Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite
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Kaludjerović, LazarTomić, Zorica
Durović-Pejcev, Rada D.
Vulić, Predrag J.
Ašanin, Darko P.
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This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch... equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM.
Keywords:
Montmorillonite / X-ray diffraction (XRD) / batch equilibrium method / hexadecyltrimethyl-ammonium bromideSource:
Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 2017, 52, 5, 291-297Publisher:
- Taylor & Francis Inc, Philadelphia
Funding / projects:
- Minerals of Serbia: composition, genesis, application and contribution to the environmental sustainability (RS-MESTD-Basic Research (BR or ON)-176010)
- Studies on plant pathogens, arthropods, weeds, and pesticides with a view to developing the methods of biorational plant protection and safe food production (RS-MESTD-Technological Development (TD or TR)-31043)
DOI: 10.1080/03601234.2017.1281636
ISSN: 0360-1234
PubMed: 28277083
WoS: 000400353100001
Scopus: 2-s2.0-85012081846
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Poljoprivredni fakultetTY - JOUR AU - Kaludjerović, Lazar AU - Tomić, Zorica AU - Durović-Pejcev, Rada D. AU - Vulić, Predrag J. AU - Ašanin, Darko P. PY - 2017 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4337 AB - This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM. PB - Taylor & Francis Inc, Philadelphia T2 - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was T1 - Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite EP - 297 IS - 5 SP - 291 VL - 52 DO - 10.1080/03601234.2017.1281636 ER -
@article{ author = "Kaludjerović, Lazar and Tomić, Zorica and Durović-Pejcev, Rada D. and Vulić, Predrag J. and Ašanin, Darko P.", year = "2017", abstract = "This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM.", publisher = "Taylor & Francis Inc, Philadelphia", journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was", title = "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite", pages = "297-291", number = "5", volume = "52", doi = "10.1080/03601234.2017.1281636" }
Kaludjerović, L., Tomić, Z., Durović-Pejcev, R. D., Vulić, P. J.,& Ašanin, D. P.. (2017). Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was Taylor & Francis Inc, Philadelphia., 52(5), 291-297. https://doi.org/10.1080/03601234.2017.1281636
Kaludjerović L, Tomić Z, Durović-Pejcev RD, Vulić PJ, Ašanin DP. Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was. 2017;52(5):291-297. doi:10.1080/03601234.2017.1281636 .
Kaludjerović, Lazar, Tomić, Zorica, Durović-Pejcev, Rada D., Vulić, Predrag J., Ašanin, Darko P., "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 52, no. 5 (2017):291-297, https://doi.org/10.1080/03601234.2017.1281636 . .