Kaluđerović, Lazar

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Authority KeyName Variants
orcid::0000-0001-5747-6892
  • Kaluđerović, Lazar (17)
  • Kaludjerović, Lazar (13)
Projects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture) Minerals of Serbia: composition, genesis, application and contribution to the environmental sustainability
Studying climate change and its influence on environment: impacts, adaptation and mitigation Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200214 (Institue of Pesticides and Environmental Protection, Belgrade)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200088 (University of Kragujevac, Faculty of Agronomy, Čačak)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200126 (University of Belgrade, Faculty of Mining and Geology) Improvement and development of hygienic and technological procedures in production of animal originating foodstuffs with the aim of producing high-quality and safe products competetive on the global market
Studies on plant pathogens, arthropods, weeds, and pesticides with a view to developing the methods of biorational plant protection and safe food production Advancing research in agricultural and food sciences at Faculty of Agriculture, University of Belgrade
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Development of technologies and products based on mineral raw materials and waste biomass for protection of natural resources for safe food production
Utilization of plant sources of protein, dietary fiber and antioxidants in food production OI 176010

Author's Bibliography

Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes

Marković, Goran; Kostić, Aleksandar Ž; Pantelić, Nebojša Đ; Maletić, Radojka; Štrbački, Jana; Cakić, Jovan; Kaluđerović, Lazar; Dojčinović, Biljana P.; Giuffrè, Angelo Maria; Popović-Djordjević, Jelena B.

(2023)

TY  - JOUR
AU  - Marković, Goran
AU  - Kostić, Aleksandar Ž
AU  - Pantelić, Nebojša Đ
AU  - Maletić, Radojka
AU  - Štrbački, Jana
AU  - Cakić, Jovan
AU  - Kaluđerović, Lazar
AU  - Dojčinović, Biljana P.
AU  - Giuffrè, Angelo Maria
AU  - Popović-Djordjević, Jelena B.
PY  - 2023
UR  - http://www.ncbi.nlm.nih.gov/pubmed/37733141
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6433
AB  - Lakes and reservoirs are the main water resources for household, irrigation, and industrial use. Hence, it is necessary to control water pollution and have reliable information on water quality, which refers to its suitability for a particular purpose. The main objective of this study was to evaluate the suitability of water for drinking and irrigation purposes from ten artificial lakes on the territory of the Republic of Serbia. The physicochemical parameters were determined using standard analytical methods, whereas the optical emission spectrometry with inductively coupled plasma, ICP-OES, was used to determine the concentrations of 23 macro-, micro-, and trace elements in water. Health risk indices of drinking water and its suitability for irrigation purposes were evaluated. The results of physicochemical parameters, except for total organic matter, indicated that most samples were within the recommended values. Among analyzed elements, the concentration of Mg was elevated in the water of the lakes Srebrno and Prvonek. The results of health risk assessment clearly showed that there was no acute health risk (HQA < 1), whereas long-term risk (HQL) in the studied lakes was observed with respect to As (lakes Grlište and Srebrno), Mn (lakes Srebrno and Prvonek), Ni (Lake Vrutci), and Sr (Lake Grlište). The irrigation criteria indicated that the water from the examined lakes had satisfactory quality for this purpose, except for residual sodium carbonates (RSC). This criterion indicated low quality or unsuitability of the water in 7 lakes. The main outcomes provided valuable information on the suitability of water from the artificial lakes for intended uses.
T2  - Environmental Monitoring and Assessment
T2  - Environmental Monitoring and AssessmentEnviron Monit Assess
T1  - Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes
IS  - 10
SP  - 1237
VL  - 195
DO  - 10.1007/s10661-023-11740-6
ER  - 
@article{
author = "Marković, Goran and Kostić, Aleksandar Ž and Pantelić, Nebojša Đ and Maletić, Radojka and Štrbački, Jana and Cakić, Jovan and Kaluđerović, Lazar and Dojčinović, Biljana P. and Giuffrè, Angelo Maria and Popović-Djordjević, Jelena B.",
year = "2023",
abstract = "Lakes and reservoirs are the main water resources for household, irrigation, and industrial use. Hence, it is necessary to control water pollution and have reliable information on water quality, which refers to its suitability for a particular purpose. The main objective of this study was to evaluate the suitability of water for drinking and irrigation purposes from ten artificial lakes on the territory of the Republic of Serbia. The physicochemical parameters were determined using standard analytical methods, whereas the optical emission spectrometry with inductively coupled plasma, ICP-OES, was used to determine the concentrations of 23 macro-, micro-, and trace elements in water. Health risk indices of drinking water and its suitability for irrigation purposes were evaluated. The results of physicochemical parameters, except for total organic matter, indicated that most samples were within the recommended values. Among analyzed elements, the concentration of Mg was elevated in the water of the lakes Srebrno and Prvonek. The results of health risk assessment clearly showed that there was no acute health risk (HQA < 1), whereas long-term risk (HQL) in the studied lakes was observed with respect to As (lakes Grlište and Srebrno), Mn (lakes Srebrno and Prvonek), Ni (Lake Vrutci), and Sr (Lake Grlište). The irrigation criteria indicated that the water from the examined lakes had satisfactory quality for this purpose, except for residual sodium carbonates (RSC). This criterion indicated low quality or unsuitability of the water in 7 lakes. The main outcomes provided valuable information on the suitability of water from the artificial lakes for intended uses.",
journal = "Environmental Monitoring and Assessment, Environmental Monitoring and AssessmentEnviron Monit Assess",
title = "Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes",
number = "10",
pages = "1237",
volume = "195",
doi = "10.1007/s10661-023-11740-6"
}
Marković, G., Kostić, A. Ž., Pantelić, N. Đ., Maletić, R., Štrbački, J., Cakić, J., Kaluđerović, L., Dojčinović, B. P., Giuffrè, A. M.,& Popović-Djordjević, J. B.. (2023). Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes. in Environmental Monitoring and Assessment, 195(10), 1237.
https://doi.org/10.1007/s10661-023-11740-6
Marković G, Kostić AŽ, Pantelić NĐ, Maletić R, Štrbački J, Cakić J, Kaluđerović L, Dojčinović BP, Giuffrè AM, Popović-Djordjević JB. Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes. in Environmental Monitoring and Assessment. 2023;195(10):1237.
doi:10.1007/s10661-023-11740-6 .
Marković, Goran, Kostić, Aleksandar Ž, Pantelić, Nebojša Đ, Maletić, Radojka, Štrbački, Jana, Cakić, Jovan, Kaluđerović, Lazar, Dojčinović, Biljana P., Giuffrè, Angelo Maria, Popović-Djordjević, Jelena B., "Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes" in Environmental Monitoring and Assessment, 195, no. 10 (2023):1237,
https://doi.org/10.1007/s10661-023-11740-6 . .
1

Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes

Marković, Goran; Kostić, Aleksandar Ž; Pantelić, Nebojša Đ; Maletić, Radojka; Štrbački, Jana; Cakić, Jovan; Kaluđerović, Lazar; Dojčinović, Biljana P.; Giuffrè, Angelo Maria; Popović-Djordjević, Jelena B.

(2023)

TY  - JOUR
AU  - Marković, Goran
AU  - Kostić, Aleksandar Ž
AU  - Pantelić, Nebojša Đ
AU  - Maletić, Radojka
AU  - Štrbački, Jana
AU  - Cakić, Jovan
AU  - Kaluđerović, Lazar
AU  - Dojčinović, Biljana P.
AU  - Giuffrè, Angelo Maria
AU  - Popović-Djordjević, Jelena B.
PY  - 2023
UR  - http://www.ncbi.nlm.nih.gov/pubmed/37733141
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6459
AB  - Lakes and reservoirs are the main water resources for household, irrigation, and industrial use. Hence, it is necessary to control water pollution and have reliable information on water quality, which refers to its suitability for a particular purpose. The main objective of this study was to evaluate the suitability of water for drinking and irrigation purposes from ten artificial lakes on the territory of the Republic of Serbia. The physicochemical parameters were determined using standard analytical methods, whereas the optical emission spectrometry with inductively coupled plasma, ICP-OES, was used to determine the concentrations of 23 macro-, micro-, and trace elements in water. Health risk indices of drinking water and its suitability for irrigation purposes were evaluated. The results of physicochemical parameters, except for total organic matter, indicated that most samples were within the recommended values. Among analyzed elements, the concentration of Mg was elevated in the water of the lakes Srebrno and Prvonek. The results of health risk assessment clearly showed that there was no acute health risk (HQA < 1), whereas long-term risk (HQL) in the studied lakes was observed with respect to As (lakes Grlište and Srebrno), Mn (lakes Srebrno and Prvonek), Ni (Lake Vrutci), and Sr (Lake Grlište). The irrigation criteria indicated that the water from the examined lakes had satisfactory quality for this purpose, except for residual sodium carbonates (RSC). This criterion indicated low quality or unsuitability of the water in 7 lakes. The main outcomes provided valuable information on the suitability of water from the artificial lakes for intended uses.
T2  - Environmental Monitoring and Assessment
T2  - Environmental Monitoring and AssessmentEnviron Monit Assess
T1  - Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes
IS  - 10
SP  - 1237
VL  - 195
DO  - 10.1007/s10661-023-11740-6
ER  - 
@article{
author = "Marković, Goran and Kostić, Aleksandar Ž and Pantelić, Nebojša Đ and Maletić, Radojka and Štrbački, Jana and Cakić, Jovan and Kaluđerović, Lazar and Dojčinović, Biljana P. and Giuffrè, Angelo Maria and Popović-Djordjević, Jelena B.",
year = "2023",
abstract = "Lakes and reservoirs are the main water resources for household, irrigation, and industrial use. Hence, it is necessary to control water pollution and have reliable information on water quality, which refers to its suitability for a particular purpose. The main objective of this study was to evaluate the suitability of water for drinking and irrigation purposes from ten artificial lakes on the territory of the Republic of Serbia. The physicochemical parameters were determined using standard analytical methods, whereas the optical emission spectrometry with inductively coupled plasma, ICP-OES, was used to determine the concentrations of 23 macro-, micro-, and trace elements in water. Health risk indices of drinking water and its suitability for irrigation purposes were evaluated. The results of physicochemical parameters, except for total organic matter, indicated that most samples were within the recommended values. Among analyzed elements, the concentration of Mg was elevated in the water of the lakes Srebrno and Prvonek. The results of health risk assessment clearly showed that there was no acute health risk (HQA < 1), whereas long-term risk (HQL) in the studied lakes was observed with respect to As (lakes Grlište and Srebrno), Mn (lakes Srebrno and Prvonek), Ni (Lake Vrutci), and Sr (Lake Grlište). The irrigation criteria indicated that the water from the examined lakes had satisfactory quality for this purpose, except for residual sodium carbonates (RSC). This criterion indicated low quality or unsuitability of the water in 7 lakes. The main outcomes provided valuable information on the suitability of water from the artificial lakes for intended uses.",
journal = "Environmental Monitoring and Assessment, Environmental Monitoring and AssessmentEnviron Monit Assess",
title = "Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes",
number = "10",
pages = "1237",
volume = "195",
doi = "10.1007/s10661-023-11740-6"
}
Marković, G., Kostić, A. Ž., Pantelić, N. Đ., Maletić, R., Štrbački, J., Cakić, J., Kaluđerović, L., Dojčinović, B. P., Giuffrè, A. M.,& Popović-Djordjević, J. B.. (2023). Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes. in Environmental Monitoring and Assessment, 195(10), 1237.
https://doi.org/10.1007/s10661-023-11740-6
Marković G, Kostić AŽ, Pantelić NĐ, Maletić R, Štrbački J, Cakić J, Kaluđerović L, Dojčinović BP, Giuffrè AM, Popović-Djordjević JB. Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes. in Environmental Monitoring and Assessment. 2023;195(10):1237.
doi:10.1007/s10661-023-11740-6 .
Marković, Goran, Kostić, Aleksandar Ž, Pantelić, Nebojša Đ, Maletić, Radojka, Štrbački, Jana, Cakić, Jovan, Kaluđerović, Lazar, Dojčinović, Biljana P., Giuffrè, Angelo Maria, Popović-Djordjević, Jelena B., "Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes" in Environmental Monitoring and Assessment, 195, no. 10 (2023):1237,
https://doi.org/10.1007/s10661-023-11740-6 . .
1

Geochemical origin of Ni and Cr in ranker-type soils formed on serpentinites massifs in Serbia

Djordjević, Aleksandar; Grujic, Gordana; Kaluđerović, Lazar; Bogosavljević, Jelena; Đorđević, Snežana

(Society for Environmental Geochemistry and Health, 2023)

TY  - CONF
AU  - Djordjević, Aleksandar
AU  - Grujic, Gordana
AU  - Kaluđerović, Lazar
AU  - Bogosavljević, Jelena
AU  - Đorđević, Snežana
PY  - 2023
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6767
AB  - The paper presents the results of research on the content of accessible forms of Ni and Cr in the ranker-type soils that are formed on the serpentinites massifs in Serbia. Soil samples were taken from seven 
different locations across Serbia (Zlatibor mountain, Kopaonik mountain, Miroč, Maljen mountain, 
Bukovi, Suvobor and Bubanj Potok) at the altitude range between 100 and 1700 m. There were 
analyzed 46 soil samples in total. The concentration of accessible forms of Ni and Cr was determined 
by extraction in a solution of DTPA-TEA (pH 7.3, ratio soil and solution = 1:2) by optical emission 
spectroscopy with induced coupled plasma (ICP-OES).
The content of accessible Ni in the all examined soil samples of ranker-type soils varies from 68 - 920 
mg/kg, while the most common results (about 70% of the total number of samples) vary from 200 -
600 mg/kg. The content of accessible Cr in all examined soils varies from 16 - 216 mg/kg. The content 
of both, Ni and Cr significantly exceeds the value limits in soils. 
The results of the analysis of all soil samples of ranker-type soils refer to high concentration of 
accessible Ni and Cr and thus correspond to phytotoxic concentrations.
Given the fact that there are no anthropogenic sources of pollution nearby the investigation locations, 
it can be concluded that such a high concentration of accessible Ni and Cr in the ranker-type soils, that 
were formed on serpentinites massifs under the various pedogenetic conditions, is of geochemical 
origin. The geochemical distribution of Ni and Cr places this type of soil in the group of lithogenic soils.
PB  - Society for Environmental Geochemistry and Health
C3  - 38th International Conference on Geochemistry and Health SEGH2023, Athens, Greece
T1  - Geochemical origin of Ni and Cr in ranker-type soils formed on serpentinites  massifs in Serbia
EP  - 111
SP  - 111
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6767
ER  - 
@conference{
author = "Djordjević, Aleksandar and Grujic, Gordana and Kaluđerović, Lazar and Bogosavljević, Jelena and Đorđević, Snežana",
year = "2023",
abstract = "The paper presents the results of research on the content of accessible forms of Ni and Cr in the ranker-type soils that are formed on the serpentinites massifs in Serbia. Soil samples were taken from seven 
different locations across Serbia (Zlatibor mountain, Kopaonik mountain, Miroč, Maljen mountain, 
Bukovi, Suvobor and Bubanj Potok) at the altitude range between 100 and 1700 m. There were 
analyzed 46 soil samples in total. The concentration of accessible forms of Ni and Cr was determined 
by extraction in a solution of DTPA-TEA (pH 7.3, ratio soil and solution = 1:2) by optical emission 
spectroscopy with induced coupled plasma (ICP-OES).
The content of accessible Ni in the all examined soil samples of ranker-type soils varies from 68 - 920 
mg/kg, while the most common results (about 70% of the total number of samples) vary from 200 -
600 mg/kg. The content of accessible Cr in all examined soils varies from 16 - 216 mg/kg. The content 
of both, Ni and Cr significantly exceeds the value limits in soils. 
The results of the analysis of all soil samples of ranker-type soils refer to high concentration of 
accessible Ni and Cr and thus correspond to phytotoxic concentrations.
Given the fact that there are no anthropogenic sources of pollution nearby the investigation locations, 
it can be concluded that such a high concentration of accessible Ni and Cr in the ranker-type soils, that 
were formed on serpentinites massifs under the various pedogenetic conditions, is of geochemical 
origin. The geochemical distribution of Ni and Cr places this type of soil in the group of lithogenic soils.",
publisher = "Society for Environmental Geochemistry and Health",
journal = "38th International Conference on Geochemistry and Health SEGH2023, Athens, Greece",
title = "Geochemical origin of Ni and Cr in ranker-type soils formed on serpentinites  massifs in Serbia",
pages = "111-111",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6767"
}
Djordjević, A., Grujic, G., Kaluđerović, L., Bogosavljević, J.,& Đorđević, S.. (2023). Geochemical origin of Ni and Cr in ranker-type soils formed on serpentinites  massifs in Serbia. in 38th International Conference on Geochemistry and Health SEGH2023, Athens, Greece
Society for Environmental Geochemistry and Health., 111-111.
https://hdl.handle.net/21.15107/rcub_agrospace_6767
Djordjević A, Grujic G, Kaluđerović L, Bogosavljević J, Đorđević S. Geochemical origin of Ni and Cr in ranker-type soils formed on serpentinites  massifs in Serbia. in 38th International Conference on Geochemistry and Health SEGH2023, Athens, Greece. 2023;:111-111.
https://hdl.handle.net/21.15107/rcub_agrospace_6767 .
Djordjević, Aleksandar, Grujic, Gordana, Kaluđerović, Lazar, Bogosavljević, Jelena, Đorđević, Snežana, "Geochemical origin of Ni and Cr in ranker-type soils formed on serpentinites  massifs in Serbia" in 38th International Conference on Geochemistry and Health SEGH2023, Athens, Greece (2023):111-111,
https://hdl.handle.net/21.15107/rcub_agrospace_6767 .

