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bilateral project Serbia-Slovakia [SK-SRB-2016-0038]

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Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity

Kepić, Dejan P.; Ristić, Ivan S.; Marinović-Cincović, Milena; Perusko, Davor; Spitalsky, Zdenko; Pavlović, Vladimir; Budimir, Milica D.; Siffalović, Peter; Dramicanin, Miroslav D.; Micusik, Matej; Kleinova, Angela; Janigova, Ivica; Marković, Zoran M.; Todorović-Marković, Biljana

(Wiley, Hoboken, 2018)

TY  - JOUR
AU  - Kepić, Dejan P.
AU  - Ristić, Ivan S.
AU  - Marinović-Cincović, Milena
AU  - Perusko, Davor
AU  - Spitalsky, Zdenko
AU  - Pavlović, Vladimir
AU  - Budimir, Milica D.
AU  - Siffalović, Peter
AU  - Dramicanin, Miroslav D.
AU  - Micusik, Matej
AU  - Kleinova, Angela
AU  - Janigova, Ivica
AU  - Marković, Zoran M.
AU  - Todorović-Marković, Biljana
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4778
AB  - This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.
PB  - Wiley, Hoboken
T2  - Polymer International
T1  - Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity
EP  - 1127
IS  - 8
SP  - 1118
VL  - 67
DO  - 10.1002/pi.5620
ER  - 
@article{
author = "Kepić, Dejan P. and Ristić, Ivan S. and Marinović-Cincović, Milena and Perusko, Davor and Spitalsky, Zdenko and Pavlović, Vladimir and Budimir, Milica D. and Siffalović, Peter and Dramicanin, Miroslav D. and Micusik, Matej and Kleinova, Angela and Janigova, Ivica and Marković, Zoran M. and Todorović-Marković, Biljana",
year = "2018",
abstract = "This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.",
publisher = "Wiley, Hoboken",
journal = "Polymer International",
title = "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity",
pages = "1127-1118",
number = "8",
volume = "67",
doi = "10.1002/pi.5620"
}
Kepić, D. P., Ristić, I. S., Marinović-Cincović, M., Perusko, D., Spitalsky, Z., Pavlović, V., Budimir, M. D., Siffalović, P., Dramicanin, M. D., Micusik, M., Kleinova, A., Janigova, I., Marković, Z. M.,& Todorović-Marković, B.. (2018). Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International
Wiley, Hoboken., 67(8), 1118-1127.
https://doi.org/10.1002/pi.5620
Kepić DP, Ristić IS, Marinović-Cincović M, Perusko D, Spitalsky Z, Pavlović V, Budimir MD, Siffalović P, Dramicanin MD, Micusik M, Kleinova A, Janigova I, Marković ZM, Todorović-Marković B. Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International. 2018;67(8):1118-1127.
doi:10.1002/pi.5620 .
Kepić, Dejan P., Ristić, Ivan S., Marinović-Cincović, Milena, Perusko, Davor, Spitalsky, Zdenko, Pavlović, Vladimir, Budimir, Milica D., Siffalović, Peter, Dramicanin, Miroslav D., Micusik, Matej, Kleinova, Angela, Janigova, Ivica, Marković, Zoran M., Todorović-Marković, Biljana, "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity" in Polymer International, 67, no. 8 (2018):1118-1127,
https://doi.org/10.1002/pi.5620 . .
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Antibacterial potential of electrochemically exfoliated graphene sheets

Marković, Zoran M.; Matijašević, Danka; Pavlović, Vladimir; Jovanović, Svetlana P.; Holclajtner-Antunović, Ivanka; Spitalsky, Zdenko; Micusik, Matej; Dramicanin, Miroslav D.; Milivojević, Dušan D.; Nikšić, Miomir; Todorović-Marković, Biljana

(Academic Press Inc Elsevier Science, San Diego, 2017)

