TY  - JOUR
AU  - Vujančević, Jelena
AU  - Andričević, Pavao
AU  - Djokić, Veljko
AU  - Blagojević, Vladimir
AU  - Pavlović, Vera P.
AU  - Ćirković, Jovana
AU  - Horváth, Endre
AU  - Forró, László
AU  - Karoui, Abdennaceur
AU  - Pavlović, Vladimir B.
AU  - Janaćković, Djordje
PY  - 2023
UR  - https://www.mdpi.com/2073-4344/13/2/352
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6305
AB  - In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.
T2  - Catalysts
T2  - Catalysts
T1  - Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal
IS  - 2
SP  - 352
VL  - 13
DO  - 10.3390/catal13020352
ER  - 

@article{
author = "Vujančević, Jelena and Andričević, Pavao and Djokić, Veljko and Blagojević, Vladimir and Pavlović, Vera P. and Ćirković, Jovana and Horváth, Endre and Forró, László and Karoui, Abdennaceur and Pavlović, Vladimir B. and Janaćković, Djordje",
year = "2023",
abstract = "In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.",
journal = "Catalysts, Catalysts",
title = "Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal",
number = "2",
pages = "352",
volume = "13",
doi = "10.3390/catal13020352"
}

Vujančević, J., Andričević, P., Djokić, V., Blagojević, V., Pavlović, V. P., Ćirković, J., Horváth, E., Forró, L., Karoui, A., Pavlović, V. B.,& Janaćković, D.. (2023). Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal. in Catalysts, 13(2), 352.
https://doi.org/10.3390/catal13020352

Vujančević J, Andričević P, Djokić V, Blagojević V, Pavlović VP, Ćirković J, Horváth E, Forró L, Karoui A, Pavlović VB, Janaćković D. Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal. in Catalysts. 2023;13(2):352.
doi:10.3390/catal13020352 .

Vujančević, Jelena, Andričević, Pavao, Djokić, Veljko, Blagojević, Vladimir, Pavlović, Vera P., Ćirković, Jovana, Horváth, Endre, Forró, László, Karoui, Abdennaceur, Pavlović, Vladimir B., Janaćković, Djordje, "Effect of the Deposition of Vanadium-Oxide on the Photocatalytic Activity of TiO2 Nanotubes and Its Photodiode Performance Interfaced with CH3NH3PbI3 Single Crystal" in Catalysts, 13, no. 2 (2023):352,
https://doi.org/10.3390/catal13020352 . .

TY  - JOUR
AU  - Višnjevac, Aleksandar
AU  - Araškov, Jovana B.
AU  - Nikolić, Milan
AU  - Bojić-Trbojević, Žanka
AU  - Pirković, Andrea
AU  - Dekanski, Dragana
AU  - Mitić, Dragana
AU  - Blagojević, Vladimir
AU  - Filipović, Nenad R.
AU  - Todorović, Tamara R.
PY  - 2023
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6304
AB  - The Zn(II) complexes [Zn(HLSe2)2](NO3)2∙CH3OH (2-NO3-Se) and [Zn(HLSe3)2](NO3)2·DMF (3-NO3-Se) with selenazolyl-hydrazone ligands 4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HLSe2) and 4-(4-methylphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HLSe3) have been synthesized and characterized using singe crystal X-ray diffraction analysis. Antiproliferative activities of 2-NO3-Se and 3-NO3-Se, the corresponding ligands and sulphur isosteres of the complexes and the ligands were determined on non-malignant HTR-8/SVneo extravillous trophoblast cell line and malignant JEG-3 and JAr choriocarcinoma cell lines. All Zn complexes exhibited cytotoxic effect, comparable to that of a reference metal-based drug, cisplatin. The antioxidant activity of all compounds was determined in three antioxidant assays: ORAC (Oxygen Radical Absorbance Capacity), ABTS [(2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt] and CERAC [Ce(IV)-based reducing capacity]. As a result of synergy between Zn(II) and selenazolyl-hydrazone ligands, the complexes 2-NO3-Se and 3-NO3-Se appeared to be more active than Trolox, which is not the case for their sulfur counterparts. In-silico calculations of ADME properties pointed that the compounds possess some of desirable Lipinski rule principles. Applied algorithms did not report the compounds as potential PAINS or covalent inhibitors, although due to high molecular weight none of the compounds represent a potential lead compound. Toxicity prediction of the compounds is performed using machine learning models. The complexation of the ligands most likely reduces their toxicity or reduces their negative metabolic effects. © 2023 Elsevier B.V.
T2  - Journal of Molecular Structure
T2  - Journal of Molecular Structure
T1  - Zn(II) complexes with pyridyl-based 1,3-selen/thiazolyl-hydrazones: A comparative study
VL  - 1281
DO  - 10.1016/j.molstruc.2023.135193
ER  - 

@article{
author = "Višnjevac, Aleksandar and Araškov, Jovana B. and Nikolić, Milan and Bojić-Trbojević, Žanka and Pirković, Andrea and Dekanski, Dragana and Mitić, Dragana and Blagojević, Vladimir and Filipović, Nenad R. and Todorović, Tamara R.",
year = "2023",
abstract = "The Zn(II) complexes [Zn(HLSe2)2](NO3)2∙CH3OH (2-NO3-Se) and [Zn(HLSe3)2](NO3)2·DMF (3-NO3-Se) with selenazolyl-hydrazone ligands 4-(4-methoxyphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HLSe2) and 4-(4-methylphenyl)-2-(2-(pyridin-2-ylmethylene)hydrazinyl)-1,3-selenazole (HLSe3) have been synthesized and characterized using singe crystal X-ray diffraction analysis. Antiproliferative activities of 2-NO3-Se and 3-NO3-Se, the corresponding ligands and sulphur isosteres of the complexes and the ligands were determined on non-malignant HTR-8/SVneo extravillous trophoblast cell line and malignant JEG-3 and JAr choriocarcinoma cell lines. All Zn complexes exhibited cytotoxic effect, comparable to that of a reference metal-based drug, cisplatin. The antioxidant activity of all compounds was determined in three antioxidant assays: ORAC (Oxygen Radical Absorbance Capacity), ABTS [(2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt] and CERAC [Ce(IV)-based reducing capacity]. As a result of synergy between Zn(II) and selenazolyl-hydrazone ligands, the complexes 2-NO3-Se and 3-NO3-Se appeared to be more active than Trolox, which is not the case for their sulfur counterparts. In-silico calculations of ADME properties pointed that the compounds possess some of desirable Lipinski rule principles. Applied algorithms did not report the compounds as potential PAINS or covalent inhibitors, although due to high molecular weight none of the compounds represent a potential lead compound. Toxicity prediction of the compounds is performed using machine learning models. The complexation of the ligands most likely reduces their toxicity or reduces their negative metabolic effects. © 2023 Elsevier B.V.",
journal = "Journal of Molecular Structure, Journal of Molecular Structure",
title = "Zn(II) complexes with pyridyl-based 1,3-selen/thiazolyl-hydrazones: A comparative study",
volume = "1281",
doi = "10.1016/j.molstruc.2023.135193"
}

Višnjevac, A., Araškov, J. B., Nikolić, M., Bojić-Trbojević, Ž., Pirković, A., Dekanski, D., Mitić, D., Blagojević, V., Filipović, N. R.,& Todorović, T. R.. (2023). Zn(II) complexes with pyridyl-based 1,3-selen/thiazolyl-hydrazones: A comparative study. in Journal of Molecular Structure, 1281.
https://doi.org/10.1016/j.molstruc.2023.135193

Višnjevac A, Araškov JB, Nikolić M, Bojić-Trbojević Ž, Pirković A, Dekanski D, Mitić D, Blagojević V, Filipović NR, Todorović TR. Zn(II) complexes with pyridyl-based 1,3-selen/thiazolyl-hydrazones: A comparative study. in Journal of Molecular Structure. 2023;1281.
doi:10.1016/j.molstruc.2023.135193 .

Višnjevac, Aleksandar, Araškov, Jovana B., Nikolić, Milan, Bojić-Trbojević, Žanka, Pirković, Andrea, Dekanski, Dragana, Mitić, Dragana, Blagojević, Vladimir, Filipović, Nenad R., Todorović, Tamara R., "Zn(II) complexes with pyridyl-based 1,3-selen/thiazolyl-hydrazones: A comparative study" in Journal of Molecular Structure, 1281 (2023),
https://doi.org/10.1016/j.molstruc.2023.135193 . .

