TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Aleksić, Stanko O.
AU  - Živojinović, Jelena
AU  - Tadić, Adriana Peleš
AU  - Pavlović, Vladimir B.
AU  - Obradović, Nina
PY  - 2023
UR  - http://ojs.itn.sanu.ac.rs/index.php/scisint/article/view/1108
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6468
AB  - BZT ceramics was prepared by using fine powder mixture of BaCO3, TiO2 and ZrO2 in the respective molar ratio to form Ba(Zr0.10Ti0.90)O3 via solid state reaction at elevated temperature. The prepared BZT was milled in the planetary ball mill from 0-120 min to achieve different powder grades from micron to nano-sized particles. After the powder characterization by XRD and SEM the samples were pressed in disc shape and sintered at different temperatures from 1100-1350°C in the air. The sintered samples were characterized by SEM and their density and average grain size was determined and presented vs. sintering temperature and powder grades (milling time). After that the silver epoxy electrodes were deposited on sintered disc samples. The disc samples capacity and resistivity were measured at low frequency region from 1 Hz to 200 kHz using low frequency impedance analyzer. The sintering temperatures and powder grades were used as parameters. Finally the specific resistance ρ, dielectric constant (ε' + jε") and tgδ where determined from the impedance measurements. The behavior of electronic properties where analyzed e.g. the relaxation effect of the space charge (inter-granular electric charges) vs. sintering temperature and ceramic grades. The results obtained were compared with best literature data for the losses in BZT ceramics at low frequencies.
T2  - Science of Sintering
T2  - Science of Sintering
T1  - Electronic Properties of BZT Nano-Ceramic Grades at Low Frequency Region
IS  - 3
VL  - 55
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_6468
ER  - 

@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Aleksić, Stanko O. and Živojinović, Jelena and Tadić, Adriana Peleš and Pavlović, Vladimir B. and Obradović, Nina",
year = "2023",
abstract = "BZT ceramics was prepared by using fine powder mixture of BaCO3, TiO2 and ZrO2 in the respective molar ratio to form Ba(Zr0.10Ti0.90)O3 via solid state reaction at elevated temperature. The prepared BZT was milled in the planetary ball mill from 0-120 min to achieve different powder grades from micron to nano-sized particles. After the powder characterization by XRD and SEM the samples were pressed in disc shape and sintered at different temperatures from 1100-1350°C in the air. The sintered samples were characterized by SEM and their density and average grain size was determined and presented vs. sintering temperature and powder grades (milling time). After that the silver epoxy electrodes were deposited on sintered disc samples. The disc samples capacity and resistivity were measured at low frequency region from 1 Hz to 200 kHz using low frequency impedance analyzer. The sintering temperatures and powder grades were used as parameters. Finally the specific resistance ρ, dielectric constant (ε' + jε") and tgδ where determined from the impedance measurements. The behavior of electronic properties where analyzed e.g. the relaxation effect of the space charge (inter-granular electric charges) vs. sintering temperature and ceramic grades. The results obtained were compared with best literature data for the losses in BZT ceramics at low frequencies.",
journal = "Science of Sintering, Science of Sintering",
title = "Electronic Properties of BZT Nano-Ceramic Grades at Low Frequency Region",
number = "3",
volume = "55",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_6468"
}

Kosanović, D., Blagojević, V. A., Aleksić, S. O., Živojinović, J., Tadić, A. P., Pavlović, V. B.,& Obradović, N.. (2023). Electronic Properties of BZT Nano-Ceramic Grades at Low Frequency Region. in Science of Sintering, 55(3).
https://hdl.handle.net/21.15107/rcub_agrospace_6468

Kosanović D, Blagojević VA, Aleksić SO, Živojinović J, Tadić AP, Pavlović VB, Obradović N. Electronic Properties of BZT Nano-Ceramic Grades at Low Frequency Region. in Science of Sintering. 2023;55(3).
https://hdl.handle.net/21.15107/rcub_agrospace_6468 .

Kosanović, Darko, Blagojević, Vladimir A., Aleksić, Stanko O., Živojinović, Jelena, Tadić, Adriana Peleš, Pavlović, Vladimir B., Obradović, Nina, "Electronic Properties of BZT Nano-Ceramic Grades at Low Frequency Region" in Science of Sintering, 55, no. 3 (2023),
https://hdl.handle.net/21.15107/rcub_agrospace_6468 .

TY  - JOUR
AU  - Živojinović, Jelena
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vera P.
AU  - Tadić, Nenad
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6243
AB  - In this study, microstructure evolution and dielectric properties of SrTiO3 ceramic have been investigated, whereby mechanical activation of SrTiO3 powders was used to modify the functional properties of ceramic materials. Microstructural SEM analysis of SrTiO3 ceramics showed that the increase in mechanical activation time results in less porous samples. Raman spectroscopy indicated changes in the broadening and asymmetry of the TO2 mode with a change in the time of mechanical activation. TO2 mode showed a Fano asymmetry due to its interaction with polarization fluctuations in polar micro-regions, which are a consequence of the presence of oxygen vacancies caused by activation. The maximum value of dielectric permittivity was observed in the sample activated for 10 min. Also, the sample activated for 10 min exhibits relatively low values of loss tangent, compared to the other mechanically activated samples, providing the best overall dielectric performance compared to other samples. © 2022 Authors. Published by association for ETRAN Society.
T2  - Science of Sintering
T2  - Science of Sintering
T1  - Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics
EP  - 404
IS  - 4
SP  - 401
VL  - 54
DO  - 10.2298/SOS2204401Z
ER  - 

@article{
author = "Živojinović, Jelena and Kosanović, Darko and Blagojević, Vladimir A. and Pavlović, Vera P. and Tadić, Nenad and Vlahović, Branislav and Pavlović, Vladimir B.",
year = "2022",
abstract = "In this study, microstructure evolution and dielectric properties of SrTiO3 ceramic have been investigated, whereby mechanical activation of SrTiO3 powders was used to modify the functional properties of ceramic materials. Microstructural SEM analysis of SrTiO3 ceramics showed that the increase in mechanical activation time results in less porous samples. Raman spectroscopy indicated changes in the broadening and asymmetry of the TO2 mode with a change in the time of mechanical activation. TO2 mode showed a Fano asymmetry due to its interaction with polarization fluctuations in polar micro-regions, which are a consequence of the presence of oxygen vacancies caused by activation. The maximum value of dielectric permittivity was observed in the sample activated for 10 min. Also, the sample activated for 10 min exhibits relatively low values of loss tangent, compared to the other mechanically activated samples, providing the best overall dielectric performance compared to other samples. © 2022 Authors. Published by association for ETRAN Society.",
journal = "Science of Sintering, Science of Sintering",
title = "Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics",
pages = "404-401",
number = "4",
volume = "54",
doi = "10.2298/SOS2204401Z"
}

Živojinović, J., Kosanović, D., Blagojević, V. A., Pavlović, V. P., Tadić, N., Vlahović, B.,& Pavlović, V. B.. (2022). Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics. in Science of Sintering, 54(4), 401-404.
https://doi.org/10.2298/SOS2204401Z

Živojinović J, Kosanović D, Blagojević VA, Pavlović VP, Tadić N, Vlahović B, Pavlović VB. Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics. in Science of Sintering. 2022;54(4):401-404.
doi:10.2298/SOS2204401Z .

Živojinović, Jelena, Kosanović, Darko, Blagojević, Vladimir A., Pavlović, Vera P., Tadić, Nenad, Vlahović, Branislav, Pavlović, Vladimir B., "Dielectric Properties of Mechanically Activated Strontium Titanate Ceramics" in Science of Sintering, 54, no. 4 (2022):401-404,
https://doi.org/10.2298/SOS2204401Z . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Rusmirović, Jelena D.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Marinković, Aleksandar
AU  - Radić, Danka
AU  - Pavlović, Vladimir
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5248
AB  - Industrial/technological growth is directly connected with environmental pollution, but its influence can be minimized through pollution abatement approaches such as the treatment of industrial wastewater. In this study, novel porous amine-functionalized silicate minerals, specifically, cordierite was investigated for the removal of toxic heavy metals from industrial wastewaters. Cordierite supports were synthesized by mixing MgO, Al2O3, and SiO2 powders in 2:2:5 molar ratios, and mechanically activated via ball milling in ethanol for 10, 40, or 80 min. Pellets were sintered by heating in air at 20 degrees C min(-1) to 1,350 degrees C, for 2 h. Porous supports were produced by coarsely crushing the sintered pellets and mixing the crushed and sieved cordierite powder with 20 wt.% of a pore-forming agent, either nanocellulose or yeast. The resulting pellets were sintered by heating at 5 degrees C min(-1) to 700 degrees C in air. The synthetic cordierite support was modified by treatment in poly-ethylenimine. Activated supports were then tested for the removal of Ni2+ and Cd2+ ions. The phase composition of the cordierite supports was analyzed by the X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy. Analysis of adsorption isotherms, kinetics, and thermodynamic parameters indicated that adsorption was a spontaneous, endothermic process with a maximum adsorption capacity of 36 mg g(-1) for Cd2+ and 43 mg g(-1) for Ni2+. This work has shed light on the mechanism of heavy metal removal from the aquatic medium using the novel hybrid functionalized cordierite-based ceramic.
PB  - Desalination Publ, Hopkinton
T2  - Desalination and Water Treatment
T1  - Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal
EP  - 296
SP  - 283
VL  - 192
DO  - 10.5004/dwt.2020.25736
ER  - 