Potencijal huminskih kiselina i glina u remedijaciji životne sredine kontaminirane klomazonom

Đurović-Pejčev, Rada; Kaluđerović, Lazar; Šantrić, Ljiljana; Đorđević, Tijana; Radmanović, Svjetlana

(Srpsko hemijsko društvo/Serbian Chemical Society, 2023)

TY  - CONF
AU  - Đurović-Pejčev, Rada
AU  - Kaluđerović, Lazar
AU  - Šantrić, Ljiljana
AU  - Đorđević, Tijana
AU  - Radmanović, Svjetlana
PY  - 2023
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6686
AB  - Klomazon (IUPAC: 2-(2-hlorobenzil)-4,4-dimetil-1,2-oksazolidin-3-on) je selektivni
herbicid iz grupe izoksazolidinona, koji se na osnovu svojih fizičko-hemijskih karakteristika
može svrstati u grupu pesticida koji predstavljaju potencijalne kontaminante površinskih
voda, dubljih slojeva zemljišta i podzemnih voda.
Glina i organska materija, pre svega huminske kiseline (HA), su glavne sorbujuće
komponente zemljišta. Literaturni podaci ukazuju da u sorpciji klomazona u zemljištu
učestvuje ili organska materija [1-3]ili glina i organska materija [4,5]. S toga je cilj ovog
radabio ispitati potencijal HA i glina izdvojenih iz različitih tipova poljoprivrednog zemljišta
sa područja Republike Srbije (rendzina, černozem i smonica) u sorpciji klomazona, odnosno
odrediti njihov remedijacioni potencijal.
Za proučavanje sorpcionog ponašanja klomazona i određivanje njegovih sorpcionih
konstanti (Kd) za pomenute supstrate je korišćen batch metod [6], zasnovan na ravnotežnoj
raspodeli molekula klomazona u sistemu supstrat/vodena faza. U slučaju HA, sistem se
sastojao od smeše 25 mg supstratai 2,5 mL rastvora određene koncentracije (0,5 – 25
g/mL)klomazona u 0,01 M CaCl2, dok je u slučaju glina sistem sadržao 250 mg gline i 2
mL pomenutih rastvora. Svaka smeša je homogenizovana 24 h radi dostizanja ravnotežne
raspodele ovog jedinjenja između dve faze sistema. Nakon centrifugiranja, vodena faza je
analizirana HPLC-om opremljenim sa PDA detektorom, pri čemu su Kd koeficijenti
klomazona za proučavane supstrate računati kao odnos koncentracije pesticida koja je
sorbovana za supstrat (Cs) i koncentracije jedinjenja koja je zaostala u vodenoj fazi (Ce), u
uslovima ravnotežne raspodele. Adsorpcione izoterme su dobijene primenom Frojndlihove
jednačine na eksperimentalno dobijene rezultate, pri čemu su Frojndlihovi koeficijenti Kf i
n, dobijeni primenom linearne forme Frojdlihove jednačine.
Dobijeni rezultati ukazuju da je sorpcija klomazona mnogo veća za HA nego za gline,
i da opada u sledećem nizu: HA, rendzina (Kd=114,02 mL/g) >HA, smonica
(Kd=97,71 mL/g) >HA, černozem (Kd=91,24 mL/g)>> glina, smonica (Kd=2,29 mL/g)>
glina, černozem (Kd=2,16 mL/g)>glina, rendzina(Kd=1,61 mL/g).
Da je sorpcija klomazona za HA znatno veća nego za gline, ukazuju i vrednosti
Frojndlihovih Kf koeficijenata, koji za pomenute supstrate imaju sledeće vrednosti:
Kf=188,63 (HA, rendzina), Kf=170,61 (HA, smonica), Kf=167,19 (HA, černozem), Kf=1,80
(glina, černozem), Kf=1,10 (glina, rendzina) i Kf=0,98 (glina, smonica). Dobijene vrednosti
Frojndlihovih 1/n koeficijenata ukazuju da su izoterme dobijene za sve analizirane HA Ltpa (0,767, 0,698 i 0,708 za HA poreklom iz zemljišta tipa rendzina, černozem i smonica,
redom), što ukazuje na snažnu sorpciju molekula klomazona za sorpcione centre analiziranih
HA pri nižim koncentracijama pesticida, pri čemu ona opada kako koncentracija jedinjenja
raste. Sa druge strane, izoterme dobijene za gline poreklom iz rendzine i smonice (1/n=1,146
i 1,342, redom) su tzv. S-tipa, što ukazuje na slabiju adsorpciju klomazona za sorpcione
centre supstrata pri nižim koncentracijama pesticida u sistemu, nakon čega se sorpcija
pojačava, da bi pri većim količinama pesticida u sistemu, ona opet počela da se smanjuje
(postepena saturacija sorpcionih centara supstrata). Izoterma dobijena za glinu izdvojenu iz
zemljišta tipa černozem (1/n=1,074) je C-tipa i karakteriše je linearna zavisnost između
sorbovane količine klomazona i količine ovog pesticida koja zaostaje u rastvoru u sistemu
glina/voda.
Prikazani rezultati ukazuju da HA imaju dobar sorpcioni potencijal za klomazon,
odnosno da se mogu koristiti za remedijaciju zemljišta i različitih vodenih sistema
kontaminiranim klomazonom. Dodatne FTIR analize treba da pokažu koje funkcionalne
grupe HA i glina su odgovorne za vezivanje molekula klomazona i samim tim objasne
razlike u veličini sorpcije između različitih HA i glina poreklom iz različitih zemljišta.
PB  - Srpsko hemijsko društvo/Serbian Chemical Society
C3  - 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with international participation, Kladovo, Serbia
T1  - Potencijal huminskih kiselina i glina u remedijaciji životne sredine kontaminirane klomazonom
T1  - Potential of humic acids and clays in the remediation of clomazonecontaminated environment
EP  - 72
EP  - 72
SP  - 71
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6686
ER  - 
@conference{
author = "Đurović-Pejčev, Rada and Kaluđerović, Lazar and Šantrić, Ljiljana and Đorđević, Tijana and Radmanović, Svjetlana",
year = "2023",
abstract = "Klomazon (IUPAC: 2-(2-hlorobenzil)-4,4-dimetil-1,2-oksazolidin-3-on) je selektivni
herbicid iz grupe izoksazolidinona, koji se na osnovu svojih fizičko-hemijskih karakteristika
može svrstati u grupu pesticida koji predstavljaju potencijalne kontaminante površinskih
voda, dubljih slojeva zemljišta i podzemnih voda.
Glina i organska materija, pre svega huminske kiseline (HA), su glavne sorbujuće
komponente zemljišta. Literaturni podaci ukazuju da u sorpciji klomazona u zemljištu
učestvuje ili organska materija [1-3]ili glina i organska materija [4,5]. S toga je cilj ovog
radabio ispitati potencijal HA i glina izdvojenih iz različitih tipova poljoprivrednog zemljišta
sa područja Republike Srbije (rendzina, černozem i smonica) u sorpciji klomazona, odnosno
odrediti njihov remedijacioni potencijal.
Za proučavanje sorpcionog ponašanja klomazona i određivanje njegovih sorpcionih
konstanti (Kd) za pomenute supstrate je korišćen batch metod [6], zasnovan na ravnotežnoj
raspodeli molekula klomazona u sistemu supstrat/vodena faza. U slučaju HA, sistem se
sastojao od smeše 25 mg supstratai 2,5 mL rastvora određene koncentracije (0,5 – 25
g/mL)klomazona u 0,01 M CaCl2, dok je u slučaju glina sistem sadržao 250 mg gline i 2
mL pomenutih rastvora. Svaka smeša je homogenizovana 24 h radi dostizanja ravnotežne
raspodele ovog jedinjenja između dve faze sistema. Nakon centrifugiranja, vodena faza je
analizirana HPLC-om opremljenim sa PDA detektorom, pri čemu su Kd koeficijenti
klomazona za proučavane supstrate računati kao odnos koncentracije pesticida koja je
sorbovana za supstrat (Cs) i koncentracije jedinjenja koja je zaostala u vodenoj fazi (Ce), u
uslovima ravnotežne raspodele. Adsorpcione izoterme su dobijene primenom Frojndlihove
jednačine na eksperimentalno dobijene rezultate, pri čemu su Frojndlihovi koeficijenti Kf i
n, dobijeni primenom linearne forme Frojdlihove jednačine.
Dobijeni rezultati ukazuju da je sorpcija klomazona mnogo veća za HA nego za gline,
i da opada u sledećem nizu: HA, rendzina (Kd=114,02 mL/g) >HA, smonica
(Kd=97,71 mL/g) >HA, černozem (Kd=91,24 mL/g)>> glina, smonica (Kd=2,29 mL/g)>
glina, černozem (Kd=2,16 mL/g)>glina, rendzina(Kd=1,61 mL/g).
Da je sorpcija klomazona za HA znatno veća nego za gline, ukazuju i vrednosti
Frojndlihovih Kf koeficijenata, koji za pomenute supstrate imaju sledeće vrednosti:
Kf=188,63 (HA, rendzina), Kf=170,61 (HA, smonica), Kf=167,19 (HA, černozem), Kf=1,80
(glina, černozem), Kf=1,10 (glina, rendzina) i Kf=0,98 (glina, smonica). Dobijene vrednosti
Frojndlihovih 1/n koeficijenata ukazuju da su izoterme dobijene za sve analizirane HA Ltpa (0,767, 0,698 i 0,708 za HA poreklom iz zemljišta tipa rendzina, černozem i smonica,
redom), što ukazuje na snažnu sorpciju molekula klomazona za sorpcione centre analiziranih
HA pri nižim koncentracijama pesticida, pri čemu ona opada kako koncentracija jedinjenja
raste. Sa druge strane, izoterme dobijene za gline poreklom iz rendzine i smonice (1/n=1,146
i 1,342, redom) su tzv. S-tipa, što ukazuje na slabiju adsorpciju klomazona za sorpcione
centre supstrata pri nižim koncentracijama pesticida u sistemu, nakon čega se sorpcija
pojačava, da bi pri većim količinama pesticida u sistemu, ona opet počela da se smanjuje
(postepena saturacija sorpcionih centara supstrata). Izoterma dobijena za glinu izdvojenu iz
zemljišta tipa černozem (1/n=1,074) je C-tipa i karakteriše je linearna zavisnost između
sorbovane količine klomazona i količine ovog pesticida koja zaostaje u rastvoru u sistemu
glina/voda.
Prikazani rezultati ukazuju da HA imaju dobar sorpcioni potencijal za klomazon,
odnosno da se mogu koristiti za remedijaciju zemljišta i različitih vodenih sistema
kontaminiranim klomazonom. Dodatne FTIR analize treba da pokažu koje funkcionalne
grupe HA i glina su odgovorne za vezivanje molekula klomazona i samim tim objasne
razlike u veličini sorpcije između različitih HA i glina poreklom iz različitih zemljišta.",
publisher = "Srpsko hemijsko društvo/Serbian Chemical Society",
journal = "9th Symposium Chemistry and Environmental Protection EnviroChem2023 with international participation, Kladovo, Serbia",
title = "Potencijal huminskih kiselina i glina u remedijaciji životne sredine kontaminirane klomazonom, Potential of humic acids and clays in the remediation of clomazonecontaminated environment",
pages = "72-72-71",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6686"
}
Đurović-Pejčev, R., Kaluđerović, L., Šantrić, L., Đorđević, T.,& Radmanović, S.. (2023). Potencijal huminskih kiselina i glina u remedijaciji životne sredine kontaminirane klomazonom. in 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with international participation, Kladovo, Serbia
Srpsko hemijsko društvo/Serbian Chemical Society., 71-72.
https://hdl.handle.net/21.15107/rcub_agrospace_6686
Đurović-Pejčev R, Kaluđerović L, Šantrić L, Đorđević T, Radmanović S. Potencijal huminskih kiselina i glina u remedijaciji životne sredine kontaminirane klomazonom. in 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with international participation, Kladovo, Serbia. 2023;:71-72.
https://hdl.handle.net/21.15107/rcub_agrospace_6686 .
Đurović-Pejčev, Rada, Kaluđerović, Lazar, Šantrić, Ljiljana, Đorđević, Tijana, Radmanović, Svjetlana, "Potencijal huminskih kiselina i glina u remedijaciji životne sredine kontaminirane klomazonom" in 9th Symposium Chemistry and Environmental Protection EnviroChem2023 with international participation, Kladovo, Serbia (2023):71-72,
https://hdl.handle.net/21.15107/rcub_agrospace_6686 .

Characterization of the clomazone sorption process in four agricultural soils using different kinetic models

Ðurović-Pejčev, Rada; Radmanović, Svjetlana; Tomić, Zorica P.; Kaluđerović, Lazar; Đorđević, Tijana

(2023)

TY  - JOUR
AU  - Ðurović-Pejčev, Rada
AU  - Radmanović, Svjetlana
AU  - Tomić, Zorica P.
AU  - Kaluđerović, Lazar
AU  - Đorđević, Tijana
PY  - 2023
UR  - https://pubs.rsc.org/en/content/articlelanding/2023/em/d2em00272h
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6286
AB  - Kinetic studies are important for understanding the parameters and processes involved in the sorption of pesticides to soil. Considering the agricultural and environmental relevance of clomazone, its sorption kinetics was studied in four agricultural soils (Regosol, Planosol, Chernozem and Vertisol) at two concentrations (0.5 and 15 mg L−1). Different kinetic models were applied to the experimental data. The pseudo-second-order model described the data much better than the hyperbolic and pseudo-first-order models, and the kinetic rate constants indicated concentration-dependent clomazone sorption kinetics. The application of the two-site nonequilibrium model (TSNE) revealed a more time-dependent sorption of the lower clomazone concentration than that of the higher clomazone concentration, and the greatest concentration impact occurred in Regosol. Elovich and intraparticle diffusion models predicted more intensive sorption during the slower second phase and that sorption kinetics is governed more by mass transfer across the boundary layer than by a intraparticle diffusion process at higher clomazone concentration. Intraparticle diffusion is the rate-controlling process in Regosol at lower concentration, while this process and the boundary layer control the sorption kinetics in other soils. Significant correlations between some kinetic parameters and soil properties indicate an impact of the soil texture on the clomazone sorption mechanism, which must be considered in assessing the clomazone leaching behavior.
T2  - Environmental Science: Processes & Impacts
T2  - Environmental Science: Processes & ImpactsEnviron. Sci.: Processes Impacts
T1  - Characterization of the clomazone sorption process in four agricultural soils using different kinetic models
DO  - 10.1039/D2EM00272H
ER  - 
@article{
author = "Ðurović-Pejčev, Rada and Radmanović, Svjetlana and Tomić, Zorica P. and Kaluđerović, Lazar and Đorđević, Tijana",
year = "2023",
abstract = "Kinetic studies are important for understanding the parameters and processes involved in the sorption of pesticides to soil. Considering the agricultural and environmental relevance of clomazone, its sorption kinetics was studied in four agricultural soils (Regosol, Planosol, Chernozem and Vertisol) at two concentrations (0.5 and 15 mg L−1). Different kinetic models were applied to the experimental data. The pseudo-second-order model described the data much better than the hyperbolic and pseudo-first-order models, and the kinetic rate constants indicated concentration-dependent clomazone sorption kinetics. The application of the two-site nonequilibrium model (TSNE) revealed a more time-dependent sorption of the lower clomazone concentration than that of the higher clomazone concentration, and the greatest concentration impact occurred in Regosol. Elovich and intraparticle diffusion models predicted more intensive sorption during the slower second phase and that sorption kinetics is governed more by mass transfer across the boundary layer than by a intraparticle diffusion process at higher clomazone concentration. Intraparticle diffusion is the rate-controlling process in Regosol at lower concentration, while this process and the boundary layer control the sorption kinetics in other soils. Significant correlations between some kinetic parameters and soil properties indicate an impact of the soil texture on the clomazone sorption mechanism, which must be considered in assessing the clomazone leaching behavior.",
journal = "Environmental Science: Processes & Impacts, Environmental Science: Processes & ImpactsEnviron. Sci.: Processes Impacts",
title = "Characterization of the clomazone sorption process in four agricultural soils using different kinetic models",
doi = "10.1039/D2EM00272H"
}
Ðurović-Pejčev, R., Radmanović, S., Tomić, Z. P., Kaluđerović, L.,& Đorđević, T.. (2023). Characterization of the clomazone sorption process in four agricultural soils using different kinetic models. in Environmental Science: Processes & Impacts.
https://doi.org/10.1039/D2EM00272H
Ðurović-Pejčev R, Radmanović S, Tomić ZP, Kaluđerović L, Đorđević T. Characterization of the clomazone sorption process in four agricultural soils using different kinetic models. in Environmental Science: Processes & Impacts. 2023;.
doi:10.1039/D2EM00272H .
Ðurović-Pejčev, Rada, Radmanović, Svjetlana, Tomić, Zorica P., Kaluđerović, Lazar, Đorđević, Tijana, "Characterization of the clomazone sorption process in four agricultural soils using different kinetic models" in Environmental Science: Processes & Impacts (2023),
https://doi.org/10.1039/D2EM00272H . .
1

Prostorni prikaz sadržaja organske materije u rendzinama Krnjevačkog Vinogorja, Srbija.

