Kljajević, Ljiljana M.

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  • Kljajević, Ljiljana M. (14)
  • Kljajević, Ljiljana (2)

Author's Bibliography

Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing

Mirković, Miljana; Yilmaz, Muge Sari; Kljajević, Ljiljana; Pavlović, Vladimir; Ivanović, Marija; Djukić, Dunja; Eren, Tarik

(2023)

TY  - JOUR
AU  - Mirković, Miljana
AU  - Yilmaz, Muge Sari
AU  - Kljajević, Ljiljana
AU  - Pavlović, Vladimir
AU  - Ivanović, Marija
AU  - Djukić, Dunja
AU  - Eren, Tarik
PY  - 2023
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6332
AB  - In this paper, the properties of organic-inorganic hybrid polymer materials, which were synthesized from an aluminosilicate inorganic matrix with the addition of brushite and aminosilane grafted on one side and PEI covalently bonded composites on the other side, were examined. The synthesized organic-inorganic hybrid polymers were examined in terms of a structural, morphological, thermo-gravimetric, and adsorption-desorption analysis and also as potential CO2 capturers. The structural and phase properties as well as the percentage contents of the crystalline and amorphous phase were determined by the X-ray diffraction method. The higher content of the amorphous phase in the structure of hybrid polymers was proven in metakaolin and metakaolin-brushite hybrid samples with the addition of amino silane and with 1,000,000 PEI in a structure. The DRIFT method showed the main band changes with the addition of an organic phase and inorganic matrix. Microstructural studies with the EDS analysis showed a uniform distribution of organic and inorganic phases in the hybrid geopolymers. The thermo-gravimetric analysis showed that organic compounds are successfully bonded to inorganic polymer matrix, while adsorption-desorption analysis confirmed that the organic phase completely covered the surface of the inorganic matrix. The CO2 adsorption experiments showed that the amine-modified composites have the higher capture capacity, which is 0.685 mmol·g−1 for the GM10 sample and 0.581 mmol·g−1 for the BGM10 sample, with 1,000,000 PEI in the structure. © 2023 by the authors.
T2  - Polymers
T2  - Polymers
T1  - Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing
IS  - 7
VL  - 15
DO  - 10.3390/polym15071669
ER  - 
@article{
author = "Mirković, Miljana and Yilmaz, Muge Sari and Kljajević, Ljiljana and Pavlović, Vladimir and Ivanović, Marija and Djukić, Dunja and Eren, Tarik",
year = "2023",
abstract = "In this paper, the properties of organic-inorganic hybrid polymer materials, which were synthesized from an aluminosilicate inorganic matrix with the addition of brushite and aminosilane grafted on one side and PEI covalently bonded composites on the other side, were examined. The synthesized organic-inorganic hybrid polymers were examined in terms of a structural, morphological, thermo-gravimetric, and adsorption-desorption analysis and also as potential CO2 capturers. The structural and phase properties as well as the percentage contents of the crystalline and amorphous phase were determined by the X-ray diffraction method. The higher content of the amorphous phase in the structure of hybrid polymers was proven in metakaolin and metakaolin-brushite hybrid samples with the addition of amino silane and with 1,000,000 PEI in a structure. The DRIFT method showed the main band changes with the addition of an organic phase and inorganic matrix. Microstructural studies with the EDS analysis showed a uniform distribution of organic and inorganic phases in the hybrid geopolymers. The thermo-gravimetric analysis showed that organic compounds are successfully bonded to inorganic polymer matrix, while adsorption-desorption analysis confirmed that the organic phase completely covered the surface of the inorganic matrix. The CO2 adsorption experiments showed that the amine-modified composites have the higher capture capacity, which is 0.685 mmol·g−1 for the GM10 sample and 0.581 mmol·g−1 for the BGM10 sample, with 1,000,000 PEI in the structure. © 2023 by the authors.",
journal = "Polymers, Polymers",
title = "Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing",
number = "7",
volume = "15",
doi = "10.3390/polym15071669"
}
Mirković, M., Yilmaz, M. S., Kljajević, L., Pavlović, V., Ivanović, M., Djukić, D.,& Eren, T.. (2023). Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing. in Polymers, 15(7).
https://doi.org/10.3390/polym15071669
Mirković M, Yilmaz MS, Kljajević L, Pavlović V, Ivanović M, Djukić D, Eren T. Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing. in Polymers. 2023;15(7).
doi:10.3390/polym15071669 .
Mirković, Miljana, Yilmaz, Muge Sari, Kljajević, Ljiljana, Pavlović, Vladimir, Ivanović, Marija, Djukić, Dunja, Eren, Tarik, "Design of PEI and Amine Modified Metakaolin-Brushite Hybrid Polymeric Composite Materials for CO2 Capturing" in Polymers, 15, no. 7 (2023),
https://doi.org/10.3390/polym15071669 . .
2

Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties

Mirković, Miljana; Kljajević, Ljiljana; Dolenec, Sabina; Nenadović, Miloš; Pavlović, Vladimir; Rajačić, Milica; Nenadović, Snežana

(MDPI, 2021)

TY  - JOUR
AU  - Mirković, Miljana
AU  - Kljajević, Ljiljana
AU  - Dolenec, Sabina
AU  - Nenadović, Miloš
AU  - Pavlović, Vladimir
AU  - Rajačić, Milica
AU  - Nenadović, Snežana
PY  - 2021
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6004
AB  - Since recycled technologies usage is mandatory for environmental safety, and in this regard, it is important to examine new materials that can be used in construction and are primarily produced from fly ash. In addition to characteristics such as hardness and compressive strength, the given materials must also be radiologically and environmentally safe. The main concept of engineered geopolymer gel composites based on fly ash residues is focused on developing binder materials via gel formation processes that can replace ordinary cement materials. This study is unique in researching the potential use of fly ash from the Nikola Tesla thermal power plant in Serbia, where the hybrid geopolymeric materials synthesized from fly ash are experimentally examined with the addition 1 wt% and 2 wt% of polyvinyl alcohol (PVA). This paper aims to investigate the structural, morphological, mechanical, and radiological properties of hybrid materials with the addition of PVA and without additive in the period of ageing for 28 days at room temperature. The phase composition was investigated using X-ray powder diffraction (XRPD) analysis, while morphological characteristics of these materials were examined using scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDS). Vibrational spectra of obtained samples are investigated using diffuse reflectance infrared Fourier transform (DRIFT) and Fourier transform infrared (FTIR) techniques. The hardness and compressive strength are also examined, indicating that the 1 wt% addition in geopolymeric matrix results in the best mechanical properties. Radiological measurements of investigated all geopolymer samples show decreasing activity concentrations of radionuclides for 50% compared to fly ash.
PB  - MDPI
T2  - Gels
T1  - Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties
IS  - 4
SP  - 270
VL  - 7
DO  - 10.3390/gels7040270
ER  - 
@article{
author = "Mirković, Miljana and Kljajević, Ljiljana and Dolenec, Sabina and Nenadović, Miloš and Pavlović, Vladimir and Rajačić, Milica and Nenadović, Snežana",
year = "2021",
abstract = "Since recycled technologies usage is mandatory for environmental safety, and in this regard, it is important to examine new materials that can be used in construction and are primarily produced from fly ash. In addition to characteristics such as hardness and compressive strength, the given materials must also be radiologically and environmentally safe. The main concept of engineered geopolymer gel composites based on fly ash residues is focused on developing binder materials via gel formation processes that can replace ordinary cement materials. This study is unique in researching the potential use of fly ash from the Nikola Tesla thermal power plant in Serbia, where the hybrid geopolymeric materials synthesized from fly ash are experimentally examined with the addition 1 wt% and 2 wt% of polyvinyl alcohol (PVA). This paper aims to investigate the structural, morphological, mechanical, and radiological properties of hybrid materials with the addition of PVA and without additive in the period of ageing for 28 days at room temperature. The phase composition was investigated using X-ray powder diffraction (XRPD) analysis, while morphological characteristics of these materials were examined using scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDS). Vibrational spectra of obtained samples are investigated using diffuse reflectance infrared Fourier transform (DRIFT) and Fourier transform infrared (FTIR) techniques. The hardness and compressive strength are also examined, indicating that the 1 wt% addition in geopolymeric matrix results in the best mechanical properties. Radiological measurements of investigated all geopolymer samples show decreasing activity concentrations of radionuclides for 50% compared to fly ash.",
publisher = "MDPI",
journal = "Gels",
title = "Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties",
number = "4",
pages = "270",
volume = "7",
doi = "10.3390/gels7040270"
}
Mirković, M., Kljajević, L., Dolenec, S., Nenadović, M., Pavlović, V., Rajačić, M.,& Nenadović, S.. (2021). Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties. in Gels
MDPI., 7(4), 270.
https://doi.org/10.3390/gels7040270
Mirković M, Kljajević L, Dolenec S, Nenadović M, Pavlović V, Rajačić M, Nenadović S. Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties. in Gels. 2021;7(4):270.
doi:10.3390/gels7040270 .
Mirković, Miljana, Kljajević, Ljiljana, Dolenec, Sabina, Nenadović, Miloš, Pavlović, Vladimir, Rajačić, Milica, Nenadović, Snežana, "Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties" in Gels, 7, no. 4 (2021):270,
https://doi.org/10.3390/gels7040270 . .
3
3

Characterization of red mud/metakaolin-based geopolymers as modified by Ca(OH)2

Bošković, I.; Vukčević, M.; Nenadović, Snežana S.; Mirković, M.; Stojmenović, M.; Pavlović, Vladimir; Kljajević, Ljiljana M.