@article{
author = "Obradović, Nina and Rusmirović, Jelena D. and Filipović, Suzana and Kosanović, Darko and Marinković, Aleksandar and Radić, Danka and Pavlović, Vladimir",
year = "2020",
abstract = "Industrial/technological growth is directly connected with environmental pollution, but its influence can be minimized through pollution abatement approaches such as the treatment of industrial wastewater. In this study, novel porous amine-functionalized silicate minerals, specifically, cordierite was investigated for the removal of toxic heavy metals from industrial wastewaters. Cordierite supports were synthesized by mixing MgO, Al2O3, and SiO2 powders in 2:2:5 molar ratios, and mechanically activated via ball milling in ethanol for 10, 40, or 80 min. Pellets were sintered by heating in air at 20 degrees C min(-1) to 1,350 degrees C, for 2 h. Porous supports were produced by coarsely crushing the sintered pellets and mixing the crushed and sieved cordierite powder with 20 wt.% of a pore-forming agent, either nanocellulose or yeast. The resulting pellets were sintered by heating at 5 degrees C min(-1) to 700 degrees C in air. The synthetic cordierite support was modified by treatment in poly-ethylenimine. Activated supports were then tested for the removal of Ni2+ and Cd2+ ions. The phase composition of the cordierite supports was analyzed by the X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy. Analysis of adsorption isotherms, kinetics, and thermodynamic parameters indicated that adsorption was a spontaneous, endothermic process with a maximum adsorption capacity of 36 mg g(-1) for Cd2+ and 43 mg g(-1) for Ni2+. This work has shed light on the mechanism of heavy metal removal from the aquatic medium using the novel hybrid functionalized cordierite-based ceramic.",
publisher = "Desalination Publ, Hopkinton",
journal = "Desalination and Water Treatment",
title = "Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal",
pages = "296-283",
volume = "192",
doi = "10.5004/dwt.2020.25736"
}

Obradović, N., Rusmirović, J. D., Filipović, S., Kosanović, D., Marinković, A., Radić, D.,& Pavlović, V.. (2020). Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal. in Desalination and Water Treatment
Desalination Publ, Hopkinton., 192, 283-296.
https://doi.org/10.5004/dwt.2020.25736

Obradović N, Rusmirović JD, Filipović S, Kosanović D, Marinković A, Radić D, Pavlović V. Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal. in Desalination and Water Treatment. 2020;192:283-296.
doi:10.5004/dwt.2020.25736 .

Obradović, Nina, Rusmirović, Jelena D., Filipović, Suzana, Kosanović, Darko, Marinković, Aleksandar, Radić, Danka, Pavlović, Vladimir, "Porous cordierite-supported polyethyleneimine composites for nickel(II) and cadmium(II) ions removal" in Desalination and Water Treatment, 192 (2020):283-296,
https://doi.org/10.5004/dwt.2020.25736 . .

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Vujancević, Jelena D.
AU  - Masković, Pavle Z.
AU  - Cirković, Jovana
AU  - Papan, Jelena M.
AU  - Kosanović, Darko
AU  - Dramicanin, Miroslav D.
AU  - Petrović, Predrag B.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4931
AB  - Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (E-g) and, consequently, to investigate changes in the E-g value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.
PB  - Wiley, Hoboken
T2  - Journal of the American Ceramic Society
T1  - Structure and enhanced antimicrobial activity of mechanically activated nano TiO2
EP  - 7745
IS  - 12
SP  - 7735
VL  - 102
DO  - 10.1111/jace.16668
ER  - 

@article{
author = "Pavlović, Vera P. and Vujancević, Jelena D. and Masković, Pavle Z. and Cirković, Jovana and Papan, Jelena M. and Kosanović, Darko and Dramicanin, Miroslav D. and Petrović, Predrag B. and Vlahović, Branislav and Pavlović, Vladimir",
year = "2019",
abstract = "Titanium dioxide is a photocatalyst, known not only for its ability to oxidize organic contaminants, but also for its antimicrobial properties. In this article, significant enhancement of the antimicrobial activity of TiO2 (up to 32 times) was demonstrated after its activation by ball milling. The antimicrobial activity was analyzed for one fungal and 13 bacterial ATCC strains using the microdilution method and recording the minimum inhibitory concentration (MIC) values. In order to further investigate the correlation between the mechanical activation of TiO2 and its antimicrobial activity, the structure, morphology and phase composition of the material were studied by means of Electron Microscopy, X-ray diffraction and nitrogen adsorption-desorption measurements. UV-Vis diffuse reflectance spectra were recorded and the Kubelka-Munk function was applied to convert reflectance into the equivalent band gap energy (E-g) and, consequently, to investigate changes in the E-g value. X-ray photoelectron spectroscopy was used to analyze the influence of mechanical activation on the Ti 2p and O 1s spectra. The presented results are expected to enable the development of more sustainable and effective advanced TiO2-based materials with antimicrobial properties that could be used in numerous green technology applications.",
publisher = "Wiley, Hoboken",
journal = "Journal of the American Ceramic Society",
title = "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2",
pages = "7745-7735",
number = "12",
volume = "102",
doi = "10.1111/jace.16668"
}

Pavlović, V. P., Vujancević, J. D., Masković, P. Z., Cirković, J., Papan, J. M., Kosanović, D., Dramicanin, M. D., Petrović, P. B., Vlahović, B.,& Pavlović, V.. (2019). Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society
Wiley, Hoboken., 102(12), 7735-7745.
https://doi.org/10.1111/jace.16668

Pavlović VP, Vujancević JD, Masković PZ, Cirković J, Papan JM, Kosanović D, Dramicanin MD, Petrović PB, Vlahović B, Pavlović V. Structure and enhanced antimicrobial activity of mechanically activated nano TiO2. in Journal of the American Ceramic Society. 2019;102(12):7735-7745.
doi:10.1111/jace.16668 .

Pavlović, Vera P., Vujancević, Jelena D., Masković, Pavle Z., Cirković, Jovana, Papan, Jelena M., Kosanović, Darko, Dramicanin, Miroslav D., Petrović, Predrag B., Vlahović, Branislav, Pavlović, Vladimir, "Structure and enhanced antimicrobial activity of mechanically activated nano TiO2" in Journal of the American Ceramic Society, 102, no. 12 (2019):7735-7745,
https://doi.org/10.1111/jace.16668 . .

TY  - JOUR
AU  - Živojinović, J.
AU  - Pavlović, Vera P.
AU  - Labus, Nebojša
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5167
AB  - The initial-stage of sintering plays a significant role in determining the final microstructure that defines the main characteristics of electroceramics materials such as functional properties. In this article non-isothermal sintering of non-activated and mechanically activated SrTiO3 samples was investigated up to 1300 °C. Dilatometric curves indicate that mechanical activation leads to an earlier onset of sintering, suggesting that it should lead to a more homogenous and denser sintered product. Analysis of the initial stage of sintering reveals that the sintering process of all examinated samples consists of two or three overlapping single-step processes, with a change in the dominant mass transport mechanism. The values of apparent activation energy of the considered single-step process exhibit a significant decrease with an increase in mechanical activation time. The values of the density of samples after isothermal sintering indicate that the final stage of sintering has not been reached by 1300 °C.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Analysis of the initial-stage sintering of mechanically activated SrTiO3
EP  - 10
IS  - 2
SP  - 1
VL  - 51
DO  - 10.2298/sos1902199z
ER  - 

@article{
author = "Živojinović, J. and Pavlović, Vera P. and Labus, Nebojša and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir",
year = "2019",
abstract = "The initial-stage of sintering plays a significant role in determining the final microstructure that defines the main characteristics of electroceramics materials such as functional properties. In this article non-isothermal sintering of non-activated and mechanically activated SrTiO3 samples was investigated up to 1300 °C. Dilatometric curves indicate that mechanical activation leads to an earlier onset of sintering, suggesting that it should lead to a more homogenous and denser sintered product. Analysis of the initial stage of sintering reveals that the sintering process of all examinated samples consists of two or three overlapping single-step processes, with a change in the dominant mass transport mechanism. The values of apparent activation energy of the considered single-step process exhibit a significant decrease with an increase in mechanical activation time. The values of the density of samples after isothermal sintering indicate that the final stage of sintering has not been reached by 1300 °C.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Analysis of the initial-stage sintering of mechanically activated SrTiO3",
pages = "10-1",
number = "2",
volume = "51",
doi = "10.2298/sos1902199z"
}

Živojinović, J., Pavlović, V. P., Labus, N., Blagojević, V. A., Kosanović, D.,& Pavlović, V.. (2019). Analysis of the initial-stage sintering of mechanically activated SrTiO3. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(2), 1-10.
https://doi.org/10.2298/sos1902199z

Živojinović J, Pavlović VP, Labus N, Blagojević VA, Kosanović D, Pavlović V. Analysis of the initial-stage sintering of mechanically activated SrTiO3. in Science of Sintering. 2019;51(2):1-10.
doi:10.2298/sos1902199z .