Bogosavljević, Jelena; Nikolić, Nataša; Radmanović, Svjetlana; Branković, Snežana; Kaluđerović, Lazar; Đorđević, Aleksandar

(Poljoprivredni fakultet Novi Sad, 2022)

TY  - CONF
AU  - Bogosavljević, Jelena
AU  - Nikolić, Nataša
AU  - Radmanović, Svjetlana
AU  - Branković, Snežana
AU  - Kaluđerović, Lazar
AU  - Đorđević, Aleksandar
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6575
AB  - UVOD i CILjEVI: Sadržaja organske materije (OM) u zemljištu je bitan faktor pri odabiru
loznih podloga i sorti vinove loze pošto značajno utiče na vegetativni porast i prinos, koji su u
proizvodnji vina kontrolisani, tako da je važno precizno odrediti sadržaj OM pri podizanju i
eksploataciji zasada vinove loze. Cilj ovog istraživanja jeste precizno i prostorno predstavljanje
sadržaja OM u rendzinama na području Krnjevačkog vinogorja. Rendzina je jedno od najpogodnijih
vinogradarskih zemljišta kod nas. Prema zvaničnom sistemu klasifikacije zemljišta Srbije,
rendzina je tip zemljišta sa A – AC – C – R profilom, razvijen na matičnoj steni koja sadrži
više od 20% krečnjačkog materijala (osim zemljišta sa A – R profilom na tvrdom čistom
krečnjaku ili dolomitu). U Svetskoj referentnoj bazi za zemljišne resurse (WRB) rendzine
odgovaraju uglavnom renzičnim leptosolima (Rendzic Leptosols) ili faozemima (Phaeozems).
MATERIJAL i METOD: Krnjevačko vinogorje je deo Šumadijskog vinogradarskog rejona, nalazi
se na brežuljkastim padinama i kosama zapadno od Velike Morave, a severno od Smederevske
Palanke i Velike Plane, prostire se na površini od 11188,22 ha. Istraživanje je sprovedeno u
vinogradu Podruma Radovanović (44°25ʹ57,60ʺ SGŠ; 21°02ʹ40,34ʺ IGD i 44°25ʹ 41,33ʺ SGŠ;
21°02ʹ51,29ʺ IGD), na pet parcela zasađenih različitim sortama vinove loze gde je otvoreno i
opisano 15 pedoloških profila. Uzorci u narušenom stanju su uzeti iz svih genetskih horizonata
od površine do matične stene. Sadržaj organskog ugljenika (OC) određen je dihromatnom metodom
u 54 uzorka zemljišta, a sadržaj OM je proračunat prema formuli OM = OC x 1,72. Prostorni
prikaz sadržaja OM u ispitivanim zemljištima urađen je korišćenjem programa ArcGis 10.0.
REZULTATI i ZAKLjUČCI: Na ispitivanom lokalitetu identifikovana su tri varijeteta
rendzine: karbonatana rendzina, rendzina u ogajnjačavanju i izlužena rendzina. Sadržaj OM u
humusnom horizontu rendzina varirao je u opsegu od 1,18% do 4,17%, sa prosečno vrednošću od
2,55 ± 0,56%. Zemljišta ispitivanog područja su slabo i srednje humusna, što je povoljno s
obzirom na to da se najbolji vinogradraski i vinarski rezultati dobijaju na srednje plodnim
zemljištima koja imaju neka pedološka ograničenja. Idealno vinogradarsko zemljište sadrži 2–
4% OM. Sadržaj OM se pravilno smanjivao po dubini profila, tako da je u C horizontu iznosio od
0,67% do 1,04%, a prosečna vrednost je bila 0,97 ± 0,21%. Relativno visok sadržaj OM u C
horizontu je posledica dubokog prodiranja korenovog sistema vinove loze. Na tematskoj karti koja
prostorno prikazuje sadržaj OM u površinskom horizontu može se uočiti da je najviši sadržaj
OM u zoni gde se vinograd graniči sa šumom, što dovodi do zaključka da je u ovom delu izraženije
nakupljanje OM (u odnosu na preostalu ispitivanu površinu), verovatno kao posledica prirodnog
unošenja organskih ostataka šumske vegetacije. Na osnovu rezultat studije može se zaključiti da
su ispitivana zemljišta prema sadržaju OM pogodna za uzgoj vinove loze. Prostorni prikaz
sadržaja OM omogućava izdvajanje određenih površina za dalje analize kvaliteta grožđa i vina.
PB  - Poljoprivredni fakultet Novi Sad
C3  - Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''
T1  - Prostorni prikaz sadržaja organske materije u rendzinama Krnjevačkog Vinogorja, Srbija.
EP  - 27
SP  - 26
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6575
ER  - 
@conference{
author = "Bogosavljević, Jelena and Nikolić, Nataša and Radmanović, Svjetlana and Branković, Snežana and Kaluđerović, Lazar and Đorđević, Aleksandar",
year = "2022",
abstract = "UVOD i CILjEVI: Sadržaja organske materije (OM) u zemljištu je bitan faktor pri odabiru
loznih podloga i sorti vinove loze pošto značajno utiče na vegetativni porast i prinos, koji su u
proizvodnji vina kontrolisani, tako da je važno precizno odrediti sadržaj OM pri podizanju i
eksploataciji zasada vinove loze. Cilj ovog istraživanja jeste precizno i prostorno predstavljanje
sadržaja OM u rendzinama na području Krnjevačkog vinogorja. Rendzina je jedno od najpogodnijih
vinogradarskih zemljišta kod nas. Prema zvaničnom sistemu klasifikacije zemljišta Srbije,
rendzina je tip zemljišta sa A – AC – C – R profilom, razvijen na matičnoj steni koja sadrži
više od 20% krečnjačkog materijala (osim zemljišta sa A – R profilom na tvrdom čistom
krečnjaku ili dolomitu). U Svetskoj referentnoj bazi za zemljišne resurse (WRB) rendzine
odgovaraju uglavnom renzičnim leptosolima (Rendzic Leptosols) ili faozemima (Phaeozems).
MATERIJAL i METOD: Krnjevačko vinogorje je deo Šumadijskog vinogradarskog rejona, nalazi
se na brežuljkastim padinama i kosama zapadno od Velike Morave, a severno od Smederevske
Palanke i Velike Plane, prostire se na površini od 11188,22 ha. Istraživanje je sprovedeno u
vinogradu Podruma Radovanović (44°25ʹ57,60ʺ SGŠ; 21°02ʹ40,34ʺ IGD i 44°25ʹ 41,33ʺ SGŠ;
21°02ʹ51,29ʺ IGD), na pet parcela zasađenih različitim sortama vinove loze gde je otvoreno i
opisano 15 pedoloških profila. Uzorci u narušenom stanju su uzeti iz svih genetskih horizonata
od površine do matične stene. Sadržaj organskog ugljenika (OC) određen je dihromatnom metodom
u 54 uzorka zemljišta, a sadržaj OM je proračunat prema formuli OM = OC x 1,72. Prostorni
prikaz sadržaja OM u ispitivanim zemljištima urađen je korišćenjem programa ArcGis 10.0.
REZULTATI i ZAKLjUČCI: Na ispitivanom lokalitetu identifikovana su tri varijeteta
rendzine: karbonatana rendzina, rendzina u ogajnjačavanju i izlužena rendzina. Sadržaj OM u
humusnom horizontu rendzina varirao je u opsegu od 1,18% do 4,17%, sa prosečno vrednošću od
2,55 ± 0,56%. Zemljišta ispitivanog područja su slabo i srednje humusna, što je povoljno s
obzirom na to da se najbolji vinogradraski i vinarski rezultati dobijaju na srednje plodnim
zemljištima koja imaju neka pedološka ograničenja. Idealno vinogradarsko zemljište sadrži 2–
4% OM. Sadržaj OM se pravilno smanjivao po dubini profila, tako da je u C horizontu iznosio od
0,67% do 1,04%, a prosečna vrednost je bila 0,97 ± 0,21%. Relativno visok sadržaj OM u C
horizontu je posledica dubokog prodiranja korenovog sistema vinove loze. Na tematskoj karti koja
prostorno prikazuje sadržaj OM u površinskom horizontu može se uočiti da je najviši sadržaj
OM u zoni gde se vinograd graniči sa šumom, što dovodi do zaključka da je u ovom delu izraženije
nakupljanje OM (u odnosu na preostalu ispitivanu površinu), verovatno kao posledica prirodnog
unošenja organskih ostataka šumske vegetacije. Na osnovu rezultat studije može se zaključiti da
su ispitivana zemljišta prema sadržaju OM pogodna za uzgoj vinove loze. Prostorni prikaz
sadržaja OM omogućava izdvajanje određenih površina za dalje analize kvaliteta grožđa i vina.",
publisher = "Poljoprivredni fakultet Novi Sad",
journal = "Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''",
title = "Prostorni prikaz sadržaja organske materije u rendzinama Krnjevačkog Vinogorja, Srbija.",
pages = "27-26",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6575"
}
Bogosavljević, J., Nikolić, N., Radmanović, S., Branković, S., Kaluđerović, L.,& Đorđević, A.. (2022). Prostorni prikaz sadržaja organske materije u rendzinama Krnjevačkog Vinogorja, Srbija.. in Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''
Poljoprivredni fakultet Novi Sad., 26-27.
https://hdl.handle.net/21.15107/rcub_agrospace_6575
Bogosavljević J, Nikolić N, Radmanović S, Branković S, Kaluđerović L, Đorđević A. Prostorni prikaz sadržaja organske materije u rendzinama Krnjevačkog Vinogorja, Srbija.. in Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''. 2022;:26-27.
https://hdl.handle.net/21.15107/rcub_agrospace_6575 .
Bogosavljević, Jelena, Nikolić, Nataša, Radmanović, Svjetlana, Branković, Snežana, Kaluđerović, Lazar, Đorđević, Aleksandar, "Prostorni prikaz sadržaja organske materije u rendzinama Krnjevačkog Vinogorja, Srbija." in Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022'' (2022):26-27,
https://hdl.handle.net/21.15107/rcub_agrospace_6575 .

Ambiguity in the results of USLE K–factor obtained by nomograph and erodibility equation

Životić, Ljubomir; Gajić, Boško; Ćosić, Marija; Kaluđerović, Lazar; Lazović, Vojislav

(University of East Sarajevo, Faculty of Agriculture, Republic of Srpska, Bosnia, 2022)

TY  - CONF
AU  - Životić, Ljubomir
AU  - Gajić, Boško
AU  - Ćosić, Marija
AU  - Kaluđerović, Lazar
AU  - Lazović, Vojislav
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6500
AB  - Universal Soil Loss Equation (USLE) is the most applied model for soil erosion assessment. It
takes into consideration five soil erosion factors among which soil erodibilty factor (K) is a
measure of inheritant reistance of soils to erosion. In the formulation of USLE model, K–factor
was determined experimentally, and then the authors created USLE nomograph to facilitate the
work, and in the next step, created the equation for faster K–factor determination. This paper
aims to compare K–factor obtained by USLE nomograph and USLE equation. A total number of
108 soil samples have been collected in Western Serbia. For the determination of K–values,
particle size distribution and soil organic matter were analyzed in the laboratory, whereas soil
permeability and soil structure were assessed according to the USLE document procedure. The
results have been compared using basic statistics. The average K–values obtained by nomograph
and equation differ for almost 15%. There is statistically significant correlation between the two
methods, but coefficient of determination amounts to 0.5802, which indicates pretty high
deviation. Root Mean Square Error (RMSE) amounts to 0.008, which is quite high, whereas
index of agreement amounts to 0.93, representing good agreement. These results are ambiguous.
We think that 15% of absolute error is a threshold value between single samples, which occur in
only 56% of the cases. Therefore, the obtained results indicate the gaps in the determination of
K–factor and could contribute to further improvment of soil erodibilty determination and
consequently, soil erosion assessment.
PB  - University of East Sarajevo, Faculty of Agriculture, Republic of Srpska, Bosnia
C3  - XIII International Scientific Agricultural Symposium “Agrosym 2022"
T1  - Ambiguity in the results of USLE K–factor obtained by nomograph and erodibility equation
EP  - 968
SP  - 962
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6500
ER  - 
@conference{
author = "Životić, Ljubomir and Gajić, Boško and Ćosić, Marija and Kaluđerović, Lazar and Lazović, Vojislav",
year = "2022",
abstract = "Universal Soil Loss Equation (USLE) is the most applied model for soil erosion assessment. It
takes into consideration five soil erosion factors among which soil erodibilty factor (K) is a
measure of inheritant reistance of soils to erosion. In the formulation of USLE model, K–factor
was determined experimentally, and then the authors created USLE nomograph to facilitate the
work, and in the next step, created the equation for faster K–factor determination. This paper
aims to compare K–factor obtained by USLE nomograph and USLE equation. A total number of
108 soil samples have been collected in Western Serbia. For the determination of K–values,
particle size distribution and soil organic matter were analyzed in the laboratory, whereas soil
permeability and soil structure were assessed according to the USLE document procedure. The
results have been compared using basic statistics. The average K–values obtained by nomograph
and equation differ for almost 15%. There is statistically significant correlation between the two
methods, but coefficient of determination amounts to 0.5802, which indicates pretty high
deviation. Root Mean Square Error (RMSE) amounts to 0.008, which is quite high, whereas
index of agreement amounts to 0.93, representing good agreement. These results are ambiguous.
We think that 15% of absolute error is a threshold value between single samples, which occur in
only 56% of the cases. Therefore, the obtained results indicate the gaps in the determination of
K–factor and could contribute to further improvment of soil erodibilty determination and
consequently, soil erosion assessment.",
publisher = "University of East Sarajevo, Faculty of Agriculture, Republic of Srpska, Bosnia",
journal = "XIII International Scientific Agricultural Symposium “Agrosym 2022"",
title = "Ambiguity in the results of USLE K–factor obtained by nomograph and erodibility equation",
pages = "968-962",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6500"
}
Životić, L., Gajić, B., Ćosić, M., Kaluđerović, L.,& Lazović, V.. (2022). Ambiguity in the results of USLE K–factor obtained by nomograph and erodibility equation. in XIII International Scientific Agricultural Symposium “Agrosym 2022"
University of East Sarajevo, Faculty of Agriculture, Republic of Srpska, Bosnia., 962-968.
https://hdl.handle.net/21.15107/rcub_agrospace_6500
Životić L, Gajić B, Ćosić M, Kaluđerović L, Lazović V. Ambiguity in the results of USLE K–factor obtained by nomograph and erodibility equation. in XIII International Scientific Agricultural Symposium “Agrosym 2022". 2022;:962-968.
https://hdl.handle.net/21.15107/rcub_agrospace_6500 .
Životić, Ljubomir, Gajić, Boško, Ćosić, Marija, Kaluđerović, Lazar, Lazović, Vojislav, "Ambiguity in the results of USLE K–factor obtained by nomograph and erodibility equation" in XIII International Scientific Agricultural Symposium “Agrosym 2022" (2022):962-968,
https://hdl.handle.net/21.15107/rcub_agrospace_6500 .

Differences in Determination of Soil Erodibility Between USLE Nomograph and Erodibility Equation

Životić, Ljubomir; Gajić, Boško; Ćosić, Marija; Kaluđerović, Lazar; Lazović, Vojislav

(University of Banja Luka Faculty of Agriculture, 2022)

TY  - CONF
AU  - Životić, Ljubomir
AU  - Gajić, Boško
AU  - Ćosić, Marija
AU  - Kaluđerović, Lazar
AU  - Lazović, Vojislav
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6501
AB  - Universal Soil Loss Equation (USLE) is the most applied model for soil erosion assessment. It takes into consideration five soil erosion factors: rainfall erosivity, topographic factor, vegetation cover, applied conservation practices, and soil erodibility. Soil erodibilty factor (K-factor) is a measure of inheritant reistance of soils to erosion. In the formulation of USLE model, K-factor was determined experimentally. Experimental determinations are costly and time- consuming, so the authors have encouraged scientists to utilise USLE nomograph or derived equations. This paper aims to compare USLE nomograph and soil erodibility equation which was derived from nomograph by the same authors. A total number of 108 soil samples have been collected on agricultural land of Western Serbia. For the determination of K-values, particle size distribution and soil organic matter content were determined in the laboratory, whereas soil permeability and soil structure were assessed according to the nomograph. The results have been compared using basic statistics. The average K-values obtained by nomograph and derived equation are 0.034±0.010 and 0.029±0.012, which is 14.7% difference. Coefficient of determination (R2) amounts to 0.5802, which indicates deviation of 23.9%, although there is statistically significant correlation between two methods. Root Mean Square Error (RMSE) is 0.008, which is 23–27% difference. The RMSE is not low, whereas index of agreement amounts to 0.93, which represent good agreement, and also there is significant correlation. These results are ambiguous. We think that 15% of absolute error is a threshold value for good correlation, which occur on only 56% of samples. K-factor is an important part of various soil erosion models and it is of high importance to determine it in the best manner. Therefore, the obtained results indicate the gaps in the determination of K-factor and could contribute to further improvment of soil erodibilty determination and consequently, soil erosion assessment.
PB  - University of Banja Luka Faculty of Agriculture
C3  - 11th International Symposium of Agricultural Sciences "AGRORES 2022", 26–28 May, 2022, Trebinje, Bosnia and Herzegovina
T1  - Differences in Determination of Soil Erodibility Between USLE Nomograph and Erodibility Equation
EP  - 52
SP  - 52
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6501
ER  - 
@conference{
author = "Životić, Ljubomir and Gajić, Boško and Ćosić, Marija and Kaluđerović, Lazar and Lazović, Vojislav",
year = "2022",
abstract = "Universal Soil Loss Equation (USLE) is the most applied model for soil erosion assessment. It takes into consideration five soil erosion factors: rainfall erosivity, topographic factor, vegetation cover, applied conservation practices, and soil erodibility. Soil erodibilty factor (K-factor) is a measure of inheritant reistance of soils to erosion. In the formulation of USLE model, K-factor was determined experimentally. Experimental determinations are costly and time- consuming, so the authors have encouraged scientists to utilise USLE nomograph or derived equations. This paper aims to compare USLE nomograph and soil erodibility equation which was derived from nomograph by the same authors. A total number of 108 soil samples have been collected on agricultural land of Western Serbia. For the determination of K-values, particle size distribution and soil organic matter content were determined in the laboratory, whereas soil permeability and soil structure were assessed according to the nomograph. The results have been compared using basic statistics. The average K-values obtained by nomograph and derived equation are 0.034±0.010 and 0.029±0.012, which is 14.7% difference. Coefficient of determination (R2) amounts to 0.5802, which indicates deviation of 23.9%, although there is statistically significant correlation between two methods. Root Mean Square Error (RMSE) is 0.008, which is 23–27% difference. The RMSE is not low, whereas index of agreement amounts to 0.93, which represent good agreement, and also there is significant correlation. These results are ambiguous. We think that 15% of absolute error is a threshold value for good correlation, which occur on only 56% of samples. K-factor is an important part of various soil erosion models and it is of high importance to determine it in the best manner. Therefore, the obtained results indicate the gaps in the determination of K-factor and could contribute to further improvment of soil erodibilty determination and consequently, soil erosion assessment.",
publisher = "University of Banja Luka Faculty of Agriculture",
journal = "11th International Symposium of Agricultural Sciences "AGRORES 2022", 26–28 May, 2022, Trebinje, Bosnia and Herzegovina",
title = "Differences in Determination of Soil Erodibility Between USLE Nomograph and Erodibility Equation",
pages = "52-52",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6501"
}
Životić, L., Gajić, B., Ćosić, M., Kaluđerović, L.,& Lazović, V.. (2022). Differences in Determination of Soil Erodibility Between USLE Nomograph and Erodibility Equation. in 11th International Symposium of Agricultural Sciences "AGRORES 2022", 26–28 May, 2022, Trebinje, Bosnia and Herzegovina
University of Banja Luka Faculty of Agriculture., 52-52.
https://hdl.handle.net/21.15107/rcub_agrospace_6501
Životić L, Gajić B, Ćosić M, Kaluđerović L, Lazović V. Differences in Determination of Soil Erodibility Between USLE Nomograph and Erodibility Equation. in 11th International Symposium of Agricultural Sciences "AGRORES 2022", 26–28 May, 2022, Trebinje, Bosnia and Herzegovina. 2022;:52-52.
https://hdl.handle.net/21.15107/rcub_agrospace_6501 .
Životić, Ljubomir, Gajić, Boško, Ćosić, Marija, Kaluđerović, Lazar, Lazović, Vojislav, "Differences in Determination of Soil Erodibility Between USLE Nomograph and Erodibility Equation" in 11th International Symposium of Agricultural Sciences "AGRORES 2022", 26–28 May, 2022, Trebinje, Bosnia and Herzegovina (2022):52-52,
https://hdl.handle.net/21.15107/rcub_agrospace_6501 .