(Institute of Metals Technology, 2019)

TY  - JOUR
AU  - Bošković, I.
AU  - Vukčević, M.
AU  - Nenadović, Snežana S.
AU  - Mirković, M.
AU  - Stojmenović, M.
AU  - Pavlović, Vladimir
AU  - Kljajević, Ljiljana M.
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5129
AB  - Geopolymers are an emerging class of materials that offer an alternative to the Portland cement as the binder of structural concrete. One of the advantages is that the primary source of their production is waste alumosilicate materials from different industries. One of the key issues in geopolymer synthesis is the low level of mechanical properties due to porosity as well as the high activity of conductivity carriers. It can often lead to limited application possibilities, so the objective is to obtain an enhanced strength as well as decreased cracking tendency through microstructure modification. The introduction of Ca(OH)2, under certain pH conditions could lead to the filling-the-pores process and improving the mechanical properties. The aim was to understand the role that calcium plays in the geopolymer synthesis, and to define which reaction prevails under the synthesis conditions: formation of geopolymer gel or calcium silicate hydrate that contains aluminum substitution (CASH). The synthesis was performed with different raw materials (with or without red mud) and different alkalinity conditions. Ca(OH)2 was the obligatory supplement to both of the mixtures. Different techniques were performed for the testing of reaction products, as well as to define the microstructural changes as the generator of improved mechanical properties and changed electrical conductivity. The characteristics of the geopolymer's macrostructure were defined by means of an SEM analysis. Compressive strength and electrical conductivity are among the investigated product's properties. X-ray diffraction (XRD) and Fourier transform infra-red spectroscopy (FTIR) were used for the identification of various crystalline phases and an amorphous phase.
PB  - Institute of Metals Technology
T2  - Materiali in Tehnologije
T1  - Characterization of red mud/metakaolin-based geopolymers as modified by Ca(OH)2
EP  - 348
IS  - 3
SP  - 341
VL  - 53
DO  - 10.17222/mit.2018.130
ER  - 
@article{
author = "Bošković, I. and Vukčević, M. and Nenadović, Snežana S. and Mirković, M. and Stojmenović, M. and Pavlović, Vladimir and Kljajević, Ljiljana M.",
year = "2019",
abstract = "Geopolymers are an emerging class of materials that offer an alternative to the Portland cement as the binder of structural concrete. One of the advantages is that the primary source of their production is waste alumosilicate materials from different industries. One of the key issues in geopolymer synthesis is the low level of mechanical properties due to porosity as well as the high activity of conductivity carriers. It can often lead to limited application possibilities, so the objective is to obtain an enhanced strength as well as decreased cracking tendency through microstructure modification. The introduction of Ca(OH)2, under certain pH conditions could lead to the filling-the-pores process and improving the mechanical properties. The aim was to understand the role that calcium plays in the geopolymer synthesis, and to define which reaction prevails under the synthesis conditions: formation of geopolymer gel or calcium silicate hydrate that contains aluminum substitution (CASH). The synthesis was performed with different raw materials (with or without red mud) and different alkalinity conditions. Ca(OH)2 was the obligatory supplement to both of the mixtures. Different techniques were performed for the testing of reaction products, as well as to define the microstructural changes as the generator of improved mechanical properties and changed electrical conductivity. The characteristics of the geopolymer's macrostructure were defined by means of an SEM analysis. Compressive strength and electrical conductivity are among the investigated product's properties. X-ray diffraction (XRD) and Fourier transform infra-red spectroscopy (FTIR) were used for the identification of various crystalline phases and an amorphous phase.",
publisher = "Institute of Metals Technology",
journal = "Materiali in Tehnologije",
title = "Characterization of red mud/metakaolin-based geopolymers as modified by Ca(OH)2",
pages = "348-341",
number = "3",
volume = "53",
doi = "10.17222/mit.2018.130"
}
Bošković, I., Vukčević, M., Nenadović, S. S., Mirković, M., Stojmenović, M., Pavlović, V.,& Kljajević, L. M.. (2019). Characterization of red mud/metakaolin-based geopolymers as modified by Ca(OH)2. in Materiali in Tehnologije
Institute of Metals Technology., 53(3), 341-348.
https://doi.org/10.17222/mit.2018.130
Bošković I, Vukčević M, Nenadović SS, Mirković M, Stojmenović M, Pavlović V, Kljajević LM. Characterization of red mud/metakaolin-based geopolymers as modified by Ca(OH)2. in Materiali in Tehnologije. 2019;53(3):341-348.
doi:10.17222/mit.2018.130 .
Bošković, I., Vukčević, M., Nenadović, Snežana S., Mirković, M., Stojmenović, M., Pavlović, Vladimir, Kljajević, Ljiljana M., "Characterization of red mud/metakaolin-based geopolymers as modified by Ca(OH)2" in Materiali in Tehnologije, 53, no. 3 (2019):341-348,
https://doi.org/10.17222/mit.2018.130 . .
7
4
9

The potential of hybrid geopolymer composites

Vukčević, Mira; Bošković, Ivana; Nenadović, Snežana S.; Mirković, Miljana M.; Gulicovski, Jelena; Pavlović, Vladimir; Kljajević, Ljiljana M.

(Belgrade : Institute for Multidisciplinary Research, 2019)

TY  - CONF
AU  - Vukčević, Mira
AU  - Bošković, Ivana
AU  - Nenadović, Snežana S.
AU  - Mirković, Miljana M.
AU  - Gulicovski, Jelena
AU  - Pavlović, Vladimir
AU  - Kljajević, Ljiljana M.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/7004
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5750
AB  - Hybrid geopolymers represent a new class of composite materials formed by incorporating organic polymer into a geopolymer matrix. The properties of hybrid geopolymer depend on the addition of organic phase and the starting raw material composition (concentration of NaOH in alkaline activator, Si/Al mass ratio and solid/liquid mass ratio). In addition to these relevant parameters, this paper examines the synthesis conditions of these materials through the influence of the type, amount and manner of adding organic modifiers (commercial epoxy resins and 3- (methoxyl) propyl methacrylates) on forming the structure with significantly reduced pore distribution and decreased pore size, which exhibits good mechanical properties. The purpose of this research is to define the optimal conditions of the hybrid geopolymers' synthesis through the examination of relevant parameters. Expected improvement of mechanical properties was confirmed through values of compressive stength. Characterization of hybrid geopolymer composities was performed by XRD analysis, DRIFT spectroscopy and SEM analysis.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
T1  - The potential of hybrid geopolymer composites
EP  - 71
SP  - 71
UR  - https://hdl.handle.net/21.15107/rcub_dais_7004
ER  - 
@conference{
author = "Vukčević, Mira and Bošković, Ivana and Nenadović, Snežana S. and Mirković, Miljana M. and Gulicovski, Jelena and Pavlović, Vladimir and Kljajević, Ljiljana M.",
year = "2019",
abstract = "Hybrid geopolymers represent a new class of composite materials formed by incorporating organic polymer into a geopolymer matrix. The properties of hybrid geopolymer depend on the addition of organic phase and the starting raw material composition (concentration of NaOH in alkaline activator, Si/Al mass ratio and solid/liquid mass ratio). In addition to these relevant parameters, this paper examines the synthesis conditions of these materials through the influence of the type, amount and manner of adding organic modifiers (commercial epoxy resins and 3- (methoxyl) propyl methacrylates) on forming the structure with significantly reduced pore distribution and decreased pore size, which exhibits good mechanical properties. The purpose of this research is to define the optimal conditions of the hybrid geopolymers' synthesis through the examination of relevant parameters. Expected improvement of mechanical properties was confirmed through values of compressive stength. Characterization of hybrid geopolymer composities was performed by XRD analysis, DRIFT spectroscopy and SEM analysis.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia",
title = "The potential of hybrid geopolymer composites",
pages = "71-71",
url = "https://hdl.handle.net/21.15107/rcub_dais_7004"
}
Vukčević, M., Bošković, I., Nenadović, S. S., Mirković, M. M., Gulicovski, J., Pavlović, V.,& Kljajević, L. M.. (2019). The potential of hybrid geopolymer composites. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 71-71.
https://hdl.handle.net/21.15107/rcub_dais_7004
Vukčević M, Bošković I, Nenadović SS, Mirković MM, Gulicovski J, Pavlović V, Kljajević LM. The potential of hybrid geopolymer composites. in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia. 2019;:71-71.
https://hdl.handle.net/21.15107/rcub_dais_7004 .
Vukčević, Mira, Bošković, Ivana, Nenadović, Snežana S., Mirković, Miljana M., Gulicovski, Jelena, Pavlović, Vladimir, Kljajević, Ljiljana M., "The potential of hybrid geopolymer composites" in Programme and the Book of Abstracts / 5th Conference of The Serbian Society for Ceramic Materials, 5CSCS-2019, June 11-13, 2019, Belgrade, Serbia (2019):71-71,
https://hdl.handle.net/21.15107/rcub_dais_7004 .