Živojinović, J., Pavlović, Vera P., Labus, Nebojša, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir, "Analysis of the initial-stage sintering of mechanically activated SrTiO3" in Science of Sintering, 51, no. 2 (2019):1-10,
https://doi.org/10.2298/sos1902199z . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir A.
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5756
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
EP  - 2998
SP  - 2989
VL  - 138
DO  - 10.1007/s10973-018-7924-1
ER  - 

@article{
author = "Obradović, Nina and Blagojević, Vladimir A. and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2998-2989",
volume = "138",
doi = "10.1007/s10973-018-7924-1"
}

Obradović, N., Blagojević, V. A., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 138, 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1

Obradović N, Blagojević VA, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović V. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138:2989-2998.
doi:10.1007/s10973-018-7924-1 .

Obradović, Nina, Blagojević, Vladimir A., Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir, "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, A.
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5761
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
EP  - 12021
IS  - 9
SP  - 12015
VL  - 45
DO  - 10.1016/j.ceramint.2019.03.095
ER  - 

@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, A. and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12021-12015",
number = "9",
volume = "45",
doi = "10.1016/j.ceramint.2019.03.095"
}

Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095

Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović V. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095 .

Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, A., Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir, "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 . .

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, Aleksandra
AU  - Rogan, Jelena
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/7022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5753
AB  - Magnesium aluminate, MgAl2O4, and other alumina-based spinels are refractory ceramics with high hardness and resistance to chemical attack while also being possible microwave dielectrics. Pure MgAl2O4 can be optically transparent when fully dense. Spinels exhibit inversion, which results in disorder among occupancy of A and B site cations. The goal of this study was to examine the effects of mechanical activation and composition on the temperature required for spinel formation and the site occupancy in the resulting spinel. 
MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3. The starting powders were mixed by ball milling to homogenize the powders without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1500 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influence of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. 
The main results of this study were that mechanical activation for 60 minutes initiated a mechano-chemical reaction, and resulted in spinel formation at much lower temperatures than within non-activated powders. Microstructures of ceramics sintered below 1400 oC indicated that final stage sintering started at much lower temperatures for activated samples than for non-activated samples. 
Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Societa ceramica italiana
PB  - Politecnico di Torino
C3  - Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
EP  - 262
SP  - 262
UR  - https://hdl.handle.net/21.15107/rcub_dais_7022
ER  - 

@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, Aleksandra and Rogan, Jelena and Pavlović, Vladimir",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4, and other alumina-based spinels are refractory ceramics with high hardness and resistance to chemical attack while also being possible microwave dielectrics. Pure MgAl2O4 can be optically transparent when fully dense. Spinels exhibit inversion, which results in disorder among occupancy of A and B site cations. The goal of this study was to examine the effects of mechanical activation and composition on the temperature required for spinel formation and the site occupancy in the resulting spinel. 
MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3. The starting powders were mixed by ball milling to homogenize the powders without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1500 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influence of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. 
The main results of this study were that mechanical activation for 60 minutes initiated a mechano-chemical reaction, and resulted in spinel formation at much lower temperatures than within non-activated powders. Microstructures of ceramics sintered below 1400 oC indicated that final stage sintering started at much lower temperatures for activated samples than for non-activated samples. 
Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Societa ceramica italiana, Politecnico di Torino",
journal = "Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "262-262",
url = "https://hdl.handle.net/21.15107/rcub_dais_7022"
}

Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Rogan, J.,& Pavlović, V.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019
Societa ceramica italiana., 262-262.
https://hdl.handle.net/21.15107/rcub_dais_7022

Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Rogan J, Pavlović V. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019. 2019;:262-262.
https://hdl.handle.net/21.15107/rcub_dais_7022 .

Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, Aleksandra, Rogan, Jelena, Pavlović, Vladimir, "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Abstract Book / XVI Conference and Exhibition of the European Ceramic Society XVI ECerS Conference, Torino, 16-20 June 2019 (2019):262-262,
https://hdl.handle.net/21.15107/rcub_dais_7022 .

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Dapčević, A.
AU  - Đorđević, Antonije
AU  - Balać, Igor
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://www.sciencedirect.com/science/article/pii/S0272884219306340
UR  - http://dais.sanu.ac.rs/123456789/5272
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5740
AB  - Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.
PB  - Elsevier
T2  - Ceramics International
T1  - The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics
EP  - 12021
IS  - 9
SP  - 12015
VL  - 45
DO  - 10.1016/j.ceramint.2019.03.095
ER  - 

@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Kosanović, Darko and Dapčević, A. and Đorđević, Antonije and Balać, Igor and Pavlović, Vladimir B.",
year = "2019",
abstract = "Magnesium aluminate, MgAl2O4 and other alumina-based spinels are ceramics with high hardness, high melting point and mechanical strenght. Spinels can also be used as dielectrics in microwave applications. The goal of this study was to examine the effects of mechanical activation and sintering temperatures on physico-chemical properties of spinel. MgAl2O4 was produced by solid state reaction between MgO and α-Al2O3. The starting powders were mixed by ball milling to homogenize without significant particle size reduction. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 1 h. Powders were compacted at 300 MPa. Heat treatments were performed in air, at temperatures ranging from 1200 to 1600 °C with 2 h dwell time, to determine the amount of spinel formation as a function of temperature. Phase composition and microstructure of initial powders and heated samples were determined by means of X-ray diffraction, particle size analysis, and scanning electron microscopy. The influences of milling and consolidation parameters were studied by electrical measurements and mechanical characterization. The main conclusion of this study was that mechanical activation for 60 min initiated a mechano-chemical reaction, resulted in spinel formation at much lower temperatures than within non-activated powders, and indicated that final sintering stage started at much lower temperatures for activated powders. Changes in microstructure parameters, as a consequence of mechanical treatment and subsequent heating of investigated powder mixtures, strongly affect electrical and mechanical properties of the final ceramics.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics",
pages = "12021-12015",
number = "9",
volume = "45",
doi = "10.1016/j.ceramint.2019.03.095"
}

Obradović, N., Fahrenholtz, W. G., Filipović, S., Kosanović, D., Dapčević, A., Đorđević, A., Balać, I.,& Pavlović, V. B.. (2019). The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International
Elsevier., 45(9), 12015-12021.
https://doi.org/10.1016/j.ceramint.2019.03.095

Obradović N, Fahrenholtz WG, Filipović S, Kosanović D, Dapčević A, Đorđević A, Balać I, Pavlović VB. The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics. in Ceramics International. 2019;45(9):12015-12021.
doi:10.1016/j.ceramint.2019.03.095 .

Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Kosanović, Darko, Dapčević, A., Đorđević, Antonije, Balać, Igor, Pavlović, Vladimir B., "The effect of mechanical activation on synthesis and properties of MgAl2O4 ceramics" in Ceramics International, 45, no. 9 (2019):12015-12021,
https://doi.org/10.1016/j.ceramint.2019.03.095 . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir A.
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4558
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5733
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
EP  - 2998
SP  - 2989
VL  - 138
DO  - 10.1007/s10973-018-7924-1
ER  - 

@article{
author = "Obradović, Nina and Blagojević, Vladimir A. and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir B.",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2998-2989",
volume = "138",
doi = "10.1007/s10973-018-7924-1"
}

Obradović, N., Blagojević, V. A., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V. B.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 138, 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1

Obradović N, Blagojević VA, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović VB. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138:2989-2998.
doi:10.1007/s10973-018-7924-1 .

