TY  - JOUR
AU  - Jovanović, Svetlana P.
AU  - Holclajtner-Antunović, Ivanka
AU  - Uskoković-Marković, Snežana M.
AU  - Bajuk-Bogdanović, Danica
AU  - Pavlović, Vladimir
AU  - Tosić, Dragana
AU  - Milenković, Marina
AU  - Todorović-Marković, Biljana
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4787
AB  - Antibacterial properties of graphene oxide (GO) have been studied extensively in the last few years, while for polyoxometalates there are just a few researches. Herein, we prepared nanocomposites of GO and different amounts of 12-molybdophosphoric acid (MoPA) and analyzed their antibacterial activity and both structural and morphological properties. In nanocomposites with higher amounts of MoPA, graphene sheets were significantly changed with disrupted flat, graphene-like morphology of GO. In the nanocomposites with low MoPA content, flat GO morphology was preserved. Additionally, structural analyses showed some changes in symmetry of the Keggin anion as a consequence of interactions between GO and MoPA, the increase in structural disorder and the lowering of electron density in GO structure due to interaction with MoPA. We have studied antibacterial properties on the gram-positive: Staphylococcus aureus, Staphylococcus epidermidis, Bacillus subtilis; and the gram-negative bacteria: Escherichia coil, Klebsiella pneumoniae, Pseudomonas aeruginosa and Salmonella abony. Only a mild antibacterial effect of GO and nanocomposites with low amount of MoPA against Bacillus subtilis was observed, while the rest of analyzed materials did not show any antibacterial activity.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Chemistry and Physics
T1  - Modification of graphene oxide surfaces with 12-molybdophosphoric acid: Structural and antibacterial study
EP  - 167
SP  - 157
VL  - 213
DO  - 10.1016/j.matchemphys.2018.04.011
ER  - 

@article{
author = "Jovanović, Svetlana P. and Holclajtner-Antunović, Ivanka and Uskoković-Marković, Snežana M. and Bajuk-Bogdanović, Danica and Pavlović, Vladimir and Tosić, Dragana and Milenković, Marina and Todorović-Marković, Biljana",
year = "2018",
abstract = "Antibacterial properties of graphene oxide (GO) have been studied extensively in the last few years, while for polyoxometalates there are just a few researches. Herein, we prepared nanocomposites of GO and different amounts of 12-molybdophosphoric acid (MoPA) and analyzed their antibacterial activity and both structural and morphological properties. In nanocomposites with higher amounts of MoPA, graphene sheets were significantly changed with disrupted flat, graphene-like morphology of GO. In the nanocomposites with low MoPA content, flat GO morphology was preserved. Additionally, structural analyses showed some changes in symmetry of the Keggin anion as a consequence of interactions between GO and MoPA, the increase in structural disorder and the lowering of electron density in GO structure due to interaction with MoPA. We have studied antibacterial properties on the gram-positive: Staphylococcus aureus, Staphylococcus epidermidis, Bacillus subtilis; and the gram-negative bacteria: Escherichia coil, Klebsiella pneumoniae, Pseudomonas aeruginosa and Salmonella abony. Only a mild antibacterial effect of GO and nanocomposites with low amount of MoPA against Bacillus subtilis was observed, while the rest of analyzed materials did not show any antibacterial activity.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Chemistry and Physics",
title = "Modification of graphene oxide surfaces with 12-molybdophosphoric acid: Structural and antibacterial study",
pages = "167-157",
volume = "213",
doi = "10.1016/j.matchemphys.2018.04.011"
}

Jovanović, S. P., Holclajtner-Antunović, I., Uskoković-Marković, S. M., Bajuk-Bogdanović, D., Pavlović, V., Tosić, D., Milenković, M.,& Todorović-Marković, B.. (2018). Modification of graphene oxide surfaces with 12-molybdophosphoric acid: Structural and antibacterial study. in Materials Chemistry and Physics
Elsevier Science Sa, Lausanne., 213, 157-167.
https://doi.org/10.1016/j.matchemphys.2018.04.011

Jovanović SP, Holclajtner-Antunović I, Uskoković-Marković SM, Bajuk-Bogdanović D, Pavlović V, Tosić D, Milenković M, Todorović-Marković B. Modification of graphene oxide surfaces with 12-molybdophosphoric acid: Structural and antibacterial study. in Materials Chemistry and Physics. 2018;213:157-167.
doi:10.1016/j.matchemphys.2018.04.011 .

Jovanović, Svetlana P., Holclajtner-Antunović, Ivanka, Uskoković-Marković, Snežana M., Bajuk-Bogdanović, Danica, Pavlović, Vladimir, Tosić, Dragana, Milenković, Marina, Todorović-Marković, Biljana, "Modification of graphene oxide surfaces with 12-molybdophosphoric acid: Structural and antibacterial study" in Materials Chemistry and Physics, 213 (2018):157-167,
https://doi.org/10.1016/j.matchemphys.2018.04.011 . .

