Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands
Nema prikaza
Autori
Filipović, NenadTodorović, Tamara
Sladić, Dušan M.
Novaković, Irena
Jeremić, D.A.
Andjelković, K.K.
Konferencijski prilog (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
New complexes of Pt(II) with condensation derivatives of ethyl hydrazino acetate and either 2-acetylpyridine or 2-quinolinecarboxaldehyde, and of Pd(II) with the condensation derivative of ethyl hydrazinoacetate and 2-quinolinecarboxaldehyde were synthesized and characterized by elemental analysis, IR, H-1- and C-13-NMR spectroscopy, and molar conductivity measurements. The complexes have a square planar geometry, ligands binding as bidentates in the neutral form, and the remaining two coordination sites being occupied by chloride ions. Biological activity of new complexes, and of previously synthesized Pd(II), Cd(II), Co(III) and Zn(II) complexes with this ligand type was evaluated by the brine shrimp test. All the complexes showed a moderate activity.
Ključne reči:
2-acetylpyridine derivatives / 2-quinolinecarboxaldehyde derivatives / d-metal complexes / biological activityIzvor:
Materials Science Forum, 2007, 555, 423-427Izdavač:
- 8th Conference of the Yugoslav Materials Research Society
Finansiranje / projekti:
- Interakcije prirodnih proizvoda i njihovih analoga sa proteinima i nukleinskim kiselinama (RS-142026)
DOI: 10.4028/0-87849-441-3.423
ISSN: 0255-5476
WoS: 000249653700068
Scopus: 2-s2.0-38349028797
Institucija/grupa
Poljoprivredni fakultetTY - CONF AU - Filipović, Nenad AU - Todorović, Tamara AU - Sladić, Dušan M. AU - Novaković, Irena AU - Jeremić, D.A. AU - Andjelković, K.K. PY - 2007 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/1361 AB - New complexes of Pt(II) with condensation derivatives of ethyl hydrazino acetate and either 2-acetylpyridine or 2-quinolinecarboxaldehyde, and of Pd(II) with the condensation derivative of ethyl hydrazinoacetate and 2-quinolinecarboxaldehyde were synthesized and characterized by elemental analysis, IR, H-1- and C-13-NMR spectroscopy, and molar conductivity measurements. The complexes have a square planar geometry, ligands binding as bidentates in the neutral form, and the remaining two coordination sites being occupied by chloride ions. Biological activity of new complexes, and of previously synthesized Pd(II), Cd(II), Co(III) and Zn(II) complexes with this ligand type was evaluated by the brine shrimp test. All the complexes showed a moderate activity. PB - 8th Conference of the Yugoslav Materials Research Society C3 - Materials Science Forum T1 - Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands EP - 427 SP - 423 VL - 555 DO - 10.4028/0-87849-441-3.423 ER -
@conference{ author = "Filipović, Nenad and Todorović, Tamara and Sladić, Dušan M. and Novaković, Irena and Jeremić, D.A. and Andjelković, K.K.", year = "2007", abstract = "New complexes of Pt(II) with condensation derivatives of ethyl hydrazino acetate and either 2-acetylpyridine or 2-quinolinecarboxaldehyde, and of Pd(II) with the condensation derivative of ethyl hydrazinoacetate and 2-quinolinecarboxaldehyde were synthesized and characterized by elemental analysis, IR, H-1- and C-13-NMR spectroscopy, and molar conductivity measurements. The complexes have a square planar geometry, ligands binding as bidentates in the neutral form, and the remaining two coordination sites being occupied by chloride ions. Biological activity of new complexes, and of previously synthesized Pd(II), Cd(II), Co(III) and Zn(II) complexes with this ligand type was evaluated by the brine shrimp test. All the complexes showed a moderate activity.", publisher = "8th Conference of the Yugoslav Materials Research Society", journal = "Materials Science Forum", title = "Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands", pages = "427-423", volume = "555", doi = "10.4028/0-87849-441-3.423" }
Filipović, N., Todorović, T., Sladić, D. M., Novaković, I., Jeremić, D.A.,& Andjelković, K.K.. (2007). Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands. in Materials Science Forum 8th Conference of the Yugoslav Materials Research Society., 555, 423-427. https://doi.org/10.4028/0-87849-441-3.423
Filipović N, Todorović T, Sladić DM, Novaković I, Jeremić D, Andjelković K. Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands. in Materials Science Forum. 2007;555:423-427. doi:10.4028/0-87849-441-3.423 .
Filipović, Nenad, Todorović, Tamara, Sladić, Dušan M., Novaković, Irena, Jeremić, D.A., Andjelković, K.K., "Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands" in Materials Science Forum, 555 (2007):423-427, https://doi.org/10.4028/0-87849-441-3.423 . .