Correlation between Ranker Soil Type of National Classification System and Leptosols Reference Soil Group of World Reference Base For Soil Resources – Theoretical Approach

Životić, Ljubomir; Đorđević, Aleksandar; Mohlala, Day Boitumelo; Bogosavljević, Jelena; Kaluđerović, Lazar

(Serbian Society of Soil Science, 2022)

TY  - CONF
AU  - Životić, Ljubomir
AU  - Đorđević, Aleksandar
AU  - Mohlala, Day Boitumelo
AU  - Bogosavljević, Jelena
AU  - Kaluđerović, Lazar
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6502
AB  - National soil classification system (NSCS) used in Serbia is based on the principles of genetic classification. It is utilizes the concept of genetic soil horizons. The world reference base (WRB) for soil resources is based on soil properties defined in terms of diagnostic horizons, diagnostic properties, and diagnostic materials, which to the greatest extent possible should be measurable and observable in the field. The difference between genetic vs. diagnostic horizons creates an obstacle in correlation of soil types from NSCS with reference soil groups (RSG's) of WRB for soil resources, whereas the advantage in this work is that most of the soil names of national system correlate to the revised legend of the Soil Map of the World which is an forerunner of WRB for soil resources.
This work aims to compare Ranker soil type of NSCS with corresponding RSG from WRB for soil resources, namely with Leptosols, as they have been reported in Serbia and abroad, as an appropriate reference soil group. The comparison was conducted on the base of qualitative and semi–quantitative information collected from the literature and experience of the authors – theretical approach. It was conducted in two ways: a) Leptosols vs. Rankers, meaning which Leptosols of WRB for soil resources are Rankers in NSCS, and b) Rankers vs. Leptosols, meaning which Rankers of NSCS are Leptosols in WRB.
The conclusion of our work is that Leptosols RSG can correspond to Rankers in NSCS, but some WRB Leptosols are also Lithosols, Technosols, soils of Subaquatic soil order, Eugleys, Humogleys, Peat Soils, Rendzinas, Kalkomelanosols, Eutric and Dystric Cambisols, whereas Gypsiric Leptosols can not be classified according to NSCS. Observing in different direction, the results show that Ranker Soils could be also part of some other RSG with Leptic principal qualifier, such as Andosols, Phaeozems, Umbrisols, Cambisols, and Regosols. This work represents a small contribution to soil science in Serbia as WRB is comprehensive classification system that enables accommodation of NSCS's for communication at the international level.
PB  - Serbian Society of Soil Science
C3  - 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021
T1  - Correlation between Ranker Soil Type of National Classification System and Leptosols Reference Soil Group of World Reference Base For Soil Resources – Theoretical Approach
EP  - 78
SP  - 71
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6502
ER  - 
@conference{
author = "Životić, Ljubomir and Đorđević, Aleksandar and Mohlala, Day Boitumelo and Bogosavljević, Jelena and Kaluđerović, Lazar",
year = "2022",
abstract = "National soil classification system (NSCS) used in Serbia is based on the principles of genetic classification. It is utilizes the concept of genetic soil horizons. The world reference base (WRB) for soil resources is based on soil properties defined in terms of diagnostic horizons, diagnostic properties, and diagnostic materials, which to the greatest extent possible should be measurable and observable in the field. The difference between genetic vs. diagnostic horizons creates an obstacle in correlation of soil types from NSCS with reference soil groups (RSG's) of WRB for soil resources, whereas the advantage in this work is that most of the soil names of national system correlate to the revised legend of the Soil Map of the World which is an forerunner of WRB for soil resources.
This work aims to compare Ranker soil type of NSCS with corresponding RSG from WRB for soil resources, namely with Leptosols, as they have been reported in Serbia and abroad, as an appropriate reference soil group. The comparison was conducted on the base of qualitative and semi–quantitative information collected from the literature and experience of the authors – theretical approach. It was conducted in two ways: a) Leptosols vs. Rankers, meaning which Leptosols of WRB for soil resources are Rankers in NSCS, and b) Rankers vs. Leptosols, meaning which Rankers of NSCS are Leptosols in WRB.
The conclusion of our work is that Leptosols RSG can correspond to Rankers in NSCS, but some WRB Leptosols are also Lithosols, Technosols, soils of Subaquatic soil order, Eugleys, Humogleys, Peat Soils, Rendzinas, Kalkomelanosols, Eutric and Dystric Cambisols, whereas Gypsiric Leptosols can not be classified according to NSCS. Observing in different direction, the results show that Ranker Soils could be also part of some other RSG with Leptic principal qualifier, such as Andosols, Phaeozems, Umbrisols, Cambisols, and Regosols. This work represents a small contribution to soil science in Serbia as WRB is comprehensive classification system that enables accommodation of NSCS's for communication at the international level.",
publisher = "Serbian Society of Soil Science",
journal = "3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021",
title = "Correlation between Ranker Soil Type of National Classification System and Leptosols Reference Soil Group of World Reference Base For Soil Resources – Theoretical Approach",
pages = "78-71",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6502"
}
Životić, L., Đorđević, A., Mohlala, D. B., Bogosavljević, J.,& Kaluđerović, L.. (2022). Correlation between Ranker Soil Type of National Classification System and Leptosols Reference Soil Group of World Reference Base For Soil Resources – Theoretical Approach. in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021
Serbian Society of Soil Science., 71-78.
https://hdl.handle.net/21.15107/rcub_agrospace_6502
Životić L, Đorđević A, Mohlala DB, Bogosavljević J, Kaluđerović L. Correlation between Ranker Soil Type of National Classification System and Leptosols Reference Soil Group of World Reference Base For Soil Resources – Theoretical Approach. in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021. 2022;:71-78.
https://hdl.handle.net/21.15107/rcub_agrospace_6502 .
Životić, Ljubomir, Đorđević, Aleksandar, Mohlala, Day Boitumelo, Bogosavljević, Jelena, Kaluđerović, Lazar, "Correlation between Ranker Soil Type of National Classification System and Leptosols Reference Soil Group of World Reference Base For Soil Resources – Theoretical Approach" in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021 (2022):71-78,
https://hdl.handle.net/21.15107/rcub_agrospace_6502 .

Soil Structure of Calcomelanosols from the Rtanj Mountain, Serbia

Bogosavljević, Jelena; Radmanović, Svjetlana; Životić, Ljubomir; Kaluđerović, Lazar; Đorđević, Aleksandar

(Serbian Society of Soil Science, 2022)

TY  - CONF
AU  - Bogosavljević, Jelena
AU  - Radmanović, Svjetlana
AU  - Životić, Ljubomir
AU  - Kaluđerović, Lazar
AU  - Đorđević, Aleksandar
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6503
AB  - Soil structure pertains to the natural organization of soil particles into various forms as a result of pedogenic processes. On one hand, it is formed in interaction of physical, chemical, mineralogical, and biological factors, whereas on the other hand it affects them. Soil structure can differ in grade of development, size and type of aggregates, and their stability to mechanical pressure and water, which is often soil-horizon or soil-type dependent. This paper aims to analyze the structure of Calcomelanosols of mountain Rtanj, Serbia, as that is the most widespread soil type in this area. Calcomelanosols are soils from the national classification system that often correspond to Rendzic Leptosols in the World Reference Base (WRB) for soil resources. Soil structure is analyzed in terms of soil dry aggregate size distribution (ASD) and soil aggregate stability to water (WAS), and related soil structure indices, as they are essential parameters in understanding the structural state of the soil. Eight soil profiles have been excavated, described and sampled in the field. Soil horizon sequence of all profiles was A – R, with humus-accumulative horizon overlying calcareous bedrock. Six profiles of Calcomelanosols correspond to Rendzic Leptosols of WRB, whereas other two profiles correspond to Leptic Rendzic Phaeozems and Leptic Chernic Rendzic Phaeozems. Basic physical and chemical soil properties were determined. Both ASD and WAS were determined by Savinov's method. The following soil structure indices were calculated: dry mean weight diameter (dMWD), wet mean weight diameter (wMWD), dry geometric mean diameter (dGMD), wet geometric mean diameter (wGMD) and structural stability index (SI). The results indicate favorable structure of the examined Calcomelanosols. The content of agronomically most valuable aggregates (0.25–10 mm) in all soil profiles exceeds 80% (90.5±3.6% on average). Among these aggregates, very fine, fine and medium size aggregates dominate. Dry MWD showed values ranging from 3.0–5.5 mm, whereas wMWD ranges from 1.9– 3.3 mm. The wMWD and dMWD ratio is an indicator of the stability of structural aggregates. A small change in the aggregate size after wet sieving was found, 0.7±0.1 mm on average. In all examined soil profiles SI is higher than 19% (32.9±7.1% on average), which indicates an extremely stable structure, without risk of the structural degradation of soil. Correlation analysis showed a significant positive relationship between the content of agronomically valuable fractions (0.25–10 mm) and the following soil parameters: soil organic matter (SOM), pH, and base saturation (%V). Also, there is a strong positive correlation between SI and pH, and SI with %V. Other calculated structural indices show a strong negative correlation with SOM, pH and %V. All analyzed soil profiles have favorable soil structure and water stable soil aggregates with low risk of soil structure degradation. This is of extreme importance because Calcomelanosols cover the steep and
sloping land which is naturally more prone to soil water erosion and soil degradation.
PB  - Serbian Society of Soil Science
C3  - 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021
T1  - Soil Structure of Calcomelanosols from the Rtanj Mountain, Serbia
EP  - 165
SP  - 154
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6503
ER  - 
@conference{
author = "Bogosavljević, Jelena and Radmanović, Svjetlana and Životić, Ljubomir and Kaluđerović, Lazar and Đorđević, Aleksandar",
year = "2022",
abstract = "Soil structure pertains to the natural organization of soil particles into various forms as a result of pedogenic processes. On one hand, it is formed in interaction of physical, chemical, mineralogical, and biological factors, whereas on the other hand it affects them. Soil structure can differ in grade of development, size and type of aggregates, and their stability to mechanical pressure and water, which is often soil-horizon or soil-type dependent. This paper aims to analyze the structure of Calcomelanosols of mountain Rtanj, Serbia, as that is the most widespread soil type in this area. Calcomelanosols are soils from the national classification system that often correspond to Rendzic Leptosols in the World Reference Base (WRB) for soil resources. Soil structure is analyzed in terms of soil dry aggregate size distribution (ASD) and soil aggregate stability to water (WAS), and related soil structure indices, as they are essential parameters in understanding the structural state of the soil. Eight soil profiles have been excavated, described and sampled in the field. Soil horizon sequence of all profiles was A – R, with humus-accumulative horizon overlying calcareous bedrock. Six profiles of Calcomelanosols correspond to Rendzic Leptosols of WRB, whereas other two profiles correspond to Leptic Rendzic Phaeozems and Leptic Chernic Rendzic Phaeozems. Basic physical and chemical soil properties were determined. Both ASD and WAS were determined by Savinov's method. The following soil structure indices were calculated: dry mean weight diameter (dMWD), wet mean weight diameter (wMWD), dry geometric mean diameter (dGMD), wet geometric mean diameter (wGMD) and structural stability index (SI). The results indicate favorable structure of the examined Calcomelanosols. The content of agronomically most valuable aggregates (0.25–10 mm) in all soil profiles exceeds 80% (90.5±3.6% on average). Among these aggregates, very fine, fine and medium size aggregates dominate. Dry MWD showed values ranging from 3.0–5.5 mm, whereas wMWD ranges from 1.9– 3.3 mm. The wMWD and dMWD ratio is an indicator of the stability of structural aggregates. A small change in the aggregate size after wet sieving was found, 0.7±0.1 mm on average. In all examined soil profiles SI is higher than 19% (32.9±7.1% on average), which indicates an extremely stable structure, without risk of the structural degradation of soil. Correlation analysis showed a significant positive relationship between the content of agronomically valuable fractions (0.25–10 mm) and the following soil parameters: soil organic matter (SOM), pH, and base saturation (%V). Also, there is a strong positive correlation between SI and pH, and SI with %V. Other calculated structural indices show a strong negative correlation with SOM, pH and %V. All analyzed soil profiles have favorable soil structure and water stable soil aggregates with low risk of soil structure degradation. This is of extreme importance because Calcomelanosols cover the steep and
sloping land which is naturally more prone to soil water erosion and soil degradation.",
publisher = "Serbian Society of Soil Science",
journal = "3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021",
title = "Soil Structure of Calcomelanosols from the Rtanj Mountain, Serbia",
pages = "165-154",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6503"
}
Bogosavljević, J., Radmanović, S., Životić, L., Kaluđerović, L.,& Đorđević, A.. (2022). Soil Structure of Calcomelanosols from the Rtanj Mountain, Serbia. in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021
Serbian Society of Soil Science., 154-165.
https://hdl.handle.net/21.15107/rcub_agrospace_6503
Bogosavljević J, Radmanović S, Životić L, Kaluđerović L, Đorđević A. Soil Structure of Calcomelanosols from the Rtanj Mountain, Serbia. in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021. 2022;:154-165.
https://hdl.handle.net/21.15107/rcub_agrospace_6503 .
Bogosavljević, Jelena, Radmanović, Svjetlana, Životić, Ljubomir, Kaluđerović, Lazar, Đorđević, Aleksandar, "Soil Structure of Calcomelanosols from the Rtanj Mountain, Serbia" in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021 (2022):154-165,
https://hdl.handle.net/21.15107/rcub_agrospace_6503 .

FTIR SPECTROSCOPIC STUDY OF S-METOLACHLOR SORPTION ON INORGANIC AND ORGANICALLY MODIFIED MONTMORILLONITE FROM BOGOVINA

Kaluđerović, Lazar; Tomić, Zorica; Bogosavljević, Jelena; Životić, Ljubomir; Milošević, Maja

(Serbian Society of Soil Science, 2022)

TY  - CONF
AU  - Kaluđerović, Lazar
AU  - Tomić, Zorica
AU  - Bogosavljević, Jelena
AU  - Životić, Ljubomir
AU  - Milošević, Maja
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6494
AB  - Environmental problems related to the application of herbicides are causing a concern due to their increasing presence in soil, groundwater and surface water. Numerous methods have been developed in order to reduce herbicide mobility and protect natural water resources. The results presented in this paper show the interaction of herbicide S- metolachlor with inorganic and organically modified montmorillonite from Bogovina (Boljevac municipality, Serbia). Clay sample from Bogovina represents Ca-Na montmorillonite with a small amount of quartz, cristobalite and carbonate minerals. Organic montmorillonites were obtained after modification with different concentrations of organic complex (HDTMA and PTMA), whereas inorganic modification was performed with 1M NaCl solution. The interaction between minerals and herbicide was monitored using infrared spectroscopy. IR bands observed in the inorganic modified montmorillonite (Na-montmorillonite) are typical for smectites with a high Al content in the octahedron position.
The intercalation of HDTMA+ cations into the interlayer space produces redshift of the IR bands that originate from the vibrations of the adsorbed water, as a consequence of the hydrogen bond strength reduction in HDTMA-montmorillonite. Also, the intensity of these bands decreases significantly with the increasing concentration of HDTMA+ cation. All these changes are related to the decreasing of the water content in the interlayer space by increasing the content of HDTMA. The occurrence of the stretching CH2 vibrations is generally the main difference in the spectrum of HDTMA modified montmorillonite in comparison with the spectrum of inorganically modified montmorillonite. The wavenumber, intensity and width of these bands are sensitive to conformation in hydrocarbon chains. After the organic modification of the montmorillonite with the PTMA complex, stretching vibrations of the phenyl ring occurred.
Analysis of FTIR spectroscopy data showed that the hydrogen bond is one of the most important mechanisms that occur between Na-montmorillonite and S-metolachlor. Comparing the FTIR spectra of herbicides before and after the sorption, it can be concluded that the carbonyl group participate in the binding process. Sorption of S- metolachlor on HDTMA-montmorillonites causes the redshift of the C=O absorption band. Shifting to lower wavenumbers and joining with the deformation vibration band of water indicates that the C=O group participated in the formation of a bond with the montmorillonite. Sorption of S-metolachlor molecules on PTMA-montmorillonite takes place through the interaction between the aromatic benzene ring of S-metolachlor and the aromatic benzene ring of the organic complex (π-π bonds). Also, the formation of a hydrogen bond occurs between the molecules of S-metolachlor and the molecules of water that are in the interlayer space and/or oxygen on the surface of the tetrahedral sheet of the montmorillonite.
PB  - Serbian Society of Soil Science
C3  - 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021
T1  - FTIR SPECTROSCOPIC STUDY OF S-METOLACHLOR SORPTION ON INORGANIC AND ORGANICALLY MODIFIED MONTMORILLONITE FROM BOGOVINA
EP  - 337
SP  - 329
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6494
ER  - 
@conference{
author = "Kaluđerović, Lazar and Tomić, Zorica and Bogosavljević, Jelena and Životić, Ljubomir and Milošević, Maja",
year = "2022",
abstract = "Environmental problems related to the application of herbicides are causing a concern due to their increasing presence in soil, groundwater and surface water. Numerous methods have been developed in order to reduce herbicide mobility and protect natural water resources. The results presented in this paper show the interaction of herbicide S- metolachlor with inorganic and organically modified montmorillonite from Bogovina (Boljevac municipality, Serbia). Clay sample from Bogovina represents Ca-Na montmorillonite with a small amount of quartz, cristobalite and carbonate minerals. Organic montmorillonites were obtained after modification with different concentrations of organic complex (HDTMA and PTMA), whereas inorganic modification was performed with 1M NaCl solution. The interaction between minerals and herbicide was monitored using infrared spectroscopy. IR bands observed in the inorganic modified montmorillonite (Na-montmorillonite) are typical for smectites with a high Al content in the octahedron position.
The intercalation of HDTMA+ cations into the interlayer space produces redshift of the IR bands that originate from the vibrations of the adsorbed water, as a consequence of the hydrogen bond strength reduction in HDTMA-montmorillonite. Also, the intensity of these bands decreases significantly with the increasing concentration of HDTMA+ cation. All these changes are related to the decreasing of the water content in the interlayer space by increasing the content of HDTMA. The occurrence of the stretching CH2 vibrations is generally the main difference in the spectrum of HDTMA modified montmorillonite in comparison with the spectrum of inorganically modified montmorillonite. The wavenumber, intensity and width of these bands are sensitive to conformation in hydrocarbon chains. After the organic modification of the montmorillonite with the PTMA complex, stretching vibrations of the phenyl ring occurred.
Analysis of FTIR spectroscopy data showed that the hydrogen bond is one of the most important mechanisms that occur between Na-montmorillonite and S-metolachlor. Comparing the FTIR spectra of herbicides before and after the sorption, it can be concluded that the carbonyl group participate in the binding process. Sorption of S- metolachlor on HDTMA-montmorillonites causes the redshift of the C=O absorption band. Shifting to lower wavenumbers and joining with the deformation vibration band of water indicates that the C=O group participated in the formation of a bond with the montmorillonite. Sorption of S-metolachlor molecules on PTMA-montmorillonite takes place through the interaction between the aromatic benzene ring of S-metolachlor and the aromatic benzene ring of the organic complex (π-π bonds). Also, the formation of a hydrogen bond occurs between the molecules of S-metolachlor and the molecules of water that are in the interlayer space and/or oxygen on the surface of the tetrahedral sheet of the montmorillonite.",
publisher = "Serbian Society of Soil Science",
journal = "3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021",
title = "FTIR SPECTROSCOPIC STUDY OF S-METOLACHLOR SORPTION ON INORGANIC AND ORGANICALLY MODIFIED MONTMORILLONITE FROM BOGOVINA",
pages = "337-329",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6494"
}
Kaluđerović, L., Tomić, Z., Bogosavljević, J., Životić, L.,& Milošević, M.. (2022). FTIR SPECTROSCOPIC STUDY OF S-METOLACHLOR SORPTION ON INORGANIC AND ORGANICALLY MODIFIED MONTMORILLONITE FROM BOGOVINA. in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021
Serbian Society of Soil Science., 329-337.
https://hdl.handle.net/21.15107/rcub_agrospace_6494
Kaluđerović L, Tomić Z, Bogosavljević J, Životić L, Milošević M. FTIR SPECTROSCOPIC STUDY OF S-METOLACHLOR SORPTION ON INORGANIC AND ORGANICALLY MODIFIED MONTMORILLONITE FROM BOGOVINA. in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021. 2022;:329-337.
https://hdl.handle.net/21.15107/rcub_agrospace_6494 .
Kaluđerović, Lazar, Tomić, Zorica, Bogosavljević, Jelena, Životić, Ljubomir, Milošević, Maja, "FTIR SPECTROSCOPIC STUDY OF S-METOLACHLOR SORPTION ON INORGANIC AND ORGANICALLY MODIFIED MONTMORILLONITE FROM BOGOVINA" in 3rd International and 15th National Congress of Serbian Society of Soil Science: Soils for Future under Global Challenges, Sokobanja, Serbia, 21-24 September 2021 (2022):329-337,
https://hdl.handle.net/21.15107/rcub_agrospace_6494 .