TY  - JOUR
AU  - Vujković, Milica J.
AU  - Vidoeski, Bojan A.
AU  - Jovanović, Svetlana P.
AU  - Bajuk-Bogdanović, Danica
AU  - Budimir, Milica D.
AU  - Marković, Zoran M.
AU  - Pavlović, Vladimir
AU  - Todorović-Marković, Biljana
AU  - Holclajtner-Antunović, Ivanka
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4097
AB  - A novel electrochemically exfoliated graphene-molybdophosphoric acid nanohybride (EG-MoPA) was prepared via a simple method. Both scanning electron (SEM) and atomic force microscopy (AFM) results show that MoPA clusters are attached to the surfaces of graphene sheets. By changing the mass ratio of EG-MoPA, the morphology of nanohybrid itself can be significantly modulated, from mostly flat graphene like structure at low amount of MoPA to very uneven, wavy surfaces when MoPA is present in higher concentration. The Raman and Fourier transform infra red (FTIR) spectra in conjunction with electrochemical results indicate that strong interaction exists between the components of nanohybride based on charge transfer and electrostatic interaction of graphene sheets and MoPA. The electrochemical performances are improved by synergetic effect of reversible redox properties of MoPA and the double layer capacitance of a high-surface area of the obtained nanohybrides. The higher current capability of EG was achieved by anchoring the small MoPA concentration on the graphene support. The strong bonding of EG with the MoPA prevents acid to dissolve in the electrolyte upon cycling, enabling the stable capacitance behaviour of the low-doped EG sample. The capacitance for the EG doped with the high amount of MoPA was found to be much larger than for EG. However, the obtained capacitance decreases at the beginning of cycling due to the dissolution of excessive amount of surface MoPA, weakly bonded to the graphene support.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Synthesis and characterization of electrochemically exfoliated graphene-molybdophosphate hybrid materials for charge storage devices
EP  - 46
SP  - 34
VL  - 217
DO  - 10.1016/j.electacta.2016.09.067
ER  - 

@article{
author = "Vujković, Milica J. and Vidoeski, Bojan A. and Jovanović, Svetlana P. and Bajuk-Bogdanović, Danica and Budimir, Milica D. and Marković, Zoran M. and Pavlović, Vladimir and Todorović-Marković, Biljana and Holclajtner-Antunović, Ivanka",
year = "2016",
abstract = "A novel electrochemically exfoliated graphene-molybdophosphoric acid nanohybride (EG-MoPA) was prepared via a simple method. Both scanning electron (SEM) and atomic force microscopy (AFM) results show that MoPA clusters are attached to the surfaces of graphene sheets. By changing the mass ratio of EG-MoPA, the morphology of nanohybrid itself can be significantly modulated, from mostly flat graphene like structure at low amount of MoPA to very uneven, wavy surfaces when MoPA is present in higher concentration. The Raman and Fourier transform infra red (FTIR) spectra in conjunction with electrochemical results indicate that strong interaction exists between the components of nanohybride based on charge transfer and electrostatic interaction of graphene sheets and MoPA. The electrochemical performances are improved by synergetic effect of reversible redox properties of MoPA and the double layer capacitance of a high-surface area of the obtained nanohybrides. The higher current capability of EG was achieved by anchoring the small MoPA concentration on the graphene support. The strong bonding of EG with the MoPA prevents acid to dissolve in the electrolyte upon cycling, enabling the stable capacitance behaviour of the low-doped EG sample. The capacitance for the EG doped with the high amount of MoPA was found to be much larger than for EG. However, the obtained capacitance decreases at the beginning of cycling due to the dissolution of excessive amount of surface MoPA, weakly bonded to the graphene support.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Synthesis and characterization of electrochemically exfoliated graphene-molybdophosphate hybrid materials for charge storage devices",
pages = "46-34",
volume = "217",
doi = "10.1016/j.electacta.2016.09.067"
}

Vujković, M. J., Vidoeski, B. A., Jovanović, S. P., Bajuk-Bogdanović, D., Budimir, M. D., Marković, Z. M., Pavlović, V., Todorović-Marković, B.,& Holclajtner-Antunović, I.. (2016). Synthesis and characterization of electrochemically exfoliated graphene-molybdophosphate hybrid materials for charge storage devices. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 217, 34-46.
https://doi.org/10.1016/j.electacta.2016.09.067

Vujković MJ, Vidoeski BA, Jovanović SP, Bajuk-Bogdanović D, Budimir MD, Marković ZM, Pavlović V, Todorović-Marković B, Holclajtner-Antunović I. Synthesis and characterization of electrochemically exfoliated graphene-molybdophosphate hybrid materials for charge storage devices. in Electrochimica Acta. 2016;217:34-46.
doi:10.1016/j.electacta.2016.09.067 .

Vujković, Milica J., Vidoeski, Bojan A., Jovanović, Svetlana P., Bajuk-Bogdanović, Danica, Budimir, Milica D., Marković, Zoran M., Pavlović, Vladimir, Todorović-Marković, Biljana, Holclajtner-Antunović, Ivanka, "Synthesis and characterization of electrochemically exfoliated graphene-molybdophosphate hybrid materials for charge storage devices" in Electrochimica Acta, 217 (2016):34-46,
https://doi.org/10.1016/j.electacta.2016.09.067 . .