Obradović, Nina, Blagojević, Vladimir A., Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir B., "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Djordjević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5028
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources - talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 degrees C and holding period conducted at 1250 degrees C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
EP  - 3022
IS  - 3
SP  - 3013
VL  - 45
DO  - 10.1016/j.ceramint.2018.10.120
ER  - 

@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Djordjević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir",
year = "2019",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources - talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 degrees C and holding period conducted at 1250 degrees C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3022-3013",
number = "3",
volume = "45",
doi = "10.1016/j.ceramint.2018.10.120"
}

Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Djordjević, A., Andrić, L.,& Pavlović, V.. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120

Terzić A, Obradović N, Kosanović D, Stojanović J, Djordjević A, Andrić L, Pavlović V. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International. 2019;45(3):3013-3022.
doi:10.1016/j.ceramint.2018.10.120 .

Terzić, Anja, Obradović, Nina, Kosanović, Darko, Stojanović, Jovica, Djordjević, Antonije, Andrić, Ljubiša, Pavlović, Vladimir, "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" in Ceramics International, 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 . .

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maricić, A.
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir
AU  - Vlahović, Branislav
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4755
AB  - Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100-240 min) and sintered at 1100 and 1200 degrees C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84-89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 degrees C are superior to those sintered at 1100 degrees C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350-420 degrees C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 degrees C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Influence of mechanical activation on functional properties of barium hexaferrite ceramics
EP  - 6672
IS  - 6
SP  - 6666
VL  - 44
DO  - 10.1016/j.ceramint.2018.01.078
ER  - 

@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maricić, A. and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir and Vlahović, Branislav",
year = "2018",
abstract = "Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100-240 min) and sintered at 1100 and 1200 degrees C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84-89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 degrees C are superior to those sintered at 1100 degrees C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350-420 degrees C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 degrees C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Influence of mechanical activation on functional properties of barium hexaferrite ceramics",
pages = "6672-6666",
number = "6",
volume = "44",
doi = "10.1016/j.ceramint.2018.01.078"
}

Kosanović, D., Blagojević, V. A., Maricić, A., Aleksić, S., Pavlović, V. P., Pavlović, V.,& Vlahović, B.. (2018). Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 44(6), 6666-6672.
https://doi.org/10.1016/j.ceramint.2018.01.078

Kosanović D, Blagojević VA, Maricić A, Aleksić S, Pavlović VP, Pavlović V, Vlahović B. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International. 2018;44(6):6666-6672.
doi:10.1016/j.ceramint.2018.01.078 .

Kosanović, Darko, Blagojević, Vladimir A., Maricić, A., Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir, Vlahović, Branislav, "Influence of mechanical activation on functional properties of barium hexaferrite ceramics" in Ceramics International, 44, no. 6 (2018):6666-6672,
https://doi.org/10.1016/j.ceramint.2018.01.078 . .

TY  - DATA
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maričić, Aleksa
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
PY  - 2018
UR  - https://ars.els-cdn.com/content/image/1-s2.0-S0272884218300919-mmc1.pdf
UR  - http://dais.sanu.ac.rs/123456789/3788
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5729
AB  - Rietveld analysis of XRD patterns of mechanically activated Fe:BaTiO3 powder mixtures sintered at 1200°C
T2  - Ceramics International
T1  - Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement
IS  - 6
VL  - 44
UR  - https://hdl.handle.net/21.15107/rcub_dais_4606
ER  - 

@misc{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maričić, Aleksa and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir B. and Vlahović, Branislav",
year = "2018",
abstract = "Rietveld analysis of XRD patterns of mechanically activated Fe:BaTiO3 powder mixtures sintered at 1200°C",
journal = "Ceramics International",
title = "Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement",
number = "6",
volume = "44",
url = "https://hdl.handle.net/21.15107/rcub_dais_4606"
}

Kosanović, D., Blagojević, V. A., Maričić, A., Aleksić, S., Pavlović, V. P., Pavlović, V. B.,& Vlahović, B.. (2018). Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement. in Ceramics International, 44(6).
https://hdl.handle.net/21.15107/rcub_dais_4606

Kosanović D, Blagojević VA, Maričić A, Aleksić S, Pavlović VP, Pavlović VB, Vlahović B. Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement. in Ceramics International. 2018;44(6).
https://hdl.handle.net/21.15107/rcub_dais_4606 .

Kosanović, Darko, Blagojević, Vladimir A., Maričić, Aleksa, Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir B., Vlahović, Branislav, "Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement" in Ceramics International, 44, no. 6 (2018),
https://hdl.handle.net/21.15107/rcub_dais_4606 .

TY  - CONF
AU  - Obradović, Nina
AU  - Rusmirović, Jelena
AU  - Kosanović, Darko
AU  - Đolić, Maja B.
AU  - Popović, Ana L.
AU  - Pavlović, Vladimir B.
AU  - Marinković, Aleksandar D.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4573
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5734
AB  - This study presents the synthesis of porous cordierite- based ceramics and its surface activation by polyethylenimine/nano-CeO2 for the heavy metal removal. The synthesis was carried out by the addition of following powders: MgO, Al2O3, and SiO2 in 2:2:5 molar ratios, respectively. The oxide(s) mixture was further processed in two sequential stages: i) ball milled in the ethanol for 40 minutes and palletized under the pressure of 3 t/cm2, as a pre-sintering process, and ii) the pallets were further sintered for 2h in the air atmosphere at 1350 oC, under a heating rate of 20 oC/min. The sintered mineral composite was crashed and sieved, and mixed with 20 wt % of nanocellulose, as a pore forming agent. Nanocellulose mixture was pressed into pallets under 5 t/cm2 and sintered at 700 oC, under a heating rate of 5 oC/ min. The obtained synthetic cordierite was further tested as the adsorbent activated by polyethylenimine/ nano-CeO2 for the removal of Ni2+ and Cd2+ -ions. The adsorption isotherms, kinetics models, and thermodynamic parameters were also analyzed, manifesting that the adsorption is a spontaneous and endothermic process. The phase composition of the pristine and activated cordierite was analyzed by the X-ray diffraction method (XRD), Fourier transformation infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). This work has shed light on the mechanism of heavy metals removal from the aquatic medium using the novel hybrid (nano)synthesized material.
PB  - Beograd : Serbian Society of Toxicology
C3  - Book of Abstracts / 10th Congress of Toxicology in Developing Countries (CTDC10) [and] 12th Congress of the Serbian Society of Toxicology (12th SCT), April 18-21, 2018, Belgrade, Serbia
T1  - The Removal of Ni2+ and Cd2+ -ions onto Synthetic Mineral Based Composite Functionalized by Polyethylenimine
EP  - 145
SP  - 144
UR  - https://hdl.handle.net/21.15107/rcub_dais_4573
ER  - 

@conference{
author = "Obradović, Nina and Rusmirović, Jelena and Kosanović, Darko and Đolić, Maja B. and Popović, Ana L. and Pavlović, Vladimir B. and Marinković, Aleksandar D.",
year = "2018",
abstract = "This study presents the synthesis of porous cordierite- based ceramics and its surface activation by polyethylenimine/nano-CeO2 for the heavy metal removal. The synthesis was carried out by the addition of following powders: MgO, Al2O3, and SiO2 in 2:2:5 molar ratios, respectively. The oxide(s) mixture was further processed in two sequential stages: i) ball milled in the ethanol for 40 minutes and palletized under the pressure of 3 t/cm2, as a pre-sintering process, and ii) the pallets were further sintered for 2h in the air atmosphere at 1350 oC, under a heating rate of 20 oC/min. The sintered mineral composite was crashed and sieved, and mixed with 20 wt % of nanocellulose, as a pore forming agent. Nanocellulose mixture was pressed into pallets under 5 t/cm2 and sintered at 700 oC, under a heating rate of 5 oC/ min. The obtained synthetic cordierite was further tested as the adsorbent activated by polyethylenimine/ nano-CeO2 for the removal of Ni2+ and Cd2+ -ions. The adsorption isotherms, kinetics models, and thermodynamic parameters were also analyzed, manifesting that the adsorption is a spontaneous and endothermic process. The phase composition of the pristine and activated cordierite was analyzed by the X-ray diffraction method (XRD), Fourier transformation infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). This work has shed light on the mechanism of heavy metals removal from the aquatic medium using the novel hybrid (nano)synthesized material.",
publisher = "Beograd : Serbian Society of Toxicology",
journal = "Book of Abstracts / 10th Congress of Toxicology in Developing Countries (CTDC10) [and] 12th Congress of the Serbian Society of Toxicology (12th SCT), April 18-21, 2018, Belgrade, Serbia",
title = "The Removal of Ni2+ and Cd2+ -ions onto Synthetic Mineral Based Composite Functionalized by Polyethylenimine",
pages = "145-144",
url = "https://hdl.handle.net/21.15107/rcub_dais_4573"
}

Obradović, N., Rusmirović, J., Kosanović, D., Đolić, M. B., Popović, A. L., Pavlović, V. B.,& Marinković, A. D.. (2018). The Removal of Ni2+ and Cd2+ -ions onto Synthetic Mineral Based Composite Functionalized by Polyethylenimine. in Book of Abstracts / 10th Congress of Toxicology in Developing Countries (CTDC10) [and] 12th Congress of the Serbian Society of Toxicology (12th SCT), April 18-21, 2018, Belgrade, Serbia
Beograd : Serbian Society of Toxicology., 144-145.
https://hdl.handle.net/21.15107/rcub_dais_4573

Obradović N, Rusmirović J, Kosanović D, Đolić MB, Popović AL, Pavlović VB, Marinković AD. The Removal of Ni2+ and Cd2+ -ions onto Synthetic Mineral Based Composite Functionalized by Polyethylenimine. in Book of Abstracts / 10th Congress of Toxicology in Developing Countries (CTDC10) [and] 12th Congress of the Serbian Society of Toxicology (12th SCT), April 18-21, 2018, Belgrade, Serbia. 2018;:144-145.
https://hdl.handle.net/21.15107/rcub_dais_4573 .

