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Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate
dc.creator | Andjelković, K | |
dc.creator | Sladić, Dušan M. | |
dc.creator | Bacchi, Alessia | |
dc.creator | Pelizzi, Giancarlo | |
dc.creator | Filipović, Nenad | |
dc.creator | Rajković, M | |
dc.date.accessioned | 2020-12-17T18:33:11Z | |
dc.date.available | 2020-12-17T18:33:11Z | |
dc.date.issued | 2005 | |
dc.identifier.issn | 0340-4285 | |
dc.identifier.uri | http://aspace.agrif.bg.ac.rs/handle/123456789/1024 | |
dc.description.abstract | Complexes of zinc and iron with N', N'(2)- bis[(1E)-1-(2-pyridyl) ethylidene] ethanedihydrazide (H(2)L1) and N', N'(2)-bis[( 1E)-1-(2-pyridyl) ethylidene] propanedihydrazide (H(2)L2) were prepared. Zn-II complexes with both ligands have an octahedral geometry. In the complex of Zn-II with H(2)L1, the ligand is coordinated as a tridentate species in the monoanionic form, building two five-membered rings around Zn-II. Three remaining coordination sites are occupied by water molecules, and in the outer sphere there is a ClO4- ion. In the other Zn-II complex, the H(2)L2 ligand is coordinated in the enol form as a tetradenate species, forming a five-memebered, a six-membered and a seven-membered ring, the remaining coordination sites being occupied by water molecules, while in the outer sphere there are two ClO4- ions. The Fe-III complex with H(2)L2 is a high-spin octahedral complex. The ligand is coordinated in the enol form, in a tetradentate fashion via pyridine and hydrazone nitrogens. The remaining two coordination sites in the complex are occupied by water molecules and a Cl) ion, and in the outer sphere there are two Cl) anions. The octahedral Fe-III complex obtained from the reaction of FeCl(3)center dot 6H(2)O and H(2)L1 in absolute ethanol has the formula [Fe(HL1) Cl-2(H(2)0)] center dot 1.5H(2)O. However, during coordination of the H(2)L1 ligand to Fe-III in water, oxidative degradation of the side chain ( - CO - CO -) and reduction of Fe-III to Fe-II occurs, affording octahedral tris(1-(2-pyridyl) ethylidenehydrazine] iron(II) perchlorate, as confirmed by X-ray structure analysis. | en |
dc.publisher | Springer, Dordrecht | |
dc.rights | restrictedAccess | |
dc.source | Transition Metal Chemistry | |
dc.title | Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 250 | |
dc.citation.issue | 2 | |
dc.citation.other | 30(2): 243-250 | |
dc.citation.rank | M23 | |
dc.citation.spage | 243 | |
dc.citation.volume | 30 | |
dc.identifier.doi | 10.1007/s11243-004-3173-1 | |
dc.identifier.scopus | 2-s2.0-17544384308 | |
dc.identifier.wos | 000228175800019 | |
dc.type.version | publishedVersion |