Minerals of Serbia: composition, genesis, application and contribution to the environmental sustainability

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Minerals of Serbia: composition, genesis, application and contribution to the environmental sustainability (en)
Минерали Србије: састав, структура, генеза, примена и допринос одржању животне средине (sr)
Minerali Srbije: sastav, struktura, geneza, primena i doprinos održanju životne sredine (sr_RS)
Authors

Publications

Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering

Isek, Josip; Kaludjerović, Lazar; Vuković, Nikola S.; Milošević, Maja; Vukašinović, Ivana; Tomić, Zorica

(Mineralogical Soc, Twickenham, 2020)

TY  - JOUR
AU  - Isek, Josip
AU  - Kaludjerović, Lazar
AU  - Vuković, Nikola S.
AU  - Milošević, Maja
AU  - Vukašinović, Ivana
AU  - Tomić, Zorica
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5273
AB  - Two samples collected from the phosphogypsum deposits of the chemical products industry Elixir Prahovo (Serbia) were subjected to a recrystallization experiment performed over several repeated cycles. In these tests, phosphogypsum was separated into recrystallized (purified) gypsum, insoluble residue and supernatant. Both raw phosphogypsum and recrystallized gypsum were examined using inductively coupled plasma optical emission spectrometry, X-ray diffraction and scanning electron microscopy with energy-dispersive spectrometry. The activity concentrations of (238)u, (235)u, Ra-226, Pb-210,Th- 232 and 40 K were investigated using gamma-ray spectrometry. Based on the activity concentration results, a number of radiometric parameters were calculated for the original and recrystallized phosphogypsum (i.e. radium equivalent activity, y indices for construction materials, a index and external and internal hazard indices). Raw phosphogypsum samples showed greater mean activity concentration levels of U-238 and Ra-226 than the international recommended limits, while the recrystallized gypsum demonstrated notably lower activity concentrations for these two isotopes. The activity concentration of Ra-226 in recrystallized gypsum is similar to 6 times lower than in raw phosphogypsum. Therefore, recrystallized gypsum does not present a radiation hazard when used as a building material, while raw phosphogypsum meets the requirements only for road construction materials.
PB  - Mineralogical Soc, Twickenham
T2  - Clay Minerals
T1  - Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering
EP  - 70
IS  - 1
SP  - 63
VL  - 55
DO  - 10.1180/clm.2020.11
ER  - 
@article{
author = "Isek, Josip and Kaludjerović, Lazar and Vuković, Nikola S. and Milošević, Maja and Vukašinović, Ivana and Tomić, Zorica",
year = "2020",
abstract = "Two samples collected from the phosphogypsum deposits of the chemical products industry Elixir Prahovo (Serbia) were subjected to a recrystallization experiment performed over several repeated cycles. In these tests, phosphogypsum was separated into recrystallized (purified) gypsum, insoluble residue and supernatant. Both raw phosphogypsum and recrystallized gypsum were examined using inductively coupled plasma optical emission spectrometry, X-ray diffraction and scanning electron microscopy with energy-dispersive spectrometry. The activity concentrations of (238)u, (235)u, Ra-226, Pb-210,Th- 232 and 40 K were investigated using gamma-ray spectrometry. Based on the activity concentration results, a number of radiometric parameters were calculated for the original and recrystallized phosphogypsum (i.e. radium equivalent activity, y indices for construction materials, a index and external and internal hazard indices). Raw phosphogypsum samples showed greater mean activity concentration levels of U-238 and Ra-226 than the international recommended limits, while the recrystallized gypsum demonstrated notably lower activity concentrations for these two isotopes. The activity concentration of Ra-226 in recrystallized gypsum is similar to 6 times lower than in raw phosphogypsum. Therefore, recrystallized gypsum does not present a radiation hazard when used as a building material, while raw phosphogypsum meets the requirements only for road construction materials.",
publisher = "Mineralogical Soc, Twickenham",
journal = "Clay Minerals",
title = "Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering",
pages = "70-63",
number = "1",
volume = "55",
doi = "10.1180/clm.2020.11"
}
Isek, J., Kaludjerović, L., Vuković, N. S., Milošević, M., Vukašinović, I.,& Tomić, Z.. (2020). Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering. in Clay Minerals
Mineralogical Soc, Twickenham., 55(1), 63-70.
https://doi.org/10.1180/clm.2020.11
Isek J, Kaludjerović L, Vuković NS, Milošević M, Vukašinović I, Tomić Z. Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering. in Clay Minerals. 2020;55(1):63-70.
doi:10.1180/clm.2020.11 .
Isek, Josip, Kaludjerović, Lazar, Vuković, Nikola S., Milošević, Maja, Vukašinović, Ivana, Tomić, Zorica, "Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering" in Clay Minerals, 55, no. 1 (2020):63-70,
https://doi.org/10.1180/clm.2020.11 . .
1
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Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics

Milošević, Maja; Dabić, Predrag; Kovac, Sabina; Kaludjerović, Lazar; Logar, Mihovil

(Mineralogical Soc, Twickenham, 2019)

TY  - JOUR
AU  - Milošević, Maja
AU  - Dabić, Predrag
AU  - Kovac, Sabina
AU  - Kaludjerović, Lazar
AU  - Logar, Mihovil
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4911
AB  - This study focuses on the mineralogical characterization of four raw clay samples from Dobrodo deposit, Serbia. Several analytical methods were applied to determine the chemical and mineralogical composition, morphology and physical properties (colour, plasticity, specific surface area, particle size and cation-exchange capacity) of the clay samples. Kaolinite, smectite and illite are the predominant phases in all of the samples studied that contain between 60.2 and 87.1 wt.% of clay. Quartz, feldspars, paragonite and Ti- and Fe-bearing phases were also identified. The relatively high SiO2/Al2O3 mass ratio indicates abundant quartz. The cation-exchange capacity of the samples varied between low and moderately charged clay minerals (12-52 mmol 100 g(-1)) with specific surface area values ranging from 94 to 410 m(2) g(-1). The plasticity index values (11-23%) suggest low to moderate plasticity. Preliminary results show that most of the raw clay from Dobrodo deposit might be suitable for use in ceramic applications.
PB  - Mineralogical Soc, Twickenham
T2  - Clay Minerals
T1  - Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics
EP  - 377
IS  - 4
SP  - 369
VL  - 54
DO  - 10.1180/clm.2019.49
ER  - 
@article{
author = "Milošević, Maja and Dabić, Predrag and Kovac, Sabina and Kaludjerović, Lazar and Logar, Mihovil",
year = "2019",
abstract = "This study focuses on the mineralogical characterization of four raw clay samples from Dobrodo deposit, Serbia. Several analytical methods were applied to determine the chemical and mineralogical composition, morphology and physical properties (colour, plasticity, specific surface area, particle size and cation-exchange capacity) of the clay samples. Kaolinite, smectite and illite are the predominant phases in all of the samples studied that contain between 60.2 and 87.1 wt.% of clay. Quartz, feldspars, paragonite and Ti- and Fe-bearing phases were also identified. The relatively high SiO2/Al2O3 mass ratio indicates abundant quartz. The cation-exchange capacity of the samples varied between low and moderately charged clay minerals (12-52 mmol 100 g(-1)) with specific surface area values ranging from 94 to 410 m(2) g(-1). The plasticity index values (11-23%) suggest low to moderate plasticity. Preliminary results show that most of the raw clay from Dobrodo deposit might be suitable for use in ceramic applications.",
publisher = "Mineralogical Soc, Twickenham",
journal = "Clay Minerals",
title = "Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics",
pages = "377-369",
number = "4",
volume = "54",
doi = "10.1180/clm.2019.49"
}
Milošević, M., Dabić, P., Kovac, S., Kaludjerović, L.,& Logar, M.. (2019). Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics. in Clay Minerals
Mineralogical Soc, Twickenham., 54(4), 369-377.
https://doi.org/10.1180/clm.2019.49
Milošević M, Dabić P, Kovac S, Kaludjerović L, Logar M. Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics. in Clay Minerals. 2019;54(4):369-377.
doi:10.1180/clm.2019.49 .
Milošević, Maja, Dabić, Predrag, Kovac, Sabina, Kaludjerović, Lazar, Logar, Mihovil, "Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics" in Clay Minerals, 54, no. 4 (2019):369-377,
https://doi.org/10.1180/clm.2019.49 . .
5
1
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Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite

Kaludjerović, Lazar; Tomić, Zorica; Ašanin, Darko P.; Durović-Pejcev, Rada D.; Kresović, Branka

(Taylor & Francis Inc, Philadelphia, 2018)

TY  - JOUR
AU  - Kaludjerović, Lazar
AU  - Tomić, Zorica
AU  - Ašanin, Darko P.
AU  - Durović-Pejcev, Rada D.
AU  - Kresović, Branka
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4667
AB  - The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
T1  - Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite
EP  - 509
IS  - 8
SP  - 503
VL  - 53
DO  - 10.1080/03601234.2018.1462930
ER  - 
@article{
author = "Kaludjerović, Lazar and Tomić, Zorica and Ašanin, Darko P. and Durović-Pejcev, Rada D. and Kresović, Branka",
year = "2018",
abstract = "The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was",
title = "Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite",
pages = "509-503",
number = "8",
volume = "53",
doi = "10.1080/03601234.2018.1462930"
}
Kaludjerović, L., Tomić, Z., Ašanin, D. P., Durović-Pejcev, R. D.,& Kresović, B.. (2018). Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
Taylor & Francis Inc, Philadelphia., 53(8), 503-509.
https://doi.org/10.1080/03601234.2018.1462930
Kaludjerović L, Tomić Z, Ašanin DP, Durović-Pejcev RD, Kresović B. Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was. 2018;53(8):503-509.
doi:10.1080/03601234.2018.1462930 .
Kaludjerović, Lazar, Tomić, Zorica, Ašanin, Darko P., Durović-Pejcev, Rada D., Kresović, Branka, "Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 53, no. 8 (2018):503-509,
https://doi.org/10.1080/03601234.2018.1462930 . .
2
1
2

Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina

Kaludjerović, Lazar

(Univerzitet u Beogradu, Rudarsko-geološki fakultet, 2018)

TY  - THES
AU  - Kaludjerović, Lazar
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/56
AB  - Efficiency of inorganic and organic modified montmorillonites from Bogovina for sorption of the S-metolachlor and clomazone was determined using batch adsorption method. Montmorillonite samples were pretreated with NaCl solution and then with different concentrations of organic complexes. Adsorption isotherms were measured by treatment of the samples with different concentrations of herbicide. Detailed mineralogical characterization of samples was performed using the X-ray diffraction method. Results of interaction between organic complexes and herbicides were obtained using X-ray diffraction, optical, thermal and spectroscopic analysis. Based on the results obtained using X-ray diffraction, it was concluded that all examined organic complexes and herbicides intercalated into interlayer space of montmorillonite. Montmorillonites modified with HDTMA complex exhibited monolayer, bilayer and pseudotrilayer arrangement of HDTMA+ cations in interlayer space, depending on degree of saturation. It has been found that the HDTMA+ cations are forming the partition phase for the herbicide on the surface of the montmorillonite. On the other hand, montmorillonite modified with PTMA complex exhibited monolayer arrangement of cations on the surface of montmorillonite in such a way that the cations act as pillars in interlayer space. The molecules of herbicides in this case were adsorbed on the surface of the montmorillonite. Which functional groups were involved in bonding processes between montmorillonite, organic complex and herbicide best describes infrared spectroscopy. High sorption of examined herbicides on some organic modified montmorillonites creates an opportunity for application of these substrates as potentially useful material for removal of S-metolachlor and clomazone from the environment.
AB  - fikasnost prilikom sorpcije S-metolahlora i klomazona od strane neorganskih i organski modifikovanih montmorionita sa lokaliteta Bogovina odreĎena je metodom bach adsorpcije. Uzorci montmorionita su tretirani prvo rastvorom NaCl a zatim i različitim koncentracijama organskih kompleksa. Adsorpcione izoterme su dobijene tretiranjem uzoraka različitim koncentracijama herbicida. Detaljna mineraloška karakterizacija uzoraka uraĎena je metodom rendgenske difrakcije. Rezultati interakcije montmorionita sa organskim kompleksima i herbicidima dobijeni su primenom rendgenskih, optičkih, termičkih i spektroskopskih metoda. Na osnovu rezultata rendgenskih ispitivanja uzoraka, utvrĎeno je prisustvo organskih kompleksa i herbicida u meĎuslojnom prostoru montmorionita. Montmorioniti modifikovani sa HDTMA kompleksom pokazivali su jednoslojnu, dvoslojnu i pseudotroslojnu orijentaciju HDTMA+ katjona u meĎuslojnom prostoru. UtvrĎeno je da HDTMA+ katjoni formiraju particionu fazu na površini montmorionita, na kojoj dolazi do sorpcije molekula herbicida. Sa druge strane, montmorioniti modifikovani sa PTMA kompleksom pokazivali su jednoslojnu orijentaciju katjona na površini montmorionita i to na takav način da se katjoni ponašaju kao stubovi koji u zavisnosti od dimenzija dovode do širenja meĎuslojnog prostora. Molekuli herbicida se u tom slučaju vezuju za površinu montmorionita. Primenom metode infracrvene spektroskopije utvrĎeno je koje funkcionalne grupe učestvuju u interakciji izmeĎu montmorionita, organskih kompleksa i herbicida. Visoka sposobnost sorpcije odreĎenih uzoraka organski modifikovanih montmorionita otvara mogućnost njihove primene kao potencijalne sirovine za uklanjanje S-metolahlora i klomazona iz ţivotne sredine...
PB  - Univerzitet u Beogradu, Rudarsko-geološki fakultet
T1  - Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina
T1  - Sorpcija herbicida na neorganski i organski modifikovanom prirodnom montmorionitu iz Bogovine
UR  - https://hdl.handle.net/21.15107/rcub_nardus_9373
ER  - 
@phdthesis{
author = "Kaludjerović, Lazar",
year = "2018",
