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Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide

Authorized Users Only
2008
Authors
Filipović, Nenad
Bacchi, Alessia
Lazić, Milan
Pelizzi, Giancarlo
Radulović, Siniša
Sladić, Dušan M.
Todorović, Tamara R.
Andjelković, Katarina
Article (Published version)
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Abstract
A new dinuclear complex of Cd(II) with N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (H2L) was synthesized and its crystal structure determined. The basic structural unit of the complex is the binuclear [Cd-2(H2O)(2)(H2L)(2)](4+) cation, where each cadmium atom is heptacoordinated by two tridentate H2L ligands, by means of the NNO chelating system, and one water molecule. A 12-membered macrocycle is defined at the core of the binuclear cation. The complex showed a pronounced cytotoxic activity to murine melanoma B16 cells and human cervical cancer HeLa cells.
Keywords:
Cd(II) complex / hydrazone ligand / X-ray analysis / cytotoxic activity
Source:
Inorganic Chemistry Communications, 2008, 11, 1, 47-50
Publisher:
  • Elsevier, Amsterdam
Funding / projects:
  • Sinteza, analiza i aktivnost novih organskih polidentatnih liganada i njihovih kompleksa sa d-metalima (RS-142062)

DOI: 10.1016/j.inoche.2007.10.013

ISSN: 1387-7003

WoS: 000253105200013

Scopus: 2-s2.0-38049035877
[ Google Scholar ]
29
27
URI
http://aspace.agrif.bg.ac.rs/handle/123456789/1832
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Poljoprivredni fakultet
TY  - JOUR
AU  - Filipović, Nenad
AU  - Bacchi, Alessia
AU  - Lazić, Milan
AU  - Pelizzi, Giancarlo
AU  - Radulović, Siniša
AU  - Sladić, Dušan M.
AU  - Todorović, Tamara R.
AU  - Andjelković, Katarina
PY  - 2008
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/1832
AB  - A new dinuclear complex of Cd(II) with N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (H2L) was synthesized and its crystal structure determined. The basic structural unit of the complex is the binuclear [Cd-2(H2O)(2)(H2L)(2)](4+) cation, where each cadmium atom is heptacoordinated by two tridentate H2L ligands, by means of the NNO chelating system, and one water molecule. A 12-membered macrocycle is defined at the core of the binuclear cation. The complex showed a pronounced cytotoxic activity to murine melanoma B16 cells and human cervical cancer HeLa cells.
PB  - Elsevier, Amsterdam
T2  - Inorganic Chemistry Communications
T1  - Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide
EP  - 50
IS  - 1
SP  - 47
VL  - 11
DO  - 10.1016/j.inoche.2007.10.013
ER  - 
@article{
author = "Filipović, Nenad and Bacchi, Alessia and Lazić, Milan and Pelizzi, Giancarlo and Radulović, Siniša and Sladić, Dušan M. and Todorović, Tamara R. and Andjelković, Katarina",
year = "2008",
abstract = "A new dinuclear complex of Cd(II) with N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (H2L) was synthesized and its crystal structure determined. The basic structural unit of the complex is the binuclear [Cd-2(H2O)(2)(H2L)(2)](4+) cation, where each cadmium atom is heptacoordinated by two tridentate H2L ligands, by means of the NNO chelating system, and one water molecule. A 12-membered macrocycle is defined at the core of the binuclear cation. The complex showed a pronounced cytotoxic activity to murine melanoma B16 cells and human cervical cancer HeLa cells.",
publisher = "Elsevier, Amsterdam",
journal = "Inorganic Chemistry Communications",
title = "Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide",
pages = "50-47",
number = "1",
volume = "11",
doi = "10.1016/j.inoche.2007.10.013"
}
Filipović, N., Bacchi, A., Lazić, M., Pelizzi, G., Radulović, S., Sladić, D. M., Todorović, T. R.,& Andjelković, K.. (2008). Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. in Inorganic Chemistry Communications
Elsevier, Amsterdam., 11(1), 47-50.
https://doi.org/10.1016/j.inoche.2007.10.013
Filipović N, Bacchi A, Lazić M, Pelizzi G, Radulović S, Sladić DM, Todorović TR, Andjelković K. Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. in Inorganic Chemistry Communications. 2008;11(1):47-50.
doi:10.1016/j.inoche.2007.10.013 .
Filipović, Nenad, Bacchi, Alessia, Lazić, Milan, Pelizzi, Giancarlo, Radulović, Siniša, Sladić, Dušan M., Todorović, Tamara R., Andjelković, Katarina, "Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide" in Inorganic Chemistry Communications, 11, no. 1 (2008):47-50,
https://doi.org/10.1016/j.inoche.2007.10.013 . .

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