Obradović, Nina, Rusmirović, Jelena, Kosanović, Darko, Đolić, Maja B., Popović, Ana L., Pavlović, Vladimir B., Marinković, Aleksandar D., "The Removal of Ni2+ and Cd2+ -ions onto Synthetic Mineral Based Composite Functionalized by Polyethylenimine" in Book of Abstracts / 10th Congress of Toxicology in Developing Countries (CTDC10) [and] 12th Congress of the Serbian Society of Toxicology (12th SCT), April 18-21, 2018, Belgrade, Serbia (2018):144-145,
https://hdl.handle.net/21.15107/rcub_dais_4573 .

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Labus, Nebojša
AU  - Tadić, N.B.
AU  - Pavlović, Vladimir
AU  - Ristić, M.M.
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4724
AB  - Barium strontium titanate powders with different Ba: Sr ratios were investigated to determine the influence of the initial composition of powder mixture on microstructural properties and sintering kinetics. It was determined that BaCO3 and SrCO3 react differently to mixing, resulting in Ba0.5Sr0.5CO3 in the sample with 80% Ba and different contents of Ba1-xSrxTiO3 in samples with 50% and 20% Ba. In addition, the morphology is also different, with higher Sr content leading to larger particles size and less agglomeration. The different chemical content of the initial powder mixture also has a marked impact on the sintering process: the onset of sintering shifts towards higher temperature with higher Sr content, while the average apparent activation energy of sintering is the highest for the sample with 80% Ba and the lowest for the mixture with 50% Ba. In addition, hexagonal-to-cubic phase transformation was observed in parallel with the sintering process, where the position of the phase transition shifts to lower temperatures with an increase in Sr content. This is consistent with the behavior of low-temperature phase transitions of BST. The phase transition was not observed in sintered samples, suggesting that there is a size-dependence of the phase transition temperature.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders
EP  - 38
IS  - 1
SP  - 29
VL  - 50
DO  - 10.2298/SOS1801029K
ER  - 

@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Labus, Nebojša and Tadić, N.B. and Pavlović, Vladimir and Ristić, M.M.",
year = "2018",
abstract = "Barium strontium titanate powders with different Ba: Sr ratios were investigated to determine the influence of the initial composition of powder mixture on microstructural properties and sintering kinetics. It was determined that BaCO3 and SrCO3 react differently to mixing, resulting in Ba0.5Sr0.5CO3 in the sample with 80% Ba and different contents of Ba1-xSrxTiO3 in samples with 50% and 20% Ba. In addition, the morphology is also different, with higher Sr content leading to larger particles size and less agglomeration. The different chemical content of the initial powder mixture also has a marked impact on the sintering process: the onset of sintering shifts towards higher temperature with higher Sr content, while the average apparent activation energy of sintering is the highest for the sample with 80% Ba and the lowest for the mixture with 50% Ba. In addition, hexagonal-to-cubic phase transformation was observed in parallel with the sintering process, where the position of the phase transition shifts to lower temperatures with an increase in Sr content. This is consistent with the behavior of low-temperature phase transitions of BST. The phase transition was not observed in sintered samples, suggesting that there is a size-dependence of the phase transition temperature.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders",
pages = "38-29",
number = "1",
volume = "50",
doi = "10.2298/SOS1801029K"
}

Kosanović, D., Blagojević, V. A., Labus, N., Tadić, N.B., Pavlović, V.,& Ristić, M.M.. (2018). Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(1), 29-38.
https://doi.org/10.2298/SOS1801029K

Kosanović D, Blagojević VA, Labus N, Tadić N, Pavlović V, Ristić M. Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders. in Science of Sintering. 2018;50(1):29-38.
doi:10.2298/SOS1801029K .

Kosanović, Darko, Blagojević, Vladimir A., Labus, Nebojša, Tadić, N.B., Pavlović, Vladimir, Ristić, M.M., "Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders" in Science of Sintering, 50, no. 1 (2018):29-38,
https://doi.org/10.2298/SOS1801029K . .

TY  - JOUR
AU  - Zivojinović, Jelena
AU  - Pavlović, Vera P.
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Krstić, Jugoslav
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vladimir
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4358
AB  - Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 mu m in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders
EP  - 870
SP  - 863
VL  - 695
DO  - 10.1016/j.jallcom.2016.10.159
ER  - 

@article{
author = "Zivojinović, Jelena and Pavlović, Vera P. and Kosanović, Darko and Marković, Smilja and Krstić, Jugoslav and Blagojević, Vladimir A. and Pavlović, Vladimir",
year = "2017",
abstract = "Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 mu m in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders",
pages = "870-863",
volume = "695",
doi = "10.1016/j.jallcom.2016.10.159"
}

Zivojinović, J., Pavlović, V. P., Kosanović, D., Marković, S., Krstić, J., Blagojević, V. A.,& Pavlović, V.. (2017). The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 695, 863-870.
https://doi.org/10.1016/j.jallcom.2016.10.159

Zivojinović J, Pavlović VP, Kosanović D, Marković S, Krstić J, Blagojević VA, Pavlović V. The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds. 2017;695:863-870.
doi:10.1016/j.jallcom.2016.10.159 .

Zivojinović, Jelena, Pavlović, Vera P., Kosanović, Darko, Marković, Smilja, Krstić, Jugoslav, Blagojević, Vladimir A., Pavlović, Vladimir, "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders" in Journal of Alloys and Compounds, 695 (2017):863-870,
https://doi.org/10.1016/j.jallcom.2016.10.159 . .

TY  - CONF
AU  - Obradović, Nina
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Filipović, Suzana
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Olćan, Dragan
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/15444
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5720
AB  - In this study, sintering of two systems was investigated in parallel, pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with addition of 5 mass % TeO2. Green bodies were prepared from powder mixtures mechanically activated for 0, 10 and 40minutes by uniaxial pressing at 20 MPa followed by cold isostatic pressing (CIP) at 1000 MPa. The pressure-less sintering of these specimens was performed at a temperature of 1350 oC for 1 h, with 10 oC/min heating rate. Densities over 96 % of theoretical values were obtained for samples activated for 40 minutes. XRD measurements of MAS-40 sintered sample pointed at a mixture that consisted of several phases, majority of cordierite (> 73 %), spinel MgAl2O4 (> 22 %), ZrSiO4 (2.5 %), and Al2O3 (1.8%), while XRD pattern of MAS-40-TeO2 contained majority of cordierite (> 72 %), spinel MgAl2O4 (> 23 %), ZrSiO4 (1.9 %), and Al2O3 (1.9 %). The relative permittivities of the samples were measured in an open test fixture. The results for the real part of the complex relative permittivity of the samples, measured at 200 MHz, are shown in Table I. The loss tangent for all samples was very small, below the resolution of the measurement setup (0.005).
There is a strong correlation between the relative permittivity and the density, which agrees with our previous results.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
T1  - Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system
EP  - 70
SP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_dais_15444
ER  - 

