Reticulation of aqueous polyurethane systems
Proces umrežavanja vodenih poliuretanskih sistema
Abstract
The DSC method has been employed to monitor the kinetics of reticulation of aqueous polyurethane systems without catalysts, and with the commercial catalyst of zirconium (CAT®XC-6212) and the highly selective manganese catalyst, the complex Mn (III)-diacetylacetonemaleinate (MAM). Among the polyol components, the acrylic emulsions were used for reticulation in this research, and as suitable reticulation agents the water emulsible aliphatic polyisocyanates based on hexamethylendoisocyanate with the different contents of NCO-groups were employed. On the basis of DSC analysis, applying the methods of Kissinger, Freeman-Carroll and Crane-Ellerstein the pseudo kinetic parameters of the reticulation reaction of aqueous systems were determined. The temperature range of the examination was from 500C to 4500C with the heat rate of 0.50C/min. The reduction of the activation energy and the increase of the standard deviation indicate the catalytic action of the selective catalysts of zirconium and... manganese. The impact of the catalysts on the reduction of the activation energy is the strongest when using the catalysts of manganese and applying all the three afore-said methods. The least aberrations among the stated methods in defining the kinetic parameters were obtained by using the manganese catalyst.
DSC metodom praćena je kinetika umrežavanja vodenih poliuretankih sistema, bez katalizatora, sa komercijalnim katalizatorom cirkonijuma (KAT®XC-6212) i visokoselektivnim manganovim katalizatorom, kompleksom Mn(III) - diacetilacetonatomaleinatom (MAM). U ovom radu za umrežavanje od poliolnih komponenti korišćene su akrilne emulzije a kao pogodni umreživači koričćeni su vodoemulgujući alifatični poliizocijanati na bazi heksametilendiizocijanata sa različitim sadržajem NCO-grupa. Na osnovu DSC-analize, metodama Kissinger-a, Freeman-Carrollaa i Crane-Ellerstein-a, određeni su prividni kinetički parametri reakcije umrežavanja vodenih sistema. Temperaturni opseg ispitivanja koričćen je od 50 do 450oC sa brzinom grejanja od 0.5oC/min. Smanjenje energije aktivacije i povećanje standardne devijacije ukazuju na katalitičko dejstvo selektivnih katalizatora cirkonijuma i mangana. Učešće katalizatora u smanjenju energije aktivacije je najveće kod katalizatora mangana, korišćenjem sve tri bbbmetode ...izračunavanja kod ispitivanih uzoraka u odnosu na cirkonijumov katalizator. Najmanja odsupanja između pomenutih metoda u određvanju kinetičkih parametara dobijena su korišćenjem manganovog katalizatora.
Keywords:
aqueous polyurethanes / selective catalyst / differential scanning calorimetry / pseudo activation energy / vodeni poliuretani / selektivna kataliza / diferencijalna skening kalorimetrija / energija aktivacijeSource:
Zaštita materijala, 2011, 52, 1, 43-48Publisher:
- Inženjersko društvo za koroziju, Beograd
Collections
Institution/Community
Poljoprivredni fakultetTY - JOUR AU - Cakić, Suzana AU - Lačnjevac, Časlav AU - Rajković, Miloš AU - Rasković, Ljiljana AU - Stamenković, Jakov PY - 2011 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/2538 AB - The DSC method has been employed to monitor the kinetics of reticulation of aqueous polyurethane systems without catalysts, and with the commercial catalyst of zirconium (CAT®XC-6212) and the highly selective manganese catalyst, the complex Mn (III)-diacetylacetonemaleinate (MAM). Among the polyol components, the acrylic emulsions were used for reticulation in this research, and as suitable reticulation agents the water emulsible aliphatic polyisocyanates based on hexamethylendoisocyanate with the different contents of NCO-groups were employed. On the basis of DSC analysis, applying the methods of Kissinger, Freeman-Carroll and Crane-Ellerstein the pseudo kinetic parameters of the reticulation reaction of aqueous systems were determined. The temperature range of the examination was from 500C to 4500C with the heat rate of 0.50C/min. The reduction of the activation energy and the increase of the standard deviation indicate the catalytic action of the selective catalysts of zirconium and manganese. The impact of the catalysts on the reduction of the activation energy is the strongest when using the catalysts of manganese and applying all the three afore-said methods. The least aberrations among the stated methods in defining the kinetic parameters were obtained by using the manganese catalyst. AB - DSC metodom praćena je kinetika umrežavanja vodenih poliuretankih sistema, bez katalizatora, sa komercijalnim katalizatorom cirkonijuma (KAT®XC-6212) i visokoselektivnim manganovim katalizatorom, kompleksom Mn(III) - diacetilacetonatomaleinatom (MAM). U ovom radu za umrežavanje od poliolnih komponenti korišćene