The influence of thermodynamic parameters of the alkaline activator on the mechanical properties of geopolymers

Ivanović, Marija D.; Đukić, Dunja; Mladenović, Nataša; Kljajević, Ljiljana M.; Pavlović, Vladimir; Nenadović, Snežana S.; Mirković, Miljana M.

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Ivanović, Marija D.
AU  - Đukić, Dunja
AU  - Mladenović, Nataša
AU  - Kljajević, Ljiljana M.
AU  - Pavlović, Vladimir
AU  - Nenadović, Snežana S.
AU  - Mirković, Miljana M.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6965
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5746
AB  - In order to optimize process of geopolymerization, the investigation of thermodynamic parameters of alkali activators are important. The aim of this research was to investigate the influence of thermodynamic parameters (density, viscosity, refractive index and sound velocity) of alkaline activators on mechanical properties (compressive strength and hardness) of synthesized geopolymer samples. Geopolymers were synthetized by alkaline activation of metakaolin, having the density 2.524 g/cm3, using the activators at elevated temperature of 60 oC for two days. Based on the obtained results thermodynamic properties has been selected to predict the properties of materials. Four series of alkaline activators have been used. Activators remarked as AA1, AA2, AA3 and AA4 present the mixtures of Na2SiO3 and solutions of NaOH, of different molarities 2M, 4M, 6M and 8M respectively. The volume ratio of Na2SiO3 and aqueous solution of NaOH was the same for all samples. Densities, viscosities and refractive indices of alkaline activators were determined over the temperature range 15-60 oC of process of geopolymerizations. The values of density, viscosity and refractive index decrease with temperature increase over the investigated temperature range. Increasing molarity of alkali activator solutions, the sound velocity of activators is changed. For sample AA2 the values of sound velocity rises from room temperature to 45 °C and then begins to decrease while for the sample AA3 sound velocity grows until 30 °C and then starts to decrease with further increasing of temperature. Four series of geopolymer samples GP1 to GP4 were synthesiyed using the constant ratio of solid and liquid phase. FTIR, XRD, SEM-EDS methods were used for physicochemical further characterization of geopolymer samples.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - The influence of thermodynamic parameters of the alkaline activator on the mechanical properties of geopolymers
EP  - 87
SP  - 87
UR  - https://hdl.handle.net/21.15107/rcub_dais_6965
ER  - 
@conference{
author = "Ivanović, Marija D. and Đukić, Dunja and Mladenović, Nataša and Kljajević, Ljiljana M. and Pavlović, Vladimir and Nenadović, Snežana S. and Mirković, Miljana M.",
year = "2019",
abstract = "In order to optimize process of geopolymerization, the investigation of thermodynamic parameters of alkali activators are important. The aim of this research was to investigate the influence of thermodynamic parameters (density, viscosity, refractive index and sound velocity) of alkaline activators on mechanical properties (compressive strength and hardness) of synthesized geopolymer samples. Geopolymers were synthetized by alkaline activation of metakaolin, having the density 2.524 g/cm3, using the activators at elevated temperature of 60 oC for two days. Based on the obtained results thermodynamic properties has been selected to predict the properties of materials. Four series of alkaline activators have been used. Activators remarked as AA1, AA2, AA3 and AA4 present the mixtures of Na2SiO3 and solutions of NaOH, of different molarities 2M, 4M, 6M and 8M respectively. The volume ratio of Na2SiO3 and aqueous solution of NaOH was the same for all samples. Densities, viscosities and refractive indices of alkaline activators were determined over the temperature range 15-60 oC of process of geopolymerizations. The values of density, viscosity and refractive index decrease with temperature increase over the investigated temperature range. Increasing molarity of alkali activator solutions, the sound velocity of activators is changed. For sample AA2 the values of sound velocity rises from room temperature to 45 °C and then begins to decrease while for the sample AA3 sound velocity grows until 30 °C and then starts to decrease with further increasing of temperature. Four series of geopolymer samples GP1 to GP4 were synthesiyed using the constant ratio of solid and liquid phase. FTIR, XRD, SEM-EDS methods were used for physicochemical further characterization of geopolymer samples.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "The influence of thermodynamic parameters of the alkaline activator on the mechanical properties of geopolymers",
pages = "87-87",
url = "https://hdl.handle.net/21.15107/rcub_dais_6965"
}
Ivanović, M. D., Đukić, D., Mladenović, N., Kljajević, L. M., Pavlović, V., Nenadović, S. S.,& Mirković, M. M.. (2019). The influence of thermodynamic parameters of the alkaline activator on the mechanical properties of geopolymers. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 87-87.
https://hdl.handle.net/21.15107/rcub_dais_6965
Ivanović MD, Đukić D, Mladenović N, Kljajević LM, Pavlović V, Nenadović SS, Mirković MM. The influence of thermodynamic parameters of the alkaline activator on the mechanical properties of geopolymers. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:87-87.
https://hdl.handle.net/21.15107/rcub_dais_6965 .
Ivanović, Marija D., Đukić, Dunja, Mladenović, Nataša, Kljajević, Ljiljana M., Pavlović, Vladimir, Nenadović, Snežana S., Mirković, Miljana M., "The influence of thermodynamic parameters of the alkaline activator on the mechanical properties of geopolymers" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):87-87,
https://hdl.handle.net/21.15107/rcub_dais_6965 .

Synthesis and characterization of Brushite-metakaolin-based geopolymer materials

Đukić, Dunja; Nenadović, Snežana S.; Kljajević, Ljiljana M.; Pavlović, Vladimir; Ivanović, Marija D.; Nenadović, Miloš T.; Mirković, Miljana M.

(Belgrade : Institute of Technical Sciences of SASA, 2019)

