Djoković, Vladimir

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orcid::0000-0001-8237-1101
  • Djoković, Vladimir (6)
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Author's Bibliography

PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix

Pavlović, Vera P.; Tošić, Dragana; Dojćilović, Radovan; Dudić, Duško; Dramićanin, Miroslav D.; Medić, Mina; McPherson, Michael M.; Pavlović, Vladimir; Vlahović, Branislav; Djoković, Vladimir

(Elsevier Ltd, 2021)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Tošić, Dragana
AU  - Dojćilović, Radovan
AU  - Dudić, Duško
AU  - Dramićanin, Miroslav D.
AU  - Medić, Mina
AU  - McPherson, Michael M.
AU  - Pavlović, Vladimir
AU  - Vlahović, Branislav
AU  - Djoković, Vladimir
PY  - 2021
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5808
AB  - Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar β- and γ-crystals, while there is also a contribution of the non-polar α-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of ~2 kHz, the observed process appears at ~10 °C (about 45° above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from −100 to 100 °C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and ~50 kHz.
PB  - Elsevier Ltd
T2  - Polymer Testing
T1  - PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix
SP  - 107093
VL  - 96
DO  - 10.1016/j.polymertesting.2021.107093
ER  - 
@article{
author = "Pavlović, Vera P. and Tošić, Dragana and Dojćilović, Radovan and Dudić, Duško and Dramićanin, Miroslav D. and Medić, Mina and McPherson, Michael M. and Pavlović, Vladimir and Vlahović, Branislav and Djoković, Vladimir",
year = "2021",
abstract = "Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar β- and γ-crystals, while there is also a contribution of the non-polar α-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of ~2 kHz, the observed process appears at ~10 °C (about 45° above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from −100 to 100 °C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and ~50 kHz.",
publisher = "Elsevier Ltd",
journal = "Polymer Testing",
title = "PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix",
pages = "107093",
volume = "96",
doi = "10.1016/j.polymertesting.2021.107093"
}
Pavlović, V. P., Tošić, D., Dojćilović, R., Dudić, D., Dramićanin, M. D., Medić, M., McPherson, M. M., Pavlović, V., Vlahović, B.,& Djoković, V.. (2021). PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix. in Polymer Testing
Elsevier Ltd., 96, 107093.
https://doi.org/10.1016/j.polymertesting.2021.107093
Pavlović VP, Tošić D, Dojćilović R, Dudić D, Dramićanin MD, Medić M, McPherson MM, Pavlović V, Vlahović B, Djoković V. PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix. in Polymer Testing. 2021;96:107093.
doi:10.1016/j.polymertesting.2021.107093 .
Pavlović, Vera P., Tošić, Dragana, Dojćilović, Radovan, Dudić, Duško, Dramićanin, Miroslav D., Medić, Mina, McPherson, Michael M., Pavlović, Vladimir, Vlahović, Branislav, Djoković, Vladimir, "PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix" in Polymer Testing, 96 (2021):107093,
https://doi.org/10.1016/j.polymertesting.2021.107093 . .
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Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems

Danilović, Danijela; Božanić, Dušan K.; Dojčilović, Radovan; Vukmirović, Nenad; Sapkota, Pitambar; Vukašinović, Ivana; Djoković, Vladimir; Božek, John; Nicolas, Christophe; Ptasinska, Sylwia; Milosavljević, Aleksandar R.

(Amer Chemical Soc, Washington, 2020)