TY  - JOUR
AU  - Marković, Zoran M.
AU  - Matijašević, Danka
AU  - Pavlović, Vladimir
AU  - Jovanović, Svetlana P.
AU  - Holclajtner-Antunović, Ivanka
AU  - Spitalsky, Zdenko
AU  - Micusik, Matej
AU  - Dramicanin, Miroslav D.
AU  - Milivojević, Dušan D.
AU  - Nikšić, Miomir
AU  - Todorović-Marković, Biljana
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4348
AB  - Electrochemically exfoliated graphene is functionalized graphene with potential application in biomedicine. Two most relevant biological features of this material are its electrical conductivity and excellent water dispersibility. In this study we have tried to establish the correlation between graphene structure and its antibacterial properties. The exfoliation process was performed in a two electrode-highly oriented pyrolytic graphite electrochemical cell. Solution of ammonium persulfate was used as an electrolyte. Exfoliated graphene sheets were dispersed in aqueous media and characterized by atomic force microscopy, scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, X photoelectron spectroscopy, X-ray diffraction, electron paramagnetic resonance, zeta potential, contact angle measurements and surface energy. Antibacterial assays have shown lack of the significant antibacterial activity. Major effect on bacteria was slight change of bacteria morphology. Membrane remained intact despite significant change of chemical content of membrane components.
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Colloid and Interface Science
T1  - Antibacterial potential of electrochemically exfoliated graphene sheets
EP  - 43
SP  - 30
VL  - 500
DO  - 10.1016/j.jcis.2017.03.110
ER  - 
@article{
author = "Marković, Zoran M. and Matijašević, Danka and Pavlović, Vladimir and Jovanović, Svetlana P. and Holclajtner-Antunović, Ivanka and Spitalsky, Zdenko and Micusik, Matej and Dramicanin, Miroslav D. and Milivojević, Dušan D. and Nikšić, Miomir and Todorović-Marković, Biljana",
year = "2017",
abstract = "Electrochemically exfoliated graphene is functionalized graphene with potential application in biomedicine. Two most relevant biological features of this material are its electrical conductivity and excellent water dispersibility. In this study we have tried to establish the correlation between graphene structure and its antibacterial properties. The exfoliation process was performed in a two electrode-highly oriented pyrolytic graphite electrochemical cell. Solution of ammonium persulfate was used as an electrolyte. Exfoliated graphene sheets were dispersed in aqueous media and characterized by atomic force microscopy, scanning electron microscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, X photoelectron spectroscopy, X-ray diffraction, electron paramagnetic resonance, zeta potential, contact angle measurements and surface energy. Antibacterial assays have shown lack of the significant antibacterial activity. Major effect on bacteria was slight change of bacteria morphology. Membrane remained intact despite significant change of chemical content of membrane components.",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Colloid and Interface Science",
title = "Antibacterial potential of electrochemically exfoliated graphene sheets",
pages = "43-30",
volume = "500",
doi = "10.1016/j.jcis.2017.03.110"
}
Marković, Z. M., Matijašević, D., Pavlović, V., Jovanović, S. P., Holclajtner-Antunović, I., Spitalsky, Z., Micusik, M., Dramicanin, M. D., Milivojević, D. D., Nikšić, M.,& Todorović-Marković, B.. (2017). Antibacterial potential of electrochemically exfoliated graphene sheets. in Journal of Colloid and Interface Science
Academic Press Inc Elsevier Science, San Diego., 500, 30-43.
https://doi.org/10.1016/j.jcis.2017.03.110
Marković ZM, Matijašević D, Pavlović V, Jovanović SP, Holclajtner-Antunović I, Spitalsky Z, Micusik M, Dramicanin MD, Milivojević DD, Nikšić M, Todorović-Marković B. Antibacterial potential of electrochemically exfoliated graphene sheets. in Journal of Colloid and Interface Science. 2017;500:30-43.
doi:10.1016/j.jcis.2017.03.110 .
Marković, Zoran M., Matijašević, Danka, Pavlović, Vladimir, Jovanović, Svetlana P., Holclajtner-Antunović, Ivanka, Spitalsky, Zdenko, Micusik, Matej, Dramicanin, Miroslav D., Milivojević, Dušan D., Nikšić, Miomir, Todorović-Marković, Biljana, "Antibacterial potential of electrochemically exfoliated graphene sheets" in Journal of Colloid and Interface Science, 500 (2017):30-43,
https://doi.org/10.1016/j.jcis.2017.03.110 . .
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