TY  - CONF
AU  - Đukić, Dunja
AU  - Nenadović, Snežana S.
AU  - Kljajević, Ljiljana M.
AU  - Pavlović, Vladimir
AU  - Ivanović, Marija D.
AU  - Nenadović, Miloš T.
AU  - Mirković, Miljana M.
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/6964
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5747
AB  - In a field of green chemistry, environmental protection and ecological conservation of the environment there are ways to come up with new and more advanced materials using on the one hand natural, recyceled or waste materials and on the other hand syntethic materials obtained by using green chemistry synthesis procedures. The aim of this paper was to synthesize and characterize Brushite-metakaolin-based geopolymer materials and to examine the possibility of using these materials in the fields of construction, cement industry, as well as in environmental protection as potential adsorbents. Initial materials which were used for geopolymer synthesis was Brushite (CaHPO4·2H2O) which was obtained by solutionprecipitation reaction form acetate solutions and Kaolinite clay from Rudovci deposit (Serbia). The obtained mixture powders were dissolved in a strong alcaline solution with addiction of water glass. Produced geopolymers was cast into mods and preserved for 28 days. The starting materials and the synthesized Brushite-metakaolin-based geopolymer material were examined using XRPD, FTIR SEM-EDS methods. The contact angle measurements were made to test hydrophilic and wettable properties of synthesized material.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
T1  - Synthesis and characterization of Brushite-metakaolin-based geopolymer materials
EP  - 86
SP  - 86
UR  - https://hdl.handle.net/21.15107/rcub_dais_6964
ER  - 
@conference{
author = "Đukić, Dunja and Nenadović, Snežana S. and Kljajević, Ljiljana M. and Pavlović, Vladimir and Ivanović, Marija D. and Nenadović, Miloš T. and Mirković, Miljana M.",
year = "2019",
abstract = "In a field of green chemistry, environmental protection and ecological conservation of the environment there are ways to come up with new and more advanced materials using on the one hand natural, recyceled or waste materials and on the other hand syntethic materials obtained by using green chemistry synthesis procedures. The aim of this paper was to synthesize and characterize Brushite-metakaolin-based geopolymer materials and to examine the possibility of using these materials in the fields of construction, cement industry, as well as in environmental protection as potential adsorbents. Initial materials which were used for geopolymer synthesis was Brushite (CaHPO4·2H2O) which was obtained by solutionprecipitation reaction form acetate solutions and Kaolinite clay from Rudovci deposit (Serbia). The obtained mixture powders were dissolved in a strong alcaline solution with addiction of water glass. Produced geopolymers was cast into mods and preserved for 28 days. The starting materials and the synthesized Brushite-metakaolin-based geopolymer material were examined using XRPD, FTIR SEM-EDS methods. The contact angle measurements were made to test hydrophilic and wettable properties of synthesized material.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia",
title = "Synthesis and characterization of Brushite-metakaolin-based geopolymer materials",
pages = "86-86",
url = "https://hdl.handle.net/21.15107/rcub_dais_6964"
}
Đukić, D., Nenadović, S. S., Kljajević, L. M., Pavlović, V., Ivanović, M. D., Nenadović, M. T.,& Mirković, M. M.. (2019). Synthesis and characterization of Brushite-metakaolin-based geopolymer materials. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 86-86.
https://hdl.handle.net/21.15107/rcub_dais_6964
Đukić D, Nenadović SS, Kljajević LM, Pavlović V, Ivanović MD, Nenadović MT, Mirković MM. Synthesis and characterization of Brushite-metakaolin-based geopolymer materials. in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia. 2019;:86-86.
https://hdl.handle.net/21.15107/rcub_dais_6964 .
Đukić, Dunja, Nenadović, Snežana S., Kljajević, Ljiljana M., Pavlović, Vladimir, Ivanović, Marija D., Nenadović, Miloš T., Mirković, Miljana M., "Synthesis and characterization of Brushite-metakaolin-based geopolymer materials" in Program and the Book of abstracts / Eighteenth Young Researchers' Conference Materials Sciences and Engineering, December 4-6, 2019, Belgrade, Serbia (2019):86-86,
https://hdl.handle.net/21.15107/rcub_dais_6964 .

Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)

Kljajević, Ljiljana M.; Melichova, Z.; Stojmenović, M.D.; Todorović, B.Z.; Pavlović, Vladimir; Čitaković, N.M.; Nenadović, Snežana S.

(Macedonian Journal of Chemistry and Chemical Engineering, 2019)

TY  - JOUR
AU  - Kljajević, Ljiljana M.
AU  - Melichova, Z.
AU  - Stojmenović, M.D.
AU  - Todorović, B.Z.
AU  - Pavlović, Vladimir
AU  - Čitaković, N.M.
AU  - Nenadović, Snežana S.
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5148
AB  - Geopolymers (GP) were successfully synthesized from metabentonite (MB), metadiatomite (MD) and metakaolinite (MK). Characterization of their phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. A SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel, and it is significantly different from the micrographs of the other two geopolymer samples, GPMB and GPMK. A considerable amount of unreacted particles, as well as the presence of pores in the geopolymer matrix of GPMK and GPMD, indicate an incomplete reaction in the system. Aluminosilicate inorganic polymers, geopolymers, are quasi solid electrolytes which possess a high electrical conductivity at room temperature in relation to materials of similar chemical composi-tion. The highest conductivity was found for the sample obtained from GPMK, amounting to 2.14 x 10-2 Ω-1cm-1 at 700 oC. The corresponding activation energies of conductivity for this sample amounted to 0.33 eV in the temperature range of 500-700 oC. The geopolymer synthesized from metakaolin has good ionic conductivity values, which recommends it for use as an alternative material for an SOFC (Solid Ox-ide Fuel Cell).
PB  - Macedonian Journal of Chemistry and Chemical Engineering
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)
EP  - 292
IS  - 2
SP  - 283
VL  - 38
DO  - 10.20450/mjcce.2019.1678
ER  - 
@article{
author = "Kljajević, Ljiljana M. and Melichova, Z. and Stojmenović, M.D. and Todorović, B.Z. and Pavlović, Vladimir and Čitaković, N.M. and Nenadović, Snežana S.",
year = "2019",
abstract = "Geopolymers (GP) were successfully synthesized from metabentonite (MB), metadiatomite (MD) and metakaolinite (MK). Characterization of their phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. A SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel, and it is significantly different from the micrographs of the other two geopolymer samples, GPMB and GPMK. A considerable amount of unreacted particles, as well as the presence of pores in the geopolymer matrix of GPMK and GPMD, indicate an incomplete reaction in the system. Aluminosilicate inorganic polymers, geopolymers, are quasi solid electrolytes which possess a high electrical conductivity at room temperature in relation to materials of similar chemical composi-tion. The highest conductivity was found for the sample obtained from GPMK, amounting to 2.14 x 10-2 Ω-1cm-1 at 700 oC. The corresponding activation energies of conductivity for this sample amounted to 0.33 eV in the temperature range of 500-700 oC. The geopolymer synthesized from metakaolin has good ionic conductivity values, which recommends it for use as an alternative material for an SOFC (Solid Ox-ide Fuel Cell).",
publisher = "Macedonian Journal of Chemistry and Chemical Engineering",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)",
pages = "292-283",
number = "2",
volume = "38",
doi = "10.20450/mjcce.2019.1678"
}
Kljajević, L. M., Melichova, Z., Stojmenović, M.D., Todorović, B.Z., Pavlović, V., Čitaković, N.M.,& Nenadović, S. S.. (2019). Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite). in Macedonian Journal of Chemistry and Chemical Engineering
Macedonian Journal of Chemistry and Chemical Engineering., 38(2), 283-292.
https://doi.org/10.20450/mjcce.2019.1678
Kljajević LM, Melichova Z, Stojmenović M, Todorović B, Pavlović V, Čitaković N, Nenadović SS. Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite). in Macedonian Journal of Chemistry and Chemical Engineering. 2019;38(2):283-292.
doi:10.20450/mjcce.2019.1678 .
Kljajević, Ljiljana M., Melichova, Z., Stojmenović, M.D., Todorović, B.Z., Pavlović, Vladimir, Čitaković, N.M., Nenadović, Snežana S., "Structural and electrical properties of geopolymer materials based on different precursors (kaolin, bentonite and diatomite)" in Macedonian Journal of Chemistry and Chemical Engineering, 38, no. 2 (2019):283-292,
https://doi.org/10.20450/mjcce.2019.1678 . .
9
2
9

The influence of alumino-silicate matrix composition on surface hydrophobic properties

Kljajević, Ljiljana M.; Melichova, Z.; Kisić, D.D.; Nenadović, Miloš; Todorović, B.Ž.; Pavlović, Vladimir; Nenadović, Snežana S.