su akrilne emulzije a kao pogodni umreživači koričćeni su vodoemulgujući alifatični poliizocijanati na bazi heksametilendiizocijanata sa različitim sadržajem NCO-grupa. Na osnovu DSC-analize, metodama Kissinger-a, Freeman-Carrollaa i Crane-Ellerstein-a, određeni su prividni kinetički parametri reakcije umrežavanja vodenih sistema. Temperaturni opseg ispitivanja koričćen je od 50 do 450oC sa brzinom grejanja od 0.5oC/min. Smanjenje energije aktivacije i povećanje standardne devijacije ukazuju na katalitičko dejstvo selektivnih katalizatora cirkonijuma i mangana. Učešće katalizatora u smanjenju energije aktivacije je najveće kod katalizatora mangana, korišćenjem sve tri bbbmetode izračunavanja kod ispitivanih uzoraka u odnosu na cirkonijumov katalizator. Najmanja odsupanja između pomenutih metoda u određvanju kinetičkih parametara dobijena su korišćenjem manganovog katalizatora. PB - Inženjersko društvo za koroziju, Beograd T2 - Zaštita materijala T1 - Reticulation of aqueous polyurethane systems T1 - Proces umrežavanja vodenih poliuretanskih sistema EP - 48 IS - 1 SP - 43 VL - 52 UR - https://hdl.handle.net/21.15107/rcub_agrospace_2538 ER -
@article{ author = "Cakić, Suzana and Lačnjevac, Časlav and Rajković, Miloš and Rasković, Ljiljana and Stamenković, Jakov", year = "2011", abstract = "The DSC method has been employed to monitor the kinetics of reticulation of aqueous polyurethane systems without catalysts, and with the commercial catalyst of zirconium (CAT®XC-6212) and the highly selective manganese catalyst, the complex Mn (III)-diacetylacetonemaleinate (MAM). Among the polyol components, the acrylic emulsions were used for reticulation in this research, and as suitable reticulation agents the water emulsible aliphatic polyisocyanates based on hexamethylendoisocyanate with the different contents of NCO-groups were employed. On the basis of DSC analysis, applying the methods of Kissinger, Freeman-Carroll and Crane-Ellerstein the pseudo kinetic parameters of the reticulation reaction of aqueous systems were determined. The temperature range of the examination was from 500C to 4500C with the heat rate of 0.50C/min. The reduction of the activation energy and the increase of the standard deviation indicate the catalytic action of the selective catalysts of zirconium and manganese. The impact of the catalysts on the reduction of the activation energy is the strongest when using the catalysts of manganese and applying all the three afore-said methods. The least aberrations among the stated methods in defining the kinetic parameters were obtained by using the manganese catalyst., DSC metodom praćena je kinetika umrežavanja vodenih poliuretankih sistema, bez katalizatora, sa komercijalnim katalizatorom cirkonijuma (KAT®XC-6212) i visokoselektivnim manganovim katalizatorom, kompleksom Mn(III) - diacetilacetonatomaleinatom (MAM). U ovom radu za umrežavanje od poliolnih komponenti korišćene su akrilne emulzije a kao pogodni umreživači koričćeni su vodoemulgujući alifatični poliizocijanati na bazi heksametilendiizocijanata sa različitim sadržajem NCO-grupa. Na osnovu DSC-analize, metodama Kissinger-a, Freeman-Carrollaa i Crane-Ellerstein-a, određeni su prividni kinetički parametri reakcije umrežavanja vodenih sistema. Temperaturni opseg ispitivanja koričćen je od 50 do 450oC sa brzinom grejanja od 0.5oC/min. Smanjenje energije aktivacije i povećanje standardne devijacije ukazuju na katalitičko dejstvo selektivnih katalizatora cirkonijuma i mangana. Učešće katalizatora u smanjenju energije aktivacije je najveće kod katalizatora mangana, korišćenjem sve tri bbbmetode izračunavanja kod ispitivanih uzoraka u odnosu na cirkonijumov katalizator. Najmanja odsupanja između pomenutih metoda u određvanju kinetičkih parametara dobijena su korišćenjem manganovog katalizatora.", publisher = "Inženjersko društvo za koroziju, Beograd", journal = "Zaštita materijala", title = "Reticulation of aqueous polyurethane systems, Proces umrežavanja vodenih poliuretanskih sistema", pages = "48-43", number = "1", volume = "52", url = "https://hdl.handle.net/21.15107/rcub_agrospace_2538" }
Cakić, S., Lačnjevac, Č., Rajković, M., Rasković, L.,& Stamenković, J.. (2011). Reticulation of aqueous polyurethane systems. in Zaštita materijala Inženjersko društvo za koroziju, Beograd., 52(1), 43-48. https://hdl.handle.net/21.15107/rcub_agrospace_2538
Cakić S, Lačnjevac Č, Rajković M, Rasković L, Stamenković J. Reticulation of aqueous polyurethane systems. in Zaštita materijala. 2011;52(1):43-48. https://hdl.handle.net/21.15107/rcub_agrospace_2538 .
Cakić, Suzana, Lačnjevac, Časlav, Rajković, Miloš, Rasković, Ljiljana, Stamenković, Jakov, "Reticulation of aqueous polyurethane systems" in Zaštita materijala, 52, no. 1 (2011):43-48, https://hdl.handle.net/21.15107/rcub_agrospace_2538 .