TY  - JOUR
AU  - Kepić, Dejan P.
AU  - Stefanović, Andjela M.
AU  - Budimir, Milica D.
AU  - Pavlović, Vladimir B.
AU  - Bonasera, Aurelio
AU  - Scopelliti, Michelangelo
AU  - Todorović-Marković, Biljana M.
PY  - 2023
UR  - https://www.sciencedirect.com/science/article/pii/S0969806X22005813
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6176
AB  - Gamma irradiation provides an alternative pathway to conventional gold nanoparticle synthesis because it is simple, fast, and economical. Here, we employed gamma irradiation at low doses (1–20 kGy) to obtain gold nanoparticles (Au NPs) anchored onto graphene oxide (GO) sheets. GO was selected as a suitable platform for the nucleation and growth of Au NPs because of its large surface area and good dispersibility in water due to the presence of polar oxygen-containing functional groups in its structure. Gamma irradiation at all the applied doses led to the reduction of chloroauric acid and the formation of evenly distributed Au NPs at the GO surface, simultaneously causing the reduction of GO and partial restoration of the graphene structure. As-prepared Au NPs have predominately spheric shapes and the smallest nanoparticles were reported for the dose of 1 kGy. The increase in the irradiation dose caused either the growth of larger particles (5 and 10 kGy) or the broad distribution of particles’ sizes (20 kGy). All samples showed a temperature increase upon exposure to 800 nm laser and photothermal efficiency was the highest for the sample prepared at 20 kGy.
T2  - Radiation Physics and Chemistry
T2  - Radiation Physics and ChemistryRadiation Physics and Chemistry
T1  - Gamma rays induced synthesis of graphene oxide/gold nanoparticle composites: structural and photothermal study
SP  - 110545
VL  - 202
DO  - 10.1016/j.radphyschem.2022.110545
ER  - 

@article{
author = "Kepić, Dejan P. and Stefanović, Andjela M. and Budimir, Milica D. and Pavlović, Vladimir B. and Bonasera, Aurelio and Scopelliti, Michelangelo and Todorović-Marković, Biljana M.",
year = "2023",
abstract = "Gamma irradiation provides an alternative pathway to conventional gold nanoparticle synthesis because it is simple, fast, and economical. Here, we employed gamma irradiation at low doses (1–20 kGy) to obtain gold nanoparticles (Au NPs) anchored onto graphene oxide (GO) sheets. GO was selected as a suitable platform for the nucleation and growth of Au NPs because of its large surface area and good dispersibility in water due to the presence of polar oxygen-containing functional groups in its structure. Gamma irradiation at all the applied doses led to the reduction of chloroauric acid and the formation of evenly distributed Au NPs at the GO surface, simultaneously causing the reduction of GO and partial restoration of the graphene structure. As-prepared Au NPs have predominately spheric shapes and the smallest nanoparticles were reported for the dose of 1 kGy. The increase in the irradiation dose caused either the growth of larger particles (5 and 10 kGy) or the broad distribution of particles’ sizes (20 kGy). All samples showed a temperature increase upon exposure to 800 nm laser and photothermal efficiency was the highest for the sample prepared at 20 kGy.",
journal = "Radiation Physics and Chemistry, Radiation Physics and ChemistryRadiation Physics and Chemistry",
title = "Gamma rays induced synthesis of graphene oxide/gold nanoparticle composites: structural and photothermal study",
pages = "110545",
volume = "202",
doi = "10.1016/j.radphyschem.2022.110545"
}

Kepić, D. P., Stefanović, A. M., Budimir, M. D., Pavlović, V. B., Bonasera, A., Scopelliti, M.,& Todorović-Marković, B. M.. (2023). Gamma rays induced synthesis of graphene oxide/gold nanoparticle composites: structural and photothermal study. in Radiation Physics and Chemistry, 202, 110545.
https://doi.org/10.1016/j.radphyschem.2022.110545

Kepić DP, Stefanović AM, Budimir MD, Pavlović VB, Bonasera A, Scopelliti M, Todorović-Marković BM. Gamma rays induced synthesis of graphene oxide/gold nanoparticle composites: structural and photothermal study. in Radiation Physics and Chemistry. 2023;202:110545.
doi:10.1016/j.radphyschem.2022.110545 .

Kepić, Dejan P., Stefanović, Andjela M., Budimir, Milica D., Pavlović, Vladimir B., Bonasera, Aurelio, Scopelliti, Michelangelo, Todorović-Marković, Biljana M., "Gamma rays induced synthesis of graphene oxide/gold nanoparticle composites: structural and photothermal study" in Radiation Physics and Chemistry, 202 (2023):110545,
https://doi.org/10.1016/j.radphyschem.2022.110545 . .