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Kljajević, Ljiljana M.
AU  - Melichova, Z.
AU  - Kisić, D.D.
AU  - Nenadović, Miloš
AU  - Todorović, B.Ž.
AU  - Pavlović, Vladimir
AU  - Nenadović, Snežana S.
PY  - 2019
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5132
AB  - The purpose of this investigation is to investigate the hydrophobicity of geopolymers, new alumino-silicate materials and the influence of Si/Al ratio on their surface properties. Contact angle measurement (CAM) as reliable indicator of hydrophobicity was determined for synthesized geopolymers using water and ethylene-glycol as reference liquids. Geopolymers were synthesized from various precursors: Kaolin, bentonite and diatomite. Characterization of phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. Contact angle measurements confirmed that the geopolymers synthesized from metakaolin are the most porous, which can be explained by the smallest Si/Al ratio. The maximum value of contact angle and free surface energy (110.2 mJ/m2) has been achieved for geopolymer synthesized by diatoms (GPMD). SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel and is significantly different from the micrographs of other two geopolymer samples, GPMB and GPMK.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - The influence of alumino-silicate matrix composition on surface hydrophobic properties
EP  - 10
IS  - 2
SP  - 1
VL  - 51
DO  - 10.2298/sos1902163k
ER  - 
@article{
author = "Kljajević, Ljiljana M. and Melichova, Z. and Kisić, D.D. and Nenadović, Miloš and Todorović, B.Ž. and Pavlović, Vladimir and Nenadović, Snežana S.",
year = "2019",
abstract = "The purpose of this investigation is to investigate the hydrophobicity of geopolymers, new alumino-silicate materials and the influence of Si/Al ratio on their surface properties. Contact angle measurement (CAM) as reliable indicator of hydrophobicity was determined for synthesized geopolymers using water and ethylene-glycol as reference liquids. Geopolymers were synthesized from various precursors: Kaolin, bentonite and diatomite. Characterization of phase structure and microstructure was performed by XRD, FTIR, SEM/EDX methods. Contact angle measurements confirmed that the geopolymers synthesized from metakaolin are the most porous, which can be explained by the smallest Si/Al ratio. The maximum value of contact angle and free surface energy (110.2 mJ/m2) has been achieved for geopolymer synthesized by diatoms (GPMD). SEM micrograph of GPMD shows a homogeneous surface with some longitudinal cavities in the gel and is significantly different from the micrographs of other two geopolymer samples, GPMB and GPMK.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "The influence of alumino-silicate matrix composition on surface hydrophobic properties",
pages = "10-1",
number = "2",
volume = "51",
doi = "10.2298/sos1902163k"
}
Kljajević, L. M., Melichova, Z., Kisić, D.D., Nenadović, M., Todorović, B.Ž., Pavlović, V.,& Nenadović, S. S.. (2019). The influence of alumino-silicate matrix composition on surface hydrophobic properties. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(2), 1-10.
https://doi.org/10.2298/sos1902163k
Kljajević LM, Melichova Z, Kisić D, Nenadović M, Todorović B, Pavlović V, Nenadović SS. The influence of alumino-silicate matrix composition on surface hydrophobic properties. in Science of Sintering. 2019;51(2):1-10.
doi:10.2298/sos1902163k .
Kljajević, Ljiljana M., Melichova, Z., Kisić, D.D., Nenadović, Miloš, Todorović, B.Ž., Pavlović, Vladimir, Nenadović, Snežana S., "The influence of alumino-silicate matrix composition on surface hydrophobic properties" in Science of Sintering, 51, no. 2 (2019):1-10,
https://doi.org/10.2298/sos1902163k . .
8
7
14

The Effect of Alkaline Activator Molarity and Aging Time on the Structure of Inorganic Polymer

Ivanović, Marija; Kljajević, Ljiljana M.; Gulicovski, Jelena; Todorović, Bratislav Ž.; Egelja, Adela; Pavlović, Vladimir B.; Nenadović, Snežana S.

(Belgrade : Serbian Academy of Sciences and Arts, 2018)

TY  - CONF
AU  - Ivanović, Marija
AU  - Kljajević, Ljiljana M.
AU  - Gulicovski, Jelena
AU  - Todorović, Bratislav Ž.
AU  - Egelja, Adela
AU  - Pavlović, Vladimir B.
AU  - Nenadović, Snežana S.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/3630
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5724
AB  - The goal of this research was to produce an environmental friendly, energy saving inorganic polymer using a metakaolin as a precursor. The clean technology which conserve the natural environment was employed for the production of these materials. The used kaolinite is clay obtained from Rudovci, Lazarevac, Serbia. Physicochemical properties of kaolin were investigated in previous work by Nenadović et al. [1]. Metakaolin (MK) was prepared by calcining kaolinite at 750 °C for 1 h. The influence of alkali activation, i.e. different concentration of NaOH as a component of alkali activator mixture on the process of polymerization of metakaolin is investigated. The alkaline solution was prepared from sodium silicate and 2M, 4M, 6M and 8 M NaOH (analytical grade) (volume ratio Na2SiO3/NaOH = 1.6). The inorganic polymer (IP) samples were formed from metakaolin and the four different alkaline solution (solid/liquid ratio was about 1), which were mixed for 15 min and then left at room temperature for one day. Finally, the mixture was kept in a sample drying oven for 2 days at 60 °C. Process of aging time of inorganic polymer samples at 7th, 14th, 21st and 28th days is followed by some analytical methods (XRD, FTIR). X-ray diffraction (XRD) and Fourier transformation infrared spectroscopy (FTIR) were used for characterization of metakaolin and metakaolin based inorganic polymers. After 28th days when the aging time were finished, on the surface of the samples were used scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS). XRD analysis almost of all inorganic polymer samples revealed their amorphouslike structure with the position of an amorphous halo in the range 18°-32°, which indicates short range ordering of the reference sample with crystalline admixture of SiO2 (α-quartz, ICSD 89). The FTIR spectra of all samples shows a strong peak at ∼1000 cm−1 which is associated with Si–O–Si asymmetric stretching vibrations and is the finger print of the geopolymerization [2,3]. The FT-IR results show a shift of the Si-O or Si-O-X bands as the molarity of activator increasing during polymerization process, where X can be Si or Al. Both methods and XRD, as well as FTIR, show greater sensitivity to monitoring the effects of molarity, than the aging time within the same molarity to structural changes in inorganic polymer. SEM micrographs (Fig.1) showed a denser matrix, and a lower content of unreacted metakaolin particles due to increasing of molarity of NaOH. Structural reorganization of inorganic polymer samples occurs during the curing or aging in accordance with a polymerization mechanism.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
T1  - The Effect of Alkaline Activator Molarity and Aging Time on the Structure of Inorganic Polymer
EP  - 206
SP  - 204
UR  - https://hdl.handle.net/21.15107/rcub_dais_3630
ER  - 
@conference{
author = "Ivanović, Marija and Kljajević, Ljiljana M. and Gulicovski, Jelena and Todorović, Bratislav Ž. and Egelja, Adela and Pavlović, Vladimir B. and Nenadović, Snežana S.",
year = "2018",
abstract = "The goal of this research was to produce an environmental friendly, energy saving inorganic polymer using a metakaolin as a precursor. The clean technology which conserve the natural environment was employed for the production of these materials. The used kaolinite is clay obtained from Rudovci, Lazarevac, Serbia. Physicochemical properties of kaolin were investigated in previous work by Nenadović et al. [1]. Metakaolin (MK) was prepared by calcining kaolinite at 750 °C for 1 h. The influence of alkali activation, i.e. different concentration of NaOH as a component of alkali activator mixture on the process of polymerization of metakaolin is investigated. The alkaline solution was prepared from sodium silicate and 2M, 4M, 6M and 8 M NaOH (analytical grade) (volume ratio Na2SiO3/NaOH = 1.6). The inorganic polymer (IP) samples were formed from metakaolin and the four different alkaline solution (solid/liquid ratio was about 1), which were mixed for 15 min and then left at room temperature for one day. Finally, the mixture was kept in a sample drying oven for 2 days at 60 °C. Process of aging time of inorganic polymer samples at 7th, 14th, 21st and 28th days is followed by some analytical methods (XRD, FTIR). X-ray diffraction (XRD) and Fourier transformation infrared spectroscopy (FTIR) were used for characterization of metakaolin and metakaolin based inorganic polymers. After 28th days when the aging time were finished, on the surface of the samples were used scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS). XRD analysis almost of all inorganic polymer samples revealed their amorphouslike structure with the position of an amorphous halo in the range 18°-32°, which indicates short range ordering of the reference sample with crystalline admixture of SiO2 (α-quartz, ICSD 89). The FTIR spectra of all samples shows a strong peak at ∼1000 cm−1 which is associated with Si–O–Si asymmetric stretching vibrations and is the finger print of the geopolymerization [2,3]. The FT-IR results show a shift of the Si-O or Si-O-X bands as the molarity of activator increasing during polymerization process, where X can be Si or Al. Both methods and XRD, as well as FTIR, show greater sensitivity to monitoring the effects of molarity, than the aging time within the same molarity to structural changes in inorganic polymer. SEM micrographs (Fig.1) showed a denser matrix, and a lower content of unreacted metakaolin particles due to increasing of molarity of NaOH. Structural reorganization of inorganic polymer samples occurs during the curing or aging in accordance with a polymerization mechanism.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia",
title = "The Effect of Alkaline Activator Molarity and Aging Time on the Structure of Inorganic Polymer",
pages = "206-204",
url = "https://hdl.handle.net/21.15107/rcub_dais_3630"
}
Ivanović, M., Kljajević, L. M., Gulicovski, J., Todorović, B. Ž., Egelja, A., Pavlović, V. B.,& Nenadović, S. S.. (2018). The Effect of Alkaline Activator Molarity and Aging Time on the Structure of Inorganic Polymer. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia
Belgrade : Serbian Academy of Sciences and Arts., 204-206.
https://hdl.handle.net/21.15107/rcub_dais_3630
Ivanović M, Kljajević LM, Gulicovski J, Todorović BŽ, Egelja A, Pavlović VB, Nenadović SS. The Effect of Alkaline Activator Molarity and Aging Time on the Structure of Inorganic Polymer. in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia. 2018;:204-206.
https://hdl.handle.net/21.15107/rcub_dais_3630 .
Ivanović, Marija, Kljajević, Ljiljana M., Gulicovski, Jelena, Todorović, Bratislav Ž., Egelja, Adela, Pavlović, Vladimir B., Nenadović, Snežana S., "The Effect of Alkaline Activator Molarity and Aging Time on the Structure of Inorganic Polymer" in Program and Book of Abstracts / First International Conference on Electron Microscopy of Nanostructures ELMINA 2018, August 27-29, 2018, Belgrade, Serbia (2018):204-206,
https://hdl.handle.net/21.15107/rcub_dais_3630 .

