TY  - JOUR
AU  - Ličina, Vlado
AU  - Fotirić-Akšić, Milica
AU  - Tomić, Zorica
AU  - Trajković, Ivana
AU  - Antić-Mladenović, Svetlana
AU  - Marjanović, Milena
AU  - Rinklebe, Joerg
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4359
AB  - The contemporary reclamation method in an opencast coal mine closure comprises the use of the preserved surface soil layer (SSL) before mining, and can be directly returned to the areas being rehabilitated. The present study emphasizes a risk in the use of such a SSL in mine rehabilitation due to the possible excessive amount of heavy metals which usually derives from a metal-rich sediment or fluvial character of overburden material. This indication was approved by the bioassessment of cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), lead (Pb), nickel (Ni), and zinc (Zn) in root and aerial parts of maize (Zea mays), alfalfa (Medicago sativa), sweet clover (Melilotus officinalis), wheat (Triticum aestivum), barley (Hordeum sativum), white clover (Trifolium repens), pasture (Poales sp.), tomato (Solanum lycopersicum), potato (Solanum tuberosum) and carrot (Daucus carota) grown on SSL in the opencast mine area. The fluvial layers of the investigated mine SSL revealed the excessive existence of Ni and Cr, probably of geogenic origin, according to the X-ray diffraction (XRD) which detected Ni- and Cr-bearing minerals in soil fractions. In addition, the highest residual fraction of these two heavy metals, obtained by sequential extraction analyses, together with all other tested soil parameters, supported this assumption. Nevertheless, the accumulations of Cr in tomato fruit (2.93 mg kg(-1)), potato tuber (5.89 mg kg(-1)) and carrot root (7.35 mg kg(-1)) grown on the investigated SSL were found to exceed a critical level of this element for human nutrition. However, despite the evident excess of Ni in the investigated SSL, a similar trend was not found in edible part of plants. The transfer and mobility of the investigated metals was evaluated using the accumulation factor (AF  lt  1.0) where the root were the preferential organ for the storage of heavy metals. This investigation could bring an important input for its acceptability of use in soil restoration after mining for food fodder production, or it could indicate the potential risks of the presence of heavy metals regarding its possible use in improving the human surrounding.
PB  - Academic Press Ltd- Elsevier Science Ltd, London
T2  - Journal of Environmental Management
T1  - Bioassessment of heavy metals in the surface soil layer of an opencast mine aimed for its rehabilitation
EP  - 252
SP  - 240
VL  - 186
DO  - 10.1016/j.jenvman.2016.06.050
ER  - 

@article{
author = "Ličina, Vlado and Fotirić-Akšić, Milica and Tomić, Zorica and Trajković, Ivana and Antić-Mladenović, Svetlana and Marjanović, Milena and Rinklebe, Joerg",
year = "2017",
abstract = "The contemporary reclamation method in an opencast coal mine closure comprises the use of the preserved surface soil layer (SSL) before mining, and can be directly returned to the areas being rehabilitated. The present study emphasizes a risk in the use of such a SSL in mine rehabilitation due to the possible excessive amount of heavy metals which usually derives from a metal-rich sediment or fluvial character of overburden material. This indication was approved by the bioassessment of cadmium (Cd), chromium (Cr), cobalt (Co), copper (Cu), lead (Pb), nickel (Ni), and zinc (Zn) in root and aerial parts of maize (Zea mays), alfalfa (Medicago sativa), sweet clover (Melilotus officinalis), wheat (Triticum aestivum), barley (Hordeum sativum), white clover (Trifolium repens), pasture (Poales sp.), tomato (Solanum lycopersicum), potato (Solanum tuberosum) and carrot (Daucus carota) grown on SSL in the opencast mine area. The fluvial layers of the investigated mine SSL revealed the excessive existence of Ni and Cr, probably of geogenic origin, according to the X-ray diffraction (XRD) which detected Ni- and Cr-bearing minerals in soil fractions. In addition, the highest residual fraction of these two heavy metals, obtained by sequential extraction analyses, together with all other tested soil parameters, supported this assumption. Nevertheless, the accumulations of Cr in tomato fruit (2.93 mg kg(-1)), potato tuber (5.89 mg kg(-1)) and carrot root (7.35 mg kg(-1)) grown on the investigated SSL were found to exceed a critical level of this element for human nutrition. However, despite the evident excess of Ni in the investigated SSL, a similar trend was not found in edible part of plants. The transfer and mobility of the investigated metals was evaluated using the accumulation factor (AF  lt  1.0) where the root were the preferential organ for the storage of heavy metals. This investigation could bring an important input for its acceptability of use in soil restoration after mining for food fodder production, or it could indicate the potential risks of the presence of heavy metals regarding its possible use in improving the human surrounding.",
publisher = "Academic Press Ltd- Elsevier Science Ltd, London",
journal = "Journal of Environmental Management",
title = "Bioassessment of heavy metals in the surface soil layer of an opencast mine aimed for its rehabilitation",
pages = "252-240",
volume = "186",
doi = "10.1016/j.jenvman.2016.06.050"
}

Ličina, V., Fotirić-Akšić, M., Tomić, Z., Trajković, I., Antić-Mladenović, S., Marjanović, M.,& Rinklebe, J.. (2017). Bioassessment of heavy metals in the surface soil layer of an opencast mine aimed for its rehabilitation. in Journal of Environmental Management
Academic Press Ltd- Elsevier Science Ltd, London., 186, 240-252.
https://doi.org/10.1016/j.jenvman.2016.06.050

Ličina V, Fotirić-Akšić M, Tomić Z, Trajković I, Antić-Mladenović S, Marjanović M, Rinklebe J. Bioassessment of heavy metals in the surface soil layer of an opencast mine aimed for its rehabilitation. in Journal of Environmental Management. 2017;186:240-252.
doi:10.1016/j.jenvman.2016.06.050 .