TY  - JOUR
AU  - Danilović, Danijela
AU  - Božanić, Dušan K.
AU  - Dojčilović, Radovan
AU  - Vukmirović, Nenad
AU  - Sapkota, Pitambar
AU  - Vukašinović, Ivana
AU  - Djoković, Vladimir
AU  - Božek, John
AU  - Nicolas, Christophe
AU  - Ptasinska, Sylwia
AU  - Milosavljević, Aleksandar R.
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5301
AB  - We report on the aerosol generation of ligand-free silver iodobismuthate (Ag-Bi-I) nanoparticles (NPs) and on in situ investigation of their electronic structure using synchrotron radiation soft X-ray aerosol photoelectron spectroscopy (XAPS). The structural and morphological characterizations revealed the aerosol to be composed of spherical rudorffite Ag3BiI6 particles, approximately 100 nm in size. The XAPS showed well-resolved signals from all expected elements (Ag, Bi, and I) and allowed estimation of the NP work function to be about 4.5 eV. The ionization energy of Ag3BiI6 NPs was determined to be 6.1 eV that is in good agreement with our calculations based on a hybrid functional approach. The presented method of production of Ag3BiI6 aerosol can prove beneficial for the future development of Ag-Bi-I-based photovoltaic materials, since it allows the deposition of Ag-Bi-I particles on large surface areas of arbitrary shape and roughness.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry C
T1  - Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems
EP  - 23937
IS  - 43
SP  - 23930
VL  - 124
DO  - 10.1021/acs.jpcc.0c06819
ER  - 
@article{
author = "Danilović, Danijela and Božanić, Dušan K. and Dojčilović, Radovan and Vukmirović, Nenad and Sapkota, Pitambar and Vukašinović, Ivana and Djoković, Vladimir and Božek, John and Nicolas, Christophe and Ptasinska, Sylwia and Milosavljević, Aleksandar R.",
year = "2020",
abstract = "We report on the aerosol generation of ligand-free silver iodobismuthate (Ag-Bi-I) nanoparticles (NPs) and on in situ investigation of their electronic structure using synchrotron radiation soft X-ray aerosol photoelectron spectroscopy (XAPS). The structural and morphological characterizations revealed the aerosol to be composed of spherical rudorffite Ag3BiI6 particles, approximately 100 nm in size. The XAPS showed well-resolved signals from all expected elements (Ag, Bi, and I) and allowed estimation of the NP work function to be about 4.5 eV. The ionization energy of Ag3BiI6 NPs was determined to be 6.1 eV that is in good agreement with our calculations based on a hybrid functional approach. The presented method of production of Ag3BiI6 aerosol can prove beneficial for the future development of Ag-Bi-I-based photovoltaic materials, since it allows the deposition of Ag-Bi-I particles on large surface areas of arbitrary shape and roughness.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry C",
title = "Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems",
pages = "23937-23930",
number = "43",
volume = "124",
doi = "10.1021/acs.jpcc.0c06819"
}
Danilović, D., Božanić, D. K., Dojčilović, R., Vukmirović, N., Sapkota, P., Vukašinović, I., Djoković, V., Božek, J., Nicolas, C., Ptasinska, S.,& Milosavljević, A. R.. (2020). Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems. in Journal of Physical Chemistry C
Amer Chemical Soc, Washington., 124(43), 23930-23937.
https://doi.org/10.1021/acs.jpcc.0c06819
Danilović D, Božanić DK, Dojčilović R, Vukmirović N, Sapkota P, Vukašinović I, Djoković V, Božek J, Nicolas C, Ptasinska S, Milosavljević AR. Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems. in Journal of Physical Chemistry C. 2020;124(43):23930-23937.
doi:10.1021/acs.jpcc.0c06819 .
Danilović, Danijela, Božanić, Dušan K., Dojčilović, Radovan, Vukmirović, Nenad, Sapkota, Pitambar, Vukašinović, Ivana, Djoković, Vladimir, Božek, John, Nicolas, Christophe, Ptasinska, Sylwia, Milosavljević, Aleksandar R., "Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems" in Journal of Physical Chemistry C, 124, no. 43 (2020):23930-23937,
https://doi.org/10.1021/acs.jpcc.0c06819 . .
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DUV fluorescence bioimaging study of the interaction of partially reduced graphene oxide and liver cancer cells

Dojčilović, Radovan; Pajović, Jelena D.; Božanić, Dušan K.; Jović, Nataša; Pavlović, Vera P.; Pavlović, Vladimir; Lenhardt-Acković, Lea; Zeković, Ivana; Dramicanin, Miroslav D.; Kascakova, Slavka; Refregiers, Matthieu; Rasić, Goran; Vlahović, Branislav; Djoković, Vladimir

(IOP Publishing Ltd, Bristol, 2018)