TY  - JOUR
AU  - Jovanović, Svetlana P.
AU  - Syrgiannis, Zois
AU  - Marković, Zoran M.
AU  - Bonasera, Aurelio
AU  - Kepić, Dejan P.
AU  - Budimir, Milica D.
AU  - Milivojević, Dušan D.
AU  - Spasojević, Vuk D.
AU  - Dramicanin, Miroslav D.
AU  - Pavlović, Vladimir
AU  - Todorović-Marković, Biljana
PY  - 2015
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3755
AB  - Herein, the ability of gamma irradiation to enhance the photoluminescence properties of graphene quantum dots (GQDs) was investigated. Different doses of gamma-irradiation were used on GQDs to examine the way in which their structure and optical properties can be affected. The photoluminescence quantum yield was increased six times for the GQDs irradiated with high doses compared to the nonirradiated material. Both photoluminescence lifetime and values of optical band gap were increased with the dose of applied gamma irradiation. In addition, the exploitation of the gamma-irradiated GQDs as photosensitizers was examined by monitoring the production of singlet oxygen under UV illumination. The main outcome was that the GQDs irradiated at lower doses act as better photoproducers than the ones irradiated at higher doses. These results corroborate that the structural changes caused by gamma irradiation have a direct impact on GQD ability to produce singlet oxygen and their photostability under prolonged UV illumination. This makes low-dose irradiated GQDs promising candidates for photodynamic therapy.
PB  - Amer Chemical Soc, Washington
T2  - ACS Applied Materials & Interfaces
T1  - Modification of Structural and Luminescence Properties of Graphene Quantum Dots by Gamma Irradiation and Their Application in a Photodynamic Therapy
EP  - 25874
IS  - 46
SP  - 25865
VL  - 7
DO  - 10.1021/acsami.5b08226
ER  - 

@article{
author = "Jovanović, Svetlana P. and Syrgiannis, Zois and Marković, Zoran M. and Bonasera, Aurelio and Kepić, Dejan P. and Budimir, Milica D. and Milivojević, Dušan D. and Spasojević, Vuk D. and Dramicanin, Miroslav D. and Pavlović, Vladimir and Todorović-Marković, Biljana",
year = "2015",
abstract = "Herein, the ability of gamma irradiation to enhance the photoluminescence properties of graphene quantum dots (GQDs) was investigated. Different doses of gamma-irradiation were used on GQDs to examine the way in which their structure and optical properties can be affected. The photoluminescence quantum yield was increased six times for the GQDs irradiated with high doses compared to the nonirradiated material. Both photoluminescence lifetime and values of optical band gap were increased with the dose of applied gamma irradiation. In addition, the exploitation of the gamma-irradiated GQDs as photosensitizers was examined by monitoring the production of singlet oxygen under UV illumination. The main outcome was that the GQDs irradiated at lower doses act as better photoproducers than the ones irradiated at higher doses. These results corroborate that the structural changes caused by gamma irradiation have a direct impact on GQD ability to produce singlet oxygen and their photostability under prolonged UV illumination. This makes low-dose irradiated GQDs promising candidates for photodynamic therapy.",
publisher = "Amer Chemical Soc, Washington",
journal = "ACS Applied Materials & Interfaces",
title = "Modification of Structural and Luminescence Properties of Graphene Quantum Dots by Gamma Irradiation and Their Application in a Photodynamic Therapy",
pages = "25874-25865",
number = "46",
volume = "7",
doi = "10.1021/acsami.5b08226"
}

Jovanović, S. P., Syrgiannis, Z., Marković, Z. M., Bonasera, A., Kepić, D. P., Budimir, M. D., Milivojević, D. D., Spasojević, V. D., Dramicanin, M. D., Pavlović, V.,& Todorović-Marković, B.. (2015). Modification of Structural and Luminescence Properties of Graphene Quantum Dots by Gamma Irradiation and Their Application in a Photodynamic Therapy. in ACS Applied Materials & Interfaces
Amer Chemical Soc, Washington., 7(46), 25865-25874.
https://doi.org/10.1021/acsami.5b08226

Jovanović SP, Syrgiannis Z, Marković ZM, Bonasera A, Kepić DP, Budimir MD, Milivojević DD, Spasojević VD, Dramicanin MD, Pavlović V, Todorović-Marković B. Modification of Structural and Luminescence Properties of Graphene Quantum Dots by Gamma Irradiation and Their Application in a Photodynamic Therapy. in ACS Applied Materials & Interfaces. 2015;7(46):25865-25874.
doi:10.1021/acsami.5b08226 .