@conference{
author = "Obradović, Nina and Đorđević, Nataša and Kosanović, Darko and Filipović, Suzana and Kachlik, Martin and Maca, Karel and Olćan, Dragan and Đorđević, Antonije and Pavlović, Vladimir B.",
year = "2017",
abstract = "In this study, sintering of two systems was investigated in parallel, pure cordierite 2MgO:2Al2O3:5SiO2, and cordierite with addition of 5 mass % TeO2. Green bodies were prepared from powder mixtures mechanically activated for 0, 10 and 40minutes by uniaxial pressing at 20 MPa followed by cold isostatic pressing (CIP) at 1000 MPa. The pressure-less sintering of these specimens was performed at a temperature of 1350 oC for 1 h, with 10 oC/min heating rate. Densities over 96 % of theoretical values were obtained for samples activated for 40 minutes. XRD measurements of MAS-40 sintered sample pointed at a mixture that consisted of several phases, majority of cordierite (> 73 %), spinel MgAl2O4 (> 22 %), ZrSiO4 (2.5 %), and Al2O3 (1.8%), while XRD pattern of MAS-40-TeO2 contained majority of cordierite (> 72 %), spinel MgAl2O4 (> 23 %), ZrSiO4 (1.9 %), and Al2O3 (1.9 %). The relative permittivities of the samples were measured in an open test fixture. The results for the real part of the complex relative permittivity of the samples, measured at 200 MHz, are shown in Table I. The loss tangent for all samples was very small, below the resolution of the measurement setup (0.005).
There is a strong correlation between the relative permittivity and the density, which agrees with our previous results.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017",
title = "Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_dais_15444"
}

Obradović, N., Đorđević, N., Kosanović, D., Filipović, S., Kachlik, M., Maca, K., Olćan, D., Đorđević, A.,& Pavlović, V. B.. (2017). Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
Belgrade : Materials Research Society of Serbia., 70-70.
https://hdl.handle.net/21.15107/rcub_dais_15444

Obradović N, Đorđević N, Kosanović D, Filipović S, Kachlik M, Maca K, Olćan D, Đorđević A, Pavlović VB. Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017. 2017;:70-70.
https://hdl.handle.net/21.15107/rcub_dais_15444 .

Obradović, Nina, Đorđević, Nataša, Kosanović, Darko, Filipović, Suzana, Kachlik, Martin, Maca, Karel, Olćan, Dragan, Đorđević, Antonije, Pavlović, Vladimir B., "Characterization of pressure-less sintered MgO-Al2O3-SiO2-TeO2 system" in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017 (2017):70-70,
https://hdl.handle.net/21.15107/rcub_dais_15444 .

TY  - CONF
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Filipović, Suzana
AU  - Rusmirović, Jelena
AU  - Marinković, Aleksandar D.
AU  - Radić, Danka
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/4776
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5737
AB  - In this study, porous cordierite-based ceramics was synthesized. In the first step, MgO, Al2O3, and SiO2 (all Aldrich, p.a.) were used. MgO and Al2O3 powders were calcined at 1000 oC for 2 h, in order to avoid hydroxides. They were mixed in 2:2:5 molar ratio, in order to form cordierite, Mg2Al4Si5O18. Ethanol was added to the mixture, and then milled in a Fritsch Pulverisette planetary mill, with 300 rpm, in air atmosfere. Times of activation were 0, 10, 40, and 80 min, while balls and vessels were made from ZrO2, and powder to balls mass ratio was 40:1. After milling, powders were dried, and then pressed under 3 t/cm2. Pallets with 8 mm radius were sintered in air at 1350 oC, for 2 h, heating rate was 20 oC/min. Sintered samples were crashed and sieved. In the secons step, the as-prepared cordierite was mixed with 20 wt.% yeast (0.1 g yeast + 0.4 g cordierite per sample). The other mixture was with 20 wt.% nanocellulose (0.1 g NC + 0.4 g cordierite per sample). Both mixtures were pressed into pallets under 5 t/cm2 and sintered at 700 oC, with 5 oC/min heating rate, in air atmosfere. During the second sintering regime, porous cordierite-based ceramics was obtained. The phase composition of the sintered samples as well as microstructures was analyzed by the means of X-ray diffraction method and SEM. Cordierite was the most abundant phase in all sintered samples. It was observed that addition of different pore-forming agent resulted in significantly different microstructures.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
T1  - Preparation of cordierite-based adsorbents for water purification
EP  - 71
SP  - 71
UR  - https://hdl.handle.net/21.15107/rcub_dais_4776
ER  - 

@conference{
author = "Obradović, Nina and Kosanović, Darko and Filipović, Suzana and Rusmirović, Jelena and Marinković, Aleksandar D. and Radić, Danka and Pavlović, Vladimir B.",
year = "2017",
abstract = "In this study, porous cordierite-based ceramics was synthesized. In the first step, MgO, Al2O3, and SiO2 (all Aldrich, p.a.) were used. MgO and Al2O3 powders were calcined at 1000 oC for 2 h, in order to avoid hydroxides. They were mixed in 2:2:5 molar ratio, in order to form cordierite, Mg2Al4Si5O18. Ethanol was added to the mixture, and then milled in a Fritsch Pulverisette planetary mill, with 300 rpm, in air atmosfere. Times of activation were 0, 10, 40, and 80 min, while balls and vessels were made from ZrO2, and powder to balls mass ratio was 40:1. After milling, powders were dried, and then pressed under 3 t/cm2. Pallets with 8 mm radius were sintered in air at 1350 oC, for 2 h, heating rate was 20 oC/min. Sintered samples were crashed and sieved. In the secons step, the as-prepared cordierite was mixed with 20 wt.% yeast (0.1 g yeast + 0.4 g cordierite per sample). The other mixture was with 20 wt.% nanocellulose (0.1 g NC + 0.4 g cordierite per sample). Both mixtures were pressed into pallets under 5 t/cm2 and sintered at 700 oC, with 5 oC/min heating rate, in air atmosfere. During the second sintering regime, porous cordierite-based ceramics was obtained. The phase composition of the sintered samples as well as microstructures was analyzed by the means of X-ray diffraction method and SEM. Cordierite was the most abundant phase in all sintered samples. It was observed that addition of different pore-forming agent resulted in significantly different microstructures.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017",
title = "Preparation of cordierite-based adsorbents for water purification",
pages = "71-71",
url = "https://hdl.handle.net/21.15107/rcub_dais_4776"
}

Obradović, N., Kosanović, D., Filipović, S., Rusmirović, J., Marinković, A. D., Radić, D.,& Pavlović, V. B.. (2017). Preparation of cordierite-based adsorbents for water purification. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
Belgrade : Serbian Ceramic Society., 71-71.
https://hdl.handle.net/21.15107/rcub_dais_4776

Obradović N, Kosanović D, Filipović S, Rusmirović J, Marinković AD, Radić D, Pavlović VB. Preparation of cordierite-based adsorbents for water purification. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017. 2017;:71-71.
https://hdl.handle.net/21.15107/rcub_dais_4776 .

Obradović, Nina, Kosanović, Darko, Filipović, Suzana, Rusmirović, Jelena, Marinković, Aleksandar D., Radić, Danka, Pavlović, Vladimir B., "Preparation of cordierite-based adsorbents for water purification" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 (2017):71-71,
https://hdl.handle.net/21.15107/rcub_dais_4776 .

TY  - CONF
AU  - Lazarević, R.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
AU  - Đukić, S.
AU  - Maričić, Aleksa
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/4769
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5736
AB  - The initial powder (16 % Fe2O3, 4 % BaCO3, 80 % BaTiO3) was mechanically activated in a planetary mill for 20, 80, 120, 160, 200 and 220 minutes in air. Modified Faraday method was used to perform magnetization measurements of compressed activated powder. The value of magnetization of these samples increases with increase in time of activation from 0.77 Am2kg-1 to 1.74 Am2kg-1. Thermomagnetic measurements in 20-600 °C temperature interval was used to investigate the dependence of magnetization on temperature. Multiple heating cycles of the sample activated for 120 min shows that after heating to 540 °C and 600 °C the value of magnetization increases 17 % and 62 %, respectively. Compressed powder samples were sintered for 2 hours at 1200 °C, leading to an increase in magnetization of 81 to 123 %. Thermomagnetic measurements of sintered samples in 20-450 °C temperature interval shows that sintered samples possess both ferromagnetic and ferroelectric properties. The relative dielectric constant of sintered samples at room temperature is around 8x104, depending on mechanical activation time.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
T1  - Synthesis and Characterization of Multifferoics 16%(Fe2O3)4%(BaCO3)80%(BaTiO3)
EP  - 77
SP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_dais_4769
ER  - 