TY  - JOUR
AU  - Dojčilović, Radovan
AU  - Pajović, Jelena D.
AU  - Božanić, Dušan K.
AU  - Jović, Nataša
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir
AU  - Lenhardt-Acković, Lea
AU  - Zeković, Ivana
AU  - Dramicanin, Miroslav D.
AU  - Kascakova, Slavka
AU  - Refregiers, Matthieu
AU  - Rasić, Goran
AU  - Vlahović, Branislav
AU  - Djoković, Vladimir
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4655
AB  - The interaction of partially reduced graphene oxide (prGO) and Huh7.5.1 liver cancer cells was investigated by means of DUV fluorescence bioimaging. The prGO sample was obtained by the reduction (to a certain extent) of the initially prepared graphene oxide (GO) nanosheets with hydrazine. The fluorescence of the GO nanosheets increases with time of the reduction due to a change in ratio of the sp(2) and sp(3) carbon sites and the prGO sample was extracted from the dispersion after 6 min, when the intensity of the fluorescence reached its maximum. The reduction process was left to proceed further to saturation until highly reduced graphene oxide (denoted here as rGO) was obtained. GO, prGO and rGO samples were investigated by structural (scanning electron microscopy (SEM), scanning transmission electron microscopy coupled with energy dispersive spectrometry (STEM-EDS)) and spectroscopic (UV-vis, photoluminescence (PL), Raman) methods. After that, Huh7.5.1 cells were incubated with GO, prGO and rGO nanosheets and used in bioimaging studies, which were performed on DISCO beamline of synchrotron SOLEIL. It was found that the prGO significantly enhanced the fluorescence of the cells and increased the intensity of the signal by similar to 2.5 times. Time-lapse fluorescence microscopy experiments showed that fluorescence dynamics strongly depends on the type of nanosheets used. The obtained prGO nanostructure can be easily conjugated with aromatic ring containing drugs, which opens a possibility for its applications in fluorescence microscopy monitored drug delivery.
PB  - IOP Publishing Ltd, Bristol
T2  - 2d Materials
T1  - DUV fluorescence bioimaging study of the interaction of partially reduced graphene oxide and liver cancer cells
IS  - 4
VL  - 5
DO  - 10.1088/2053-1583/aad72b
ER  - 
@article{
author = "Dojčilović, Radovan and Pajović, Jelena D. and Božanić, Dušan K. and Jović, Nataša and Pavlović, Vera P. and Pavlović, Vladimir and Lenhardt-Acković, Lea and Zeković, Ivana and Dramicanin, Miroslav D. and Kascakova, Slavka and Refregiers, Matthieu and Rasić, Goran and Vlahović, Branislav and Djoković, Vladimir",
year = "2018",
abstract = "The interaction of partially reduced graphene oxide (prGO) and Huh7.5.1 liver cancer cells was investigated by means of DUV fluorescence bioimaging. The prGO sample was obtained by the reduction (to a certain extent) of the initially prepared graphene oxide (GO) nanosheets with hydrazine. The fluorescence of the GO nanosheets increases with time of the reduction due to a change in ratio of the sp(2) and sp(3) carbon sites and the prGO sample was extracted from the dispersion after 6 min, when the intensity of the fluorescence reached its maximum. The reduction process was left to proceed further to saturation until highly reduced graphene oxide (denoted here as rGO) was obtained. GO, prGO and rGO samples were investigated by structural (scanning electron microscopy (SEM), scanning transmission electron microscopy coupled with energy dispersive spectrometry (STEM-EDS)) and spectroscopic (UV-vis, photoluminescence (PL), Raman) methods. After that, Huh7.5.1 cells were incubated with GO, prGO and rGO nanosheets and used in bioimaging studies, which were performed on DISCO beamline of synchrotron SOLEIL. It was found that the prGO significantly enhanced the fluorescence of the cells and increased the intensity of the signal by similar to 2.5 times. Time-lapse fluorescence microscopy experiments showed that fluorescence dynamics strongly depends on the type of nanosheets used. The obtained prGO nanostructure can be easily conjugated with aromatic ring containing drugs, which opens a possibility for its applications in fluorescence microscopy monitored drug delivery.",
publisher = "IOP Publishing Ltd, Bristol",
journal = "2d Materials",
title = "DUV fluorescence bioimaging study of the interaction of partially reduced graphene oxide and liver cancer cells",
number = "4",
volume = "5",
doi = "10.1088/2053-1583/aad72b"
}
Dojčilović, R., Pajović, J. D., Božanić, D. K., Jović, N., Pavlović, V. P., Pavlović, V., Lenhardt-Acković, L., Zeković, I., Dramicanin, M. D., Kascakova, S., Refregiers, M., Rasić, G., Vlahović, B.,& Djoković, V.. (2018). DUV fluorescence bioimaging study of the interaction of partially reduced graphene oxide and liver cancer cells. in 2d Materials
IOP Publishing Ltd, Bristol., 5(4).
https://doi.org/10.1088/2053-1583/aad72b
Dojčilović R, Pajović JD, Božanić DK, Jović N, Pavlović VP, Pavlović V, Lenhardt-Acković L, Zeković I, Dramicanin MD, Kascakova S, Refregiers M, Rasić G, Vlahović B, Djoković V. DUV fluorescence bioimaging study of the interaction of partially reduced graphene oxide and liver cancer cells. in 2d Materials. 2018;5(4).
doi:10.1088/2053-1583/aad72b .
Dojčilović, Radovan, Pajović, Jelena D., Božanić, Dušan K., Jović, Nataša, Pavlović, Vera P., Pavlović, Vladimir, Lenhardt-Acković, Lea, Zeković, Ivana, Dramicanin, Miroslav D., Kascakova, Slavka, Refregiers, Matthieu, Rasić, Goran, Vlahović, Branislav, Djoković, Vladimir, "DUV fluorescence bioimaging study of the interaction of partially reduced graphene oxide and liver cancer cells" in 2d Materials, 5, no. 4 (2018),
https://doi.org/10.1088/2053-1583/aad72b . .
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Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films