abstract = "Efficiency of inorganic and organic modified montmorillonites from Bogovina for sorption of the S-metolachlor and clomazone was determined using batch adsorption method. Montmorillonite samples were pretreated with NaCl solution and then with different concentrations of organic complexes. Adsorption isotherms were measured by treatment of the samples with different concentrations of herbicide. Detailed mineralogical characterization of samples was performed using the X-ray diffraction method. Results of interaction between organic complexes and herbicides were obtained using X-ray diffraction, optical, thermal and spectroscopic analysis. Based on the results obtained using X-ray diffraction, it was concluded that all examined organic complexes and herbicides intercalated into interlayer space of montmorillonite. Montmorillonites modified with HDTMA complex exhibited monolayer, bilayer and pseudotrilayer arrangement of HDTMA+ cations in interlayer space, depending on degree of saturation. It has been found that the HDTMA+ cations are forming the partition phase for the herbicide on the surface of the montmorillonite. On the other hand, montmorillonite modified with PTMA complex exhibited monolayer arrangement of cations on the surface of montmorillonite in such a way that the cations act as pillars in interlayer space. The molecules of herbicides in this case were adsorbed on the surface of the montmorillonite. Which functional groups were involved in bonding processes between montmorillonite, organic complex and herbicide best describes infrared spectroscopy. High sorption of examined herbicides on some organic modified montmorillonites creates an opportunity for application of these substrates as potentially useful material for removal of S-metolachlor and clomazone from the environment., fikasnost prilikom sorpcije S-metolahlora i klomazona od strane neorganskih i organski modifikovanih montmorionita sa lokaliteta Bogovina odreĎena je metodom bach adsorpcije. Uzorci montmorionita su tretirani prvo rastvorom NaCl a zatim i različitim koncentracijama organskih kompleksa. Adsorpcione izoterme su dobijene tretiranjem uzoraka različitim koncentracijama herbicida. Detaljna mineraloška karakterizacija uzoraka uraĎena je metodom rendgenske difrakcije. Rezultati interakcije montmorionita sa organskim kompleksima i herbicidima dobijeni su primenom rendgenskih, optičkih, termičkih i spektroskopskih metoda. Na osnovu rezultata rendgenskih ispitivanja uzoraka, utvrĎeno je prisustvo organskih kompleksa i herbicida u meĎuslojnom prostoru montmorionita. Montmorioniti modifikovani sa HDTMA kompleksom pokazivali su jednoslojnu, dvoslojnu i pseudotroslojnu orijentaciju HDTMA+ katjona u meĎuslojnom prostoru. UtvrĎeno je da HDTMA+ katjoni formiraju particionu fazu na površini montmorionita, na kojoj dolazi do sorpcije molekula herbicida. Sa druge strane, montmorioniti modifikovani sa PTMA kompleksom pokazivali su jednoslojnu orijentaciju katjona na površini montmorionita i to na takav način da se katjoni ponašaju kao stubovi koji u zavisnosti od dimenzija dovode do širenja meĎuslojnog prostora. Molekuli herbicida se u tom slučaju vezuju za površinu montmorionita. Primenom metode infracrvene spektroskopije utvrĎeno je koje funkcionalne grupe učestvuju u interakciji izmeĎu montmorionita, organskih kompleksa i herbicida. Visoka sposobnost sorpcije odreĎenih uzoraka organski modifikovanih montmorionita otvara mogućnost njihove primene kao potencijalne sirovine za uklanjanje S-metolahlora i klomazona iz ţivotne sredine...",
publisher = "Univerzitet u Beogradu, Rudarsko-geološki fakultet",
title = "Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina, Sorpcija herbicida na neorganski i organski modifikovanom prirodnom montmorionitu iz Bogovine",
url = "https://hdl.handle.net/21.15107/rcub_nardus_9373"
}
Kaludjerović, L.. (2018). Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina. 
Univerzitet u Beogradu, Rudarsko-geološki fakultet..
https://hdl.handle.net/21.15107/rcub_nardus_9373
Kaludjerović L. Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina. 2018;.
https://hdl.handle.net/21.15107/rcub_nardus_9373 .
Kaludjerović, Lazar, "Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina" (2018),
https://hdl.handle.net/21.15107/rcub_nardus_9373 .

Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry

Milošević, Maja; Logar, Mihovil; Kaludjerović, Lazar; Jelić, Ivana

(Elsevier Science Bv, Amsterdam, 2017)

TY  - CONF
AU  - Milošević, Maja
AU  - Logar, Mihovil
AU  - Kaludjerović, Lazar
AU  - Jelić, Ivana
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4435
AB  - This study focuses on the mineralogical and thermal properties of clay from "Slatina" deposit, Ub, Serbia. Sampled clays were analysed by XRD, IR spectroscopy, ICP-OES, DTA, specific surface area (SSA), cationic exchange capacity (CEC), gravimetric and grain size measurements. Results show that the studied samples have a medium content of smectite-illite minerals with smaller amount of kaolinite together with quartz, feldspars and goethite. They consist generally of fine particles with medium to high plasticity. Based on their mineral composition and physical properties (grain size, plasticity, CEC) the clays are suitable as raw material for the ceramics industry.
PB  - Elsevier Science Bv, Amsterdam
C3  - European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere)
T1  - Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry
EP  - 655
SP  - 650
VL  - 125
DO  - 10.1016/j.egypro.2017.08.270
ER  - 
@conference{
author = "Milošević, Maja and Logar, Mihovil and Kaludjerović, Lazar and Jelić, Ivana",
year = "2017",
abstract = "This study focuses on the mineralogical and thermal properties of clay from "Slatina" deposit, Ub, Serbia. Sampled clays were analysed by XRD, IR spectroscopy, ICP-OES, DTA, specific surface area (SSA), cationic exchange capacity (CEC), gravimetric and grain size measurements. Results show that the studied samples have a medium content of smectite-illite minerals with smaller amount of kaolinite together with quartz, feldspars and goethite. They consist generally of fine particles with medium to high plasticity. Based on their mineral composition and physical properties (grain size, plasticity, CEC) the clays are suitable as raw material for the ceramics industry.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere)",
title = "Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry",
pages = "655-650",
volume = "125",
doi = "10.1016/j.egypro.2017.08.270"
}
Milošević, M., Logar, M., Kaludjerović, L.,& Jelić, I.. (2017). Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry. in European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere)
Elsevier Science Bv, Amsterdam., 125, 650-655.
https://doi.org/10.1016/j.egypro.2017.08.270
Milošević M, Logar M, Kaludjerović L, Jelić I. Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry. in European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere). 2017;125:650-655.
doi:10.1016/j.egypro.2017.08.270 .
Milošević, Maja, Logar, Mihovil, Kaludjerović, Lazar, Jelić, Ivana, "Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry" in European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere), 125 (2017):650-655,
https://doi.org/10.1016/j.egypro.2017.08.270 . .
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Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite

Kaludjerović, Lazar; Tomić, Zorica; Durović-Pejcev, Rada D.; Vulić, Predrag J.; Ašanin, Darko P.

(Taylor & Francis Inc, Philadelphia, 2017)

TY  - JOUR
AU  - Kaludjerović, Lazar
AU  - Tomić, Zorica
AU  - Durović-Pejcev, Rada D.
AU  - Vulić, Predrag J.
AU  - Ašanin, Darko P.
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4337
AB  - This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
T1  - Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite
EP  - 297
IS  - 5
SP  - 291
VL  - 52
DO  - 10.1080/03601234.2017.1281636
ER  - 
@article{
author = "Kaludjerović, Lazar and Tomić, Zorica and Durović-Pejcev, Rada D. and Vulić, Predrag J. and Ašanin, Darko P.",
year = "2017",
abstract = "This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was",
title = "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite",
pages = "297-291",
number = "5",
volume = "52",
doi = "10.1080/03601234.2017.1281636"
}
Kaludjerović, L., Tomić, Z., Durović-Pejcev, R. D., Vulić, P. J.,& Ašanin, D. P.. (2017). Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
Taylor & Francis Inc, Philadelphia., 52(5), 291-297.
https://doi.org/10.1080/03601234.2017.1281636
Kaludjerović L, Tomić Z, Durović-Pejcev RD, Vulić PJ, Ašanin DP. Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was. 2017;52(5):291-297.
doi:10.1080/03601234.2017.1281636 .
Kaludjerović, Lazar, Tomić, Zorica, Durović-Pejcev, Rada D., Vulić, Predrag J., Ašanin, Darko P., "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 52, no. 5 (2017):291-297,
https://doi.org/10.1080/03601234.2017.1281636 . .
7
5
8

Thermal investigation of acetochlor adsorption on inorganic- and organic-modified montmorillonite

Tomić, Zorica; Kaludjerović, Lazar; Nikolić, Nataša; Marković, Smilja; Makreski, Petre

(Springer, Dordrecht, 2016)

