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Identification and spectra-structure determination of soil minerals: Raman study supported by IR spectroscopy and X-ray powder diffraction

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2010
Authors
Tomić, Zorica
Makreski, Petre
Gajić, Boško
article (publishedVersion)
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Abstract
Raman and IR spectroscopy were used for the characterization of several minerals in morphologically similar vertisol sequences from Kizevak (Serbia). It helped us to establish the surface layer transition going from calcic vertisols (containing gypsum and calcite) to calcimagnesic vertisols (containing aragonite, magnesium-calcite and dolomite) derived from peridotite and serpentinite. The observed band positions are found to be solely characteristic for each carbonate mineral and are used to discuss the main structural features of carbonates and sulfates present in the studied soil. It was found that the dolomite, calcite and aragonite concretions are present in the deepest layer of the soil, whereas the gypsum is found in the topsoil. The identification was confirmed of the carbonates having calcite and aragonite structure, and the representative from the sulfate group (gypsum) was confirmed by X-ray powder diffraction.
Keywords:
soil / minerals / Raman spectroscopy / IR spectroscopy / X-ray powder diffraction (XRPD)
Source:
Journal of Raman Spectroscopy, 2010, 41, 5, 582-586
Publisher:
  • Wiley, Hoboken

DOI: 10.1002/jrs.2476

ISSN: 0377-0486

WoS: 000278338200016

Scopus: 2-s2.0-77952937748
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URI
http://aspace.agrif.bg.ac.rs/handle/123456789/2329
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Poljoprivredni fakultet

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