Andjelković, Katarina

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  • Andjelković, Katarina (1)
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Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin

Filipović, Nenad; Bacchi, Alessia; Pelizzi, Giancarlo; Marković, R; Mitić, Dragana; Andjelković, Katarina

(Taylor & Francis Ltd, Abingdon, 2005)

TY  - JOUR
AU  - Filipović, Nenad
AU  - Bacchi, Alessia
AU  - Pelizzi, Giancarlo
AU  - Marković, R
AU  - Mitić, Dragana
AU  - Andjelković, Katarina
PY  - 2005
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/1006
AB  - Four Co(III), Zn(II), Pd(II) and Cd(II) complexes with ligands derived in situ from acetylpyridine and ethyl hydrazinoacetate or hydrolysed ethyl hydrazinoacetate were prepared. An X-ray structural analysis showed that the Co(III) complex is octahedral with two tridentate (E)-2-[N'-(1-pyridin-2-yl-ethylidene) hydrazino] acetate (apha) ligands, each forming two five-membered rings with the metal ion. In the tetrahedral Zn(II) complex, only a single apha ligand was coordinated, in the same way as that in the Co(III) complex. In the case of the tetrahedral Cd(II) complex the non-hydrolysed form of (E)-2-[N'-(1-pyridin2-yl-ethylidene)hydrazino]acetic acid ethyl ester (aphaoet) coordinated as a bidentate and the two remaining coordination sites were occupied by Cl- and CH3COO- ions. In addition, the square-planar neutral Pd(II) complex was synthesized, having the same bidentate as in the Cd(II) complex and two Cl- ions in the remaining coordination sites. Due to their being diamagnetic, all four complexes were characterized by H-1-NMR and C-13-NMR spectroscopy.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin
EP  - 1550
IS  - 17
SP  - 1541
VL  - 58
DO  - 10.1080/00958970500240383
ER  - 
@article{
author = "Filipović, Nenad and Bacchi, Alessia and Pelizzi, Giancarlo and Marković, R and Mitić, Dragana and Andjelković, Katarina",
year = "2005",
abstract = "Four Co(III), Zn(II), Pd(II) and Cd(II) complexes with ligands derived in situ from acetylpyridine and ethyl hydrazinoacetate or hydrolysed ethyl hydrazinoacetate were prepared. An X-ray structural analysis showed that the Co(III) complex is octahedral with two tridentate (E)-2-[N'-(1-pyridin-2-yl-ethylidene) hydrazino] acetate (apha) ligands, each forming two five-membered rings with the metal ion. In the tetrahedral Zn(II) complex, only a single apha ligand was coordinated, in the same way as that in the Co(III) complex. In the case of the tetrahedral Cd(II) complex the non-hydrolysed form of (E)-2-[N'-(1-pyridin2-yl-ethylidene)hydrazino]acetic acid ethyl ester (aphaoet) coordinated as a bidentate and the two remaining coordination sites were occupied by Cl- and CH3COO- ions. In addition, the square-planar neutral Pd(II) complex was synthesized, having the same bidentate as in the Cd(II) complex and two Cl- ions in the remaining coordination sites. Due to their being diamagnetic, all four complexes were characterized by H-1-NMR and C-13-NMR spectroscopy.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin",
pages = "1550-1541",
number = "17",
volume = "58",
doi = "10.1080/00958970500240383"
}
Filipović, N., Bacchi, A., Pelizzi, G., Marković, R., Mitić, D.,& Andjelković, K.. (2005). Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 58(17), 1541-1550.
https://doi.org/10.1080/00958970500240383
Filipović N, Bacchi A, Pelizzi G, Marković R, Mitić D, Andjelković K. Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin. in Journal of Coordination Chemistry. 2005;58(17):1541-1550.
doi:10.1080/00958970500240383 .
Filipović, Nenad, Bacchi, Alessia, Pelizzi, Giancarlo, Marković, R, Mitić, Dragana, Andjelković, Katarina, "Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin" in Journal of Coordination Chemistry, 58, no. 17 (2005):1541-1550,
https://doi.org/10.1080/00958970500240383 . .
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