Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]
Samo za registrovane korisnike
2013
Autori
Filipović, NenadBorna, Marija
Klisurić, Olivera
Pregelj, Matej
Jagodić, Marko
Andjelković, Katarina
Todorović, Tamara
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.
Ključne reči:
Copper(II) / Zinc(II) / X-ray analysis / EPR spectroscopy / Thermogravimetric analysisIzvor:
Journal of Coordination Chemistry, 2013, 66, 9, 1549-1560Izdavač:
- Taylor & Francis Ltd, Abingdon
Finansiranje / projekti:
- Max Planck SocietyMax Planck Society
- Interakcije prirodnih proizvoda, njihovih derivata i kompleksnih jedinjenja sa proteinima i nukleinskim kiselinama (RS-MESTD-Basic Research (BR or ON)-172055)
DOI: 10.1080/00958972.2013.786052
ISSN: 0095-8972
WoS: 000318280000008
Scopus: 2-s2.0-84877640099
Institucija/grupa
Poljoprivredni fakultetTY - JOUR AU - Filipović, Nenad AU - Borna, Marija AU - Klisurić, Olivera AU - Pregelj, Matej AU - Jagodić, Marko AU - Andjelković, Katarina AU - Todorović, Tamara PY - 2013 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/3288 AB - Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2] EP - 1560 IS - 9 SP - 1549 VL - 66 DO - 10.1080/00958972.2013.786052 ER -
@article{ author = "Filipović, Nenad and Borna, Marija and Klisurić, Olivera and Pregelj, Matej and Jagodić, Marko and Andjelković, Katarina and Todorović, Tamara", year = "2013", abstract = "Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]", pages = "1560-1549", number = "9", volume = "66", doi = "10.1080/00958972.2013.786052" }
Filipović, N., Borna, M., Klisurić, O., Pregelj, M., Jagodić, M., Andjelković, K.,& Todorović, T.. (2013). Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 66(9), 1549-1560. https://doi.org/10.1080/00958972.2013.786052
Filipović N, Borna M, Klisurić O, Pregelj M, Jagodić M, Andjelković K, Todorović T. Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]. in Journal of Coordination Chemistry. 2013;66(9):1549-1560. doi:10.1080/00958972.2013.786052 .
Filipović, Nenad, Borna, Marija, Klisurić, Olivera, Pregelj, Matej, Jagodić, Marko, Andjelković, Katarina, Todorović, Tamara, "Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]" in Journal of Coordination Chemistry, 66, no. 9 (2013):1549-1560, https://doi.org/10.1080/00958972.2013.786052 . .