TY  - JOUR
AU  - Araškov, Jovana B.
AU  - Višnjevac, Aleksandar
AU  - Popović, Jasminka
AU  - Blagojević, Vladimir
AU  - Fernandes, Henrique S.
AU  - Sousa, Sérgio F.
AU  - Novaković, Irena
AU  - Padrón, José M.
AU  - Holló, Berta Barta
AU  - Monge, Miguel
AU  - Rodríguez-Castillo, María
AU  - López-de-Luzuriaga, José M.
AU  - Filipović, Nenad R.
AU  - Todorović, Tamara R.
PY  - 2022
UR  - https://pubs.rsc.org/en/content/articlelanding/2022/ce/d2ce00443g
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6118
AB  - Earth-abundant, cheap and non-toxic zinc-based coordination compounds are drawing research attention as promising candidates for various applications, such as photoluminescent materials and anticancer agents. In this paper we report six zinc complexes (1–3-NO3 and 1–3-Cl) with pyridyl-based thiazolyl–hydrazone ligands, which differ in the nature of substituents at the ligands' periphery, anion type, and geometry around the metal ion. The complexes were characterized by single-crystal and powder X-ray diffraction analysis, as well as IR and NMR spectroscopy. The symmetrical complexes 2-Cl and 3-Cl, where zinc atoms are located at a two-fold axis, do not exhibit photophysical properties, unlike their asymmetrical analogs 2-NO3 and 3-NO3 with the same complex cation. Asymmetrical pentacoordinated 1-Cl and hexacoordinated 1-NO3 complexes exhibit photophysical properties. An admixture of allowed intra-ligand (1IL) and chloro (X)-to-ligand charge-transfer (1XLCT) electronic transitions is responsible for the fluorescence of the 1-Cl complex. The origin of the emission of the 1-NO3 complex is ascribed to an admixture of 3IL and ligand-to-ligand charge-transfer (3LLCT) forbidden electronic transitions, while for 3-NO3 most electronic excitations are of LLCT character. The thermal stability of the complexes is in accord with the strength of respective intermolecular interactions. The antiproliferative activity of the complexes was in the nanomolar range on some of the investigated cancer cell lines. Contrary to the increase of antiproliferative activity of the complexes in comparison to the free ligands in cancer cell lines, an acute toxicity determined in the brine shrimp assay follows the opposite trend. The overall results suggest that Zn(II) thiazoyl–hydrazone complexes have considerable potential as multifunctional materials.
T2  - CrystEngComm
T2  - CrystEngCommCrystEngComm
T1  - Zn(II) complexes with thiazolyl–hydrazones: structure, intermolecular interactions, photophysical properties, computational study and anticancer activity
DO  - 10.1039/D2CE00443G
ER  - 

@article{
author = "Araškov, Jovana B. and Višnjevac, Aleksandar and Popović, Jasminka and Blagojević, Vladimir and Fernandes, Henrique S. and Sousa, Sérgio F. and Novaković, Irena and Padrón, José M. and Holló, Berta Barta and Monge, Miguel and Rodríguez-Castillo, María and López-de-Luzuriaga, José M. and Filipović, Nenad R. and Todorović, Tamara R.",
year = "2022",
abstract = "Earth-abundant, cheap and non-toxic zinc-based coordination compounds are drawing research attention as promising candidates for various applications, such as photoluminescent materials and anticancer agents. In this paper we report six zinc complexes (1–3-NO3 and 1–3-Cl) with pyridyl-based thiazolyl–hydrazone ligands, which differ in the nature of substituents at the ligands' periphery, anion type, and geometry around the metal ion. The complexes were characterized by single-crystal and powder X-ray diffraction analysis, as well as IR and NMR spectroscopy. The symmetrical complexes 2-Cl and 3-Cl, where zinc atoms are located at a two-fold axis, do not exhibit photophysical properties, unlike their asymmetrical analogs 2-NO3 and 3-NO3 with the same complex cation. Asymmetrical pentacoordinated 1-Cl and hexacoordinated 1-NO3 complexes exhibit photophysical properties. An admixture of allowed intra-ligand (1IL) and chloro (X)-to-ligand charge-transfer (1XLCT) electronic transitions is responsible for the fluorescence of the 1-Cl complex. The origin of the emission of the 1-NO3 complex is ascribed to an admixture of 3IL and ligand-to-ligand charge-transfer (3LLCT) forbidden electronic transitions, while for 3-NO3 most electronic excitations are of LLCT character. The thermal stability of the complexes is in accord with the strength of respective intermolecular interactions. The antiproliferative activity of the complexes was in the nanomolar range on some of the investigated cancer cell lines. Contrary to the increase of antiproliferative activity of the complexes in comparison to the free ligands in cancer cell lines, an acute toxicity determined in the brine shrimp assay follows the opposite trend. The overall results suggest that Zn(II) thiazoyl–hydrazone complexes have considerable potential as multifunctional materials.",
journal = "CrystEngComm, CrystEngCommCrystEngComm",
title = "Zn(II) complexes with thiazolyl–hydrazones: structure, intermolecular interactions, photophysical properties, computational study and anticancer activity",
doi = "10.1039/D2CE00443G"
}

Araškov, J. B., Višnjevac, A., Popović, J., Blagojević, V., Fernandes, H. S., Sousa, S. F., Novaković, I., Padrón, J. M., Holló, B. B., Monge, M., Rodríguez-Castillo, M., López-de-Luzuriaga, J. M., Filipović, N. R.,& Todorović, T. R.. (2022). Zn(II) complexes with thiazolyl–hydrazones: structure, intermolecular interactions, photophysical properties, computational study and anticancer activity. in CrystEngComm.
https://doi.org/10.1039/D2CE00443G

Araškov JB, Višnjevac A, Popović J, Blagojević V, Fernandes HS, Sousa SF, Novaković I, Padrón JM, Holló BB, Monge M, Rodríguez-Castillo M, López-de-Luzuriaga JM, Filipović NR, Todorović TR. Zn(II) complexes with thiazolyl–hydrazones: structure, intermolecular interactions, photophysical properties, computational study and anticancer activity. in CrystEngComm. 2022;.
doi:10.1039/D2CE00443G .

Araškov, Jovana B., Višnjevac, Aleksandar, Popović, Jasminka, Blagojević, Vladimir, Fernandes, Henrique S., Sousa, Sérgio F., Novaković, Irena, Padrón, José M., Holló, Berta Barta, Monge, Miguel, Rodríguez-Castillo, María, López-de-Luzuriaga, José M., Filipović, Nenad R., Todorović, Tamara R., "Zn(II) complexes with thiazolyl–hydrazones: structure, intermolecular interactions, photophysical properties, computational study and anticancer activity" in CrystEngComm (2022),
https://doi.org/10.1039/D2CE00443G . .

TY  - JOUR
AU  - Ristić, Predrag
AU  - Filipović, Nenad
AU  - Blagojević, Vladimir
AU  - Ćirković, Jovana
AU  - Barta Holló, Berta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara R.
PY  - 2021
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5898
AB  - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.
PB  - Royal Society of Chemistry
T2  - CrystEngComm
T1  - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
EP  - 4815
IS  - 27
SP  - 4799
VL  - 23
DO  - 10.1039/d1ce00394a
ER  - 

@article{
author = "Ristić, Predrag and Filipović, Nenad and Blagojević, Vladimir and Ćirković, Jovana and Barta Holló, Berta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara R.",
year = "2021",
abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.",
publisher = "Royal Society of Chemistry",
journal = "CrystEngComm",
title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior",
pages = "4815-4799",
number = "27",
volume = "23",
doi = "10.1039/d1ce00394a"
}

Ristić, P., Filipović, N., Blagojević, V., Ćirković, J., Barta Holló, B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T. R.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm
Royal Society of Chemistry., 23(27), 4799-4815.
https://doi.org/10.1039/d1ce00394a

Ristić P, Filipović N, Blagojević V, Ćirković J, Barta Holló B, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović TR. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm. 2021;23(27):4799-4815.
doi:10.1039/d1ce00394a .

Ristić, Predrag, Filipović, Nenad, Blagojević, Vladimir, Ćirković, Jovana, Barta Holló, Berta, Đokić, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisurić, Olivera R., Todorović, Tamara R., "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in CrystEngComm, 23, no. 27 (2021):4799-4815,
https://doi.org/10.1039/d1ce00394a . .