Ličina, Vlado, Fotirić-Akšić, Milica, Tomić, Zorica, Trajković, Ivana, Antić-Mladenović, Svetlana, Marjanović, Milena, Rinklebe, Joerg, "Bioassessment of heavy metals in the surface soil layer of an opencast mine aimed for its rehabilitation" in Journal of Environmental Management, 186 (2017):240-252,
https://doi.org/10.1016/j.jenvman.2016.06.050 . .

TY  - JOUR
AU  - Trajković, Ivana
AU  - Ličina, Vlado
AU  - Antić-Mladenović, Svetlana
AU  - Wenzel, Walter
PY  - 2014
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3411
AB  - This paper deals with the problem of hazardous elements (HE) speciation in sandy, alkaline coal mine overburden destined for restoration. Two sequential extraction procedures [five stages Tesier's (T) and seven stages Zeien and Brummner's method (ZB)] were employed that focused on potentially bioavailable HE fractions previously found in plants growing during this soil restoration process. The results showed that the selection of the extraction procedure in HE speciation is essential, due to the different potential threats of HE fractions obtained for plants. The biggest residual fraction obtained by both extractions suggest geogenic origin of Cu, Zn, Ni, Cr and Pb. Tesier's extraction procedure works reasonably well for low concentration of water soluble and exchangeable HEs, whilst giving higher values for their organically bound forms. Zeien and Brummner's method, however, was found to be more appropriate for evaluation of the mobility of HE as Mn and Fe oxide fractions. The principal component analysis test estimated three main groups where the relationship between soil properties (pH, clay and silt), total content of element and available fractions (Zn, Ni, Cr, Pb-T and Ni-ZB) was defined as a PC 1 group. Other PC 2 and PC 3 from the PCA analysis include C-org and CEC, and available Cu-T and Cr, Pb-ZB, respectively. The PC 3 factor linked fine sand and available Zn-ZB. Pearson's correlation coefficients showed a high correlation between available HE and high pH(KCl) obtained by T-extraction, and Ni by Zn-extraction. Also, clay, silt and fine sand were highly correlated with the Ni-ZB available forms.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Chemical Speciation and Bioavailability
T1  - Hazardous elements speciation in sandy, alkaline coal mine overburden by using different sequential extraction procedures
EP  - 91
IS  - 2
SP  - 85
VL  - 26
DO  - 10.3184/095422914X13950805573918
ER  - 

@article{
author = "Trajković, Ivana and Ličina, Vlado and Antić-Mladenović, Svetlana and Wenzel, Walter",
year = "2014",
abstract = "This paper deals with the problem of hazardous elements (HE) speciation in sandy, alkaline coal mine overburden destined for restoration. Two sequential extraction procedures [five stages Tesier's (T) and seven stages Zeien and Brummner's method (ZB)] were employed that focused on potentially bioavailable HE fractions previously found in plants growing during this soil restoration process. The results showed that the selection of the extraction procedure in HE speciation is essential, due to the different potential threats of HE fractions obtained for plants. The biggest residual fraction obtained by both extractions suggest geogenic origin of Cu, Zn, Ni, Cr and Pb. Tesier's extraction procedure works reasonably well for low concentration of water soluble and exchangeable HEs, whilst giving higher values for their organically bound forms. Zeien and Brummner's method, however, was found to be more appropriate for evaluation of the mobility of HE as Mn and Fe oxide fractions. The principal component analysis test estimated three main groups where the relationship between soil properties (pH, clay and silt), total content of element and available fractions (Zn, Ni, Cr, Pb-T and Ni-ZB) was defined as a PC 1 group. Other PC 2 and PC 3 from the PCA analysis include C-org and CEC, and available Cu-T and Cr, Pb-ZB, respectively. The PC 3 factor linked fine sand and available Zn-ZB. Pearson's correlation coefficients showed a high correlation between available HE and high pH(KCl) obtained by T-extraction, and Ni by Zn-extraction. Also, clay, silt and fine sand were highly correlated with the Ni-ZB available forms.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Chemical Speciation and Bioavailability",
title = "Hazardous elements speciation in sandy, alkaline coal mine overburden by using different sequential extraction procedures",
pages = "91-85",
number = "2",
volume = "26",
doi = "10.3184/095422914X13950805573918"
}

Trajković, I., Ličina, V., Antić-Mladenović, S.,& Wenzel, W.. (2014). Hazardous elements speciation in sandy, alkaline coal mine overburden by using different sequential extraction procedures. in Chemical Speciation and Bioavailability
Taylor & Francis Ltd, Abingdon., 26(2), 85-91.
https://doi.org/10.3184/095422914X13950805573918

Trajković I, Ličina V, Antić-Mladenović S, Wenzel W. Hazardous elements speciation in sandy, alkaline coal mine overburden by using different sequential extraction procedures. in Chemical Speciation and Bioavailability. 2014;26(2):85-91.
doi:10.3184/095422914X13950805573918 .

Trajković, Ivana, Ličina, Vlado, Antić-Mladenović, Svetlana, Wenzel, Walter, "Hazardous elements speciation in sandy, alkaline coal mine overburden by using different sequential extraction procedures" in Chemical Speciation and Bioavailability, 26, no. 2 (2014):85-91,
https://doi.org/10.3184/095422914X13950805573918 . .