Jovanović, Svetlana P., Syrgiannis, Zois, Marković, Zoran M., Bonasera, Aurelio, Kepić, Dejan P., Budimir, Milica D., Milivojević, Dušan D., Spasojević, Vuk D., Dramicanin, Miroslav D., Pavlović, Vladimir, Todorović-Marković, Biljana, "Modification of Structural and Luminescence Properties of Graphene Quantum Dots by Gamma Irradiation and Their Application in a Photodynamic Therapy" in ACS Applied Materials & Interfaces, 7, no. 46 (2015):25865-25874,
https://doi.org/10.1021/acsami.5b08226 . .

TY  - JOUR
AU  - Prekodravac, Jovana
AU  - Marković, Zoran
AU  - Jovanović, Svetlana P.
AU  - Budimir, Milica D.
AU  - Perusko, Davor
AU  - Holclajtner-Antunović, Ivanka
AU  - Pavlović, Vladimir
AU  - Syrgiannis, Zois
AU  - Bonasera, Aurelio
AU  - Todorović-Marković, Biljana
PY  - 2015
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3685
AB  - In this paper, we performed synthesis of graphene thin films by rapid thermal annealing (RTA) of thin nickel copper (Ni/Cu) layers deposited on spectroscopic graphite as a carbon source. Furthermore, we investigated the effect of annealing temperature and annealing time on formation and quality of synthesized graphene films. Raman spectroscopy study showed that annealing at lower temperatures results in formation of monolayer graphene films, while annealing at higher temperatures results in formation of multilayer graphene films. We used Raman mapping to determine the distribution of graphene sheets. Surface morphology of graphene thin films was investigated by atomic force microscopy and scanning electron microscopy with EDS probe.
PB  - Elsevier Science Sa, Lausanne
T2  - Synthetic Metals
T1  - The effect of annealing temperature and time on synthesis of graphene thin films by rapid thermal annealing
EP  - 467
SP  - 461
VL  - 209
DO  - 10.1016/j.synthmet.2015.08.015
ER  - 

@article{
author = "Prekodravac, Jovana and Marković, Zoran and Jovanović, Svetlana P. and Budimir, Milica D. and Perusko, Davor and Holclajtner-Antunović, Ivanka and Pavlović, Vladimir and Syrgiannis, Zois and Bonasera, Aurelio and Todorović-Marković, Biljana",
year = "2015",
abstract = "In this paper, we performed synthesis of graphene thin films by rapid thermal annealing (RTA) of thin nickel copper (Ni/Cu) layers deposited on spectroscopic graphite as a carbon source. Furthermore, we investigated the effect of annealing temperature and annealing time on formation and quality of synthesized graphene films. Raman spectroscopy study showed that annealing at lower temperatures results in formation of monolayer graphene films, while annealing at higher temperatures results in formation of multilayer graphene films. We used Raman mapping to determine the distribution of graphene sheets. Surface morphology of graphene thin films was investigated by atomic force microscopy and scanning electron microscopy with EDS probe.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Synthetic Metals",
title = "The effect of annealing temperature and time on synthesis of graphene thin films by rapid thermal annealing",
pages = "467-461",
volume = "209",
doi = "10.1016/j.synthmet.2015.08.015"
}

Prekodravac, J., Marković, Z., Jovanović, S. P., Budimir, M. D., Perusko, D., Holclajtner-Antunović, I., Pavlović, V., Syrgiannis, Z., Bonasera, A.,& Todorović-Marković, B.. (2015). The effect of annealing temperature and time on synthesis of graphene thin films by rapid thermal annealing. in Synthetic Metals
Elsevier Science Sa, Lausanne., 209, 461-467.
https://doi.org/10.1016/j.synthmet.2015.08.015

Prekodravac J, Marković Z, Jovanović SP, Budimir MD, Perusko D, Holclajtner-Antunović I, Pavlović V, Syrgiannis Z, Bonasera A, Todorović-Marković B. The effect of annealing temperature and time on synthesis of graphene thin films by rapid thermal annealing. in Synthetic Metals. 2015;209:461-467.
doi:10.1016/j.synthmet.2015.08.015 .

Prekodravac, Jovana, Marković, Zoran, Jovanović, Svetlana P., Budimir, Milica D., Perusko, Davor, Holclajtner-Antunović, Ivanka, Pavlović, Vladimir, Syrgiannis, Zois, Bonasera, Aurelio, Todorović-Marković, Biljana, "The effect of annealing temperature and time on synthesis of graphene thin films by rapid thermal annealing" in Synthetic Metals, 209 (2015):461-467,
https://doi.org/10.1016/j.synthmet.2015.08.015 . .