Peles, A.; Aleksić, O.; Pavlović, Vera P.; Djoković, Vladimir; Dojčilović, Radovan; Nikolić, Z.; Marinković, F.; Mitrić, M.; Blagojević, Vladimir A.; Vlahović, Branislav; Pavlović, Vladimir

(IOP Publishing Ltd, Bristol, 2018)

TY  - JOUR
AU  - Peles, A.
AU  - Aleksić, O.
AU  - Pavlović, Vera P.
AU  - Djoković, Vladimir
AU  - Dojčilović, Radovan
AU  - Nikolić, Z.
AU  - Marinković, F.
AU  - Mitrić, M.
AU  - Blagojević, Vladimir A.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4658
AB  - The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles.
PB  - IOP Publishing Ltd, Bristol
T2  - Physica Scripta
T1  - Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films
IS  - 10
VL  - 93
DO  - 10.1088/1402-4896/aad749
ER  - 
@article{
author = "Peles, A. and Aleksić, O. and Pavlović, Vera P. and Djoković, Vladimir and Dojčilović, Radovan and Nikolić, Z. and Marinković, F. and Mitrić, M. and Blagojević, Vladimir A. and Vlahović, Branislav and Pavlović, Vladimir",
year = "2018",
abstract = "The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles.",
publisher = "IOP Publishing Ltd, Bristol",
journal = "Physica Scripta",
title = "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films",
number = "10",
volume = "93",
doi = "10.1088/1402-4896/aad749"
}
Peles, A., Aleksić, O., Pavlović, V. P., Djoković, V., Dojčilović, R., Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, V. A., Vlahović, B.,& Pavlović, V.. (2018). Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta
IOP Publishing Ltd, Bristol., 93(10).
https://doi.org/10.1088/1402-4896/aad749
Peles A, Aleksić O, Pavlović VP, Djoković V, Dojčilović R, Nikolić Z, Marinković F, Mitrić M, Blagojević VA, Vlahović B, Pavlović V. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta. 2018;93(10).
doi:10.1088/1402-4896/aad749 .
Peles, A., Aleksić, O., Pavlović, Vera P., Djoković, Vladimir, Dojčilović, Radovan, Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, Vladimir A., Vlahović, Branislav, Pavlović, Vladimir, "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films" in Physica Scripta, 93, no. 10 (2018),
https://doi.org/10.1088/1402-4896/aad749 . .
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Ferroelectric nanocomposites of polyvinylidene fluoride/polymethyl methacrylate blend and BaTiO3 particles: Fabrication of beta-crystal polymorph rich matrix through mechanical activation of the filler