TY  - JOUR
AU  - Ristić, Predrag
AU  - Todorović, Tamara R.
AU  - Blagojević, Vladimir A.
AU  - Klisurić, Olivera
AU  - Marjanović, Ivana
AU  - Hollo, Berta Barta
AU  - Vulić, Predrag J.
AU  - Gulea, Mihaela
AU  - Donnard, Morgan
AU  - Monge, Miguel
AU  - Rodriguez-Castillo, Maria
AU  - Lopez-de-Luzuriaga, Jose M.
AU  - Filipović, Nenad
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5281
AB  - Four silver-based coordination polymers, {[Ag(L)(2)](BF4)}(infinity) (1), {[Ag(H2BTC)(L)]center dot(H3BTC)}(infinity) (2), {[Ag-2(H2BTEC)(L)(2)]..3.33H(2)O}(infinity) (3), and [Ag(H(25)SSA)(L)](infinity) (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H(35)SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036-0.056 min(-1) range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet-singlet electronic excitations to the fluorescence, indicating that metal- intraligand transitions are responsible for luminescence in both complexes.
PB  - Amer Chemical Soc, Washington
T2  - Crystal Growth & Design
T1  - 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study
EP  - 4478
IS  - 7
SP  - 4461
VL  - 20
DO  - 10.1021/acs.cgd.0c00287
ER  - 

@article{
author = "Ristić, Predrag and Todorović, Tamara R. and Blagojević, Vladimir A. and Klisurić, Olivera and Marjanović, Ivana and Hollo, Berta Barta and Vulić, Predrag J. and Gulea, Mihaela and Donnard, Morgan and Monge, Miguel and Rodriguez-Castillo, Maria and Lopez-de-Luzuriaga, Jose M. and Filipović, Nenad",
year = "2020",
abstract = "Four silver-based coordination polymers, {[Ag(L)(2)](BF4)}(infinity) (1), {[Ag(H2BTC)(L)]center dot(H3BTC)}(infinity) (2), {[Ag-2(H2BTEC)(L)(2)]..3.33H(2)O}(infinity) (3), and [Ag(H(25)SSA)(L)](infinity) (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H(35)SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036-0.056 min(-1) range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet-singlet electronic excitations to the fluorescence, indicating that metal- intraligand transitions are responsible for luminescence in both complexes.",
publisher = "Amer Chemical Soc, Washington",
journal = "Crystal Growth & Design",
title = "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study",
pages = "4478-4461",
number = "7",
volume = "20",
doi = "10.1021/acs.cgd.0c00287"
}

Ristić, P., Todorović, T. R., Blagojević, V. A., Klisurić, O., Marjanović, I., Hollo, B. B., Vulić, P. J., Gulea, M., Donnard, M., Monge, M., Rodriguez-Castillo, M., Lopez-de-Luzuriaga, J. M.,& Filipović, N.. (2020). 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design
Amer Chemical Soc, Washington., 20(7), 4461-4478.
https://doi.org/10.1021/acs.cgd.0c00287

Ristić P, Todorović TR, Blagojević VA, Klisurić O, Marjanović I, Hollo BB, Vulić PJ, Gulea M, Donnard M, Monge M, Rodriguez-Castillo M, Lopez-de-Luzuriaga JM, Filipović N. 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design. 2020;20(7):4461-4478.
doi:10.1021/acs.cgd.0c00287 .

Ristić, Predrag, Todorović, Tamara R., Blagojević, Vladimir A., Klisurić, Olivera, Marjanović, Ivana, Hollo, Berta Barta, Vulić, Predrag J., Gulea, Mihaela, Donnard, Morgan, Monge, Miguel, Rodriguez-Castillo, Maria, Lopez-de-Luzuriaga, Jose M., Filipović, Nenad, "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study" in Crystal Growth & Design, 20, no. 7 (2020):4461-4478,
https://doi.org/10.1021/acs.cgd.0c00287 . .

TY  - JOUR
AU  - Ristić, Predrag
AU  - Blagojević, Vladimir A.
AU  - Janjić, Goran
AU  - Rodić, Marko
AU  - Vulić, Predrag J.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Chylewska, Agnieszka
AU  - Makowski, Mariusz
AU  - Todorović, Tamara
AU  - Filipović, Nenad
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5373
AB  - Pt(II) and Pd(II) complexes (1 and 2, respectively) with thiomorpholine-4-carbonitrile (TM-CN), an N-substituted thiomorpholine derivative, were synthesized from tetrachlorido precursors in water. Structural analysis has shown that 1 represents the first monomeric metal complex with this ligand type with an axial M-S bond with respect to the TM-CN ring chair conformation, while in 2 a typical equatorial M-S bond position with respect to the ring chair conformation was observed. A detailed DFT investigation revealed that axial conformers are more stable for molecular forms of both metals, while intermolecular interactions in the crystals stabilize the axial conformer for Pt(II) and the equatorial conformer for Pd(II). The magnitude of this stabilization in the case of 2 is large enough to change the most stable axial conformer in the molecular form to the equatorial conformer in the crystal. Further investigation of the strength of individual intermolecular interactions revealed significant differences of some interactions between the two structures. The likely cause of the difference in the crystal structures of experimentally obtained complexes is the fact that 1 and 2 exhibit different dominant interactions: C-H/M and C-H/S are more dominant in 1 and C-H/Cl interactions are more dominant in 2. In addition, DFT calculations have shown that while the axial position of the Pt-S bond with respect to the ring chair conformation results in a significantly shorter C-H/Pt interaction distance than that in the hypothetical equatorial conformer, there is very little difference in C-H/Pd interaction distances in conformers with axial and equatorial positions of Pd-S bond with respect to the ring chair conformation.
PB  - Amer Chemical Soc, Washington
T2  - Crystal Growth & Design
T1  - Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study
EP  - 3033
IS  - 5
SP  - 3018
VL  - 20
DO  - 10.1021/acs.cgd.9b01661
ER  - 

@article{
author = "Ristić, Predrag and Blagojević, Vladimir A. and Janjić, Goran and Rodić, Marko and Vulić, Predrag J. and Donnard, Morgan and Gulea, Mihaela and Chylewska, Agnieszka and Makowski, Mariusz and Todorović, Tamara and Filipović, Nenad",
year = "2020",
abstract = "Pt(II) and Pd(II) complexes (1 and 2, respectively) with thiomorpholine-4-carbonitrile (TM-CN), an N-substituted thiomorpholine derivative, were synthesized from tetrachlorido precursors in water. Structural analysis has shown that 1 represents the first monomeric metal complex with this ligand type with an axial M-S bond with respect to the TM-CN ring chair conformation, while in 2 a typical equatorial M-S bond position with respect to the ring chair conformation was observed. A detailed DFT investigation revealed that axial conformers are more stable for molecular forms of both metals, while intermolecular interactions in the crystals stabilize the axial conformer for Pt(II) and the equatorial conformer for Pd(II). The magnitude of this stabilization in the case of 2 is large enough to change the most stable axial conformer in the molecular form to the equatorial conformer in the crystal. Further investigation of the strength of individual intermolecular interactions revealed significant differences of some interactions between the two structures. The likely cause of the difference in the crystal structures of experimentally obtained complexes is the fact that 1 and 2 exhibit different dominant interactions: C-H/M and C-H/S are more dominant in 1 and C-H/Cl interactions are more dominant in 2. In addition, DFT calculations have shown that while the axial position of the Pt-S bond with respect to the ring chair conformation results in a significantly shorter C-H/Pt interaction distance than that in the hypothetical equatorial conformer, there is very little difference in C-H/Pd interaction distances in conformers with axial and equatorial positions of Pd-S bond with respect to the ring chair conformation.",
publisher = "Amer Chemical Soc, Washington",
journal = "Crystal Growth & Design",
title = "Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study",
pages = "3033-3018",
number = "5",
volume = "20",
doi = "10.1021/acs.cgd.9b01661"
}

Ristić, P., Blagojević, V. A., Janjić, G., Rodić, M., Vulić, P. J., Donnard, M., Gulea, M., Chylewska, A., Makowski, M., Todorović, T.,& Filipović, N.. (2020). Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study. in Crystal Growth & Design
Amer Chemical Soc, Washington., 20(5), 3018-3033.
https://doi.org/10.1021/acs.cgd.9b01661

Ristić P, Blagojević VA, Janjić G, Rodić M, Vulić PJ, Donnard M, Gulea M, Chylewska A, Makowski M, Todorović T, Filipović N. Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study. in Crystal Growth & Design. 2020;20(5):3018-3033.
doi:10.1021/acs.cgd.9b01661 .