Effect of Alkaline Activator Properties on Structure of Metakaolin-Based Geopolymer Samples

Ivanović, Marija; Mladenović, Nataša; Gulicovski, Jelena; Pavlović, Vladimir B.; Pavlović, Vera P.; Kljajević, Ljiljana M.; Nenadović, Snežana S.

(Belgrade : Serbian Ceramic Society, 2018)

TY  - CONF
AU  - Ivanović, Marija
AU  - Mladenović, Nataša
AU  - Gulicovski, Jelena
AU  - Pavlović, Vladimir B.
AU  - Pavlović, Vera P.
AU  - Kljajević, Ljiljana M.
AU  - Nenadović, Snežana S.
PY  - 2018
UR  - http://dais.sanu.ac.rs/123456789/4116
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5732
AB  - Considering geopolymers as inorganic polymers, they are actually amorphous network of interlinked silicate and aluminate groups, so they could be prospective ceramic precursors for materials with defined dimensions obtained by casting and firing, but not from powder processing. In this research, the starting material is metakaolin, which was obtained by calcining domes tic kaolinite clay. Initially, four series of alkaline activators of NaOH and sodium silicate have been used. Activators present the mixtures of Na2SiO3 and solutions of NaOH, of different molarities 2M, 4M, 6M and 8M. The prepared geopolymer slurries were cast into the designated near shape at room temperature and after that at 60oC. In fact, the post-synthesis curing process (28 days) has an important role in the obtaining good characteristics of geopolymers. Densities, viscosities and refractive index of alkaline activators were determined over the temperature range 15-60oC of process of geopolymerizations. Based on the obtained results of investigated parameters have been selected to predict the properties of materials. All geopolymer samples were characterized by XRD, FTIR, SEM/EDS analysis and Raman spectroscopy providing complementary and valuable information of the investigated materials. This route of ceramics production has advantages associated with producing an environmental friendly, energy saving, clean new technology of geopolymer materials.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
T1  - Effect of Alkaline Activator Properties on Structure of Metakaolin-Based Geopolymer Samples
EP  - 74
SP  - 73
UR  - https://hdl.handle.net/21.15107/rcub_dais_4116
ER  - 
@conference{
author = "Ivanović, Marija and Mladenović, Nataša and Gulicovski, Jelena and Pavlović, Vladimir B. and Pavlović, Vera P. and Kljajević, Ljiljana M. and Nenadović, Snežana S.",
year = "2018",
abstract = "Considering geopolymers as inorganic polymers, they are actually amorphous network of interlinked silicate and aluminate groups, so they could be prospective ceramic precursors for materials with defined dimensions obtained by casting and firing, but not from powder processing. In this research, the starting material is metakaolin, which was obtained by calcining domes tic kaolinite clay. Initially, four series of alkaline activators of NaOH and sodium silicate have been used. Activators present the mixtures of Na2SiO3 and solutions of NaOH, of different molarities 2M, 4M, 6M and 8M. The prepared geopolymer slurries were cast into the designated near shape at room temperature and after that at 60oC. In fact, the post-synthesis curing process (28 days) has an important role in the obtaining good characteristics of geopolymers. Densities, viscosities and refractive index of alkaline activators were determined over the temperature range 15-60oC of process of geopolymerizations. Based on the obtained results of investigated parameters have been selected to predict the properties of materials. All geopolymer samples were characterized by XRD, FTIR, SEM/EDS analysis and Raman spectroscopy providing complementary and valuable information of the investigated materials. This route of ceramics production has advantages associated with producing an environmental friendly, energy saving, clean new technology of geopolymer materials.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018",
title = "Effect of Alkaline Activator Properties on Structure of Metakaolin-Based Geopolymer Samples",
pages = "74-73",
url = "https://hdl.handle.net/21.15107/rcub_dais_4116"
}
Ivanović, M., Mladenović, N., Gulicovski, J., Pavlović, V. B., Pavlović, V. P., Kljajević, L. M.,& Nenadović, S. S.. (2018). Effect of Alkaline Activator Properties on Structure of Metakaolin-Based Geopolymer Samples. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018
Belgrade : Serbian Ceramic Society., 73-74.
https://hdl.handle.net/21.15107/rcub_dais_4116
Ivanović M, Mladenović N, Gulicovski J, Pavlović VB, Pavlović VP, Kljajević LM, Nenadović SS. Effect of Alkaline Activator Properties on Structure of Metakaolin-Based Geopolymer Samples. in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018. 2018;:73-74.
https://hdl.handle.net/21.15107/rcub_dais_4116 .
Ivanović, Marija, Mladenović, Nataša, Gulicovski, Jelena, Pavlović, Vladimir B., Pavlović, Vera P., Kljajević, Ljiljana M., Nenadović, Snežana S., "Effect of Alkaline Activator Properties on Structure of Metakaolin-Based Geopolymer Samples" in Program and the Book of Abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application VII : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 17-19 September 2018 (2018):73-74,
https://hdl.handle.net/21.15107/rcub_dais_4116 .

Composition of red mud and/or metakaolin-based modified geopolymers

Vukčević, Mira; Bošković, Ivana; Nenadović, Snežana S.; Mirković, Miljana M.; Čalija, Bojan; Pavlović, Vladimir B.; Kljajević, Ljiljana M.

(Belgrade : Materials Research Society of Serbia, 2017)

TY  - CONF
AU  - Vukčević, Mira
AU  - Bošković, Ivana
AU  - Nenadović, Snežana S.
AU  - Mirković, Miljana M.
AU  - Čalija, Bojan
AU  - Pavlović, Vladimir B.
AU  - Kljajević, Ljiljana M.
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/15438
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5721
AB  - There is potential use of red mud for synthesis of inorganic polymeric materials through a geopolymerization process as an alternative in the sectors of construction and building materials. By introducing of inorganic and organic modificators of microstructure (calcium hydroxide, bifunctional epoxy resins, or various types of alkoxylanes) during the geopolymer synthesis the enhanced values of ductility and strength can be obtained. Research was performed on alumosilicate material (red mud and metakaolin) and alkali activator raw mixture with defined quantity of modificator. The best sinthesys conditions were identified. Post-synthesis curing also play important role in obtaining of good-performing geopolymers. Characteristics of geopolymers were defined by measuring of compressive strength, N2-physisorption, as well as by SEM analysis, X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). In addition the lower value of zeta potential was identified as the assisting factor for the specific structure domains formation (within the certain range of pH) accompanied by the high compressive strength.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
T1  - Composition of red mud and/or metakaolin-based modified geopolymers
EP  - 72
SP  - 72
UR  - https://hdl.handle.net/21.15107/rcub_dais_15438
ER  - 
@conference{
author = "Vukčević, Mira and Bošković, Ivana and Nenadović, Snežana S. and Mirković, Miljana M. and Čalija, Bojan and Pavlović, Vladimir B. and Kljajević, Ljiljana M.",
year = "2017",
abstract = "There is potential use of red mud for synthesis of inorganic polymeric materials through a geopolymerization process as an alternative in the sectors of construction and building materials. By introducing of inorganic and organic modificators of microstructure (calcium hydroxide, bifunctional epoxy resins, or various types of alkoxylanes) during the geopolymer synthesis the enhanced values of ductility and strength can be obtained. Research was performed on alumosilicate material (red mud and metakaolin) and alkali activator raw mixture with defined quantity of modificator. The best sinthesys conditions were identified. Post-synthesis curing also play important role in obtaining of good-performing geopolymers. Characteristics of geopolymers were defined by measuring of compressive strength, N2-physisorption, as well as by SEM analysis, X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). In addition the lower value of zeta potential was identified as the assisting factor for the specific structure domains formation (within the certain range of pH) accompanied by the high compressive strength.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017",
title = "Composition of red mud and/or metakaolin-based modified geopolymers",
pages = "72-72",
url = "https://hdl.handle.net/21.15107/rcub_dais_15438"
}
Vukčević, M., Bošković, I., Nenadović, S. S., Mirković, M. M., Čalija, B., Pavlović, V. B.,& Kljajević, L. M.. (2017). Composition of red mud and/or metakaolin-based modified geopolymers. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
Belgrade : Materials Research Society of Serbia., 72-72.
https://hdl.handle.net/21.15107/rcub_dais_15438
Vukčević M, Bošković I, Nenadović SS, Mirković MM, Čalija B, Pavlović VB, Kljajević LM. Composition of red mud and/or metakaolin-based modified geopolymers. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017. 2017;:72-72.
https://hdl.handle.net/21.15107/rcub_dais_15438 .
Vukčević, Mira, Bošković, Ivana, Nenadović, Snežana S., Mirković, Miljana M., Čalija, Bojan, Pavlović, Vladimir B., Kljajević, Ljiljana M., "Composition of red mud and/or metakaolin-based modified geopolymers" in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017 (2017):72-72,
https://hdl.handle.net/21.15107/rcub_dais_15438 .