Izazovi klasifikacije koluvijalnih krečnjačkih zemljišta Velikog polja – podnožje planine Vukan

Životić, Ljubomir; Mrvić, Vesna; Gajić, Boško; Kaluđerović, Lazar

(Poljoprivredni fakultet Novi Sad, 2022)

TY  - CONF
AU  - Životić, Ljubomir
AU  - Mrvić, Vesna
AU  - Gajić, Boško
AU  - Kaluđerović, Lazar
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6576
AB  - UVOD i CILjEVI: U okviru klasifikacije zemljišta u genetskim klasifikacionim sistemima
se nekada javljaju dileme kome tipu zemljišta pripadaju neke zemljišne jedinice, jer ne postoje
direktno utvrđeni kvantitativni pokazatelji koji razgraničavaju pojedine zemljišne jedinice ili
pojedine pedogenetske procese, i utvrđuju hijerarhiju među njima za potrebe klasifikacije. U
okviru šire studije, u podnožju krečnjačkog masiva planine Vukan, na potesu Veliko polje,
otvoreno je 42 zemljišna profila. Karbonatna skeletna zemljišta na jedrim krečnjacima sa
izraženim humusno-akumulativnim horizontom su identifikovana na oko 40% područja, odnosno
na 15 otvorenih profila.
MATERIJAL i METOD: Istraživanja su obuhvatala otvaranje profila zemljišta do 90 cm
dubine, odnosno do dubine matične stene, detaljan opis zemljišta na terenu, kao i uzimanje uzoraka
zemljišta u narušenom i nenarušenom stanju za laboratorisjke analize, kao i klasifikaciju
zemljišta prema domaćem i međunarodnom sistemu (WRB) klasifikacije.
REZULTATI i ZAKLjUČCI: Zemljišta su klasifikovana kao koluvijalni kalkomelanosoli.
Koluvijalni kalkomelanosoli su identifikovani na nadmorskoj visini od svega 185–210 m, što je
neuobičajeno za ovaj tip zemljišta. Iz istog razloga i njegove ostale fizičko-hemijske osobine
odstupaju od do sada opisanih koluvijalnih kalkomelanosola. Teren pod kalkomelanosolima se
koristi kao ekstenzivni pašnjak, dominantan nagib terena je 2–5%, a skeletnost površine iznosi
10–80% u zavisnosti od profila. Građa većine ispitivanih profila je A – R. Boja humusnoakumulativnog horizonta je veoma tamna braon i veoma tamna braon siva, nešto svetlija od
tipičnih crnica. Koluvijalni kalkomelanosoli se odlikuju dubinom 40–70 cm, a sadržaj skeleta
se povećava sa dubinom. Veličina skeleta je 2–200 mm, a oblik je nepravilan – uglast. Struktura
zemljišta je umereno izražena, dominantna veličina zrnastih agregata je 1–5 mm. Veoma visok
sadržaj kalcijum-karbonata u supstratu, 90–99% u 12 profila ukazuje na jedre krečnjake. Skelet je
po dubini zemljišnog profila i karbonatan i beskarbonatan, što ukazuje na koluvijalne procese u
prošlosti. Intenzivno hemijsko raspadanje ovog skeleta je dovelo čak i do pojave
pseudomicelarnog potpovršinskog horizonta koji se nalazi iznad matične stene u dva profila,
kao i do pojave karbonatnosti zemljišne mase u horizontima, što nije tipično za kalkomelanosole.
Zemljišta nisu klasifikovana kao rendzine, jer postojeća nacionalna klasifikacija ne prepoznaje
rendzine na jedrim krečnjacima, već samo na mekim krečnjacima. Takođe, zemljišta nisu
klasifikovana ni kao karbonatni koluvijumi jer nisu nastala taloženjem podukata raspadanja
mekih karbonatnih stena. Zemljišta su dakle prema nacionalnoj klasifikaciji koluvijlni
kalkomelanosoli, organo-mineralni, i u odnosu na tipične kalkomelanosole odlikuju se većom
dubinom soluma, prisutnošću kalcijum-karbonata u zemljišnoj masi, skeletnošću, krupnijim
strukturnim agregatima, i dosta nižim sadržajem humusa. Većina ispitivanih profila pripada
Leptic Rendzic Phaeozems (Colluvic) prema WRB sistemu klasifikacije.
PB  - Poljoprivredni fakultet Novi Sad
C3  - Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''
T1  - Izazovi klasifikacije koluvijalnih krečnjačkih zemljišta Velikog polja – podnožje planine Vukan
EP  - 55
SP  - 54
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6576
ER  - 
@conference{
author = "Životić, Ljubomir and Mrvić, Vesna and Gajić, Boško and Kaluđerović, Lazar",
year = "2022",
abstract = "UVOD i CILjEVI: U okviru klasifikacije zemljišta u genetskim klasifikacionim sistemima
se nekada javljaju dileme kome tipu zemljišta pripadaju neke zemljišne jedinice, jer ne postoje
direktno utvrđeni kvantitativni pokazatelji koji razgraničavaju pojedine zemljišne jedinice ili
pojedine pedogenetske procese, i utvrđuju hijerarhiju među njima za potrebe klasifikacije. U
okviru šire studije, u podnožju krečnjačkog masiva planine Vukan, na potesu Veliko polje,
otvoreno je 42 zemljišna profila. Karbonatna skeletna zemljišta na jedrim krečnjacima sa
izraženim humusno-akumulativnim horizontom su identifikovana na oko 40% područja, odnosno
na 15 otvorenih profila.
MATERIJAL i METOD: Istraživanja su obuhvatala otvaranje profila zemljišta do 90 cm
dubine, odnosno do dubine matične stene, detaljan opis zemljišta na terenu, kao i uzimanje uzoraka
zemljišta u narušenom i nenarušenom stanju za laboratorisjke analize, kao i klasifikaciju
zemljišta prema domaćem i međunarodnom sistemu (WRB) klasifikacije.
REZULTATI i ZAKLjUČCI: Zemljišta su klasifikovana kao koluvijalni kalkomelanosoli.
Koluvijalni kalkomelanosoli su identifikovani na nadmorskoj visini od svega 185–210 m, što je
neuobičajeno za ovaj tip zemljišta. Iz istog razloga i njegove ostale fizičko-hemijske osobine
odstupaju od do sada opisanih koluvijalnih kalkomelanosola. Teren pod kalkomelanosolima se
koristi kao ekstenzivni pašnjak, dominantan nagib terena je 2–5%, a skeletnost površine iznosi
10–80% u zavisnosti od profila. Građa većine ispitivanih profila je A – R. Boja humusnoakumulativnog horizonta je veoma tamna braon i veoma tamna braon siva, nešto svetlija od
tipičnih crnica. Koluvijalni kalkomelanosoli se odlikuju dubinom 40–70 cm, a sadržaj skeleta
se povećava sa dubinom. Veličina skeleta je 2–200 mm, a oblik je nepravilan – uglast. Struktura
zemljišta je umereno izražena, dominantna veličina zrnastih agregata je 1–5 mm. Veoma visok
sadržaj kalcijum-karbonata u supstratu, 90–99% u 12 profila ukazuje na jedre krečnjake. Skelet je
po dubini zemljišnog profila i karbonatan i beskarbonatan, što ukazuje na koluvijalne procese u
prošlosti. Intenzivno hemijsko raspadanje ovog skeleta je dovelo čak i do pojave
pseudomicelarnog potpovršinskog horizonta koji se nalazi iznad matične stene u dva profila,
kao i do pojave karbonatnosti zemljišne mase u horizontima, što nije tipično za kalkomelanosole.
Zemljišta nisu klasifikovana kao rendzine, jer postojeća nacionalna klasifikacija ne prepoznaje
rendzine na jedrim krečnjacima, već samo na mekim krečnjacima. Takođe, zemljišta nisu
klasifikovana ni kao karbonatni koluvijumi jer nisu nastala taloženjem podukata raspadanja
mekih karbonatnih stena. Zemljišta su dakle prema nacionalnoj klasifikaciji koluvijlni
kalkomelanosoli, organo-mineralni, i u odnosu na tipične kalkomelanosole odlikuju se većom
dubinom soluma, prisutnošću kalcijum-karbonata u zemljišnoj masi, skeletnošću, krupnijim
strukturnim agregatima, i dosta nižim sadržajem humusa. Većina ispitivanih profila pripada
Leptic Rendzic Phaeozems (Colluvic) prema WRB sistemu klasifikacije.",
publisher = "Poljoprivredni fakultet Novi Sad",
journal = "Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''",
title = "Izazovi klasifikacije koluvijalnih krečnjačkih zemljišta Velikog polja – podnožje planine Vukan",
pages = "55-54",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6576"
}
Životić, L., Mrvić, V., Gajić, B.,& Kaluđerović, L.. (2022). Izazovi klasifikacije koluvijalnih krečnjačkih zemljišta Velikog polja – podnožje planine Vukan. in Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''
Poljoprivredni fakultet Novi Sad., 54-55.
https://hdl.handle.net/21.15107/rcub_agrospace_6576
Životić L, Mrvić V, Gajić B, Kaluđerović L. Izazovi klasifikacije koluvijalnih krečnjačkih zemljišta Velikog polja – podnožje planine Vukan. in Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022''. 2022;:54-55.
https://hdl.handle.net/21.15107/rcub_agrospace_6576 .
Životić, Ljubomir, Mrvić, Vesna, Gajić, Boško, Kaluđerović, Lazar, "Izazovi klasifikacije koluvijalnih krečnjačkih zemljišta Velikog polja – podnožje planine Vukan" in Simpozijum ''Zemljište u doba precizne poljoprivrede i informacionih tehnologija – Soil AgroIT 2022'' (2022):54-55,
https://hdl.handle.net/21.15107/rcub_agrospace_6576 .

Adsorption behaviour of clomazone on inorganic and organically modified natural montmorillonite from Bogovina (Serbia)

Kaluđerović, Lazar; Tomić, Zorica; Đurović-Pejčev, Rada; Životić, Ljubomir

(Cambridge University Press, 2021)

TY  - JOUR
AU  - Kaluđerović, Lazar
AU  - Tomić, Zorica
AU  - Đurović-Pejčev, Rada
AU  - Životić, Ljubomir
PY  - 2021
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6777
AB  - The adsorption behaviour of the herbicide clomazone on inorganic and organically modified montmorillonite from the Bogovina deposit in Serbia was investigated. Montmorillonite was modified first with NaCl and then with organic complexes such as hexadecyltrimethylammonium bromide (HDTMA) and phenyltrimethylammonium chloride (PTMA). Changes in the surface properties and morphology of the montmorillonite before and after the modification with various concentrations of organic complexes were investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Adsorption of clomazone on all examined samples was investigated using the batch adsorption method. Montmorillonite modified with HDTMA-bromide displayed greater uptake of the clomazone compared to the PTMA-montmorillonite, and both organically modified montmorillonites displayed greater uptake of the herbicide compared to the inorganic montmorillonite. Comparing the Freundlich coefficient and maximum adsorbed clomazone quantity values obtained by Langmuir model, the levels of adsorption of clomazone decreased in the following order: HDTMA-montmorillonite with 1.00 cation-exchange capacity (CEC) saturation > HDTMA-montmorillonite with 0.75 CEC saturation > PTMA-montmorillonite with 1.00 CEC saturation > PTMA-montmorillonite with 0.75 CEC saturation > HDTMA-montmorillonite with 0.50 CEC saturation > HDTMA-montmorillonite with 0.25 CEC saturation > PTMA-montmorillonite with 0.50 CEC saturation > PTMA-montmorillonite with 0.25 CEC saturation > Na-montmorillonite > raw sample. The type and content of an organic cation plays an important role in the behaviour of clomazone in a solid/liquid system. It is concluded that organically modified montmorillonite from Bogovina might be used as an effective adsorbent for clomazone.
PB  - Cambridge University Press
T2  - Clay Minerals
T1  - Adsorption behaviour of clomazone on inorganic and organically modified natural montmorillonite from Bogovina (Serbia)
EP  - 350
IS  - 4
SP  - 342
VL  - 55
DO  - 10.1180/clm.2021.3
ER  - 
@article{
author = "Kaluđerović, Lazar and Tomić, Zorica and Đurović-Pejčev, Rada and Životić, Ljubomir",
year = "2021",
abstract = "The adsorption behaviour of the herbicide clomazone on inorganic and organically modified montmorillonite from the Bogovina deposit in Serbia was investigated. Montmorillonite was modified first with NaCl and then with organic complexes such as hexadecyltrimethylammonium bromide (HDTMA) and phenyltrimethylammonium chloride (PTMA). Changes in the surface properties and morphology of the montmorillonite before and after the modification with various concentrations of organic complexes were investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Adsorption of clomazone on all examined samples was investigated using the batch adsorption method. Montmorillonite modified with HDTMA-bromide displayed greater uptake of the clomazone compared to the PTMA-montmorillonite, and both organically modified montmorillonites displayed greater uptake of the herbicide compared to the inorganic montmorillonite. Comparing the Freundlich coefficient and maximum adsorbed clomazone quantity values obtained by Langmuir model, the levels of adsorption of clomazone decreased in the following order: HDTMA-montmorillonite with 1.00 cation-exchange capacity (CEC) saturation > HDTMA-montmorillonite with 0.75 CEC saturation > PTMA-montmorillonite with 1.00 CEC saturation > PTMA-montmorillonite with 0.75 CEC saturation > HDTMA-montmorillonite with 0.50 CEC saturation > HDTMA-montmorillonite with 0.25 CEC saturation > PTMA-montmorillonite with 0.50 CEC saturation > PTMA-montmorillonite with 0.25 CEC saturation > Na-montmorillonite > raw sample. The type and content of an organic cation plays an important role in the behaviour of clomazone in a solid/liquid system. It is concluded that organically modified montmorillonite from Bogovina might be used as an effective adsorbent for clomazone.",
publisher = "Cambridge University Press",
journal = "Clay Minerals",
title = "Adsorption behaviour of clomazone on inorganic and organically modified natural montmorillonite from Bogovina (Serbia)",
pages = "350-342",
number = "4",
volume = "55",
doi = "10.1180/clm.2021.3"
}
Kaluđerović, L., Tomić, Z., Đurović-Pejčev, R.,& Životić, L.. (2021). Adsorption behaviour of clomazone on inorganic and organically modified natural montmorillonite from Bogovina (Serbia). in Clay Minerals
Cambridge University Press., 55(4), 342-350.
https://doi.org/10.1180/clm.2021.3
Kaluđerović L, Tomić Z, Đurović-Pejčev R, Životić L. Adsorption behaviour of clomazone on inorganic and organically modified natural montmorillonite from Bogovina (Serbia). in Clay Minerals. 2021;55(4):342-350.
doi:10.1180/clm.2021.3 .
Kaluđerović, Lazar, Tomić, Zorica, Đurović-Pejčev, Rada, Životić, Ljubomir, "Adsorption behaviour of clomazone on inorganic and organically modified natural montmorillonite from Bogovina (Serbia)" in Clay Minerals, 55, no. 4 (2021):342-350,
https://doi.org/10.1180/clm.2021.3 . .
2

Adsorption-desorption behaviour of clomazone in Regosol and Chernozem agricultural soils

Durović-Pejcev, Rada D.; Radmanović, Svjetlana; Tomić, Zorica; Kaludjerović, Lazar; Bursić, Vojislava P.; Santrić, Ljiljana R.

