Isothermal kinetics of copper (ion) binding to poly(acrylic acid) (PAA) hydrogel at 20, 25, 35 and 45 C was investigated. Isothermal conversions and kinetic curves of Cu2+ binding to the PAA hydrogel were determined. It was found that the well-known kinetic models of Peppas cannot be applied to describing the entire process of Cu2+ binding. The new method for the determination of the kinetic model of the Cu2+ binding process, as well as the activation energy density distribution functions of PAA hydrogel interaction with Cu2+, were established. It was found that Cu2+ diffusion to the active centers (with E-a = 9 kJ/mol) has a dominant influence on the kinetics of the process at temperatures T >= 30 degrees C, but at T >= 30 degrees C and for the degree of bound Cu2+ alpha >= 0.2, the interaction of Cu2+ from the adsorption center with E-a = 26 kJ/mol is dominant.
Source:
Russian Journal of Physical Chemistry A, 2007, 81, 9, 1374-1379
TY - CONF
AU - Kostić, Aleksandar
AU - Jovanović, J.
AU - Adnadjević, Borivoj
AU - Popović, A.
PY - 2007
UR - http://aspace.agrif.bg.ac.rs/handle/123456789/1573
AB - Isothermal kinetics of copper (ion) binding to poly(acrylic acid) (PAA) hydrogel at 20, 25, 35 and 45 C was investigated. Isothermal conversions and kinetic curves of Cu2+ binding to the PAA hydrogel were determined. It was found that the well-known kinetic models of Peppas cannot be applied to describing the entire process of Cu2+ binding. The new method for the determination of the kinetic model of the Cu2+ binding process, as well as the activation energy density distribution functions of PAA hydrogel interaction with Cu2+, were established. It was found that Cu2+ diffusion to the active centers (with E-a = 9 kJ/mol) has a dominant influence on the kinetics of the process at temperatures T >= 30 degrees C, but at T >= 30 degrees C and for the degree of bound Cu2+ alpha >= 0.2, the interaction of Cu2+ from the adsorption center with E-a = 26 kJ/mol is dominant.
PB - Maik Nauka/Interperiodica/Springer, New York
C3 - Russian Journal of Physical Chemistry A
T1 - Kinetics of Cu2+ binding to the poly(acrylic acid) hydrogel
EP - 1379
IS - 9
SP - 1374
VL - 81
DO - 10.1134/S0036024407090051
ER -
@conference{
author = "Kostić, Aleksandar and Jovanović, J. and Adnadjević, Borivoj and Popović, A.",
year = "2007",
abstract = "Isothermal kinetics of copper (ion) binding to poly(acrylic acid) (PAA) hydrogel at 20, 25, 35 and 45 C was investigated. Isothermal conversions and kinetic curves of Cu2+ binding to the PAA hydrogel were determined. It was found that the well-known kinetic models of Peppas cannot be applied to describing the entire process of Cu2+ binding. The new method for the determination of the kinetic model of the Cu2+ binding process, as well as the activation energy density distribution functions of PAA hydrogel interaction with Cu2+, were established. It was found that Cu2+ diffusion to the active centers (with E-a = 9 kJ/mol) has a dominant influence on the kinetics of the process at temperatures T >= 30 degrees C, but at T >= 30 degrees C and for the degree of bound Cu2+ alpha >= 0.2, the interaction of Cu2+ from the adsorption center with E-a = 26 kJ/mol is dominant.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Kinetics of Cu2+ binding to the poly(acrylic acid) hydrogel",
pages = "1379-1374",
number = "9",
volume = "81",
doi = "10.1134/S0036024407090051"
}
Kostić, A., Jovanović, J., Adnadjević, B.,& Popović, A.. (2007). Kinetics of Cu2+ binding to the poly(acrylic acid) hydrogel. in Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 81(9), 1374-1379.
https://doi.org/10.1134/S0036024407090051
Kostić A, Jovanović J, Adnadjević B, Popović A. Kinetics of Cu2+ binding to the poly(acrylic acid) hydrogel. in Russian Journal of Physical Chemistry A. 2007;81(9):1374-1379.
doi:10.1134/S0036024407090051 .
Kostić, Aleksandar, Jovanović, J., Adnadjević, Borivoj, Popović, A., "Kinetics of Cu2+ binding to the poly(acrylic acid) hydrogel" in Russian Journal of Physical Chemistry A, 81, no. 9 (2007):1374-1379,
https://doi.org/10.1134/S0036024407090051 . .
