Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia
TY - JOUR
AU - Filipović, Nenad
AU - Todorović, Tamara
AU - Radanović, Dušanka
AU - Divjaković, Vladimir
AU - Marković, Rade
AU - Pajić, Ivana A.
AU - Andjelković, Katarina
PY - 2012
UR - http://aspace.agrif.bg.ac.rs/handle/123456789/3003
AB - Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Polyhedron
T1 - Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups
EP - 28
IS - 1
SP - 19
VL - 31
DO - 10.1016/j.poly.2011.07.023
ER -
@article{
author = "Filipović, Nenad and Todorović, Tamara and Radanović, Dušanka and Divjaković, Vladimir and Marković, Rade and Pajić, Ivana A. and Andjelković, Katarina",
year = "2012",
abstract = "Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups",
pages = "28-19",
number = "1",
volume = "31",
doi = "10.1016/j.poly.2011.07.023"
}
Filipović, N., Todorović, T., Radanović, D., Divjaković, V., Marković, R., Pajić, I. A.,& Andjelković, K.. (2012). Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 31(1), 19-28.
https://doi.org/10.1016/j.poly.2011.07.023
Filipović N, Todorović T, Radanović D, Divjaković V, Marković R, Pajić IA, Andjelković K. Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups. in Polyhedron. 2012;31(1):19-28.
doi:10.1016/j.poly.2011.07.023 .
Filipović, Nenad, Todorović, Tamara, Radanović, Dušanka, Divjaković, Vladimir, Marković, Rade, Pajić, Ivana A., Andjelković, Katarina, "Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups" in Polyhedron, 31, no. 1 (2012):19-28,
https://doi.org/10.1016/j.poly.2011.07.023 . .