TY  - JOUR
AU  - Tomić, Zorica
AU  - Kaludjerović, Lazar
AU  - Nikolić, Nataša
AU  - Marković, Smilja
AU  - Makreski, Petre
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4117
AB  - Results presented in this paper are pioneering attempt toward better understanding of the thermal stability of acetochlor sorption in inorganic and organic montmorillonites. Changes in surface properties of acetochlor adsorbed on montmorillonites and montmorillonites modified with hexadecyltrimethylammonium bromide have been investigated by thermogravimetry, derivative thermogravimetry and infrared spectroscopy. The mass loss, as a result of the heating treatment, indicates release of free water, transformation of hydrophilic to hydrophobic surface, the release of acetochlor sorbed on the montmorillonite, the release of acetochlor sorbed on the montmorillonite and dehydroxylation of the structural OH units.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Thermal investigation of acetochlor adsorption on inorganic- and organic-modified montmorillonite
EP  - 2319
IS  - 3
SP  - 2313
VL  - 123
DO  - 10.1007/s10973-015-5102-2
ER  - 
@article{
author = "Tomić, Zorica and Kaludjerović, Lazar and Nikolić, Nataša and Marković, Smilja and Makreski, Petre",
year = "2016",
abstract = "Results presented in this paper are pioneering attempt toward better understanding of the thermal stability of acetochlor sorption in inorganic and organic montmorillonites. Changes in surface properties of acetochlor adsorbed on montmorillonites and montmorillonites modified with hexadecyltrimethylammonium bromide have been investigated by thermogravimetry, derivative thermogravimetry and infrared spectroscopy. The mass loss, as a result of the heating treatment, indicates release of free water, transformation of hydrophilic to hydrophobic surface, the release of acetochlor sorbed on the montmorillonite, the release of acetochlor sorbed on the montmorillonite and dehydroxylation of the structural OH units.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Thermal investigation of acetochlor adsorption on inorganic- and organic-modified montmorillonite",
pages = "2319-2313",
number = "3",
volume = "123",
doi = "10.1007/s10973-015-5102-2"
}
Tomić, Z., Kaludjerović, L., Nikolić, N., Marković, S.,& Makreski, P.. (2016). Thermal investigation of acetochlor adsorption on inorganic- and organic-modified montmorillonite. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 123(3), 2313-2319.
https://doi.org/10.1007/s10973-015-5102-2
Tomić Z, Kaludjerović L, Nikolić N, Marković S, Makreski P. Thermal investigation of acetochlor adsorption on inorganic- and organic-modified montmorillonite. in Journal of Thermal Analysis and Calorimetry. 2016;123(3):2313-2319.
doi:10.1007/s10973-015-5102-2 .
Tomić, Zorica, Kaludjerović, Lazar, Nikolić, Nataša, Marković, Smilja, Makreski, Petre, "Thermal investigation of acetochlor adsorption on inorganic- and organic-modified montmorillonite" in Journal of Thermal Analysis and Calorimetry, 123, no. 3 (2016):2313-2319,
https://doi.org/10.1007/s10973-015-5102-2 . .
9
8
9

Adsorption of Acetochlor Herbicide on Inorganic- and Organic-Modified Bentonite Monitored by Mid-Infrared Spectroscopy and Batch Adsorption

Tomić, Zorica; Ašanin, Darko P.; Durović-Pejcev, Rada D.; Djordjević, Aleksandar; Makreski, Petre

(Taylor & Francis Inc, Philadelphia, 2015)

TY  - JOUR
AU  - Tomić, Zorica
AU  - Ašanin, Darko P.
AU  - Durović-Pejcev, Rada D.
AU  - Djordjević, Aleksandar
AU  - Makreski, Petre
PY  - 2015
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3832
AB  - The results of sorption of acetochlor herbicide with different concentrations (1-15 mu g/mL) in inorganic- and organic-modified bentonite are presented. Acetochlor sorption in both bentonite types was studied by attenuated total reflectance spectroscopy in the mid-infrared region and by batch equilibrium method. Infrared spectroscopy results suggest that the interaction of acetochlor with inorganic (or organic) bentonite takes place by mechanism involving the carbonyl stretching vibration and phenyl ring in the acetochlor molecule. The increase of the acetochlor concentration results in red shift of both corresponding band wavenumbers. Batch adsorption study pointed out more expressed sorption of acetochlor in organic bentonite.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Spectroscopy Letters
T1  - Adsorption of Acetochlor Herbicide on Inorganic- and Organic-Modified Bentonite Monitored by Mid-Infrared Spectroscopy and Batch Adsorption
EP  - 690
IS  - 9
SP  - 685
VL  - 48
DO  - 10.1080/00387010.2014.962705
ER  - 
@article{
author = "Tomić, Zorica and Ašanin, Darko P. and Durović-Pejcev, Rada D. and Djordjević, Aleksandar and Makreski, Petre",
year = "2015",
abstract = "The results of sorption of acetochlor herbicide with different concentrations (1-15 mu g/mL) in inorganic- and organic-modified bentonite are presented. Acetochlor sorption in both bentonite types was studied by attenuated total reflectance spectroscopy in the mid-infrared region and by batch equilibrium method. Infrared spectroscopy results suggest that the interaction of acetochlor with inorganic (or organic) bentonite takes place by mechanism involving the carbonyl stretching vibration and phenyl ring in the acetochlor molecule. The increase of the acetochlor concentration results in red shift of both corresponding band wavenumbers. Batch adsorption study pointed out more expressed sorption of acetochlor in organic bentonite.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Spectroscopy Letters",
title = "Adsorption of Acetochlor Herbicide on Inorganic- and Organic-Modified Bentonite Monitored by Mid-Infrared Spectroscopy and Batch Adsorption",
pages = "690-685",
number = "9",
volume = "48",
doi = "10.1080/00387010.2014.962705"
}
Tomić, Z., Ašanin, D. P., Durović-Pejcev, R. D., Djordjević, A.,& Makreski, P.. (2015). Adsorption of Acetochlor Herbicide on Inorganic- and Organic-Modified Bentonite Monitored by Mid-Infrared Spectroscopy and Batch Adsorption. in Spectroscopy Letters
Taylor & Francis Inc, Philadelphia., 48(9), 685-690.
https://doi.org/10.1080/00387010.2014.962705
Tomić Z, Ašanin DP, Durović-Pejcev RD, Djordjević A, Makreski P. Adsorption of Acetochlor Herbicide on Inorganic- and Organic-Modified Bentonite Monitored by Mid-Infrared Spectroscopy and Batch Adsorption. in Spectroscopy Letters. 2015;48(9):685-690.
doi:10.1080/00387010.2014.962705 .
Tomić, Zorica, Ašanin, Darko P., Durović-Pejcev, Rada D., Djordjević, Aleksandar, Makreski, Petre, "Adsorption of Acetochlor Herbicide on Inorganic- and Organic-Modified Bentonite Monitored by Mid-Infrared Spectroscopy and Batch Adsorption" in Spectroscopy Letters, 48, no. 9 (2015):685-690,
https://doi.org/10.1080/00387010.2014.962705 . .
8
9
11

