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The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials
Ugradnja Me-histidin kompleksa u strukturu FAU zeolita - karakterizacija odbijenih materijala
dc.creator | Stošić, Dušan | |
dc.creator | Damjanović, Ljiljana | |
dc.creator | Hercigonja, Radmila | |
dc.creator | Dondur, Vera | |
dc.creator | Rac, Vladislav | |
dc.creator | Rakić, Vesna | |
dc.date.accessioned | 2020-12-17T19:10:00Z | |
dc.date.available | 2020-12-17T19:10:00Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 0367-598X | |
dc.identifier.uri | http://aspace.agrif.bg.ac.rs/handle/123456789/1647 | |
dc.description.abstract | L-histidine, a naturally occurring amino acid, was incorporated inside the supercages of FAU type zeolite in a form of Me-complex entity (Me = Cu(II), Zn(II), Fe(III)). The preparation was done either by ion-exchange procedure, or previously prepared Me-histidine complex was incorporated into the a cages of Y zeolite by occlusion. The preparation procedure was found to be a very important factor, as well as the amount of metal complex loaded on the zeolite. The characterization of obtained samples was performed using Diffuse Reflectance Ultraviolet-Visible Spectroscopy (DRUV-Vis), 13C MAS NMR and Infrared Spectroscopy (FTIR). It was noticed that 1-hostidine interacted with the zeolitic framework, and with the extra-framework cation, as well. The results obtained by TG-DSC/MAS technique, revealed that the thermal stability of incorporated histidine was increased, in comparison with that one of pure histidine. | en |
dc.description.abstract | U ovom radu, Me-histidin (Me = Zn(II), Cu(II), Fe(III)) kompleksi ugrađivani su u strukturu Yzeolita, primenom dva različita postupka: (1) Me-histidin kompleksi su pravljeni u dejonizovanoj vodi i zatim mešani sa NaY zeolitom, (2) histidinje rastvoren u vodi i u rastvor su dodavani jonski izmenjeni Y zeoliti. UV-spektroskopijom tečne faze je utvrđeno da je proces imobilizacije izvršen za 24 h. Ovako dobijem čvrsti materijali su detaljno okarakterisani hemijski i metodama XRD, NMR, IR, DR UV-VIS, dok su njihove termalne stabilnosti ispitivane primenom TG-DSC/MAS tehnike. Dobijem rezultati omogućili su poređenje osobina sintetisanih uzoraka. | sr |
dc.publisher | Savez hemijskih inženjera, Beograd | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Hemijska industrija | |
dc.subject | metaloenzymes | en |
dc.subject | histidine | en |
dc.subject | transition metals | en |
dc.subject | Y-zeolite | en |
dc.subject | catalysis | en |
dc.subject | metaloenzimi | sr |
dc.subject | histidin | sr |
dc.subject | prelazni metali | sr |
dc.subject | Y-zeolit | sr |
dc.subject | kataliza | sr |
dc.title | The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials | en |
dc.title | Ugradnja Me-histidin kompleksa u strukturu FAU zeolita - karakterizacija odbijenih materijala | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.epage | 130 | |
dc.citation.issue | 3 | |
dc.citation.other | 62(3): 125-130 | |
dc.citation.spage | 125 | |
dc.citation.volume | 62 | |
dc.identifier.doi | 10.2298/HEMIND0803125S | |
dc.identifier.fulltext | http://aspace.agrif.bg.ac.rs/bitstream/id/554/1644.pdf | |
dc.identifier.scopus | 2-s2.0-77952936206 | |
dc.identifier.wos | 000257697700006 | |
dc.type.version | publishedVersion |