@conference{
author = "Lazarević, R. and Kosanović, Darko and Pavlović, Vladimir B. and Đukić, S. and Maričić, Aleksa",
year = "2017",
abstract = "The initial powder (16 % Fe2O3, 4 % BaCO3, 80 % BaTiO3) was mechanically activated in a planetary mill for 20, 80, 120, 160, 200 and 220 minutes in air. Modified Faraday method was used to perform magnetization measurements of compressed activated powder. The value of magnetization of these samples increases with increase in time of activation from 0.77 Am2kg-1 to 1.74 Am2kg-1. Thermomagnetic measurements in 20-600 °C temperature interval was used to investigate the dependence of magnetization on temperature. Multiple heating cycles of the sample activated for 120 min shows that after heating to 540 °C and 600 °C the value of magnetization increases 17 % and 62 %, respectively. Compressed powder samples were sintered for 2 hours at 1200 °C, leading to an increase in magnetization of 81 to 123 %. Thermomagnetic measurements of sintered samples in 20-450 °C temperature interval shows that sintered samples possess both ferromagnetic and ferroelectric properties. The relative dielectric constant of sintered samples at room temperature is around 8x104, depending on mechanical activation time.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017",
title = "Synthesis and Characterization of Multifferoics 16%(Fe2O3)4%(BaCO3)80%(BaTiO3)",
pages = "77-77",
url = "https://hdl.handle.net/21.15107/rcub_dais_4769"
}

Lazarević, R., Kosanović, D., Pavlović, V. B., Đukić, S.,& Maričić, A.. (2017). Synthesis and Characterization of Multifferoics 16%(Fe2O3)4%(BaCO3)80%(BaTiO3). in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017
Belgrade : Serbian Ceramic Society., 77-77.
https://hdl.handle.net/21.15107/rcub_dais_4769

Lazarević R, Kosanović D, Pavlović VB, Đukić S, Maričić A. Synthesis and Characterization of Multifferoics 16%(Fe2O3)4%(BaCO3)80%(BaTiO3). in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017. 2017;:77-77.
https://hdl.handle.net/21.15107/rcub_dais_4769 .

Lazarević, R., Kosanović, Darko, Pavlović, Vladimir B., Đukić, S., Maričić, Aleksa, "Synthesis and Characterization of Multifferoics 16%(Fe2O3)4%(BaCO3)80%(BaTiO3)" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VI: New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, September 18-20, 2017 (2017):77-77,
https://hdl.handle.net/21.15107/rcub_dais_4769 .

TY  - CONF
AU  - Đorđević, Nataša
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/894
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5719
AB  - Cordierite 2MgO+2Al2O3+5SiO2 is frequently used ceramic material, that is commonly used as a carrier of electrical components due to its low dielectric constant (~ 5), and low temperature thermal expansion coefficient (20•10-7 ºC-1). In order to accelerate the process of sintering, 5.00 mass% TeO2 was added to the starting mixtures. System was tested in two parallel mixtures, one with no added additives, and the other one with TeO2. The mechanical activation of the both mixtures was performed in a high-energy ball mill in time intervals from 0 to 40 min with ball to powder mass ratio 1:40. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders as well as microstructures was analyzed by the means of X-ray diffraction method and SEM.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016
T1  - Influence of mechanical activation on the MgO-Al2O3-SiO2 system with TeO2
EP  - 75
SP  - 75
UR  - https://hdl.handle.net/21.15107/rcub_dais_894
ER  - 

@conference{
author = "Đorđević, Nataša and Obradović, Nina and Filipović, Suzana and Kosanović, Darko and Marković, Smilja and Mitrić, Miodrag and Pavlović, Vladimir B.",
year = "2016",
abstract = "Cordierite 2MgO+2Al2O3+5SiO2 is frequently used ceramic material, that is commonly used as a carrier of electrical components due to its low dielectric constant (~ 5), and low temperature thermal expansion coefficient (20•10-7 ºC-1). In order to accelerate the process of sintering, 5.00 mass% TeO2 was added to the starting mixtures. System was tested in two parallel mixtures, one with no added additives, and the other one with TeO2. The mechanical activation of the both mixtures was performed in a high-energy ball mill in time intervals from 0 to 40 min with ball to powder mass ratio 1:40. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders as well as microstructures was analyzed by the means of X-ray diffraction method and SEM.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016",
title = "Influence of mechanical activation on the MgO-Al2O3-SiO2 system with TeO2",
pages = "75-75",
url = "https://hdl.handle.net/21.15107/rcub_dais_894"
}

Đorđević, N., Obradović, N., Filipović, S., Kosanović, D., Marković, S., Mitrić, M.,& Pavlović, V. B.. (2016). Influence of mechanical activation on the MgO-Al2O3-SiO2 system with TeO2. in Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016
Belgrade : Materials Research Society of Serbia., 75-75.
https://hdl.handle.net/21.15107/rcub_dais_894

Đorđević N, Obradović N, Filipović S, Kosanović D, Marković S, Mitrić M, Pavlović VB. Influence of mechanical activation on the MgO-Al2O3-SiO2 system with TeO2. in Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016. 2016;:75-75.
https://hdl.handle.net/21.15107/rcub_dais_894 .

Đorđević, Nataša, Obradović, Nina, Filipović, Suzana, Kosanović, Darko, Marković, Smilja, Mitrić, Miodrag, Pavlović, Vladimir B., "Influence of mechanical activation on the MgO-Al2O3-SiO2 system with TeO2" in Programme and The Book of Abstracts / Eighteenth Annual Conference YUCOMAT 2016, Herceg Novi, September 5-10, 2016 (2016):75-75,
https://hdl.handle.net/21.15107/rcub_dais_894 .

TY  - CONF
AU  - Živojinović, Jelena
AU  - Peleš, Adriana
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/882
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5717
AB  - The influence of mechanically activated fillers (ZnO, BaTiO3 and SrTiO3 ultra-fine powders) on mechanical properties of poly(vinylidene) fluoride (PVDF) and oxide nanoparticle composite was investigated using molecular simulations. Mechanical activation leads to the creation of new surfaces and the comminution of the initial powder particles, which affects the crystallization of PVDF matrix. In addition, prolonged mechanical activation leads to agglomeration of nanoparticles into “soft” and “hard” agglomerates of different sizes. All of this has a significant effect on mechanical properties of PVDF-nanoparticle composites. Microstructural changes due to mechanical activation in ZnO, BaTiO3 and SrTiO3 powders were investigated using SEM and XRD, while dependence of mechanical properties on nanoparticle size was investigated using molecular simulation. These show that smaller nanoparticles significantly enhance the mechanical properties of PVDF-nanoparticle composite and allow use of mechanical activation as a means of reducing the amount of nanoparticle filler in the composite, while achieving the same of superior mechanical properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
T1  - Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites
EP  - 64
SP  - 63
UR  - https://hdl.handle.net/21.15107/rcub_dais_882
ER  - 

@conference{
author = "Živojinović, Jelena and Peleš, Adriana and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2016",
abstract = "The influence of mechanically activated fillers (ZnO, BaTiO3 and SrTiO3 ultra-fine powders) on mechanical properties of poly(vinylidene) fluoride (PVDF) and oxide nanoparticle composite was investigated using molecular simulations. Mechanical activation leads to the creation of new surfaces and the comminution of the initial powder particles, which affects the crystallization of PVDF matrix. In addition, prolonged mechanical activation leads to agglomeration of nanoparticles into “soft” and “hard” agglomerates of different sizes. All of this has a significant effect on mechanical properties of PVDF-nanoparticle composites. Microstructural changes due to mechanical activation in ZnO, BaTiO3 and SrTiO3 powders were investigated using SEM and XRD, while dependence of mechanical properties on nanoparticle size was investigated using molecular simulation. These show that smaller nanoparticles significantly enhance the mechanical properties of PVDF-nanoparticle composite and allow use of mechanical activation as a means of reducing the amount of nanoparticle filler in the composite, while achieving the same of superior mechanical properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade",
title = "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites",
pages = "64-63",
url = "https://hdl.handle.net/21.15107/rcub_dais_882"
}

Živojinović, J., Peleš, A., Blagojević, V. A., Kosanović, D.,& Pavlović, V. B.. (2016). Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
Belgrade : Serbian Ceramic Society., 63-64.
https://hdl.handle.net/21.15107/rcub_dais_882

Živojinović J, Peleš A, Blagojević VA, Kosanović D, Pavlović VB. Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade. 2016;:63-64.
https://hdl.handle.net/21.15107/rcub_dais_882 .

Živojinović, Jelena, Peleš, Adriana, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir B., "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade (2016):63-64,
https://hdl.handle.net/21.15107/rcub_dais_882 .