Mineral characterization of soil type ranker formed on serpentines occurring in southern Belgrade environs Bubanj Potok

Cekić, Božidar dj.; Ivanovski, Valentin N.; Djordjević, Aleksandar; Aleksić, Velimir; Tomić, Zorica; Bogdanović, Stefan; Umićević, Ana B.

(Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd, 2012)

TY  - JOUR
AU  - Cekić, Božidar dj.
AU  - Ivanovski, Valentin N.
AU  - Djordjević, Aleksandar
AU  - Aleksić, Velimir
AU  - Tomić, Zorica
AU  - Bogdanović, Stefan
AU  - Umićević, Ana B.
PY  - 2012
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/2957
AB  - The paper addresses the issue of health risk associated with the presence of chrysotile in the soil type ranker formed on massive serpentines occurring in the area of Bubanj Potok, a settlement located in the southern Belgrade environs, Serbia. Characterization of the ranker soil was conducted by scanning electron microscopy, X-ray diffraction, micro-Raman spectroscopy and transmission 57Fe Mössbauer spectroscopy. Scanning electron microscopy figures showed regular shaped smectite (montmorillonite) particles, aggregates of chlorite, and elongated sheets of serpentines minerals antigorite. X-ray diffraction analysis confirmed the presence of detrital mineral quartz polymorph as well as minor amounts of other mineral species. Micro-Raman spectroscopy identified the presence of dominant minerals, such as montmorillonite, kaolinite, muscovite, gypsum, calcite, albite, amphiboles (hornblende/kaersutite) and orthoclase. Important polymorph silica modifications of quartz, olivine (forsterite), pyroxene (enstatite/ferrosilite, diopside/hedenbergite), and serpentine (antigorite/lizardite/chrysotile) were identified.
AB  - Rad se bavi pitanjem zdravstvenog rizika povezanog sa prisustvom hrizotila u rankeru (tip zemljišta) formiranom na masivnom serpentinitu u oblasti Bubanj Potoka, naselju koje se nalazi u južnoj okolini Beograda. Karakterizacija rankera je izvršena skenirajućom elektronskom mikroskopijom, rendgenskom difrakcijom praha, mikro-Raman spektroskopijom i transmisionom 57Fe Mesbauer spektroskopijom. Slike dobijene skenirajućim elektronskim mikroskopom pokazuju čestice smektita regularnog oblika montmorionita, agregata hlorita i izdužene listove serpentinskog minerala antigorita. Rendgenska difrakciona analiza potvrdila je prisustvo detrital minerala kvarcnog polimorfa kao i manje količine drugih mineralnih vrsta. Mikro-Raman spektroskopija identifikovala je prisustvo dominantnih minerala, kao što su montmorionit i kaolinit, muskovit, gips, kalcit, albit, amfibol (kaersutit/hornblenda) i ortoklas. Važni polimorfi silika modifikacije kvarca, olivina (forsterit), piroksena (enstatit, ferosilit, hedenbergit, diopsid), i serpentina (antigorit, lizardit, hrizotil) su bili identifikovani.
PB  - Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd
T2  - Nuclear Technology & Radiation Protection
T1  - Mineral characterization of soil type ranker formed on serpentines occurring in southern Belgrade environs Bubanj Potok
T1  - Mineralna karakterizacija rankera formiranog na serpentinitu iz oblasti Bubanj Potoka južno od Beograda
EP  - 136
IS  - 2
SP  - 131
VL  - 27
DO  - 10.2298/NTRP1202131C
ER  - 
@article{
author = "Cekić, Božidar dj. and Ivanovski, Valentin N. and Djordjević, Aleksandar and Aleksić, Velimir and Tomić, Zorica and Bogdanović, Stefan and Umićević, Ana B.",
year = "2012",