Ristić, Predrag, Blagojević, Vladimir A., Janjić, Goran, Rodić, Marko, Vulić, Predrag J., Donnard, Morgan, Gulea, Mihaela, Chylewska, Agnieszka, Makowski, Mariusz, Todorović, Tamara, Filipović, Nenad, "Influence of C-H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study" in Crystal Growth & Design, 20, no. 5 (2020):3018-3033,
https://doi.org/10.1021/acs.cgd.9b01661 . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Savić, Slobodan
AU  - Djordjević, Antonije
AU  - Pavlović, Vladimir
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5344
AB  - Solid-state mechanical activation of MgO and alpha-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 degrees C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)(2) shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 degrees C for non-activated samples, and 1400 degrees C for activated samples.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics
EP  - 107
IS  - 1
SP  - 95
VL  - 140
DO  - 10.1007/s10973-019-08846-w
ER  - 

@article{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Savić, Slobodan and Djordjević, Antonije and Pavlović, Vladimir",
year = "2020",
abstract = "Solid-state mechanical activation of MgO and alpha-Al2O3 powders was used to produce MgAl2O4. The cation site occupancy in the resulting MgAl2O4 spinel was investigated using different methods. Differential thermal analysis and thermal gravimetry showed that mechanical activation reduced the spinel formation temperature by around 200 degrees C, and the corresponding activation energy by about 25%. In addition, characteristic temperatures for evaporation of physisorbed water and decomposition of Mg(OH)(2) shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of the sintering temperature for all of the sintered specimens, indicating that the breaking point for ordering of the crystal structure was around 1500 degrees C for non-activated samples, and 1400 degrees C for activated samples.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics",
pages = "107-95",
number = "1",
volume = "140",
doi = "10.1007/s10973-019-08846-w"
}

Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Savić, S., Djordjević, A.,& Pavlović, V.. (2020). Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 140(1), 95-107.
https://doi.org/10.1007/s10973-019-08846-w

Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Savić S, Djordjević A, Pavlović V. Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics. in Journal of Thermal Analysis and Calorimetry. 2020;140(1):95-107.
doi:10.1007/s10973-019-08846-w .

Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Marković, Smilja, Blagojević, Vladimir A., Lević, Steva, Savić, Slobodan, Djordjević, Antonije, Pavlović, Vladimir, "Formation kinetics and cation inversion in mechanically activated MgAl2O4 spinel ceramics" in Journal of Thermal Analysis and Calorimetry, 140, no. 1 (2020):95-107,
https://doi.org/10.1007/s10973-019-08846-w . .

TY  - JOUR
AU  - Živojinović, J.
AU  - Pavlović, Vera P.
AU  - Labus, Nebojša
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5167
AB  - The initial-stage of sintering plays a significant role in determining the final microstructure that defines the main characteristics of electroceramics materials such as functional properties. In this article non-isothermal sintering of non-activated and mechanically activated SrTiO3 samples was investigated up to 1300 °C. Dilatometric curves indicate that mechanical activation leads to an earlier onset of sintering, suggesting that it should lead to a more homogenous and denser sintered product. Analysis of the initial stage of sintering reveals that the sintering process of all examinated samples consists of two or three overlapping single-step processes, with a change in the dominant mass transport mechanism. The values of apparent activation energy of the considered single-step process exhibit a significant decrease with an increase in mechanical activation time. The values of the density of samples after isothermal sintering indicate that the final stage of sintering has not been reached by 1300 °C.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Analysis of the initial-stage sintering of mechanically activated SrTiO3
EP  - 10
IS  - 2
SP  - 1
VL  - 51
DO  - 10.2298/sos1902199z
ER  - 

@article{
author = "Živojinović, J. and Pavlović, Vera P. and Labus, Nebojša and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir",
year = "2019",
abstract = "The initial-stage of sintering plays a significant role in determining the final microstructure that defines the main characteristics of electroceramics materials such as functional properties. In this article non-isothermal sintering of non-activated and mechanically activated SrTiO3 samples was investigated up to 1300 °C. Dilatometric curves indicate that mechanical activation leads to an earlier onset of sintering, suggesting that it should lead to a more homogenous and denser sintered product. Analysis of the initial stage of sintering reveals that the sintering process of all examinated samples consists of two or three overlapping single-step processes, with a change in the dominant mass transport mechanism. The values of apparent activation energy of the considered single-step process exhibit a significant decrease with an increase in mechanical activation time. The values of the density of samples after isothermal sintering indicate that the final stage of sintering has not been reached by 1300 °C.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Analysis of the initial-stage sintering of mechanically activated SrTiO3",
pages = "10-1",
number = "2",
volume = "51",
doi = "10.2298/sos1902199z"
}

Živojinović, J., Pavlović, V. P., Labus, N., Blagojević, V. A., Kosanović, D.,& Pavlović, V.. (2019). Analysis of the initial-stage sintering of mechanically activated SrTiO3. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(2), 1-10.
https://doi.org/10.2298/sos1902199z

Živojinović J, Pavlović VP, Labus N, Blagojević VA, Kosanović D, Pavlović V. Analysis of the initial-stage sintering of mechanically activated SrTiO3. in Science of Sintering. 2019;51(2):1-10.
doi:10.2298/sos1902199z .

Živojinović, J., Pavlović, Vera P., Labus, Nebojša, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir, "Analysis of the initial-stage sintering of mechanically activated SrTiO3" in Science of Sintering, 51, no. 2 (2019):1-10,
https://doi.org/10.2298/sos1902199z . .

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir A.
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5756
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
EP  - 2998
SP  - 2989
VL  - 138
DO  - 10.1007/s10973-018-7924-1
ER  - 

@article{
author = "Obradović, Nina and Blagojević, Vladimir A. and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2998-2989",
volume = "138",
doi = "10.1007/s10973-018-7924-1"
}

Obradović, N., Blagojević, V. A., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 138, 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1

Obradović N, Blagojević VA, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović V. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138:2989-2998.
doi:10.1007/s10973-018-7924-1 .

Obradović, Nina, Blagojević, Vladimir A., Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir, "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 . .

TY  - CONF
AU  - Obradović, Nina
AU  - Fahrenholtz, William G.
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Blagojević, Vladimir A.
AU  - Lević, Steva
AU  - Đorđević, Antonije
AU  - Pavlović, Vladimir
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/7020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5752
AB  - Magnesium aluminate and other alumina-based spinels are refractory ceramics with excellent properties, such as high hardness, high mechanical strength, and low dielectric constant, applicable in many modern industries. MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3 powders. Mechanical activation represents a very efficient method for increasing the reactivity of powders, accelerating chemical reactions and decreasing the sintering temperatures. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 60 minutes. Sintering was performed in air at temperatures ranging from 1200°C to 1600 °C with a 2 h dwell time. Initial powders and sintered samples were characterized using X-ray diffraction and scanning electron microscopy. Differential thermal analysis (DTA) and thermal gravimetry (TG) were used to determine the temperatures for synthesis reactions and phase transformations. Based on the DTA results, several different processes occured during heating, including evaporation of physisorbed water, decomposition of Mg(OH)2, and spinel formation. With mechanical activation, all characteristic temperatures shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of sintering temperature for all of the sintered specimens.
PB  - Central and Eastern European Committee for Thermal Analysis and Calorimetry
C3  - Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019)
T1  - Influence of mechanical activation on kinetics and formation of spinel monitored by DTA
EP  - 70
SP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_dais_7020
ER  - 

@conference{
author = "Obradović, Nina and Fahrenholtz, William G. and Filipović, Suzana and Marković, Smilja and Blagojević, Vladimir A. and Lević, Steva and Đorđević, Antonije and Pavlović, Vladimir",
year = "2019",
abstract = "Magnesium aluminate and other alumina-based spinels are refractory ceramics with excellent properties, such as high hardness, high mechanical strength, and low dielectric constant, applicable in many modern industries. MgAl2O4 was produced by solid state reaction between MgO and alpha-Al2O3 powders. Mechanical activation represents a very efficient method for increasing the reactivity of powders, accelerating chemical reactions and decreasing the sintering temperatures. Mechanical activation of mixed powders was performed in a high-energy planetary ball mill in air for 60 minutes. Sintering was performed in air at temperatures ranging from 1200°C to 1600 °C with a 2 h dwell time. Initial powders and sintered samples were characterized using X-ray diffraction and scanning electron microscopy. Differential thermal analysis (DTA) and thermal gravimetry (TG) were used to determine the temperatures for synthesis reactions and phase transformations. Based on the DTA results, several different processes occured during heating, including evaporation of physisorbed water, decomposition of Mg(OH)2, and spinel formation. With mechanical activation, all characteristic temperatures shifted to lower values, and peaks were more pronounced. Raman spectra were used to characterize the degree of inversion as a function of sintering temperature for all of the sintered specimens.",
publisher = "Central and Eastern European Committee for Thermal Analysis and Calorimetry",
journal = "Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019)",
title = "Influence of mechanical activation on kinetics and formation of spinel monitored by DTA",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_dais_7020"
}

Obradović, N., Fahrenholtz, W. G., Filipović, S., Marković, S., Blagojević, V. A., Lević, S., Đorđević, A.,& Pavlović, V.. (2019). Influence of mechanical activation on kinetics and formation of spinel monitored by DTA. in Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019)
Central and Eastern European Committee for Thermal Analysis and Calorimetry., 70-70.
https://hdl.handle.net/21.15107/rcub_dais_7020

Obradović N, Fahrenholtz WG, Filipović S, Marković S, Blagojević VA, Lević S, Đorđević A, Pavlović V. Influence of mechanical activation on kinetics and formation of spinel monitored by DTA. in Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019). 2019;:70-70.
https://hdl.handle.net/21.15107/rcub_dais_7020 .

