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The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials

Ugradnja Me-histidin kompleksa u strukturu FAU zeolita - karakterizacija odbijenih materijala

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Authors
Stošić, Dušan
Damjanović, Ljiljana
Hercigonja, Radmila
Dondur, Vera
Rac, Vladislav
Rakić, Vesna
Article (Published version)
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Abstract
L-histidine, a naturally occurring amino acid, was incorporated inside the supercages of FAU type zeolite in a form of Me-complex entity (Me = Cu(II), Zn(II), Fe(III)). The preparation was done either by ion-exchange procedure, or previously prepared Me-histidine complex was incorporated into the a cages of Y zeolite by occlusion. The preparation procedure was found to be a very important factor, as well as the amount of metal complex loaded on the zeolite. The characterization of obtained samples was performed using Diffuse Reflectance Ultraviolet-Visible Spectroscopy (DRUV-Vis), 13C MAS NMR and Infrared Spectroscopy (FTIR). It was noticed that 1-hostidine interacted with the zeolitic framework, and with the extra-framework cation, as well. The results obtained by TG-DSC/MAS technique, revealed that the thermal stability of incorporated histidine was increased, in comparison with that one of pure histidine.
U ovom radu, Me-histidin (Me = Zn(II), Cu(II), Fe(III)) kompleksi ugrađivani su u strukturu Yzeolita, primenom dva različita postupka: (1) Me-histidin kompleksi su pravljeni u dejonizovanoj vodi i zatim mešani sa NaY zeolitom, (2) histidinje rastvoren u vodi i u rastvor su dodavani jonski izmenjeni Y zeoliti. UV-spektroskopijom tečne faze je utvrđeno da je proces imobilizacije izvršen za 24 h. Ovako dobijem čvrsti materijali su detaljno okarakterisani hemijski i metodama XRD, NMR, IR, DR UV-VIS, dok su njihove termalne stabilnosti ispitivane primenom TG-DSC/MAS tehnike. Dobijem rezultati omogućili su poređenje osobina sintetisanih uzoraka.
Keywords:
metaloenzymes / histidine / transition metals / Y-zeolite / catalysis / metaloenzimi / histidin / prelazni metali / Y-zeolit / kataliza
Source:
Hemijska industrija, 2008, 62, 3, 125-130
Publisher:
  • Savez hemijskih inženjera, Beograd

DOI: 10.2298/HEMIND0803125S

ISSN: 0367-598X

WoS: 000257697700006

Scopus: 2-s2.0-77952936206
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URI
http://aspace.agrif.bg.ac.rs/handle/123456789/1647
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Poljoprivredni fakultet

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