abstract = "The paper addresses the issue of health risk associated with the presence of chrysotile in the soil type ranker formed on massive serpentines occurring in the area of Bubanj Potok, a settlement located in the southern Belgrade environs, Serbia. Characterization of the ranker soil was conducted by scanning electron microscopy, X-ray diffraction, micro-Raman spectroscopy and transmission 57Fe Mössbauer spectroscopy. Scanning electron microscopy figures showed regular shaped smectite (montmorillonite) particles, aggregates of chlorite, and elongated sheets of serpentines minerals antigorite. X-ray diffraction analysis confirmed the presence of detrital mineral quartz polymorph as well as minor amounts of other mineral species. Micro-Raman spectroscopy identified the presence of dominant minerals, such as montmorillonite, kaolinite, muscovite, gypsum, calcite, albite, amphiboles (hornblende/kaersutite) and orthoclase. Important polymorph silica modifications of quartz, olivine (forsterite), pyroxene (enstatite/ferrosilite, diopside/hedenbergite), and serpentine (antigorite/lizardite/chrysotile) were identified., Rad se bavi pitanjem zdravstvenog rizika povezanog sa prisustvom hrizotila u rankeru (tip zemljišta) formiranom na masivnom serpentinitu u oblasti Bubanj Potoka, naselju koje se nalazi u južnoj okolini Beograda. Karakterizacija rankera je izvršena skenirajućom elektronskom mikroskopijom, rendgenskom difrakcijom praha, mikro-Raman spektroskopijom i transmisionom 57Fe Mesbauer spektroskopijom. Slike dobijene skenirajućim elektronskim mikroskopom pokazuju čestice smektita regularnog oblika montmorionita, agregata hlorita i izdužene listove serpentinskog minerala antigorita. Rendgenska difrakciona analiza potvrdila je prisustvo detrital minerala kvarcnog polimorfa kao i manje količine drugih mineralnih vrsta. Mikro-Raman spektroskopija identifikovala je prisustvo dominantnih minerala, kao što su montmorionit i kaolinit, muskovit, gips, kalcit, albit, amfibol (kaersutit/hornblenda) i ortoklas. Važni polimorfi silika modifikacije kvarca, olivina (forsterit), piroksena (enstatit, ferosilit, hedenbergit, diopsid), i serpentina (antigorit, lizardit, hrizotil) su bili identifikovani.",
publisher = "Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd",
journal = "Nuclear Technology & Radiation Protection",
title = "Mineral characterization of soil type ranker formed on serpentines occurring in southern Belgrade environs Bubanj Potok, Mineralna karakterizacija rankera formiranog na serpentinitu iz oblasti Bubanj Potoka južno od Beograda",
pages = "136-131",
number = "2",
volume = "27",
doi = "10.2298/NTRP1202131C"
}
Cekić, B. dj., Ivanovski, V. N., Djordjević, A., Aleksić, V., Tomić, Z., Bogdanović, S.,& Umićević, A. B.. (2012). Mineral characterization of soil type ranker formed on serpentines occurring in southern Belgrade environs Bubanj Potok. in Nuclear Technology & Radiation Protection
Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd., 27(2), 131-136.
https://doi.org/10.2298/NTRP1202131C
Cekić BD, Ivanovski VN, Djordjević A, Aleksić V, Tomić Z, Bogdanović S, Umićević AB. Mineral characterization of soil type ranker formed on serpentines occurring in southern Belgrade environs Bubanj Potok. in Nuclear Technology & Radiation Protection. 2012;27(2):131-136.
doi:10.2298/NTRP1202131C .
Cekić, Božidar dj., Ivanovski, Valentin N., Djordjević, Aleksandar, Aleksić, Velimir, Tomić, Zorica, Bogdanović, Stefan, Umićević, Ana B., "Mineral characterization of soil type ranker formed on serpentines occurring in southern Belgrade environs Bubanj Potok" in Nuclear Technology & Radiation Protection, 27, no. 2 (2012):131-136,
https://doi.org/10.2298/NTRP1202131C . .