Obradović, Nina, Fahrenholtz, William G., Filipović, Suzana, Marković, Smilja, Blagojević, Vladimir A., Lević, Steva, Đorđević, Antonije, Pavlović, Vladimir, "Influence of mechanical activation on kinetics and formation of spinel monitored by DTA" in Book of abstracts of the 5th Central and Eastern European Conference on Thermal Analysis and Calorimetry (CEEC-TAC5) and 14th Mediterranean Conference on Calorimetry and Thermal Analysis (Medicta2019) (2019):70-70,
https://hdl.handle.net/21.15107/rcub_dais_7020 .

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir A.
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4558
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5733
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
EP  - 2998
SP  - 2989
VL  - 138
DO  - 10.1007/s10973-018-7924-1
ER  - 

@article{
author = "Obradović, Nina and Blagojević, Vladimir A. and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir B.",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100–1400 °C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 °C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2998-2989",
volume = "138",
doi = "10.1007/s10973-018-7924-1"
}

Obradović, N., Blagojević, V. A., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V. B.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer., 138, 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1

Obradović N, Blagojević VA, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović VB. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138:2989-2998.
doi:10.1007/s10973-018-7924-1 .

Obradović, Nina, Blagojević, Vladimir A., Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir B., "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 . .

TY  - JOUR
AU  - Peles, A.
AU  - Aleksić, O.
AU  - Pavlović, Vera P.
AU  - Djoković, Vladimir
AU  - Dojčilović, Radovan
AU  - Nikolić, Z.
AU  - Marinković, F.
AU  - Mitrić, M.
AU  - Blagojević, Vladimir A.
AU  - Vlahović, Branislav
AU  - Pavlović, Vladimir
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4658
AB  - The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles.
PB  - IOP Publishing Ltd, Bristol
T2  - Physica Scripta
T1  - Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films
IS  - 10
VL  - 93
DO  - 10.1088/1402-4896/aad749
ER  - 

@article{
author = "Peles, A. and Aleksić, O. and Pavlović, Vera P. and Djoković, Vladimir and Dojčilović, Radovan and Nikolić, Z. and Marinković, F. and Mitrić, M. and Blagojević, Vladimir A. and Vlahović, Branislav and Pavlović, Vladimir",
year = "2018",
abstract = "The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the gamma-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of alpha-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of beta-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric beta-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of beta-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles.",
publisher = "IOP Publishing Ltd, Bristol",
journal = "Physica Scripta",
title = "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films",
number = "10",
volume = "93",
doi = "10.1088/1402-4896/aad749"
}

Peles, A., Aleksić, O., Pavlović, V. P., Djoković, V., Dojčilović, R., Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, V. A., Vlahović, B.,& Pavlović, V.. (2018). Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta
IOP Publishing Ltd, Bristol., 93(10).
https://doi.org/10.1088/1402-4896/aad749

Peles A, Aleksić O, Pavlović VP, Djoković V, Dojčilović R, Nikolić Z, Marinković F, Mitrić M, Blagojević VA, Vlahović B, Pavlović V. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta. 2018;93(10).
doi:10.1088/1402-4896/aad749 .

Peles, A., Aleksić, O., Pavlović, Vera P., Djoković, Vladimir, Dojčilović, Radovan, Nikolić, Z., Marinković, F., Mitrić, M., Blagojević, Vladimir A., Vlahović, Branislav, Pavlović, Vladimir, "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films" in Physica Scripta, 93, no. 10 (2018),
https://doi.org/10.1088/1402-4896/aad749 . .

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maricić, A.
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir
AU  - Vlahović, Branislav
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4755
AB  - Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100-240 min) and sintered at 1100 and 1200 degrees C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84-89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 degrees C are superior to those sintered at 1100 degrees C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350-420 degrees C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 degrees C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Influence of mechanical activation on functional properties of barium hexaferrite ceramics
EP  - 6672
IS  - 6
SP  - 6666
VL  - 44
DO  - 10.1016/j.ceramint.2018.01.078
ER  - 

@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maricić, A. and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir and Vlahović, Branislav",
year = "2018",
abstract = "Barium hexaferrite ceramics were prepared using mechanically activated mixtures of iron and barium titanate. The 60:40 mass% Fe:BaTiO3 powder mixtures were mechanically activated for different times (100-240 min) and sintered at 1100 and 1200 degrees C in order to determine the influence of mechanical activation of the precursor on the magnetic and dielectric properties of the resulting barium hexaferrite ceramics. The final product contained 84-89 mass% of Ba2Fe22.46O38Ti1.54 phase, with higher content corresponding to longer mechanical activation of the precursor. XRD and Raman measurements indicated that the remainder of the sample consists of leftover BaTiO3 and hematite, which was formed by the oxidation of iron during mechanical activation and sintering in air. Magnetic properties of samples sintered at 1200 degrees C are superior to those sintered at 1100 degrees C, which can be attributed to higher Ba2Fe22.46O38Ti1.54 phase content. The position of the Curie temperature in 350-420 degrees C temperature region is consistent with 0.8:1 ratio of Ti to Ba. Maximum magnetization was observed for samples activated for 120 min. Dielectric properties of samples sintered at 1200 degrees C showed a dependence on frequency, with a significant drop in relative permittivity with an increase in frequency in the low-frequency region, and relatively constant values of relative permittivity in the high-frequency region. The tangent loss showed a decrease with increase in frequency, where peaks corresponding to the resonance of the electron hopping frequency with the external field were observed in the samples corresponding to the longer mechanical activation. Dielectric properties showed relatively small changes for samples activated longer than 150 min.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Influence of mechanical activation on functional properties of barium hexaferrite ceramics",
pages = "6672-6666",
number = "6",
volume = "44",
doi = "10.1016/j.ceramint.2018.01.078"
}

Kosanović, D., Blagojević, V. A., Maricić, A., Aleksić, S., Pavlović, V. P., Pavlović, V.,& Vlahović, B.. (2018). Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 44(6), 6666-6672.
https://doi.org/10.1016/j.ceramint.2018.01.078

Kosanović D, Blagojević VA, Maricić A, Aleksić S, Pavlović VP, Pavlović V, Vlahović B. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. in Ceramics International. 2018;44(6):6666-6672.
doi:10.1016/j.ceramint.2018.01.078 .

Kosanović, Darko, Blagojević, Vladimir A., Maricić, A., Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir, Vlahović, Branislav, "Influence of mechanical activation on functional properties of barium hexaferrite ceramics" in Ceramics International, 44, no. 6 (2018):6666-6672,
https://doi.org/10.1016/j.ceramint.2018.01.078 . .

TY  - DATA
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Maričić, Aleksa
AU  - Aleksić, S.
AU  - Pavlović, Vera P.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
PY  - 2018
UR  - https://ars.els-cdn.com/content/image/1-s2.0-S0272884218300919-mmc1.pdf
UR  - http://dais.sanu.ac.rs/123456789/3788
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5729
AB  - Rietveld analysis of XRD patterns of mechanically activated Fe:BaTiO3 powder mixtures sintered at 1200°C
T2  - Ceramics International
T1  - Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement
IS  - 6
VL  - 44
UR  - https://hdl.handle.net/21.15107/rcub_dais_4606
ER  - 

@misc{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Maričić, Aleksa and Aleksić, S. and Pavlović, Vera P. and Pavlović, Vladimir B. and Vlahović, Branislav",
year = "2018",
abstract = "Rietveld analysis of XRD patterns of mechanically activated Fe:BaTiO3 powder mixtures sintered at 1200°C",
journal = "Ceramics International",
title = "Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement",
number = "6",
volume = "44",
url = "https://hdl.handle.net/21.15107/rcub_dais_4606"
}

Kosanović, D., Blagojević, V. A., Maričić, A., Aleksić, S., Pavlović, V. P., Pavlović, V. B.,& Vlahović, B.. (2018). Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement. in Ceramics International, 44(6).
https://hdl.handle.net/21.15107/rcub_dais_4606

Kosanović D, Blagojević VA, Maričić A, Aleksić S, Pavlović VP, Pavlović VB, Vlahović B. Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement. in Ceramics International. 2018;44(6).
https://hdl.handle.net/21.15107/rcub_dais_4606 .

Kosanović, Darko, Blagojević, Vladimir A., Maričić, Aleksa, Aleksić, S., Pavlović, Vera P., Pavlović, Vladimir B., Vlahović, Branislav, "Kosanović, D., Blagojević, V.A., Maričić, A., Aleksić, S., Pavlović, V.P., Pavlović, V.B., Vlahović, B., 2018. Influence of mechanical activation on functional properties of barium hexaferrite ceramics. Ceramics International 44, 6666–6672. https://doi.org/10.1016/j.ceramint.2018.01.078: Supplement" in Ceramics International, 44, no. 6 (2018),
https://hdl.handle.net/21.15107/rcub_dais_4606 .