(Srpsko hemijsko društvo, Beograd, 2020)

TY  - JOUR
AU  - Durović-Pejcev, Rada D.
AU  - Radmanović, Svjetlana
AU  - Tomić, Zorica
AU  - Kaludjerović, Lazar
AU  - Bursić, Vojislava P.
AU  - Santrić, Ljiljana R.
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5277
AB  - Studies of adsorption and desorption of pesticides by soils are important for understanding and predicting their fate and transmission in the environment. Considering the agricultural and environmental relevance of clomazone, its sorption-desorption behaviour was studied in two widespread Serbian agricultural soil types named Regosol and Chernozem. Both phenomena are well-described by the Freundlich equation, which shows that clomazone is generally sorbed more to organic matter than to the mineral soil fractions. Chernozem, a soil containing more of both organic matter and clay, was found to bind more, and desorb less herbicide, than Regosol. Higher desorption hysteresis obtained for Chernozem could be attributed to its larger number of high-energy sorption sites, compared to Regosol. In both soils, the hysteresis effect increases with the rise of initial clomazone concentration in the soil-water system, while the percentage of desorbed amount during successive desorption cycles decreases. The presented adsorption-desorption study shows that soil composition plays an important role in clomazone behaviour and fate in the environment, and a significantly reduced probability of contamination of both the deeper soil layers and groundwater may be expected when this herbicide is found in humus-rich soils.
PB  - Srpsko hemijsko društvo, Beograd
T2  - JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
T1  - Adsorption-desorption behaviour of clomazone in Regosol and Chernozem agricultural soils
EP  - 819
IS  - 6
SP  - 809
VL  - 85
DO  - 10.2298/JSC190917122D
ER  - 
@article{
author = "Durović-Pejcev, Rada D. and Radmanović, Svjetlana and Tomić, Zorica and Kaludjerović, Lazar and Bursić, Vojislava P. and Santrić, Ljiljana R.",
year = "2020",
abstract = "Studies of adsorption and desorption of pesticides by soils are important for understanding and predicting their fate and transmission in the environment. Considering the agricultural and environmental relevance of clomazone, its sorption-desorption behaviour was studied in two widespread Serbian agricultural soil types named Regosol and Chernozem. Both phenomena are well-described by the Freundlich equation, which shows that clomazone is generally sorbed more to organic matter than to the mineral soil fractions. Chernozem, a soil containing more of both organic matter and clay, was found to bind more, and desorb less herbicide, than Regosol. Higher desorption hysteresis obtained for Chernozem could be attributed to its larger number of high-energy sorption sites, compared to Regosol. In both soils, the hysteresis effect increases with the rise of initial clomazone concentration in the soil-water system, while the percentage of desorbed amount during successive desorption cycles decreases. The presented adsorption-desorption study shows that soil composition plays an important role in clomazone behaviour and fate in the environment, and a significantly reduced probability of contamination of both the deeper soil layers and groundwater may be expected when this herbicide is found in humus-rich soils.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "JOURNAL OF THE SERBIAN CHEMICAL SOCIETY",
title = "Adsorption-desorption behaviour of clomazone in Regosol and Chernozem agricultural soils",
pages = "819-809",
number = "6",
volume = "85",
doi = "10.2298/JSC190917122D"
}
Durović-Pejcev, R. D., Radmanović, S., Tomić, Z., Kaludjerović, L., Bursić, V. P.,& Santrić, L. R.. (2020). Adsorption-desorption behaviour of clomazone in Regosol and Chernozem agricultural soils. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
Srpsko hemijsko društvo, Beograd., 85(6), 809-819.
https://doi.org/10.2298/JSC190917122D
Durović-Pejcev RD, Radmanović S, Tomić Z, Kaludjerović L, Bursić VP, Santrić LR. Adsorption-desorption behaviour of clomazone in Regosol and Chernozem agricultural soils. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY. 2020;85(6):809-819.
doi:10.2298/JSC190917122D .
Durović-Pejcev, Rada D., Radmanović, Svjetlana, Tomić, Zorica, Kaludjerović, Lazar, Bursić, Vojislava P., Santrić, Ljiljana R., "Adsorption-desorption behaviour of clomazone in Regosol and Chernozem agricultural soils" in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 85, no. 6 (2020):809-819,
https://doi.org/10.2298/JSC190917122D . .
5
2
5

Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering

Isek, Josip; Kaludjerović, Lazar; Vuković, Nikola S.; Milošević, Maja; Vukašinović, Ivana; Tomić, Zorica

(Mineralogical Soc, Twickenham, 2020)

TY  - JOUR
AU  - Isek, Josip
AU  - Kaludjerović, Lazar
AU  - Vuković, Nikola S.
AU  - Milošević, Maja
AU  - Vukašinović, Ivana
AU  - Tomić, Zorica
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5273
AB  - Two samples collected from the phosphogypsum deposits of the chemical products industry Elixir Prahovo (Serbia) were subjected to a recrystallization experiment performed over several repeated cycles. In these tests, phosphogypsum was separated into recrystallized (purified) gypsum, insoluble residue and supernatant. Both raw phosphogypsum and recrystallized gypsum were examined using inductively coupled plasma optical emission spectrometry, X-ray diffraction and scanning electron microscopy with energy-dispersive spectrometry. The activity concentrations of (238)u, (235)u, Ra-226, Pb-210,Th- 232 and 40 K were investigated using gamma-ray spectrometry. Based on the activity concentration results, a number of radiometric parameters were calculated for the original and recrystallized phosphogypsum (i.e. radium equivalent activity, y indices for construction materials, a index and external and internal hazard indices). Raw phosphogypsum samples showed greater mean activity concentration levels of U-238 and Ra-226 than the international recommended limits, while the recrystallized gypsum demonstrated notably lower activity concentrations for these two isotopes. The activity concentration of Ra-226 in recrystallized gypsum is similar to 6 times lower than in raw phosphogypsum. Therefore, recrystallized gypsum does not present a radiation hazard when used as a building material, while raw phosphogypsum meets the requirements only for road construction materials.
PB  - Mineralogical Soc, Twickenham
T2  - Clay Minerals
T1  - Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering
EP  - 70
IS  - 1
SP  - 63
VL  - 55
DO  - 10.1180/clm.2020.11
ER  - 
@article{
author = "Isek, Josip and Kaludjerović, Lazar and Vuković, Nikola S. and Milošević, Maja and Vukašinović, Ivana and Tomić, Zorica",
year = "2020",
abstract = "Two samples collected from the phosphogypsum deposits of the chemical products industry Elixir Prahovo (Serbia) were subjected to a recrystallization experiment performed over several repeated cycles. In these tests, phosphogypsum was separated into recrystallized (purified) gypsum, insoluble residue and supernatant. Both raw phosphogypsum and recrystallized gypsum were examined using inductively coupled plasma optical emission spectrometry, X-ray diffraction and scanning electron microscopy with energy-dispersive spectrometry. The activity concentrations of (238)u, (235)u, Ra-226, Pb-210,Th- 232 and 40 K were investigated using gamma-ray spectrometry. Based on the activity concentration results, a number of radiometric parameters were calculated for the original and recrystallized phosphogypsum (i.e. radium equivalent activity, y indices for construction materials, a index and external and internal hazard indices). Raw phosphogypsum samples showed greater mean activity concentration levels of U-238 and Ra-226 than the international recommended limits, while the recrystallized gypsum demonstrated notably lower activity concentrations for these two isotopes. The activity concentration of Ra-226 in recrystallized gypsum is similar to 6 times lower than in raw phosphogypsum. Therefore, recrystallized gypsum does not present a radiation hazard when used as a building material, while raw phosphogypsum meets the requirements only for road construction materials.",
publisher = "Mineralogical Soc, Twickenham",
journal = "Clay Minerals",
title = "Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering",
pages = "70-63",
number = "1",
volume = "55",
doi = "10.1180/clm.2020.11"
}
Isek, J., Kaludjerović, L., Vuković, N. S., Milošević, M., Vukašinović, I.,& Tomić, Z.. (2020). Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering. in Clay Minerals
Mineralogical Soc, Twickenham., 55(1), 63-70.
https://doi.org/10.1180/clm.2020.11
Isek J, Kaludjerović L, Vuković NS, Milošević M, Vukašinović I, Tomić Z. Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering. in Clay Minerals. 2020;55(1):63-70.
doi:10.1180/clm.2020.11 .
Isek, Josip, Kaludjerović, Lazar, Vuković, Nikola S., Milošević, Maja, Vukašinović, Ivana, Tomić, Zorica, "Refinement of waste phosphogypsum from Prahovo, Serbia: characterization and assessment of application in civil engineering" in Clay Minerals, 55, no. 1 (2020):63-70,
https://doi.org/10.1180/clm.2020.11 . .
1
4
1
4

UTICAJ MODIFIKACIJE MONTMORIONITA NA SORPCIJU S-METOLAHLORA

Kaluđerović, Lazar; Tomić, Zorica P.

(UDRUŽENJE ZA UREĐENJE I KORIŠĆENJE ZEMLJIŠTA I DEPONIJA, 2019)

TY  - CONF
AU  - Kaluđerović, Lazar
AU  - Tomić, Zorica P.
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6534
AB  - U radu su prikazani rezultati sorpcije herbicida, s-metolahlora, na neoraganski i organski modifikovanom prirodnom montmorionitu iz Bogovine. Neorganska modifikacija je vršena zamenom dela Ca2+ jona iz međuslojnog prostora Na+ jonima. Organska modifikacija je vršena interkalacijom HDTMA+ (heksadeciltrimetilamonijum) katjona u međuslojni prostor. Cilj rada je praćenje i poboljšanje sorpcije herbicida upotrebom montmorionita. Promene u strukturi montmorionita praćene su metodom rendgenske difrakcije. Nakon organske modifikacije došlo je do širenja međuslojnog prostora montmorionita. Sa povećanjem stepena zasićenja došlo je do stvaranja različitih konfiguracija organskog kompleksa, od monosloja do parafinske konfiguracije. Batch adsorpcioni eksperimenti su pokazali da je sorpcija acetohlora u HDTMA-montmorionitima značajno veća u odnosu na Ca i Na-montmorionite. Iz tog razloga organo-montmorionit može poslužiti kao rešenje za uklanjanje herbicida, sličnih s-metolahloru, kao i drugih zagađivača iz vode i zemljišta.
PB  - UDRUŽENJE ZA UREĐENJE I KORIŠĆENJE ZEMLJIŠTA I DEPONIJA
C3  - V Savetovanje sa međunarodnim učešćem “ZEMLJIŠTE 2019”. 19. i 20. septembar 2019. godine, Petrovac na Mlavi.
T1  - UTICAJ MODIFIKACIJE MONTMORIONITA NA SORPCIJU S-METOLAHLORA
EP  - 14
SP  - 3
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6534
ER  - 
@conference{
author = "Kaluđerović, Lazar and Tomić, Zorica P.",
year = "2019",
abstract = "U radu su prikazani rezultati sorpcije herbicida, s-metolahlora, na neoraganski i organski modifikovanom prirodnom montmorionitu iz Bogovine. Neorganska modifikacija je vršena zamenom dela Ca2+ jona iz međuslojnog prostora Na+ jonima. Organska modifikacija je vršena interkalacijom HDTMA+ (heksadeciltrimetilamonijum) katjona u međuslojni prostor. Cilj rada je praćenje i poboljšanje sorpcije herbicida upotrebom montmorionita. Promene u strukturi montmorionita praćene su metodom rendgenske difrakcije. Nakon organske modifikacije došlo je do širenja međuslojnog prostora montmorionita. Sa povećanjem stepena zasićenja došlo je do stvaranja različitih konfiguracija organskog kompleksa, od monosloja do parafinske konfiguracije. Batch adsorpcioni eksperimenti su pokazali da je sorpcija acetohlora u HDTMA-montmorionitima značajno veća u odnosu na Ca i Na-montmorionite. Iz tog razloga organo-montmorionit može poslužiti kao rešenje za uklanjanje herbicida, sličnih s-metolahloru, kao i drugih zagađivača iz vode i zemljišta.",
publisher = "UDRUŽENJE ZA UREĐENJE I KORIŠĆENJE ZEMLJIŠTA I DEPONIJA",
journal = "V Savetovanje sa međunarodnim učešćem “ZEMLJIŠTE 2019”. 19. i 20. septembar 2019. godine, Petrovac na Mlavi.",
title = "UTICAJ MODIFIKACIJE MONTMORIONITA NA SORPCIJU S-METOLAHLORA",
pages = "14-3",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6534"
}
Kaluđerović, L.,& Tomić, Z. P.. (2019). UTICAJ MODIFIKACIJE MONTMORIONITA NA SORPCIJU S-METOLAHLORA. in V Savetovanje sa međunarodnim učešćem “ZEMLJIŠTE 2019”. 19. i 20. septembar 2019. godine, Petrovac na Mlavi.
UDRUŽENJE ZA UREĐENJE I KORIŠĆENJE ZEMLJIŠTA I DEPONIJA., 3-14.
https://hdl.handle.net/21.15107/rcub_agrospace_6534
Kaluđerović L, Tomić ZP. UTICAJ MODIFIKACIJE MONTMORIONITA NA SORPCIJU S-METOLAHLORA. in V Savetovanje sa međunarodnim učešćem “ZEMLJIŠTE 2019”. 19. i 20. septembar 2019. godine, Petrovac na Mlavi.. 2019;:3-14.
https://hdl.handle.net/21.15107/rcub_agrospace_6534 .
Kaluđerović, Lazar, Tomić, Zorica P., "UTICAJ MODIFIKACIJE MONTMORIONITA NA SORPCIJU S-METOLAHLORA" in V Savetovanje sa međunarodnim učešćem “ZEMLJIŠTE 2019”. 19. i 20. septembar 2019. godine, Petrovac na Mlavi. (2019):3-14,
https://hdl.handle.net/21.15107/rcub_agrospace_6534 .

Characterisation of Purified Gypsum and Insoluble Impurities Obtained from Phosphogypsum Waste

Kaludjerović, Lazar; Isek, Josip; Vuković, Nikola; Milošević, Maja

(Polish Mineral Eng Soc, Krakow, 2019)

TY  - JOUR
AU  - Kaludjerović, Lazar
AU  - Isek, Josip
AU  - Vuković, Nikola
AU  - Milošević, Maja
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4949
AB  - In this study, the chemical and phase composition of two samples of phosphogypsum from the waste dumps of the Industry of Chemical Products "Elixir - Prahovo" (Serbia) were examined, as well as the possibility of recrystallization of gypsum from an aqueous suspension of phosphogypsum. 'the negative effect of higher temperatures on the solubility of calcium sulfate (13.08 mmol/dm(3) at 95 degrees C vs. 15.43 mmol/dm(3) at 40 degrees C) was utilized. In several repeated cycles, calcium sulfate component was progressively dissolved in water at room temperature and then precipitated at 100 degrees C, using the same liquid phase throughout the experiment. Therefore, phosphogypsum was separated into recrystallized (purified) gypsum, insoluble residue and supernatant, and the mass balance for the experiment was calculated. Elemental, XRD and SEM-EDS analyses were performed on raw phosphogypsum, purified gypsum and insoluble residue. The whiteness of raw phosphogypsum and purified gypsum were determined and compared. The main objective of the study was to investigate the nature of insoluble impurities, in order to define and optimize the methods for their removal during a potential industrial processing of phosphogypsum.
PB  - Polish Mineral Eng Soc, Krakow
T2  - Inzynieria Mineralna-Journal of the Polish Mineral Engineering Society
T1  - Characterisation of Purified Gypsum and Insoluble Impurities Obtained from Phosphogypsum Waste
EP  - 78
IS  - 1
SP  - 73
DO  - 10.29227/IM-2019-01-13
ER  - 
@article{
author = "Kaludjerović, Lazar and Isek, Josip and Vuković, Nikola and Milošević, Maja",
year = "2019",
abstract = "In this study, the chemical and phase composition of two samples of phosphogypsum from the waste dumps of the Industry of Chemical Products "Elixir - Prahovo" (Serbia) were examined, as well as the possibility of recrystallization of gypsum from an aqueous suspension of phosphogypsum. 'the negative effect of higher temperatures on the solubility of calcium sulfate (13.08 mmol/dm(3) at 95 degrees C vs. 15.43 mmol/dm(3) at 40 degrees C) was utilized. In several repeated cycles, calcium sulfate component was progressively dissolved in water at room temperature and then precipitated at 100 degrees C, using the same liquid phase throughout the experiment. Therefore, phosphogypsum was separated into recrystallized (purified) gypsum, insoluble residue and supernatant, and the mass balance for the experiment was calculated. Elemental, XRD and SEM-EDS analyses were performed on raw phosphogypsum, purified gypsum and insoluble residue. The whiteness of raw phosphogypsum and purified gypsum were determined and compared. The main objective of the study was to investigate the nature of insoluble impurities, in order to define and optimize the methods for their removal during a potential industrial processing of phosphogypsum.",
publisher = "Polish Mineral Eng Soc, Krakow",
journal = "Inzynieria Mineralna-Journal of the Polish Mineral Engineering Society",
title = "Characterisation of Purified Gypsum and Insoluble Impurities Obtained from Phosphogypsum Waste",
pages = "78-73",
number = "1",
doi = "10.29227/IM-2019-01-13"
}
Kaludjerović, L., Isek, J., Vuković, N.,& Milošević, M.. (2019). Characterisation of Purified Gypsum and Insoluble Impurities Obtained from Phosphogypsum Waste. in Inzynieria Mineralna-Journal of the Polish Mineral Engineering Society
Polish Mineral Eng Soc, Krakow.(1), 73-78.
https://doi.org/10.29227/IM-2019-01-13
Kaludjerović L, Isek J, Vuković N, Milošević M. Characterisation of Purified Gypsum and Insoluble Impurities Obtained from Phosphogypsum Waste. in Inzynieria Mineralna-Journal of the Polish Mineral Engineering Society. 2019;(1):73-78.
doi:10.29227/IM-2019-01-13 .
Kaludjerović, Lazar, Isek, Josip, Vuković, Nikola, Milošević, Maja, "Characterisation of Purified Gypsum and Insoluble Impurities Obtained from Phosphogypsum Waste" in Inzynieria Mineralna-Journal of the Polish Mineral Engineering Society, no. 1 (2019):73-78,
https://doi.org/10.29227/IM-2019-01-13 . .
1
1

Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics

Milošević, Maja; Dabić, Predrag; Kovac, Sabina; Kaludjerović, Lazar; Logar, Mihovil

(Mineralogical Soc, Twickenham, 2019)

TY  - JOUR
AU  - Milošević, Maja
AU  - Dabić, Predrag
AU  - Kovac, Sabina
AU  - Kaludjerović, Lazar
AU  - Logar, Mihovil
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4911
AB  - This study focuses on the mineralogical characterization of four raw clay samples from Dobrodo deposit, Serbia. Several analytical methods were applied to determine the chemical and mineralogical composition, morphology and physical properties (colour, plasticity, specific surface area, particle size and cation-exchange capacity) of the clay samples. Kaolinite, smectite and illite are the predominant phases in all of the samples studied that contain between 60.2 and 87.1 wt.% of clay. Quartz, feldspars, paragonite and Ti- and Fe-bearing phases were also identified. The relatively high SiO2/Al2O3 mass ratio indicates abundant quartz. The cation-exchange capacity of the samples varied between low and moderately charged clay minerals (12-52 mmol 100 g(-1)) with specific surface area values ranging from 94 to 410 m(2) g(-1). The plasticity index values (11-23%) suggest low to moderate plasticity. Preliminary results show that most of the raw clay from Dobrodo deposit might be suitable for use in ceramic applications.
PB  - Mineralogical Soc, Twickenham
T2  - Clay Minerals
T1  - Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics
EP  - 377
IS  - 4
SP  - 369
VL  - 54
DO  - 10.1180/clm.2019.49
ER  - 
@article{
author = "Milošević, Maja and Dabić, Predrag and Kovac, Sabina and Kaludjerović, Lazar and Logar, Mihovil",
year = "2019",
abstract = "This study focuses on the mineralogical characterization of four raw clay samples from Dobrodo deposit, Serbia. Several analytical methods were applied to determine the chemical and mineralogical composition, morphology and physical properties (colour, plasticity, specific surface area, particle size and cation-exchange capacity) of the clay samples. Kaolinite, smectite and illite are the predominant phases in all of the samples studied that contain between 60.2 and 87.1 wt.% of clay. Quartz, feldspars, paragonite and Ti- and Fe-bearing phases were also identified. The relatively high SiO2/Al2O3 mass ratio indicates abundant quartz. The cation-exchange capacity of the samples varied between low and moderately charged clay minerals (12-52 mmol 100 g(-1)) with specific surface area values ranging from 94 to 410 m(2) g(-1). The plasticity index values (11-23%) suggest low to moderate plasticity. Preliminary results show that most of the raw clay from Dobrodo deposit might be suitable for use in ceramic applications.",
publisher = "Mineralogical Soc, Twickenham",
journal = "Clay Minerals",
title = "Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics",
pages = "377-369",
number = "4",
volume = "54",
doi = "10.1180/clm.2019.49"
}
Milošević, M., Dabić, P., Kovac, S., Kaludjerović, L.,& Logar, M.. (2019). Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics. in Clay Minerals
Mineralogical Soc, Twickenham., 54(4), 369-377.
https://doi.org/10.1180/clm.2019.49
Milošević M, Dabić P, Kovac S, Kaludjerović L, Logar M. Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics. in Clay Minerals. 2019;54(4):369-377.
doi:10.1180/clm.2019.49 .
Milošević, Maja, Dabić, Predrag, Kovac, Sabina, Kaludjerović, Lazar, Logar, Mihovil, "Mineralogical study of clays from Dobrodo, Serbia, for use in ceramics" in Clay Minerals, 54, no. 4 (2019):369-377,
https://doi.org/10.1180/clm.2019.49 . .
4
1
3

An analysis of naturally occurring radionuclides and Cs-137 in the soils of urban areas using gamma-ray spectrometry

Vukašinović, Ivana; Todorović, D.; Životić, Ljubomir; Kaludjerović, Lazar; Djordjević, Aleksandar

(Springer, New York, 2018)

TY  - JOUR
AU  - Vukašinović, Ivana
AU  - Todorović, D.
AU  - Životić, Ljubomir
AU  - Kaludjerović, Lazar
AU  - Djordjević, Aleksandar
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4734
AB  - This study of environmental radioactivity was carried out in the soils of an urban area. Naturally occurring gamma-emitting radionuclides and man-made Cs-137 were found in the soil profiles collected from four parks in the central Belgrade city area and the soil layer was examined every 10 cm and to a depth of 50 cm. Radioisotope activity concentrations (Bq kg(-1)) in the samples of urban soil using the gamma-ray spectrometry method were in the range of 14-46 for U-238, 33-50 for Ra-226, 29-63 for Pb-210, 1.2-3.4 for U-235, 28-50 for Th-232, 424-576 for K-40 and 0.7-35.8 for Cs-137. Some of the basic physicochemical soil properties (pH, organic matter content, calcium-carbonate content, particle size distribution) were determined to investigate the impact on the vertical distribution of radionuclides. The results of this investigation showed that variations of activity concentration ratios of radionuclides that belong to the same (U-238/Ra-226) or different radioactive series (Th-232/Ra-226; U-235/U-238), including Pb-210/Cs-137 ratios could well be explained by the properties of the soil. Alkaline pH reaction, the accumulation of organic matter in the uppermost and of carbonates in the deepest layers of urban soil had an effect on U-238/Ra-226, and Pb-210/Cs-137 activity concentration ratio values, while Th-232/Ra-226 and partially U-235/U-238 ratios were associated with the particle sizes vertical distribution. A study of radionuclides in the samples of leaves of two deciduous tree species common for these parks was also conducted and Pb-210 and K-40 were found concentrated in leaves rather than other investigated radionuclides.
PB  - Springer, New York
T2  - International Journal of Environmental Science and Technology
T1  - An analysis of naturally occurring radionuclides and Cs-137 in the soils of urban areas using gamma-ray spectrometry
EP  - 1060
IS  - 5
SP  - 1049
VL  - 15
DO  - 10.1007/s13762-017-1467-z
ER  - 
@article{
author = "Vukašinović, Ivana and Todorović, D. and Životić, Ljubomir and Kaludjerović, Lazar and Djordjević, Aleksandar",
year = "2018",
abstract = "This study of environmental radioactivity was carried out in the soils of an urban area. Naturally occurring gamma-emitting radionuclides and man-made Cs-137 were found in the soil profiles collected from four parks in the central Belgrade city area and the soil layer was examined every 10 cm and to a depth of 50 cm. Radioisotope activity concentrations (Bq kg(-1)) in the samples of urban soil using the gamma-ray spectrometry method were in the range of 14-46 for U-238, 33-50 for Ra-226, 29-63 for Pb-210, 1.2-3.4 for U-235, 28-50 for Th-232, 424-576 for K-40 and 0.7-35.8 for Cs-137. Some of the basic physicochemical soil properties (pH, organic matter content, calcium-carbonate content, particle size distribution) were determined to investigate the impact on the vertical distribution of radionuclides. The results of this investigation showed that variations of activity concentration ratios of radionuclides that belong to the same (U-238/Ra-226) or different radioactive series (Th-232/Ra-226; U-235/U-238), including Pb-210/Cs-137 ratios could well be explained by the properties of the soil. Alkaline pH reaction, the accumulation of organic matter in the uppermost and of carbonates in the deepest layers of urban soil had an effect on U-238/Ra-226, and Pb-210/Cs-137 activity concentration ratio values, while Th-232/Ra-226 and partially U-235/U-238 ratios were associated with the particle sizes vertical distribution. A study of radionuclides in the samples of leaves of two deciduous tree species common for these parks was also conducted and Pb-210 and K-40 were found concentrated in leaves rather than other investigated radionuclides.",
publisher = "Springer, New York",
journal = "International Journal of Environmental Science and Technology",
title = "An analysis of naturally occurring radionuclides and Cs-137 in the soils of urban areas using gamma-ray spectrometry",
pages = "1060-1049",
number = "5",
volume = "15",
doi = "10.1007/s13762-017-1467-z"
}
Vukašinović, I., Todorović, D., Životić, L., Kaludjerović, L.,& Djordjević, A.. (2018). An analysis of naturally occurring radionuclides and Cs-137 in the soils of urban areas using gamma-ray spectrometry. in International Journal of Environmental Science and Technology
Springer, New York., 15(5), 1049-1060.
https://doi.org/10.1007/s13762-017-1467-z
Vukašinović I, Todorović D, Životić L, Kaludjerović L, Djordjević A. An analysis of naturally occurring radionuclides and Cs-137 in the soils of urban areas using gamma-ray spectrometry. in International Journal of Environmental Science and Technology. 2018;15(5):1049-1060.
doi:10.1007/s13762-017-1467-z .
Vukašinović, Ivana, Todorović, D., Životić, Ljubomir, Kaludjerović, Lazar, Djordjević, Aleksandar, "An analysis of naturally occurring radionuclides and Cs-137 in the soils of urban areas using gamma-ray spectrometry" in International Journal of Environmental Science and Technology, 15, no. 5 (2018):1049-1060,
https://doi.org/10.1007/s13762-017-1467-z . .
17
10
18

Analysis of macro- and microelements in drinking water from the Požarevac city public water supply system

Rajković, Miloš; Stojanović, Mirjana D.; Milojković, Sladjana; Djordjević, Aleksandar; Kaludjerović, Lazar

(Univerzitet u Beogradu - Poljoprivredni fakultet, Beograd, 2018)

TY  - JOUR
AU  - Rajković, Miloš
AU  - Stojanović, Mirjana D.
AU  - Milojković, Sladjana
AU  - Djordjević, Aleksandar
AU  - Kaludjerović, Lazar
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4847
AB  - This study aims at analysing physical, chemical and microbiological properties, and content of macro- and microelements in the water from the Požarevac city public water supply system. Analysis shows an increased content of Ca in drinking water, as a result of the position of Požarevac on the sediments of river terrace of accumulative character of t1 type, predominantly consisting of quartzite. The water from the public water supply is alkaline ('calcic', 'bicarbonate water') and very hard, due to the increased Ca content. Beside Ca, potassium and aluminium exceed the maximum contaminant level, while Pb and Cd are at the very limit. Calculated data show that there are no short-term health risks regarding elements exceeding allowed concentrations found in the public water supply system. Data analysis regarding long-term health risks shows that Cd present in drinking water poses the only relevant threat to human health. Cancer risk is present in 202 out of 1000 inhabitants using this water.
AB  - Predmet ispitivanja bila je voda za piće iz vodovodne mreže Grada Požarevca, sa aspekta fizičko-hemijske i mikrobiološke ispravnosti i prisustva makro- i mikroelemenata. Ispitivanja su ukazala na povećanu koncentraciju Ca u vodi za piće kao posledica položaja Požarevca na sedimentu rečne terase akumulativnog karaktera t1, koja je pretežno sagrađena od kvarcita. Kao posledica povećane koncentracije Ca, voda iz vodovodne mreže je alkalnog karaktera ('kalcijumova', 'biokarbonatna voda') i veoma tvrda. Osim Ca, K i Al prevazilaze maksimalno dozvoljene koncentracije, dok se Pb i Cd nalaze na samoj granici. Proračunati podaci pokazuju rizik od unošenja elemenata koji se u vodi iz vodovodne mreže Grada Požarevca nalaze u vrednosti višoj od dozvoljene pravilnikom, ni za jedan metal ne postoji kratkoročni zdravstveni rizik po zdravlje ljudi. Analiza podataka o dugoročnom zdravstvenom riziku ukazuje da jedina realna opasnost postoji od prisustva Cd u vodi za piće. Rizik od pojave kancera prisutan je kod 202 stanovnika od 1000 stanovnika koji koriste ovu vodu za piće.
PB  - Univerzitet u Beogradu - Poljoprivredni fakultet, Beograd
T2  - Journal of Agricultural Sciences (Belgrade)
T1  - Analysis of macro- and microelements in drinking water from the Požarevac city public water supply system
T1  - Analiza sadržaja makro- i mikroelemenata u vodi za piće iz vodovodne mreže grada Požarevca
EP  - 260
IS  - 3
SP  - 241
VL  - 63
DO  - 10.2298/JAS1803241R
ER  - 
@article{
author = "Rajković, Miloš and Stojanović, Mirjana D. and Milojković, Sladjana and Djordjević, Aleksandar and Kaludjerović, Lazar",
year = "2018",
abstract = "This study aims at analysing physical, chemical and microbiological properties, and content of macro- and microelements in the water from the Požarevac city public water supply system. Analysis shows an increased content of Ca in drinking water, as a result of the position of Požarevac on the sediments of river terrace of accumulative character of t1 type, predominantly consisting of quartzite. The water from the public water supply is alkaline ('calcic', 'bicarbonate water') and very hard, due to the increased Ca content. Beside Ca, potassium and aluminium exceed the maximum contaminant level, while Pb and Cd are at the very limit. Calculated data show that there are no short-term health risks regarding elements exceeding allowed concentrations found in the public water supply system. Data analysis regarding long-term health risks shows that Cd present in drinking water poses the only relevant threat to human health. Cancer risk is present in 202 out of 1000 inhabitants using this water., Predmet ispitivanja bila je voda za piće iz vodovodne mreže Grada Požarevca, sa aspekta fizičko-hemijske i mikrobiološke ispravnosti i prisustva makro- i mikroelemenata. Ispitivanja su ukazala na povećanu koncentraciju Ca u vodi za piće kao posledica položaja Požarevca na sedimentu rečne terase akumulativnog karaktera t1, koja je pretežno sagrađena od kvarcita. Kao posledica povećane koncentracije Ca, voda iz vodovodne mreže je alkalnog karaktera ('kalcijumova', 'biokarbonatna voda') i veoma tvrda. Osim Ca, K i Al prevazilaze maksimalno dozvoljene koncentracije, dok se Pb i Cd nalaze na samoj granici. Proračunati podaci pokazuju rizik od unošenja elemenata koji se u vodi iz vodovodne mreže Grada Požarevca nalaze u vrednosti višoj od dozvoljene pravilnikom, ni za jedan metal ne postoji kratkoročni zdravstveni rizik po zdravlje ljudi. Analiza podataka o dugoročnom zdravstvenom riziku ukazuje da jedina realna opasnost postoji od prisustva Cd u vodi za piće. Rizik od pojave kancera prisutan je kod 202 stanovnika od 1000 stanovnika koji koriste ovu vodu za piće.",
publisher = "Univerzitet u Beogradu - Poljoprivredni fakultet, Beograd",
journal = "Journal of Agricultural Sciences (Belgrade)",
title = "Analysis of macro- and microelements in drinking water from the Požarevac city public water supply system, Analiza sadržaja makro- i mikroelemenata u vodi za piće iz vodovodne mreže grada Požarevca",
pages = "260-241",
number = "3",
volume = "63",
doi = "10.2298/JAS1803241R"
}
Rajković, M., Stojanović, M. D., Milojković, S., Djordjević, A.,& Kaludjerović, L.. (2018). Analysis of macro- and microelements in drinking water from the Požarevac city public water supply system. in Journal of Agricultural Sciences (Belgrade)
Univerzitet u Beogradu - Poljoprivredni fakultet, Beograd., 63(3), 241-260.
https://doi.org/10.2298/JAS1803241R
Rajković M, Stojanović MD, Milojković S, Djordjević A, Kaludjerović L. Analysis of macro- and microelements in drinking water from the Požarevac city public water supply system. in Journal of Agricultural Sciences (Belgrade). 2018;63(3):241-260.
doi:10.2298/JAS1803241R .
Rajković, Miloš, Stojanović, Mirjana D., Milojković, Sladjana, Djordjević, Aleksandar, Kaludjerović, Lazar, "Analysis of macro- and microelements in drinking water from the Požarevac city public water supply system" in Journal of Agricultural Sciences (Belgrade), 63, no. 3 (2018):241-260,
https://doi.org/10.2298/JAS1803241R . .

Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite

Kaludjerović, Lazar; Tomić, Zorica; Ašanin, Darko P.; Durović-Pejcev, Rada D.; Kresović, Branka

(Taylor & Francis Inc, Philadelphia, 2018)

TY  - JOUR
AU  - Kaludjerović, Lazar
AU  - Tomić, Zorica
AU  - Ašanin, Darko P.
AU  - Durović-Pejcev, Rada D.
AU  - Kresović, Branka
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4667
AB  - The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
T1  - Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite
EP  - 509
IS  - 8
SP  - 503
VL  - 53
DO  - 10.1080/03601234.2018.1462930
ER  - 
@article{
author = "Kaludjerović, Lazar and Tomić, Zorica and Ašanin, Darko P. and Durović-Pejcev, Rada D. and Kresović, Branka",
year = "2018",
abstract = "The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was",
title = "Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite",
pages = "509-503",
number = "8",
volume = "53",
doi = "10.1080/03601234.2018.1462930"
}
Kaludjerović, L., Tomić, Z., Ašanin, D. P., Durović-Pejcev, R. D.,& Kresović, B.. (2018). Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
Taylor & Francis Inc, Philadelphia., 53(8), 503-509.
https://doi.org/10.1080/03601234.2018.1462930
Kaludjerović L, Tomić Z, Ašanin DP, Durović-Pejcev RD, Kresović B. Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was. 2018;53(8):503-509.
doi:10.1080/03601234.2018.1462930 .
Kaludjerović, Lazar, Tomić, Zorica, Ašanin, Darko P., Durović-Pejcev, Rada D., Kresović, Branka, "Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 53, no. 8 (2018):503-509,
https://doi.org/10.1080/03601234.2018.1462930 . .
2
1
2

Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina

Kaludjerović, Lazar

(Univerzitet u Beogradu, Rudarsko-geološki fakultet, 2018)

TY  - THES
AU  - Kaludjerović, Lazar
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/56
AB  - Efficiency of inorganic and organic modified montmorillonites from Bogovina for sorption of the S-metolachlor and clomazone was determined using batch adsorption method. Montmorillonite samples were pretreated with NaCl solution and then with different concentrations of organic complexes. Adsorption isotherms were measured by treatment of the samples with different concentrations of herbicide. Detailed mineralogical characterization of samples was performed using the X-ray diffraction method. Results of interaction between organic complexes and herbicides were obtained using X-ray diffraction, optical, thermal and spectroscopic analysis. Based on the results obtained using X-ray diffraction, it was concluded that all examined organic complexes and herbicides intercalated into interlayer space of montmorillonite. Montmorillonites modified with HDTMA complex exhibited monolayer, bilayer and pseudotrilayer arrangement of HDTMA+ cations in interlayer space, depending on degree of saturation. It has been found that the HDTMA+ cations are forming the partition phase for the herbicide on the surface of the montmorillonite. On the other hand, montmorillonite modified with PTMA complex exhibited monolayer arrangement of cations on the surface of montmorillonite in such a way that the cations act as pillars in interlayer space. The molecules of herbicides in this case were adsorbed on the surface of the montmorillonite. Which functional groups were involved in bonding processes between montmorillonite, organic complex and herbicide best describes infrared spectroscopy. High sorption of examined herbicides on some organic modified montmorillonites creates an opportunity for application of these substrates as potentially useful material for removal of S-metolachlor and clomazone from the environment.
AB  - fikasnost prilikom sorpcije S-metolahlora i klomazona od strane neorganskih i organski modifikovanih montmorionita sa lokaliteta Bogovina odreĎena je metodom bach adsorpcije. Uzorci montmorionita su tretirani prvo rastvorom NaCl a zatim i različitim koncentracijama organskih kompleksa. Adsorpcione izoterme su dobijene tretiranjem uzoraka različitim koncentracijama herbicida. Detaljna mineraloška karakterizacija uzoraka uraĎena je metodom rendgenske difrakcije. Rezultati interakcije montmorionita sa organskim kompleksima i herbicidima dobijeni su primenom rendgenskih, optičkih, termičkih i spektroskopskih metoda. Na osnovu rezultata rendgenskih ispitivanja uzoraka, utvrĎeno je prisustvo organskih kompleksa i herbicida u meĎuslojnom prostoru montmorionita. Montmorioniti modifikovani sa HDTMA kompleksom pokazivali su jednoslojnu, dvoslojnu i pseudotroslojnu orijentaciju HDTMA+ katjona u meĎuslojnom prostoru. UtvrĎeno je da HDTMA+ katjoni formiraju particionu fazu na površini montmorionita, na kojoj dolazi do sorpcije molekula herbicida. Sa druge strane, montmorioniti modifikovani sa PTMA kompleksom pokazivali su jednoslojnu orijentaciju katjona na površini montmorionita i to na takav način da se katjoni ponašaju kao stubovi koji u zavisnosti od dimenzija dovode do širenja meĎuslojnog prostora. Molekuli herbicida se u tom slučaju vezuju za površinu montmorionita. Primenom metode infracrvene spektroskopije utvrĎeno je koje funkcionalne grupe učestvuju u interakciji izmeĎu montmorionita, organskih kompleksa i herbicida. Visoka sposobnost sorpcije odreĎenih uzoraka organski modifikovanih montmorionita otvara mogućnost njihove primene kao potencijalne sirovine za uklanjanje S-metolahlora i klomazona iz ţivotne sredine...
PB  - Univerzitet u Beogradu, Rudarsko-geološki fakultet
T1  - Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina
T1  - Sorpcija herbicida na neorganski i organski modifikovanom prirodnom montmorionitu iz Bogovine
UR  - https://hdl.handle.net/21.15107/rcub_nardus_9373
ER  - 
@phdthesis{
author = "Kaludjerović, Lazar",
year = "2018",
abstract = "Efficiency of inorganic and organic modified montmorillonites from Bogovina for sorption of the S-metolachlor and clomazone was determined using batch adsorption method. Montmorillonite samples were pretreated with NaCl solution and then with different concentrations of organic complexes. Adsorption isotherms were measured by treatment of the samples with different concentrations of herbicide. Detailed mineralogical characterization of samples was performed using the X-ray diffraction method. Results of interaction between organic complexes and herbicides were obtained using X-ray diffraction, optical, thermal and spectroscopic analysis. Based on the results obtained using X-ray diffraction, it was concluded that all examined organic complexes and herbicides intercalated into interlayer space of montmorillonite. Montmorillonites modified with HDTMA complex exhibited monolayer, bilayer and pseudotrilayer arrangement of HDTMA+ cations in interlayer space, depending on degree of saturation. It has been found that the HDTMA+ cations are forming the partition phase for the herbicide on the surface of the montmorillonite. On the other hand, montmorillonite modified with PTMA complex exhibited monolayer arrangement of cations on the surface of montmorillonite in such a way that the cations act as pillars in interlayer space. The molecules of herbicides in this case were adsorbed on the surface of the montmorillonite. Which functional groups were involved in bonding processes between montmorillonite, organic complex and herbicide best describes infrared spectroscopy. High sorption of examined herbicides on some organic modified montmorillonites creates an opportunity for application of these substrates as potentially useful material for removal of S-metolachlor and clomazone from the environment., fikasnost prilikom sorpcije S-metolahlora i klomazona od strane neorganskih i organski modifikovanih montmorionita sa lokaliteta Bogovina odreĎena je metodom bach adsorpcije. Uzorci montmorionita su tretirani prvo rastvorom NaCl a zatim i različitim koncentracijama organskih kompleksa. Adsorpcione izoterme su dobijene tretiranjem uzoraka različitim koncentracijama herbicida. Detaljna mineraloška karakterizacija uzoraka uraĎena je metodom rendgenske difrakcije. Rezultati interakcije montmorionita sa organskim kompleksima i herbicidima dobijeni su primenom rendgenskih, optičkih, termičkih i spektroskopskih metoda. Na osnovu rezultata rendgenskih ispitivanja uzoraka, utvrĎeno je prisustvo organskih kompleksa i herbicida u meĎuslojnom prostoru montmorionita. Montmorioniti modifikovani sa HDTMA kompleksom pokazivali su jednoslojnu, dvoslojnu i pseudotroslojnu orijentaciju HDTMA+ katjona u meĎuslojnom prostoru. UtvrĎeno je da HDTMA+ katjoni formiraju particionu fazu na površini montmorionita, na kojoj dolazi do sorpcije molekula herbicida. Sa druge strane, montmorioniti modifikovani sa PTMA kompleksom pokazivali su jednoslojnu orijentaciju katjona na površini montmorionita i to na takav način da se katjoni ponašaju kao stubovi koji u zavisnosti od dimenzija dovode do širenja meĎuslojnog prostora. Molekuli herbicida se u tom slučaju vezuju za površinu montmorionita. Primenom metode infracrvene spektroskopije utvrĎeno je koje funkcionalne grupe učestvuju u interakciji izmeĎu montmorionita, organskih kompleksa i herbicida. Visoka sposobnost sorpcije odreĎenih uzoraka organski modifikovanih montmorionita otvara mogućnost njihove primene kao potencijalne sirovine za uklanjanje S-metolahlora i klomazona iz ţivotne sredine...",
publisher = "Univerzitet u Beogradu, Rudarsko-geološki fakultet",
title = "Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina, Sorpcija herbicida na neorganski i organski modifikovanom prirodnom montmorionitu iz Bogovine",
url = "https://hdl.handle.net/21.15107/rcub_nardus_9373"
}
Kaludjerović, L.. (2018). Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina. 
Univerzitet u Beogradu, Rudarsko-geološki fakultet..
https://hdl.handle.net/21.15107/rcub_nardus_9373
Kaludjerović L. Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina. 2018;.
https://hdl.handle.net/21.15107/rcub_nardus_9373 .
Kaludjerović, Lazar, "Sorption of herbicides on inorganic and organic modified natural montmorillonite from Bogovina" (2018),
https://hdl.handle.net/21.15107/rcub_nardus_9373 .

Preliminary investigation of mineral content of pollen collected from different Serbian maize hybrids - is there any potential nutritional value?

Kostić, Aleksandar; Kaludjerović, Lazar; Dojčinović, Biljana; Barać, Miroljub; Babić, Vojka; Mačukanović-Jocić, Marina

(Wiley, Hoboken, 2017)

TY  - JOUR
AU  - Kostić, Aleksandar
AU  - Kaludjerović, Lazar
AU  - Dojčinović, Biljana
AU  - Barać, Miroljub
AU  - Babić, Vojka
AU  - Mačukanović-Jocić, Marina
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4338
AB  - BACKGROUND: Bee pollen has already proved to be a good supplement rich in iron and zinc. Studies on the application of flower pollen in the food industry and medicine have begun. Bearing in mind the prevalence of maize as a crop culture, its pollen will be easily available. The mineral composition of pollen of seven Serbian maize hybrids was analyzed in order to establish its nutritional value and the benefits of its implementation in the human diet using the inductively coupled plasma method. RESULTSThe presence of twenty four different macro- (nine) and micronutrients (fifteen) was detected. The most common minerals were phosphorus and potassium, while arsenic, cobalt, lead, nickel and molybdenum were found in some samples. CONCLUSIONComparing the results obtained with recommended or tolerable dietary intake references for adults, it was found that maize pollen can be used as a very good source of zinc, iron, chromium and manganese for humans. With regard to selenium content, pollen samples proved to be moderately good source of this important micronutrient. Contents of some elements (Fe, Zn, Mn, Cr, Se, Al and V) showed significant differences depending on hybrid type. In some samples increased concentrations of aluminum and vanadium were recorded, which may pose a potential problem due to their toxicity.
PB  - Wiley, Hoboken
T2  - Journal of the Science of Food and Agriculture
T1  - Preliminary investigation of mineral content of pollen collected from different Serbian maize hybrids - is there any potential nutritional value?
EP  - 2809
IS  - 9
SP  - 2803
VL  - 97
DO  - 10.1002/jsfa.8108
ER  - 
@article{
author = "Kostić, Aleksandar and Kaludjerović, Lazar and Dojčinović, Biljana and Barać, Miroljub and Babić, Vojka and Mačukanović-Jocić, Marina",
year = "2017",
abstract = "BACKGROUND: Bee pollen has already proved to be a good supplement rich in iron and zinc. Studies on the application of flower pollen in the food industry and medicine have begun. Bearing in mind the prevalence of maize as a crop culture, its pollen will be easily available. The mineral composition of pollen of seven Serbian maize hybrids was analyzed in order to establish its nutritional value and the benefits of its implementation in the human diet using the inductively coupled plasma method. RESULTSThe presence of twenty four different macro- (nine) and micronutrients (fifteen) was detected. The most common minerals were phosphorus and potassium, while arsenic, cobalt, lead, nickel and molybdenum were found in some samples. CONCLUSIONComparing the results obtained with recommended or tolerable dietary intake references for adults, it was found that maize pollen can be used as a very good source of zinc, iron, chromium and manganese for humans. With regard to selenium content, pollen samples proved to be moderately good source of this important micronutrient. Contents of some elements (Fe, Zn, Mn, Cr, Se, Al and V) showed significant differences depending on hybrid type. In some samples increased concentrations of aluminum and vanadium were recorded, which may pose a potential problem due to their toxicity.",
publisher = "Wiley, Hoboken",
journal = "Journal of the Science of Food and Agriculture",
title = "Preliminary investigation of mineral content of pollen collected from different Serbian maize hybrids - is there any potential nutritional value?",
pages = "2809-2803",
number = "9",
volume = "97",
doi = "10.1002/jsfa.8108"
}
Kostić, A., Kaludjerović, L., Dojčinović, B., Barać, M., Babić, V.,& Mačukanović-Jocić, M.. (2017). Preliminary investigation of mineral content of pollen collected from different Serbian maize hybrids - is there any potential nutritional value?. in Journal of the Science of Food and Agriculture
Wiley, Hoboken., 97(9), 2803-2809.
https://doi.org/10.1002/jsfa.8108
Kostić A, Kaludjerović L, Dojčinović B, Barać M, Babić V, Mačukanović-Jocić M. Preliminary investigation of mineral content of pollen collected from different Serbian maize hybrids - is there any potential nutritional value?. in Journal of the Science of Food and Agriculture. 2017;97(9):2803-2809.
doi:10.1002/jsfa.8108 .
Kostić, Aleksandar, Kaludjerović, Lazar, Dojčinović, Biljana, Barać, Miroljub, Babić, Vojka, Mačukanović-Jocić, Marina, "Preliminary investigation of mineral content of pollen collected from different Serbian maize hybrids - is there any potential nutritional value?" in Journal of the Science of Food and Agriculture, 97, no. 9 (2017):2803-2809,
https://doi.org/10.1002/jsfa.8108 . .
12
7
9

Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry

Milošević, Maja; Logar, Mihovil; Kaludjerović, Lazar; Jelić, Ivana

(Elsevier Science Bv, Amsterdam, 2017)

TY  - CONF
AU  - Milošević, Maja
AU  - Logar, Mihovil
AU  - Kaludjerović, Lazar
AU  - Jelić, Ivana
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4435
AB  - This study focuses on the mineralogical and thermal properties of clay from "Slatina" deposit, Ub, Serbia. Sampled clays were analysed by XRD, IR spectroscopy, ICP-OES, DTA, specific surface area (SSA), cationic exchange capacity (CEC), gravimetric and grain size measurements. Results show that the studied samples have a medium content of smectite-illite minerals with smaller amount of kaolinite together with quartz, feldspars and goethite. They consist generally of fine particles with medium to high plasticity. Based on their mineral composition and physical properties (grain size, plasticity, CEC) the clays are suitable as raw material for the ceramics industry.
PB  - Elsevier Science Bv, Amsterdam
C3  - European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere)
T1  - Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry
EP  - 655
SP  - 650
VL  - 125
DO  - 10.1016/j.egypro.2017.08.270
ER  - 
@conference{
author = "Milošević, Maja and Logar, Mihovil and Kaludjerović, Lazar and Jelić, Ivana",
year = "2017",
abstract = "This study focuses on the mineralogical and thermal properties of clay from "Slatina" deposit, Ub, Serbia. Sampled clays were analysed by XRD, IR spectroscopy, ICP-OES, DTA, specific surface area (SSA), cationic exchange capacity (CEC), gravimetric and grain size measurements. Results show that the studied samples have a medium content of smectite-illite minerals with smaller amount of kaolinite together with quartz, feldspars and goethite. They consist generally of fine particles with medium to high plasticity. Based on their mineral composition and physical properties (grain size, plasticity, CEC) the clays are suitable as raw material for the ceramics industry.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere)",
title = "Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry",
pages = "655-650",
volume = "125",
doi = "10.1016/j.egypro.2017.08.270"
}
Milošević, M., Logar, M., Kaludjerović, L.,& Jelić, I.. (2017). Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry. in European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere)
Elsevier Science Bv, Amsterdam., 125, 650-655.
https://doi.org/10.1016/j.egypro.2017.08.270
Milošević M, Logar M, Kaludjerović L, Jelić I. Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry. in European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere). 2017;125:650-655.
doi:10.1016/j.egypro.2017.08.270 .
Milošević, Maja, Logar, Mihovil, Kaludjerović, Lazar, Jelić, Ivana, "Characterization of clays from Slatina (Ub, Serbia) for potential uses in the ceramic industry" in European Geosciences Union General Assembly 2017, Egu Division Energy, Resources & Environment (Ere), 125 (2017):650-655,
https://doi.org/10.1016/j.egypro.2017.08.270 . .
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Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite

Kaludjerović, Lazar; Tomić, Zorica; Durović-Pejcev, Rada D.; Vulić, Predrag J.; Ašanin, Darko P.

(Taylor & Francis Inc, Philadelphia, 2017)

TY  - JOUR
AU  - Kaludjerović, Lazar
AU  - Tomić, Zorica
AU  - Durović-Pejcev, Rada D.
AU  - Vulić, Predrag J.
AU  - Ašanin, Darko P.
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4337
AB  - This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
T1  - Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite
EP  - 297
IS  - 5
SP  - 291
VL  - 52
DO  - 10.1080/03601234.2017.1281636
ER  - 
@article{
author = "Kaludjerović, Lazar and Tomić, Zorica and Durović-Pejcev, Rada D. and Vulić, Predrag J. and Ašanin, Darko P.",
year = "2017",
abstract = "This study was undertaken to determine the impact of the organic complex concentration on the adsorption of herbicide (acetochlor) at the surface of the organic modified montmorillonite. In this work, natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification. Cation-exchange capacity of this montmorillonite was determined using a methylene blue method (86mmol/100g of clay). Montmorillonite has been modified first with NaCl and then with hexadecyltrimethylammonium bromide (HDTMA-bromide) organic complex. Saturation of cation exchange capacity (CEC) was 50%, 100%, and 150%. Changes in the properties of the inorganic and organic montmorillonite have been examined using the X-ray diffraction, Fourier transform infrared spectroscopy, and batch equilibrium method. Montmorillonite modified with HDTMA-bromide demonstrated higher uptake of the herbicide, compared to the inorganic montmorillonite. Comparing the values Freundlich coefficients in batch equilibrium method, it can be seen that the adsorption of acetochlor decreased in the series: 0.5 CEC HM > 1 CEC HM > 1.5 CEC HM > NaM.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was",
title = "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite",
pages = "297-291",
number = "5",
volume = "52",
doi = "10.1080/03601234.2017.1281636"
}
Kaludjerović, L., Tomić, Z., Durović-Pejcev, R. D., Vulić, P. J.,& Ašanin, D. P.. (2017). Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
Taylor & Francis Inc, Philadelphia., 52(5), 291-297.
https://doi.org/10.1080/03601234.2017.1281636
Kaludjerović L, Tomić Z, Durović-Pejcev RD, Vulić PJ, Ašanin DP. Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was. 2017;52(5):291-297.
doi:10.1080/03601234.2017.1281636 .
Kaludjerović, Lazar, Tomić, Zorica, Durović-Pejcev, Rada D., Vulić, Predrag J., Ašanin, Darko P., "Influence of the organic complex concentration on adsorption of herbicide in organic modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 52, no. 5 (2017):291-297,
https://doi.org/10.1080/03601234.2017.1281636 . .
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