - Srpsko hemijsko društvo, Beograd T2 - JOURNAL OF THE SERBIAN CHEMICAL SOCIETY T1 - Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study EP - 839 IS - 7-8 SP - 825 VL - 82 DO - 10.2298/JSC170412062D ER -
@article{ author = "Djordjević, Ivana S. and Vukasinović, Jelena and Todorović, Tamara R. and Filipović, Nenad and Rodić, Marko V. and Lolić, Aleksandar and Portalone, Gustavo and Zlatović, Mario and Grubisić, Sonja", year = "2017", abstract = "Cobalt(III) complexes derived from thio-and selenosemicarbazone ligands have been studied to elucidate the nature and consequences of S to Se substitution on their possible biological activity. Solid state structures of cobalt(III) complexes with bis-tridentate coordinated 2-quinolinecarboxaldehyde thio-and selenosemicarbazone were determined by single crystal X-ray diffraction analysis. The complexes were also characterized by spectroscopic methods and cyclic voltammetry. Electronic properties of the complexes were studied using DFT and TD-DFT methods. Finally, evident in vitro antioxidant activity of the complexes was demonstrated.", publisher = "Srpsko hemijsko društvo, Beograd", journal = "JOURNAL OF THE SERBIAN CHEMICAL SOCIETY", title = "Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study", pages = "839-825", number = "7-8", volume = "82", doi = "10.2298/JSC170412062D" }
Djordjević, I. S., Vukasinović, J., Todorović, T. R., Filipović, N., Rodić, M. V., Lolić, A., Portalone, G., Zlatović, M.,& Grubisić, S.. (2017). Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY Srpsko hemijsko društvo, Beograd., 82(7-8), 825-839. https://doi.org/10.2298/JSC170412062D
Djordjević IS, Vukasinović J, Todorović TR, Filipović N, Rodić MV, Lolić A, Portalone G, Zlatović M, Grubisić S. Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY. 2017;82(7-8):825-839. doi:10.2298/JSC170412062D .
Djordjević, Ivana S., Vukasinović, Jelena, Todorović, Tamara R., Filipović, Nenad, Rodić, Marko V., Lolić, Aleksandar, Portalone, Gustavo, Zlatović, Mario, Grubisić, Sonja, "Synthesis, structures and electronic properties of Co(III) complexes with 2-quinolinecarboxaldehyde thio- and selenosemicarbazone: A combined experimental and theoretical study" in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 82, no. 7-8 (2017):825-839, https://doi.org/10.2298/JSC170412062D . .