TY  - JOUR
AU  - Kosanović, Darko
AU  - Blagojević, Vladimir A.
AU  - Labus, Nebojša
AU  - Tadić, N.B.
AU  - Pavlović, Vladimir
AU  - Ristić, M.M.
PY  - 2018
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4724
AB  - Barium strontium titanate powders with different Ba: Sr ratios were investigated to determine the influence of the initial composition of powder mixture on microstructural properties and sintering kinetics. It was determined that BaCO3 and SrCO3 react differently to mixing, resulting in Ba0.5Sr0.5CO3 in the sample with 80% Ba and different contents of Ba1-xSrxTiO3 in samples with 50% and 20% Ba. In addition, the morphology is also different, with higher Sr content leading to larger particles size and less agglomeration. The different chemical content of the initial powder mixture also has a marked impact on the sintering process: the onset of sintering shifts towards higher temperature with higher Sr content, while the average apparent activation energy of sintering is the highest for the sample with 80% Ba and the lowest for the mixture with 50% Ba. In addition, hexagonal-to-cubic phase transformation was observed in parallel with the sintering process, where the position of the phase transition shifts to lower temperatures with an increase in Sr content. This is consistent with the behavior of low-temperature phase transitions of BST. The phase transition was not observed in sintered samples, suggesting that there is a size-dependence of the phase transition temperature.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders
EP  - 38
IS  - 1
SP  - 29
VL  - 50
DO  - 10.2298/SOS1801029K
ER  - 

@article{
author = "Kosanović, Darko and Blagojević, Vladimir A. and Labus, Nebojša and Tadić, N.B. and Pavlović, Vladimir and Ristić, M.M.",
year = "2018",
abstract = "Barium strontium titanate powders with different Ba: Sr ratios were investigated to determine the influence of the initial composition of powder mixture on microstructural properties and sintering kinetics. It was determined that BaCO3 and SrCO3 react differently to mixing, resulting in Ba0.5Sr0.5CO3 in the sample with 80% Ba and different contents of Ba1-xSrxTiO3 in samples with 50% and 20% Ba. In addition, the morphology is also different, with higher Sr content leading to larger particles size and less agglomeration. The different chemical content of the initial powder mixture also has a marked impact on the sintering process: the onset of sintering shifts towards higher temperature with higher Sr content, while the average apparent activation energy of sintering is the highest for the sample with 80% Ba and the lowest for the mixture with 50% Ba. In addition, hexagonal-to-cubic phase transformation was observed in parallel with the sintering process, where the position of the phase transition shifts to lower temperatures with an increase in Sr content. This is consistent with the behavior of low-temperature phase transitions of BST. The phase transition was not observed in sintered samples, suggesting that there is a size-dependence of the phase transition temperature.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders",
pages = "38-29",
number = "1",
volume = "50",
doi = "10.2298/SOS1801029K"
}

Kosanović, D., Blagojević, V. A., Labus, N., Tadić, N.B., Pavlović, V.,& Ristić, M.M.. (2018). Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(1), 29-38.
https://doi.org/10.2298/SOS1801029K

Kosanović D, Blagojević VA, Labus N, Tadić N, Pavlović V, Ristić M. Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders. in Science of Sintering. 2018;50(1):29-38.
doi:10.2298/SOS1801029K .

Kosanović, Darko, Blagojević, Vladimir A., Labus, Nebojša, Tadić, N.B., Pavlović, Vladimir, Ristić, M.M., "Effect of Chemical Composition on Microstructural Properties and Sintering Kinetics of (Ba,Sr) TiO3 Powders" in Science of Sintering, 50, no. 1 (2018):29-38,
https://doi.org/10.2298/SOS1801029K . .

TY  - JOUR
AU  - Zivojinović, Jelena
AU  - Pavlović, Vera P.
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Krstić, Jugoslav
AU  - Blagojević, Vladimir A.
AU  - Pavlović, Vladimir
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4358
AB  - Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 mu m in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders
EP  - 870
SP  - 863
VL  - 695
DO  - 10.1016/j.jallcom.2016.10.159
ER  - 

@article{
author = "Zivojinović, Jelena and Pavlović, Vera P. and Kosanović, Darko and Marković, Smilja and Krstić, Jugoslav and Blagojević, Vladimir A. and Pavlović, Vladimir",
year = "2017",
abstract = "Structural changes caused by mechanical activation of SrTiO3 powders were investigated using a variety of methods. Average crystallite size continuously decreased with increased activation time to around 20 nm after 120 min activation, while mesopore volume and specific surface area increased accordingly. Higher activation times lead to increased agglomeration of nanoparticles to form agglomerates of around 2 mu m in size, ultimately producing a relatively stable powder, which exhibits lower microstrain than powders activated for shorter periods of time. Raman spectroscopy shows that the behavior of TO2 and TO4 modes is consistent with a decrease in particle size, while behavior of the nonpolar TO3 mode is markedly different, indicating relaxation of the inversion symmetry in polycrystalline SrTiO3. UV-VIS spectra show that mechanical activation has negligible effect on SrTiO3, with a slight shift caused by TiO2 contamination due to presence of air. Other than this, the mechanical activation process preserves the chemical purity of the initial powder.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders",
pages = "870-863",
volume = "695",
doi = "10.1016/j.jallcom.2016.10.159"
}

Zivojinović, J., Pavlović, V. P., Kosanović, D., Marković, S., Krstić, J., Blagojević, V. A.,& Pavlović, V.. (2017). The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 695, 863-870.
https://doi.org/10.1016/j.jallcom.2016.10.159

Zivojinović J, Pavlović VP, Kosanović D, Marković S, Krstić J, Blagojević VA, Pavlović V. The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders. in Journal of Alloys and Compounds. 2017;695:863-870.
doi:10.1016/j.jallcom.2016.10.159 .

Zivojinović, Jelena, Pavlović, Vera P., Kosanović, Darko, Marković, Smilja, Krstić, Jugoslav, Blagojević, Vladimir A., Pavlović, Vladimir, "The influence of mechanical activation on structural evolution of nanocrystalline SrTiO3 powders" in Journal of Alloys and Compounds, 695 (2017):863-870,
https://doi.org/10.1016/j.jallcom.2016.10.159 . .

TY  - JOUR
AU  - Begović, Nebojša
AU  - Vasić, Milica M.
AU  - Blagojević, Vladimir A.
AU  - Filipović, Nenad
AU  - Marinković, Aleksandar D.
AU  - Malesević, Aleksandar
AU  - Minić, Dragica M.
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4483
AB  - The structure of new cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex was determined using a combination of XRD and IR measurements and DFT calculations. Inherent flexibility of its structure is evident from the complexity of its IR spectrum, which could only be theoretically reproduced as a combination of several closely related structures, involving rotation around C-O bond and changes in hydrogen interactions of its -OH group. Its thermal stability and decomposition were studied non-isothermally, and the thermal decomposition mechanism was proposed using correlation with DFT calculations at the molecular level. It was determined that the initial degradation step consists of the release of Cl free radical, which then reacts with both the initial compound and the degradation products. Besides the endothermic steps, there are exothermic ones, contributing to the complex shape of the DSC curve, consisted of overlapping endothermic and exothermic peaks. Deconvolution of DTG curve allowed identification of primary fragments of the initial degradation process and, in conjunction with DFT calculations, construction of the most likely reaction mechanism.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Synthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex
EP  - 711
IS  - 2
SP  - 701
VL  - 130
DO  - 10.1007/s10973-017-6458-2
ER  - 

@article{
author = "Begović, Nebojša and Vasić, Milica M. and Blagojević, Vladimir A. and Filipović, Nenad and Marinković, Aleksandar D. and Malesević, Aleksandar and Minić, Dragica M.",
year = "2017",
abstract = "The structure of new cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex was determined using a combination of XRD and IR measurements and DFT calculations. Inherent flexibility of its structure is evident from the complexity of its IR spectrum, which could only be theoretically reproduced as a combination of several closely related structures, involving rotation around C-O bond and changes in hydrogen interactions of its -OH group. Its thermal stability and decomposition were studied non-isothermally, and the thermal decomposition mechanism was proposed using correlation with DFT calculations at the molecular level. It was determined that the initial degradation step consists of the release of Cl free radical, which then reacts with both the initial compound and the degradation products. Besides the endothermic steps, there are exothermic ones, contributing to the complex shape of the DSC curve, consisted of overlapping endothermic and exothermic peaks. Deconvolution of DTG curve allowed identification of primary fragments of the initial degradation process and, in conjunction with DFT calculations, construction of the most likely reaction mechanism.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Synthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex",
pages = "711-701",
number = "2",
volume = "130",
doi = "10.1007/s10973-017-6458-2"
}

Begović, N., Vasić, M. M., Blagojević, V. A., Filipović, N., Marinković, A. D., Malesević, A.,& Minić, D. M.. (2017). Synthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 130(2), 701-711.
https://doi.org/10.1007/s10973-017-6458-2

Begović N, Vasić MM, Blagojević VA, Filipović N, Marinković AD, Malesević A, Minić DM. Synthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex. in Journal of Thermal Analysis and Calorimetry. 2017;130(2):701-711.
doi:10.1007/s10973-017-6458-2 .

