Radulović, Jelena M.

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Ambient air particles: The use of ion chromatography and multivariate techniques in the analysis of water-soluble substances

Todorović, Žaklina N.; Radulović, Jelena M.; Sredović Ignjatović, Ivana D.; Ignjatović, Ljubiša M.; Onjia, Antonije E.

(Serbian Chemical Society, 2021)

TY  - JOUR
AU  - Todorović, Žaklina N.
AU  - Radulović, Jelena M.
AU  - Sredović Ignjatović, Ivana D.
AU  - Ignjatović, Ljubiša M.
AU  - Onjia, Antonije E.
PY  - 2021
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5924
AB  - Seventeen water-soluble substances (of sodium, ammonium, potassium, magnesium, calcium, formate, methanesulfonate, glyoxylate, chloride, nitrite, nitrate, glutarate, succinate, malate, malonate, sulfate and oxalate) in 94 samples of particle matter in the ambient air, collected over ten months, in a suburb of Belgrade (Serbia), were determined by ion chromatography. To apportion the sources of the air pollution, the log-transformed data were processed by applying multivariate techniques. Principal component and factor analysis identified three main factors controlling the data variability: stationary combustion processes with the highest loadings of oxalate, malonate and malate; landfill emission and secondary inorganic aerosol characterized by high levels of ammonium, nitrate and sulfate; a contribution of mineral dust composed of magnesium, calcium and chloride. The hierarchical cluster analysis pointed out a differentiation of the samples into five groups belonging to different variables inputs. For the classification of ambient air samples using nine selected ions, the recognition ability of linear discriminant analysis, k-nearest neighbors, and soft independent modeling of class analogy were 87.0, 94.6, and 97.8 %, respectively. Time-series analysis showed that the traffic emission is more pronounced in winter in contrast to the mineral dust influence, while the effect of waste combustion exhibits no trend.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Ambient air particles: The use of ion chromatography and multivariate techniques in the analysis of water-soluble substances
EP  - 766
IS  - 7-8
SP  - 753
VL  - 86
DO  - 10.2298/JSC200826077T
ER  - 
@article{
author = "Todorović, Žaklina N. and Radulović, Jelena M. and Sredović Ignjatović, Ivana D. and Ignjatović, Ljubiša M. and Onjia, Antonije E.",
year = "2021",
abstract = "Seventeen water-soluble substances (of sodium, ammonium, potassium, magnesium, calcium, formate, methanesulfonate, glyoxylate, chloride, nitrite, nitrate, glutarate, succinate, malate, malonate, sulfate and oxalate) in 94 samples of particle matter in the ambient air, collected over ten months, in a suburb of Belgrade (Serbia), were determined by ion chromatography. To apportion the sources of the air pollution, the log-transformed data were processed by applying multivariate techniques. Principal component and factor analysis identified three main factors controlling the data variability: stationary combustion processes with the highest loadings of oxalate, malonate and malate; landfill emission and secondary inorganic aerosol characterized by high levels of ammonium, nitrate and sulfate; a contribution of mineral dust composed of magnesium, calcium and chloride. The hierarchical cluster analysis pointed out a differentiation of the samples into five groups belonging to different variables inputs. For the classification of ambient air samples using nine selected ions, the recognition ability of linear discriminant analysis, k-nearest neighbors, and soft independent modeling of class analogy were 87.0, 94.6, and 97.8 %, respectively. Time-series analysis showed that the traffic emission is more pronounced in winter in contrast to the mineral dust influence, while the effect of waste combustion exhibits no trend.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Ambient air particles: The use of ion chromatography and multivariate techniques in the analysis of water-soluble substances",
pages = "766-753",
number = "7-8",
volume = "86",
doi = "10.2298/JSC200826077T"
}
Todorović, Ž. N., Radulović, J. M., Sredović Ignjatović, I. D., Ignjatović, L. M.,& Onjia, A. E.. (2021). Ambient air particles: The use of ion chromatography and multivariate techniques in the analysis of water-soluble substances. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 86(7-8), 753-766.
https://doi.org/10.2298/JSC200826077T
Todorović ŽN, Radulović JM, Sredović Ignjatović ID, Ignjatović LM, Onjia AE. Ambient air particles: The use of ion chromatography and multivariate techniques in the analysis of water-soluble substances. in Journal of the Serbian Chemical Society. 2021;86(7-8):753-766.
doi:10.2298/JSC200826077T .
Todorović, Žaklina N., Radulović, Jelena M., Sredović Ignjatović, Ivana D., Ignjatović, Ljubiša M., Onjia, Antonije E., "Ambient air particles: The use of ion chromatography and multivariate techniques in the analysis of water-soluble substances" in Journal of the Serbian Chemical Society, 86, no. 7-8 (2021):753-766,
https://doi.org/10.2298/JSC200826077T . .
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