Mofokeng, Tladi G.; Luyt, Adriaan S.; Pavlović, Vera P.; Pavlović, Vladimir; Dudić, Dusko; Vlahović, Branislav; Djoković, Vladimir

(Amer Inst Physics, Melville, 2014)

TY  - JOUR
AU  - Mofokeng, Tladi G.
AU  - Luyt, Adriaan S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir
AU  - Dudić, Dusko
AU  - Vlahović, Branislav
AU  - Djoković, Vladimir
PY  - 2014
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3652
AB  - Nanocomposites of polyvinylidene fluoride/polymethyl methacrylate (PVDF/PMMA) blend and mechanically activated barium titanate (BaTiO3) particles were prepared by melt mixing. Modification of filler by means of mechanical activation has a profound effect on the crystallization of PVDF in the blend matrix. Raman analysis showed that the modified BaTiO3 particles, due to higher specific surfaces, induce, predominantly, the crystallization of the electrically active beta-phase of PVDF, while the initial micron size particles induce the formation of the most common but non-polar alpha-crystal form. The introduction of activated particles reduces the overall crystallinity but slightly affects the crystallization and melting temperatures of the matrix. Dielectric spectroscopy revealed that at fixed filler content the dielectric constant of the blend increases with decreasing of the particle size (increasing of the activation time). A similar trend was observed for the storage moduli in dynamic mechanical analysis; the stiffness of the composite was higher when mechanically activated particles were used.
PB  - Amer Inst Physics, Melville
T2  - Journal of Applied Physics
T1  - Ferroelectric nanocomposites of polyvinylidene fluoride/polymethyl methacrylate blend and BaTiO3 particles: Fabrication of beta-crystal polymorph rich matrix through mechanical activation of the filler
IS  - 8
VL  - 115
DO  - 10.1063/1.4866694
ER  - 
@article{
author = "Mofokeng, Tladi G. and Luyt, Adriaan S. and Pavlović, Vera P. and Pavlović, Vladimir and Dudić, Dusko and Vlahović, Branislav and Djoković, Vladimir",
year = "2014",
abstract = "Nanocomposites of polyvinylidene fluoride/polymethyl methacrylate (PVDF/PMMA) blend and mechanically activated barium titanate (BaTiO3) particles were prepared by melt mixing. Modification of filler by means of mechanical activation has a profound effect on the crystallization of PVDF in the blend matrix. Raman analysis showed that the modified BaTiO3 particles, due to higher specific surfaces, induce, predominantly, the crystallization of the electrically active beta-phase of PVDF, while the initial micron size particles induce the formation of the most common but non-polar alpha-crystal form. The introduction of activated particles reduces the overall crystallinity but slightly affects the crystallization and melting temperatures of the matrix. Dielectric spectroscopy revealed that at fixed filler content the dielectric constant of the blend increases with decreasing of the particle size (increasing of the activation time). A similar trend was observed for the storage moduli in dynamic mechanical analysis; the stiffness of the composite was higher when mechanically activated particles were used.",
publisher = "Amer Inst Physics, Melville",
journal = "Journal of Applied Physics",
title = "Ferroelectric nanocomposites of polyvinylidene fluoride/polymethyl methacrylate blend and BaTiO3 particles: Fabrication of beta-crystal polymorph rich matrix through mechanical activation of the filler",
number = "8",
volume = "115",
doi = "10.1063/1.4866694"
}
Mofokeng, T. G., Luyt, A. S., Pavlović, V. P., Pavlović, V., Dudić, D., Vlahović, B.,& Djoković, V.. (2014). Ferroelectric nanocomposites of polyvinylidene fluoride/polymethyl methacrylate blend and BaTiO3 particles: Fabrication of beta-crystal polymorph rich matrix through mechanical activation of the filler. in Journal of Applied Physics
Amer Inst Physics, Melville., 115(8).
https://doi.org/10.1063/1.4866694
Mofokeng TG, Luyt AS, Pavlović VP, Pavlović V, Dudić D, Vlahović B, Djoković V. Ferroelectric nanocomposites of polyvinylidene fluoride/polymethyl methacrylate blend and BaTiO3 particles: Fabrication of beta-crystal polymorph rich matrix through mechanical activation of the filler. in Journal of Applied Physics. 2014;115(8).
doi:10.1063/1.4866694 .
Mofokeng, Tladi G., Luyt, Adriaan S., Pavlović, Vera P., Pavlović, Vladimir, Dudić, Dusko, Vlahović, Branislav, Djoković, Vladimir, "Ferroelectric nanocomposites of polyvinylidene fluoride/polymethyl methacrylate blend and BaTiO3 particles: Fabrication of beta-crystal polymorph rich matrix through mechanical activation of the filler" in Journal of Applied Physics, 115, no. 8 (2014),
https://doi.org/10.1063/1.4866694 . .
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Structural properties of composites of polyvinylidene fluoride and mechanically activated BaTiO3 particles