Begović, Nebojša, Vasić, Milica M., Blagojević, Vladimir A., Filipović, Nenad, Marinković, Aleksandar D., Malesević, Aleksandar, Minić, Dragica M., "Synthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-kappa(2) N]-palladium(II) complex" in Journal of Thermal Analysis and Calorimetry, 130, no. 2 (2017):701-711,
https://doi.org/10.1007/s10973-017-6458-2 . .

TY  - JOUR
AU  - Filipović, Nenad
AU  - Bjelogrlić, Snežana
AU  - Todorović, Tamara R.
AU  - Blagojević, Vladimir A.
AU  - Muller, Christian D.
AU  - Marinković, Aleksandar
AU  - Vujcić, Miroslava
AU  - Janović, Barbara
AU  - Malesević, Aleksandar
AU  - Begović, Nebojša
AU  - Sencanski, Milan
AU  - Minić, Dragica M.
PY  - 2016
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4060
AB  - A new Ni(II) complex, [Ni(L)(H2O)] (1), with diethyl 3,3'-(2,2'-(1,1'-(pyridine-2,6-diyl) bis(ethan-1-yl-1-ylidene)) bis(hydrazin-1-yl-2-ylidene)) bis(3-oxopropanoate) ligand (H2L) was synthesized as a potential chemotherapeutic agent. Polidentate ligand was coordinated to Ni(II) NNN-tridentately, in dianionic form, while monodentate water coordination completed square-planar geometry around metal. Structure in the solution was determined by NMR spectroscopy and the same coordination mode was observed in the solid state using IR spectroscopy and further verified by DFT calculations and electrochemical studies. Thermal stability of 1 was determined in both air and nitrogen atmosphere. Anticancer activity of 1 was investigated on acute monocytic leukemia (THP-1) and pancreatic adenocarcinoma (AsPC-1) cell lines. On THP-1 cells 1 induced powerful apoptotic response (ED50 = 10 +/- 3 mu M), which was revealed to be only partially caspase-dependent, with activation of caspase-8 as the dominant course. This suggested that experimentally validated covalent binding of 1 to DNA is not the only mechanism responsible for programmed cell death. This was supported with experiments on AsPC-1 cells. Although treatment of those cells with 1 resulted in poor apoptotic response, cell cycle changes showed concentration-dependent shifts indicating a dual mechanism of activity. This study also reviews the results of preliminary biological screening, which demonstrates that 1 displays a unique pattern of anticancer activity with at least two mechanisms involved.
PB  - Royal Soc Chemistry, Cambridge
T2  - RSC Advances
T1  - Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines
EP  - 108740
IS  - 110
SP  - 108726
VL  - 6
DO  - 10.1039/c6ra24604d
ER  - 

@article{
author = "Filipović, Nenad and Bjelogrlić, Snežana and Todorović, Tamara R. and Blagojević, Vladimir A. and Muller, Christian D. and Marinković, Aleksandar and Vujcić, Miroslava and Janović, Barbara and Malesević, Aleksandar and Begović, Nebojša and Sencanski, Milan and Minić, Dragica M.",
year = "2016",
abstract = "A new Ni(II) complex, [Ni(L)(H2O)] (1), with diethyl 3,3'-(2,2'-(1,1'-(pyridine-2,6-diyl) bis(ethan-1-yl-1-ylidene)) bis(hydrazin-1-yl-2-ylidene)) bis(3-oxopropanoate) ligand (H2L) was synthesized as a potential chemotherapeutic agent. Polidentate ligand was coordinated to Ni(II) NNN-tridentately, in dianionic form, while monodentate water coordination completed square-planar geometry around metal. Structure in the solution was determined by NMR spectroscopy and the same coordination mode was observed in the solid state using IR spectroscopy and further verified by DFT calculations and electrochemical studies. Thermal stability of 1 was determined in both air and nitrogen atmosphere. Anticancer activity of 1 was investigated on acute monocytic leukemia (THP-1) and pancreatic adenocarcinoma (AsPC-1) cell lines. On THP-1 cells 1 induced powerful apoptotic response (ED50 = 10 +/- 3 mu M), which was revealed to be only partially caspase-dependent, with activation of caspase-8 as the dominant course. This suggested that experimentally validated covalent binding of 1 to DNA is not the only mechanism responsible for programmed cell death. This was supported with experiments on AsPC-1 cells. Although treatment of those cells with 1 resulted in poor apoptotic response, cell cycle changes showed concentration-dependent shifts indicating a dual mechanism of activity. This study also reviews the results of preliminary biological screening, which demonstrates that 1 displays a unique pattern of anticancer activity with at least two mechanisms involved.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "RSC Advances",
title = "Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines",
pages = "108740-108726",
number = "110",
volume = "6",
doi = "10.1039/c6ra24604d"
}

Filipović, N., Bjelogrlić, S., Todorović, T. R., Blagojević, V. A., Muller, C. D., Marinković, A., Vujcić, M., Janović, B., Malesević, A., Begović, N., Sencanski, M.,& Minić, D. M.. (2016). Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines. in RSC Advances
Royal Soc Chemistry, Cambridge., 6(110), 108726-108740.
https://doi.org/10.1039/c6ra24604d

Filipović N, Bjelogrlić S, Todorović TR, Blagojević VA, Muller CD, Marinković A, Vujcić M, Janović B, Malesević A, Begović N, Sencanski M, Minić DM. Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines. in RSC Advances. 2016;6(110):108726-108740.
doi:10.1039/c6ra24604d .

Filipović, Nenad, Bjelogrlić, Snežana, Todorović, Tamara R., Blagojević, Vladimir A., Muller, Christian D., Marinković, Aleksandar, Vujcić, Miroslava, Janović, Barbara, Malesević, Aleksandar, Begović, Nebojša, Sencanski, Milan, Minić, Dragica M., "Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines" in RSC Advances, 6, no. 110 (2016):108726-108740,
https://doi.org/10.1039/c6ra24604d . .

TY  - CONF
AU  - Živojinović, Jelena
AU  - Peleš, Adriana
AU  - Blagojević, Vladimir A.
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/882
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5717
AB  - The influence of mechanically activated fillers (ZnO, BaTiO3 and SrTiO3 ultra-fine powders) on mechanical properties of poly(vinylidene) fluoride (PVDF) and oxide nanoparticle composite was investigated using molecular simulations. Mechanical activation leads to the creation of new surfaces and the comminution of the initial powder particles, which affects the crystallization of PVDF matrix. In addition, prolonged mechanical activation leads to agglomeration of nanoparticles into “soft” and “hard” agglomerates of different sizes. All of this has a significant effect on mechanical properties of PVDF-nanoparticle composites. Microstructural changes due to mechanical activation in ZnO, BaTiO3 and SrTiO3 powders were investigated using SEM and XRD, while dependence of mechanical properties on nanoparticle size was investigated using molecular simulation. These show that smaller nanoparticles significantly enhance the mechanical properties of PVDF-nanoparticle composite and allow use of mechanical activation as a means of reducing the amount of nanoparticle filler in the composite, while achieving the same of superior mechanical properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
T1  - Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites
EP  - 64
SP  - 63
UR  - https://hdl.handle.net/21.15107/rcub_dais_882
ER  - 

@conference{
author = "Živojinović, Jelena and Peleš, Adriana and Blagojević, Vladimir A. and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2016",
abstract = "The influence of mechanically activated fillers (ZnO, BaTiO3 and SrTiO3 ultra-fine powders) on mechanical properties of poly(vinylidene) fluoride (PVDF) and oxide nanoparticle composite was investigated using molecular simulations. Mechanical activation leads to the creation of new surfaces and the comminution of the initial powder particles, which affects the crystallization of PVDF matrix. In addition, prolonged mechanical activation leads to agglomeration of nanoparticles into “soft” and “hard” agglomerates of different sizes. All of this has a significant effect on mechanical properties of PVDF-nanoparticle composites. Microstructural changes due to mechanical activation in ZnO, BaTiO3 and SrTiO3 powders were investigated using SEM and XRD, while dependence of mechanical properties on nanoparticle size was investigated using molecular simulation. These show that smaller nanoparticles significantly enhance the mechanical properties of PVDF-nanoparticle composite and allow use of mechanical activation as a means of reducing the amount of nanoparticle filler in the composite, while achieving the same of superior mechanical properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade",
title = "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites",
pages = "64-63",
url = "https://hdl.handle.net/21.15107/rcub_dais_882"
}

Živojinović, J., Peleš, A., Blagojević, V. A., Kosanović, D.,& Pavlović, V. B.. (2016). Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade
Belgrade : Serbian Ceramic Society., 63-64.
https://hdl.handle.net/21.15107/rcub_dais_882

Živojinović J, Peleš A, Blagojević VA, Kosanović D, Pavlović VB. Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites. in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade. 2016;:63-64.
https://hdl.handle.net/21.15107/rcub_dais_882 .

