TY  - JOUR
AU  - Jokić, A.
AU  - Ristić, Nikola
AU  - Jaksić, M.M.
AU  - Spasojević, M.
AU  - Krstajić, N.
PY  - 1991
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/68
AB  - A new electrocatalytic process for simultaneous electrolytic production of xylitol and xylonic acid or the corresponding xylonate salts directly from α-d-xylose in alkaline solutions of neutral salt as supporting electrolyte has been developed and presented. An electrocatalytically active cathode coating with essentially hydridic features has been employed to enhance Faradaic yields in xylitol production at low current densities by heterogeneous reaction of hydrogenation with H-adatoms, and the entire mechanism has been proved by experimental evidence. An anionic selective anodic coating for titanium substrate was also used to suppress oxygen evolution and optimize the xylonic acid production by direct oxidation with anodically generated bromine, and to carry out the electrode process at almost equilibrium potential. The kinetic effect of specifically adsorbable anions for decreasing cathodic current yields in xylitol production and the resulting necessity for membrane separation of catholyte from anolyte, with proper optimization of the supporting neutral salt composition, has also been emphasized.
T2  - Journal of Applied Electrochemistry
T1  - Simultaneous electrolytic production of xylitol and xylonic acid from xylose
EP  - 326
IS  - 4
SP  - 321
VL  - 21
DO  - 10.1007/BF01020216
ER  - 

@article{
author = "Jokić, A. and Ristić, Nikola and Jaksić, M.M. and Spasojević, M. and Krstajić, N.",
year = "1991",
abstract = "A new electrocatalytic process for simultaneous electrolytic production of xylitol and xylonic acid or the corresponding xylonate salts directly from α-d-xylose in alkaline solutions of neutral salt as supporting electrolyte has been developed and presented. An electrocatalytically active cathode coating with essentially hydridic features has been employed to enhance Faradaic yields in xylitol production at low current densities by heterogeneous reaction of hydrogenation with H-adatoms, and the entire mechanism has been proved by experimental evidence. An anionic selective anodic coating for titanium substrate was also used to suppress oxygen evolution and optimize the xylonic acid production by direct oxidation with anodically generated bromine, and to carry out the electrode process at almost equilibrium potential. The kinetic effect of specifically adsorbable anions for decreasing cathodic current yields in xylitol production and the resulting necessity for membrane separation of catholyte from anolyte, with proper optimization of the supporting neutral salt composition, has also been emphasized.",
journal = "Journal of Applied Electrochemistry",
title = "Simultaneous electrolytic production of xylitol and xylonic acid from xylose",
pages = "326-321",
number = "4",
volume = "21",
doi = "10.1007/BF01020216"
}

Jokić, A., Ristić, N., Jaksić, M.M., Spasojević, M.,& Krstajić, N.. (1991). Simultaneous electrolytic production of xylitol and xylonic acid from xylose. in Journal of Applied Electrochemistry, 21(4), 321-326.
https://doi.org/10.1007/BF01020216

Jokić A, Ristić N, Jaksić M, Spasojević M, Krstajić N. Simultaneous electrolytic production of xylitol and xylonic acid from xylose. in Journal of Applied Electrochemistry. 1991;21(4):321-326.
doi:10.1007/BF01020216 .

Jokić, A., Ristić, Nikola, Jaksić, M.M., Spasojević, M., Krstajić, N., "Simultaneous electrolytic production of xylitol and xylonic acid from xylose" in Journal of Applied Electrochemistry, 21, no. 4 (1991):321-326,
https://doi.org/10.1007/BF01020216 . .