Pavlović, Vera P.; Pavlović, Vladimir; Vlahović, Branislav; Božanić, D.K.; Pajović, Jelena D.; Dojčilović, Radovan; Djoković, Vladimir

(IOP Publishing Ltd, Bristol, 2013)

TY  - CONF
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir
AU  - Vlahović, Branislav
AU  - Božanić, D.K.
AU  - Pajović, Jelena D.
AU  - Dojčilović, Radovan
AU  - Djoković, Vladimir
PY  - 2013
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3112
AB  - Nanocomposites of electroactive ceramics and ferroelectric polymers exploit favorable features of the matrix polymer and the nanostructured filler to produce new functional materials for pressure and IR sensors. In this study, the influence of mechanical activation of barium titanate (BaTiO3) particles on the structural properties of BaTiO3/polyvinylidene fluoride (PVDF) nanocomposites was investigated. Nanocomposite films were prepared by the solution casting method and characterized by scanning electron microscopy, x-ray diffraction and Raman spectroscopy. It was found that mechanically activated fillers promote the formation of a ferroelectric beta-phase during crystallization of PVDF.
PB  - IOP Publishing Ltd, Bristol
C3  - Physica Scripta
T1  - Structural properties of composites of polyvinylidene fluoride and mechanically activated BaTiO3 particles
VL  - T157
DO  - 10.1088/0031-8949/2013/T157/014006
ER  - 
@conference{
author = "Pavlović, Vera P. and Pavlović, Vladimir and Vlahović, Branislav and Božanić, D.K. and Pajović, Jelena D. and Dojčilović, Radovan and Djoković, Vladimir",
year = "2013",
abstract = "Nanocomposites of electroactive ceramics and ferroelectric polymers exploit favorable features of the matrix polymer and the nanostructured filler to produce new functional materials for pressure and IR sensors. In this study, the influence of mechanical activation of barium titanate (BaTiO3) particles on the structural properties of BaTiO3/polyvinylidene fluoride (PVDF) nanocomposites was investigated. Nanocomposite films were prepared by the solution casting method and characterized by scanning electron microscopy, x-ray diffraction and Raman spectroscopy. It was found that mechanically activated fillers promote the formation of a ferroelectric beta-phase during crystallization of PVDF.",
publisher = "IOP Publishing Ltd, Bristol",
journal = "Physica Scripta",
title = "Structural properties of composites of polyvinylidene fluoride and mechanically activated BaTiO3 particles",
volume = "T157",
doi = "10.1088/0031-8949/2013/T157/014006"
}
Pavlović, V. P., Pavlović, V., Vlahović, B., Božanić, D.K., Pajović, J. D., Dojčilović, R.,& Djoković, V.. (2013). Structural properties of composites of polyvinylidene fluoride and mechanically activated BaTiO3 particles. in Physica Scripta
IOP Publishing Ltd, Bristol., T157.
https://doi.org/10.1088/0031-8949/2013/T157/014006
Pavlović VP, Pavlović V, Vlahović B, Božanić D, Pajović JD, Dojčilović R, Djoković V. Structural properties of composites of polyvinylidene fluoride and mechanically activated BaTiO3 particles. in Physica Scripta. 2013;T157.
doi:10.1088/0031-8949/2013/T157/014006 .
Pavlović, Vera P., Pavlović, Vladimir, Vlahović, Branislav, Božanić, D.K., Pajović, Jelena D., Dojčilović, Radovan, Djoković, Vladimir, "Structural properties of composites of polyvinylidene fluoride and mechanically activated BaTiO3 particles" in Physica Scripta, T157 (2013),
https://doi.org/10.1088/0031-8949/2013/T157/014006 . .
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