The preferred orientation of bright copper deposits

Abstract

The preferred orientations of copper deposits obtained from acid sulfate solutions were examined. Mat deposits obtained in the absence of the additives and in the presence of disodium 2-naphthol-3,6-disulfonic acid possessed a weak (200) and (220) preferred orientation, respectively. Bright deposit obtained with thiourea only had (111)orientation, while the deposit obtained with mixture thiourea/disodium 2-naphthol-3,6-disulfonic acid exhibited predominant (111) orientation. Bright copper deposits had the preferred orientation in the closest-packed plane of f.c.c. copper lattice, i.e. in the (111)plane.