TY  - JOUR
AU  - Obradović, Nina
AU  - Djordjević, Nataša
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Kosanović, Darko
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4192
AB  - Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA
EP  - 673
IS  - 2
SP  - 667
VL  - 124
DO  - 10.1007/s10973-015-5132-9
ER  - 

@article{
author = "Obradović, Nina and Djordjević, Nataša and Filipović, Suzana and Marković, Smilja and Kosanović, Darko and Mitrić, Miodrag and Pavlović, Vladimir",
year = "2016",
abstract = "Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA",
pages = "673-667",
number = "2",
volume = "124",
doi = "10.1007/s10973-015-5132-9"
}

Obradović, N., Djordjević, N., Filipović, S., Marković, S., Kosanović, D., Mitrić, M.,& Pavlović, V.. (2016). Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 124(2), 667-673.
https://doi.org/10.1007/s10973-015-5132-9

Obradović N, Djordjević N, Filipović S, Marković S, Kosanović D, Mitrić M, Pavlović V. Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. in Journal of Thermal Analysis and Calorimetry. 2016;124(2):667-673.
doi:10.1007/s10973-015-5132-9 .

Obradović, Nina, Djordjević, Nataša, Filipović, Suzana, Marković, Smilja, Kosanović, Darko, Mitrić, Miodrag, Pavlović, Vladimir, "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA" in Journal of Thermal Analysis and Calorimetry, 124, no. 2 (2016):667-673,
https://doi.org/10.1007/s10973-015-5132-9 . .

TY  - JOUR
AU  - Kosanović, Darko
AU  - Obradović, N.
AU  - Pavlović, Vera P.
AU  - Marković, S.
AU  - Maricić, A.
AU  - Rasić, G.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir
AU  - Ristić, M.M.
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4010
AB  - Crystal structure and morphology of mechanically activated nanocrystalline Fe/BaTiO3 was investigated using a combination of spectroscopic and microscopic methods. These show that mechanical activation led to the creation of new surfaces and the comminution of the initial powder particles. Prolonged milling resulted in formation of larger agglomerates of BaTiO3 and bimodal particle size distribution, where BaTiO3 particles were significantly larger than those of iron-containing phases. Milling times of 210 min and above lead to a significant decrease in temperature of the oxidation of iron in the sample, indicating abrupt change in reactivity. Raman spectroscopy analysis has revealed that activation had a pronounced influence on Fe/BaTiO3 lattice, thereby affecting both the stability of the crystal structure and the phase transition phenomena.
PB  - Elsevier, Amsterdam
T2  - Materials Science and Engineering B-Advanced Functional Solid-State Materials
T1  - The influence of mechanical activation on the morphological changes of Fe/BaTiO3 powder
EP  - 95
SP  - 89
VL  - 212
DO  - 10.1016/j.mseb.2016.07.016
ER  - 

@article{
author = "Kosanović, Darko and Obradović, N. and Pavlović, Vera P. and Marković, S. and Maricić, A. and Rasić, G. and Vlahović, Branislav and Pavlović, Vladimir and Ristić, M.M.",
year = "2016",
abstract = "Crystal structure and morphology of mechanically activated nanocrystalline Fe/BaTiO3 was investigated using a combination of spectroscopic and microscopic methods. These show that mechanical activation led to the creation of new surfaces and the comminution of the initial powder particles. Prolonged milling resulted in formation of larger agglomerates of BaTiO3 and bimodal particle size distribution, where BaTiO3 particles were significantly larger than those of iron-containing phases. Milling times of 210 min and above lead to a significant decrease in temperature of the oxidation of iron in the sample, indicating abrupt change in reactivity. Raman spectroscopy analysis has revealed that activation had a pronounced influence on Fe/BaTiO3 lattice, thereby affecting both the stability of the crystal structure and the phase transition phenomena.",
publisher = "Elsevier, Amsterdam",
journal = "Materials Science and Engineering B-Advanced Functional Solid-State Materials",
title = "The influence of mechanical activation on the morphological changes of Fe/BaTiO3 powder",
pages = "95-89",
volume = "212",
doi = "10.1016/j.mseb.2016.07.016"
}

Kosanović, D., Obradović, N., Pavlović, V. P., Marković, S., Maricić, A., Rasić, G., Vlahović, B., Pavlović, V.,& Ristić, M.M.. (2016). The influence of mechanical activation on the morphological changes of Fe/BaTiO3 powder. in Materials Science and Engineering B-Advanced Functional Solid-State Materials
Elsevier, Amsterdam., 212, 89-95.
https://doi.org/10.1016/j.mseb.2016.07.016

Kosanović D, Obradović N, Pavlović VP, Marković S, Maricić A, Rasić G, Vlahović B, Pavlović V, Ristić M. The influence of mechanical activation on the morphological changes of Fe/BaTiO3 powder. in Materials Science and Engineering B-Advanced Functional Solid-State Materials. 2016;212:89-95.
doi:10.1016/j.mseb.2016.07.016 .

Kosanović, Darko, Obradović, N., Pavlović, Vera P., Marković, S., Maricić, A., Rasić, G., Vlahović, Branislav, Pavlović, Vladimir, Ristić, M.M., "The influence of mechanical activation on the morphological changes of Fe/BaTiO3 powder" in Materials Science and Engineering B-Advanced Functional Solid-State Materials, 212 (2016):89-95,
https://doi.org/10.1016/j.mseb.2016.07.016 . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Djordjević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Pavlović, Vladimir
AU  - Olcan, Dragan
AU  - Djordjević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4019
AB  - The mechanical activation can help reduce production costs and modify cordierite-based materials. In this study, the structure and electrical properties of the mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for time periods ranging from 0 to 160 min. Structural investigations were performed on the obtained powders. The effects of activation and a two-step sintering process on the microstructure and crystal structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The thermal stability was analyzed using DTA. Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the time of mechanical treatment.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics
EP  - 13918
IS  - 12
SP  - 13909
VL  - 42
DO  - 10.1016/j.ceramint.2016.05.201
ER  - 

@article{
author = "Obradović, Nina and Filipović, Suzana and Djordjević, Nataša and Kosanović, Darko and Marković, Smilja and Pavlović, Vladimir and Olcan, Dragan and Djordjević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
abstract = "The mechanical activation can help reduce production costs and modify cordierite-based materials. In this study, the structure and electrical properties of the mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for time periods ranging from 0 to 160 min. Structural investigations were performed on the obtained powders. The effects of activation and a two-step sintering process on the microstructure and crystal structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The thermal stability was analyzed using DTA. Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the time of mechanical treatment.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics",
pages = "13918-13909",
number = "12",
volume = "42",
doi = "10.1016/j.ceramint.2016.05.201"
}

Obradović, N., Filipović, S., Djordjević, N., Kosanović, D., Marković, S., Pavlović, V., Olcan, D., Djordjević, A., Kachlik, M.,& Maca, K.. (2016). Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 42(12), 13909-13918.
https://doi.org/10.1016/j.ceramint.2016.05.201

Obradović N, Filipović S, Djordjević N, Kosanović D, Marković S, Pavlović V, Olcan D, Djordjević A, Kachlik M, Maca K. Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics. in Ceramics International. 2016;42(12):13909-13918.
doi:10.1016/j.ceramint.2016.05.201 .

Obradović, Nina, Filipović, Suzana, Djordjević, Nataša, Kosanović, Darko, Marković, Smilja, Pavlović, Vladimir, Olcan, Dragan, Djordjević, Antonije, Kachlik, Martin, Maca, Karel, "Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics" in Ceramics International, 42, no. 12 (2016):13909-13918,
https://doi.org/10.1016/j.ceramint.2016.05.201 . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Djordjević, Nataša
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir
AU  - Olcan, Dragan
AU  - Djordjević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4026
AB  - Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of time of mechanical treatment.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique
EP  - 165
IS  - 2
SP  - 157
VL  - 48
DO  - 10.2298/SOS1602157O
ER  - 

@article{
author = "Obradović, Nina and Filipović, Suzana and Djordjević, Nataša and Kosanović, Darko and Pavlović, Vladimir and Olcan, Dragan and Djordjević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
abstract = "Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of time of mechanical treatment.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique",
pages = "165-157",
number = "2",
volume = "48",
doi = "10.2298/SOS1602157O"
}

Obradović, N., Filipović, S., Djordjević, N., Kosanović, D., Pavlović, V., Olcan, D., Djordjević, A., Kachlik, M.,& Maca, K.. (2016). Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 48(2), 157-165.
https://doi.org/10.2298/SOS1602157O

Obradović N, Filipović S, Djordjević N, Kosanović D, Pavlović V, Olcan D, Djordjević A, Kachlik M, Maca K. Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique. in Science of Sintering. 2016;48(2):157-165.
doi:10.2298/SOS1602157O .

Obradović, Nina, Filipović, Suzana, Djordjević, Nataša, Kosanović, Darko, Pavlović, Vladimir, Olcan, Dragan, Djordjević, Antonije, Kachlik, Martin, Maca, Karel, "Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique" in Science of Sintering, 48, no. 2 (2016):157-165,
https://doi.org/10.2298/SOS1602157O . .