Živojinović, Jelena, Peleš, Adriana, Blagojević, Vladimir A., Kosanović, Darko, Pavlović, Vladimir B., "Influence of mechanical activation on mechanical properties of PVDF-nanoparticle composites" in Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts : V Serbian Ceramic Society Conference, Sep 21-23 September 2016, Belgrade (2016):63-64,
https://hdl.handle.net/21.15107/rcub_dais_882 .

TY  - JOUR
AU  - Vasić, Milica M.
AU  - Blagojević, Vladimir A.
AU  - Begović, Nebojša
AU  - Zak, Tomas
AU  - Pavlović, Vladimir
AU  - Minić, Dragica M.
PY  - 2015
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3703
AB  - The crystallization mechanism and kinetics of Fe40Ni40P14B6 amorphous alloy were studied under non-isothermal conditions. Thermal stabilization of this alloy manifests in DSC through two complex peaks, corresponding to crystallization and recrystallization, respectively. The complex crystallization DSC peak was deconvoluted into individual steps corresponding to crystallization of individual phases, where the results using both Gaussian-Lorentzian cross-product and Fraser-Suzuki function were compared. It was determined that the values of kinetic triplets of the individual steps did not exhibit any significant difference, depending on the deconvolution function. Anisotropic growth was indicated to be the prevailing type of impingement for all crystallization steps. Using the calculated values of the respective kinetic triplets and the mechanisms determined from the value of Avrami exponent, distinct values of activation energies for nucleation and crystal growth for crystallization of each individual phase were calculated, showing significantly higher values for nucleation than those for crystal growth. Alloy samples treated non-isothermally in the DSC cell exhibit inhomogeneous surface morphology with highly granulated structure dependent on heating rate.
PB  - Elsevier Science Bv, Amsterdam
T2  - Thermochimica Acta
T1  - Thermally induced crystallization of amorphous Fe40Ni40P14B6 alloy
EP  - 136
SP  - 129
VL  - 614
DO  - 10.1016/j.tca.2015.06.015
ER  - 

@article{
author = "Vasić, Milica M. and Blagojević, Vladimir A. and Begović, Nebojša and Zak, Tomas and Pavlović, Vladimir and Minić, Dragica M.",
year = "2015",
abstract = "The crystallization mechanism and kinetics of Fe40Ni40P14B6 amorphous alloy were studied under non-isothermal conditions. Thermal stabilization of this alloy manifests in DSC through two complex peaks, corresponding to crystallization and recrystallization, respectively. The complex crystallization DSC peak was deconvoluted into individual steps corresponding to crystallization of individual phases, where the results using both Gaussian-Lorentzian cross-product and Fraser-Suzuki function were compared. It was determined that the values of kinetic triplets of the individual steps did not exhibit any significant difference, depending on the deconvolution function. Anisotropic growth was indicated to be the prevailing type of impingement for all crystallization steps. Using the calculated values of the respective kinetic triplets and the mechanisms determined from the value of Avrami exponent, distinct values of activation energies for nucleation and crystal growth for crystallization of each individual phase were calculated, showing significantly higher values for nucleation than those for crystal growth. Alloy samples treated non-isothermally in the DSC cell exhibit inhomogeneous surface morphology with highly granulated structure dependent on heating rate.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Thermochimica Acta",
title = "Thermally induced crystallization of amorphous Fe40Ni40P14B6 alloy",
pages = "136-129",
volume = "614",
doi = "10.1016/j.tca.2015.06.015"
}

Vasić, M. M., Blagojević, V. A., Begović, N., Zak, T., Pavlović, V.,& Minić, D. M.. (2015). Thermally induced crystallization of amorphous Fe40Ni40P14B6 alloy. in Thermochimica Acta
Elsevier Science Bv, Amsterdam., 614, 129-136.
https://doi.org/10.1016/j.tca.2015.06.015

Vasić MM, Blagojević VA, Begović N, Zak T, Pavlović V, Minić DM. Thermally induced crystallization of amorphous Fe40Ni40P14B6 alloy. in Thermochimica Acta. 2015;614:129-136.
doi:10.1016/j.tca.2015.06.015 .

Vasić, Milica M., Blagojević, Vladimir A., Begović, Nebojša, Zak, Tomas, Pavlović, Vladimir, Minić, Dragica M., "Thermally induced crystallization of amorphous Fe40Ni40P14B6 alloy" in Thermochimica Acta, 614 (2015):129-136,
https://doi.org/10.1016/j.tca.2015.06.015 . .

TY  - JOUR
AU  - Begović, Nebojša
AU  - Blagojević, Vladimir A.
AU  - Ostojić, Sanja
AU  - Micić, Darko
AU  - Filipović, Nenad
AU  - Andjelković, Katarina
AU  - Minić, Dragica M.
PY  - 2014
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3447
AB  - Thermal stability of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands was investigated using a combination of experimental measurements and DFT calculations. All complexes exhibit a reversible second-order transition around 333 K, which can be attributed to structural reorganization of the ligand molecules. Thermal degradation begins in 570-610 K temperature region, with an endothermic peak, followed by exothermic peaks in DSC. TG measurements show a well-defined mass loss corresponding to the initial degradation, while subsequent processes are poorly separated. DFT calculations suggest that the initial degradation step occurs with release of Cl, which then reacts with remaining part of the complex molecule in an exothermic process. This leads to decomposition of the ligand molecule into four fragments corresponding to ethyl chloride, carbon dioxide, methyl amine, and the fragment with the aromatic group. Mass spectrum suggests that creation of these fragments most likely corresponds to the initial degradation, after which some of these coordinate to Pd center, whose coordination sphere is left incomplete by release of Cl. TG measurement to 1123 K indicates that the final degradation product at this temperature is palladium.
PB  - Elsevier, Amsterdam
T2  - Thermochimica Acta
T1  - Thermally induced structural transformations of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands
EP  - 30
SP  - 23
VL  - 592
DO  - 10.1016/j.tca.2014.08.005
ER  - 

@article{
author = "Begović, Nebojša and Blagojević, Vladimir A. and Ostojić, Sanja and Micić, Darko and Filipović, Nenad and Andjelković, Katarina and Minić, Dragica M.",
year = "2014",
abstract = "Thermal stability of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands was investigated using a combination of experimental measurements and DFT calculations. All complexes exhibit a reversible second-order transition around 333 K, which can be attributed to structural reorganization of the ligand molecules. Thermal degradation begins in 570-610 K temperature region, with an endothermic peak, followed by exothermic peaks in DSC. TG measurements show a well-defined mass loss corresponding to the initial degradation, while subsequent processes are poorly separated. DFT calculations suggest that the initial degradation step occurs with release of Cl, which then reacts with remaining part of the complex molecule in an exothermic process. This leads to decomposition of the ligand molecule into four fragments corresponding to ethyl chloride, carbon dioxide, methyl amine, and the fragment with the aromatic group. Mass spectrum suggests that creation of these fragments most likely corresponds to the initial degradation, after which some of these coordinate to Pd center, whose coordination sphere is left incomplete by release of Cl. TG measurement to 1123 K indicates that the final degradation product at this temperature is palladium.",
publisher = "Elsevier, Amsterdam",
journal = "Thermochimica Acta",
title = "Thermally induced structural transformations of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands",
pages = "30-23",
volume = "592",
doi = "10.1016/j.tca.2014.08.005"
}

Begović, N., Blagojević, V. A., Ostojić, S., Micić, D., Filipović, N., Andjelković, K.,& Minić, D. M.. (2014). Thermally induced structural transformations of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands. in Thermochimica Acta
Elsevier, Amsterdam., 592, 23-30.
https://doi.org/10.1016/j.tca.2014.08.005

Begović N, Blagojević VA, Ostojić S, Micić D, Filipović N, Andjelković K, Minić DM. Thermally induced structural transformations of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands. in Thermochimica Acta. 2014;592:23-30.
doi:10.1016/j.tca.2014.08.005 .

Begović, Nebojša, Blagojević, Vladimir A., Ostojić, Sanja, Micić, Darko, Filipović, Nenad, Andjelković, Katarina, Minić, Dragica M., "Thermally induced structural transformations of a series of palladium(II) complexes with N-heteroaromatic bidentate hydrazone ligands" in Thermochimica Acta, 592 (2014):23-30,
https://doi.org/10.1016/j.tca.2014.08.005 . .