Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.
Само за регистроване кориснике
2016
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective ba...nd gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst.
Кључне речи:
Zirconia / Triclorophenol-TCP / Photocatalysis / Surface modification / Super oxide radicalsИзвор:
Applied Catalysis B-Environmental, 2016, 195, 112-120Издавач:
- Elsevier Science Bv, Amsterdam
Финансирање / пројекти:
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-172056)
DOI: 10.1016/j.apcatb.2016.05.005
ISSN: 0926-3373
WoS: 000378187100012
Scopus: 2-s2.0-84968830370
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Carević, M.V. AU - Abazović, N.D. AU - Novaković, T.B. AU - Pavlović, Vladimir AU - Comor, Mirjana I. PY - 2016 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4056 AB - We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective band gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst. PB - Elsevier Science Bv, Amsterdam T2 - Applied Catalysis B-Environmental T1 - Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light. EP - 120 SP - 112 VL - 195 DO - 10.1016/j.apcatb.2016.05.005 ER -
@article{ author = "Carević, M.V. and Abazović, N.D. and Novaković, T.B. and Pavlović, Vladimir and Comor, Mirjana I.", year = "2016", abstract = "We present a hydrothermal method for synthesis of zirconia nanopowders: pure and with incorporated Si4+ ions. Zirconyl chloride and tetraethyl orthosilicate were used as precursors. As prepared powders were annealed at 600 degrees C and characterized using structural (XRD), morphological (SEM and TEM) and optical techniques (UV/vis DR, FTIR and photoluminescence spectroscopy). Their textural properties (BET method) and photocatalytic activity toward degradation of model compounds (tricholophenol and Rhodamine B) using simmulated solar light were obtained. We showed that by using hydrothermal synthesis method pure monoclinic ZrO2 highly crystalline powder can be obtained. Incorporation of Si4+ ions induced stabilization of tetragonal crystalline phase at room temperature and decreasing of particle sizes. Incorporation of Si4+ ions in zirconia matrix also resulted in increase of specific area of nanopowders. FTIR measurements were used as proof for existence of Zr-O-Si bond. Effective band gap of zirconia powders was reduced from 5 (pure ZrO2) to 3.8 eV for samples with Si4+ ions. All zirconia powders showed significant photocatalytic activity regarding degradation of triclorophenol and no activity regarding RB (Rhodamine B dye). Photocatalytic activity of zirconia was increased by incorporation of Si ions in the host matrix. The source of this observation is discussed correlating all obtained properties of pure and Si-incorporated nanopowders. Optimization of synthesis parameters and composition of zirconia samples obviously can lead to their photocatalytic activity comparable to Degussa TiO2 powder, famous and commercial photocatalyst.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Applied Catalysis B-Environmental", title = "Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.", pages = "120-112", volume = "195", doi = "10.1016/j.apcatb.2016.05.005" }
Carević, M.V., Abazović, N.D., Novaković, T.B., Pavlović, V.,& Comor, M. I.. (2016). Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.. in Applied Catalysis B-Environmental Elsevier Science Bv, Amsterdam., 195, 112-120. https://doi.org/10.1016/j.apcatb.2016.05.005
Carević M, Abazović N, Novaković T, Pavlović V, Comor MI. Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light.. in Applied Catalysis B-Environmental. 2016;195:112-120. doi:10.1016/j.apcatb.2016.05.005 .
Carević, M.V., Abazović, N.D., Novaković, T.B., Pavlović, Vladimir, Comor, Mirjana I., "Zirconium dioxide nanopowders with incorporated Si4+ ions as efficient photocatalyst for degradation of trichlorophenol using simulated solar light." in Applied Catalysis B-Environmental, 195 (2016):112-120, https://doi.org/10.1016/j.apcatb.2016.05.005 . .