Structure analysis of geopolymers synthesized from clay originated from Serbia

Nenadović, Snežana S.; Kljajević, Ljiljana M.; Nesić, Maja A.; Petković, Marijana Z.; Trivunac, Katarina V.; Pavlović, Vladimir

(Springer, New York, 2017)

TY  - JOUR
AU  - Nenadović, Snežana S.
AU  - Kljajević, Ljiljana M.
AU  - Nesić, Maja A.
AU  - Petković, Marijana Z.
AU  - Trivunac, Katarina V.
AU  - Pavlović, Vladimir
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4365
AB  - The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), alpha-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.
PB  - Springer, New York
T2  - Environmental Earth Sciences
T1  - Structure analysis of geopolymers synthesized from clay originated from Serbia
IS  - 2
VL  - 76
DO  - 10.1007/s12665-016-6360-4
ER  - 
@article{
author = "Nenadović, Snežana S. and Kljajević, Ljiljana M. and Nesić, Maja A. and Petković, Marijana Z. and Trivunac, Katarina V. and Pavlović, Vladimir",
year = "2017",
abstract = "The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), alpha-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.",
publisher = "Springer, New York",
journal = "Environmental Earth Sciences",
title = "Structure analysis of geopolymers synthesized from clay originated from Serbia",
number = "2",
volume = "76",
doi = "10.1007/s12665-016-6360-4"
}
Nenadović, S. S., Kljajević, L. M., Nesić, M. A., Petković, M. Z., Trivunac, K. V.,& Pavlović, V.. (2017). Structure analysis of geopolymers synthesized from clay originated from Serbia. in Environmental Earth Sciences
Springer, New York., 76(2).
https://doi.org/10.1007/s12665-016-6360-4
Nenadović SS, Kljajević LM, Nesić MA, Petković MZ, Trivunac KV, Pavlović V. Structure analysis of geopolymers synthesized from clay originated from Serbia. in Environmental Earth Sciences. 2017;76(2).
doi:10.1007/s12665-016-6360-4 .
Nenadović, Snežana S., Kljajević, Ljiljana M., Nesić, Maja A., Petković, Marijana Z., Trivunac, Katarina V., Pavlović, Vladimir, "Structure analysis of geopolymers synthesized from clay originated from Serbia" in Environmental Earth Sciences, 76, no. 2 (2017),
https://doi.org/10.1007/s12665-016-6360-4 . .
1
21
14
25

Structural and chemical properties of thermally treated geopolymer samples

Kljajević, Ljiljana M.; Nenadović, Snežana S.; Nenadović, Miloš; Bundaleski, Nenad K.; Todorović, Bratislav Z.; Pavlović, Vladimir; Rakocević, Zlatko Lj.

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Kljajević, Ljiljana M.
AU  - Nenadović, Snežana S.
AU  - Nenadović, Miloš
AU  - Bundaleski, Nenad K.
AU  - Todorović, Bratislav Z.
AU  - Pavlović, Vladimir
AU  - Rakocević, Zlatko Lj.
PY  - 2017
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/4356
AB  - This article presents the results of the compositional, structural and morphological study of geopolymers synthesized from metakaolin and an alkali activator. The study involved the investigation of the structural and chemical properties of the geopolymer, in addition to thermally treated geopolymers up to 600 and 900 degrees C. The precursor of the geopolymer, and the geopolymer samples before and after the thermal treatment, were investigated by Fourier transformation infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and SEM analysis. The corrected average value of the ratio of silicon and aluminum in the geopolymer samples (SiGp:Al) is about 1.46, which suggests that the obtained geopolymer samples represent a mixture of roughly equal amounts of sialate and sialate-siloxo units. Annealing the geopolymer samples at 600 degrees C decreases the amount of Si-ONa bonds and induces the cross-linking of polymer changes. At the same time, other sodium containing alumino-silicate phases are created. The thermal treatment at 900 degrees C leads to a considerable reduction of oxygen and particularly sodium, followed by significant morphological changes i.e. formation of a complex porous structure. Additionally, a new semicrystaline phase appears. Both XRD and XPS results imply that this new phase may be nepheline and it is plausible that this phase begins to nucleate at temperatures below 900 degrees C.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Structural and chemical properties of thermally treated geopolymer samples
EP  - 6708
IS  - 9
SP  - 6700
VL  - 43
DO  - 10.1016/j.ceramint.2017.02.066
ER  - 
@article{
author = "Kljajević, Ljiljana M. and Nenadović, Snežana S. and Nenadović, Miloš and Bundaleski, Nenad K. and Todorović, Bratislav Z. and Pavlović, Vladimir and Rakocević, Zlatko Lj.",
year = "2017",
abstract = "This article presents the results of the compositional, structural and morphological study of geopolymers synthesized from metakaolin and an alkali activator. The study involved the investigation of the structural and chemical properties of the geopolymer, in addition to thermally treated geopolymers up to 600 and 900 degrees C. The precursor of the geopolymer, and the geopolymer samples before and after the thermal treatment, were investigated by Fourier transformation infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and SEM analysis. The corrected average value of the ratio of silicon and aluminum in the geopolymer samples (SiGp:Al) is about 1.46, which suggests that the obtained geopolymer samples represent a mixture of roughly equal amounts of sialate and sialate-siloxo units. Annealing the geopolymer samples at 600 degrees C decreases the amount of Si-ONa bonds and induces the cross-linking of polymer changes. At the same time, other sodium containing alumino-silicate phases are created. The thermal treatment at 900 degrees C leads to a considerable reduction of oxygen and particularly sodium, followed by significant morphological changes i.e. formation of a complex porous structure. Additionally, a new semicrystaline phase appears. Both XRD and XPS results imply that this new phase may be nepheline and it is plausible that this phase begins to nucleate at temperatures below 900 degrees C.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Structural and chemical properties of thermally treated geopolymer samples",
pages = "6708-6700",
number = "9",
volume = "43",
doi = "10.1016/j.ceramint.2017.02.066"
}
Kljajević, L. M., Nenadović, S. S., Nenadović, M., Bundaleski, N. K., Todorović, B. Z., Pavlović, V.,& Rakocević, Z. Lj.. (2017). Structural and chemical properties of thermally treated geopolymer samples. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(9), 6700-6708.
https://doi.org/10.1016/j.ceramint.2017.02.066
Kljajević LM, Nenadović SS, Nenadović M, Bundaleski NK, Todorović BZ, Pavlović V, Rakocević ZL. Structural and chemical properties of thermally treated geopolymer samples. in Ceramics International. 2017;43(9):6700-6708.
doi:10.1016/j.ceramint.2017.02.066 .
Kljajević, Ljiljana M., Nenadović, Snežana S., Nenadović, Miloš, Bundaleski, Nenad K., Todorović, Bratislav Z., Pavlović, Vladimir, Rakocević, Zlatko Lj., "Structural and chemical properties of thermally treated geopolymer samples" in Ceramics International, 43, no. 9 (2017):6700-6708,
https://doi.org/10.1016/j.ceramint.2017.02.066 . .
110
66
113

Cesium removal from aqueous solution by natural mineral clinoptilolite

Nenadović, Snežana S.; Kljajević, Ljiljana M.; Seslak, Bojan Z.; Obradović, Nina; Vukanac, Ivana S.; Pavlović, Vladimir

(Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd, 2014)

TY  - JOUR
AU  - Nenadović, Snežana S.
AU  - Kljajević, Ljiljana M.
AU  - Seslak, Bojan Z.
AU  - Obradović, Nina
AU  - Vukanac, Ivana S.
AU  - Pavlović, Vladimir
PY  - 2014
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3426
AB  - The aim of this study was to investigate the Cs+ ions sorption on natural minerals clinoptilolite. The analysis of clinoptilolite and clinoptilolite with adsorbed Cs+ ion was conducted by X-ray diffraction, scanning electron microscopy, X-ray fluorescence, and gamma spectrometry. The specific activity of naturally occurring radionuclides in clinoptilolite was determined by gamma spectrometry by using the HPGe semiconductor detector. Obtained activity concentrations ranged from 49 Bq/kg to 810 Bq/kg for K-40, 5.7 Bq/kg to 10 Bq/kg for U-238, 5.8 Bq/kg to 70 Bq/kg for Th-232(Ac-228), and the presence of artificial radionuclides was not detected (Cs-137  lt  0.02 Bq/kg). The study of the thermal decomposition of raw clinoptilolite and Cs adsorbed clinoptilolite by differential thermal analysis is presented in this paper. The activation energy of the reaction phase transformation of raw clinoptilolite is 156.7 kJ/mol, while Cs adsorbed clinoptilolite is 121.7 kJ/mol. The lower value of activation energy reaction of the phase transformation Cs adsorbed clinoptilolite indicates that Cs which is adsorbed destabilizes the crystal structure of clinoptilolite and thus facilitates the transition to the amorphous state.
PB  - Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd
T2  - Nuclear Technology & Radiation Protection
T1  - Cesium removal from aqueous solution by natural mineral clinoptilolite
EP  - 141
IS  - 2
SP  - 135
VL  - 29
DO  - 10.2298/NTRP1402135N
ER  - 
@article{
author = "Nenadović, Snežana S. and Kljajević, Ljiljana M. and Seslak, Bojan Z. and Obradović, Nina and Vukanac, Ivana S. and Pavlović, Vladimir",
year = "2014",
abstract = "The aim of this study was to investigate the Cs+ ions sorption on natural minerals clinoptilolite. The analysis of clinoptilolite and clinoptilolite with adsorbed Cs+ ion was conducted by X-ray diffraction, scanning electron microscopy, X-ray fluorescence, and gamma spectrometry. The specific activity of naturally occurring radionuclides in clinoptilolite was determined by gamma spectrometry by using the HPGe semiconductor detector. Obtained activity concentrations ranged from 49 Bq/kg to 810 Bq/kg for K-40, 5.7 Bq/kg to 10 Bq/kg for U-238, 5.8 Bq/kg to 70 Bq/kg for Th-232(Ac-228), and the presence of artificial radionuclides was not detected (Cs-137  lt  0.02 Bq/kg). The study of the thermal decomposition of raw clinoptilolite and Cs adsorbed clinoptilolite by differential thermal analysis is presented in this paper. The activation energy of the reaction phase transformation of raw clinoptilolite is 156.7 kJ/mol, while Cs adsorbed clinoptilolite is 121.7 kJ/mol. The lower value of activation energy reaction of the phase transformation Cs adsorbed clinoptilolite indicates that Cs which is adsorbed destabilizes the crystal structure of clinoptilolite and thus facilitates the transition to the amorphous state.",
publisher = "Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd",
journal = "Nuclear Technology & Radiation Protection",
title = "Cesium removal from aqueous solution by natural mineral clinoptilolite",
pages = "141-135",
number = "2",
volume = "29",
doi = "10.2298/NTRP1402135N"
}
Nenadović, S. S., Kljajević, L. M., Seslak, B. Z., Obradović, N., Vukanac, I. S.,& Pavlović, V.. (2014). Cesium removal from aqueous solution by natural mineral clinoptilolite. in Nuclear Technology & Radiation Protection
Univerzitet u Beogradu - Institut za nuklearne nauke Vinča, Beograd., 29(2), 135-141.
https://doi.org/10.2298/NTRP1402135N
Nenadović SS, Kljajević LM, Seslak BZ, Obradović N, Vukanac IS, Pavlović V. Cesium removal from aqueous solution by natural mineral clinoptilolite. in Nuclear Technology & Radiation Protection. 2014;29(2):135-141.
doi:10.2298/NTRP1402135N .
Nenadović, Snežana S., Kljajević, Ljiljana M., Seslak, Bojan Z., Obradović, Nina, Vukanac, Ivana S., Pavlović, Vladimir, "Cesium removal from aqueous solution by natural mineral clinoptilolite" in Nuclear Technology & Radiation Protection, 29, no. 2 (2014):135-141,
https://doi.org/10.2298/NTRP1402135N . .

Vertical distribution of natural radionuclides in soil: Assessment of external exposure of population in cultivated and undisturbed areas

Nenadović, Snežana S.; Nenadović, Miloš; Kljajević, Ljiljana M.; Vukanac, Ivana S.; Poznanović, Maja; Mihajlović-Radosavljević, Ana; Pavlović, Vladimir

(Elsevier, Amsterdam, 2012)

TY  - JOUR
AU  - Nenadović, Snežana S.
AU  - Nenadović, Miloš
AU  - Kljajević, Ljiljana M.
AU  - Vukanac, Ivana S.
AU  - Poznanović, Maja
AU  - Mihajlović-Radosavljević, Ana
AU  - Pavlović, Vladimir
PY  - 2012
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/2945
AB  - In the present work, naturally occurring radionuclides U-238, Th-232 and K-40 were measured in soil samples from the cultivated and undisturbed areas in Rudovci, municipality of Lazarevac, Serbia. There were three profiles, each profile divided into four horizons, giving the twelve soil samples. The specific activity of U-238, Th-232 and K-40 in soil and sediment samples was determined by gamma spectrometry using the HPGe semiconductor detector. Obtained activity concentrations ranged from 28.0 to 44.0 Bq/kg for U-238, from 59.4 to 71.4 Bq/kg for Th-232 and from 335.0 to 517.0 Bq/kg for K-40. The evaluation of the radiological hazards originated from U-238, Th-232 and K-40 in the samples, the absorbed dose rate (D) and the annual effective dose rate (E), calculated in accordance with the UNSCEAR 2000 report, are presented in this paper.
PB  - Elsevier, Amsterdam
T2  - Science of the Total Environment
T1  - Vertical distribution of natural radionuclides in soil: Assessment of external exposure of population in cultivated and undisturbed areas
EP  - 316
SP  - 309
VL  - 429
DO  - 10.1016/j.scitotenv.2012.04.054
ER  - 
@article{
author = "Nenadović, Snežana S. and Nenadović, Miloš and Kljajević, Ljiljana M. and Vukanac, Ivana S. and Poznanović, Maja and Mihajlović-Radosavljević, Ana and Pavlović, Vladimir",
year = "2012",
abstract = "In the present work, naturally occurring radionuclides U-238, Th-232 and K-40 were measured in soil samples from the cultivated and undisturbed areas in Rudovci, municipality of Lazarevac, Serbia. There were three profiles, each profile divided into four horizons, giving the twelve soil samples. The specific activity of U-238, Th-232 and K-40 in soil and sediment samples was determined by gamma spectrometry using the HPGe semiconductor detector. Obtained activity concentrations ranged from 28.0 to 44.0 Bq/kg for U-238, from 59.4 to 71.4 Bq/kg for Th-232 and from 335.0 to 517.0 Bq/kg for K-40. The evaluation of the radiological hazards originated from U-238, Th-232 and K-40 in the samples, the absorbed dose rate (D) and the annual effective dose rate (E), calculated in accordance with the UNSCEAR 2000 report, are presented in this paper.",
publisher = "Elsevier, Amsterdam",
journal = "Science of the Total Environment",
title = "Vertical distribution of natural radionuclides in soil: Assessment of external exposure of population in cultivated and undisturbed areas",
pages = "316-309",
volume = "429",
doi = "10.1016/j.scitotenv.2012.04.054"
}
Nenadović, S. S., Nenadović, M., Kljajević, L. M., Vukanac, I. S., Poznanović, M., Mihajlović-Radosavljević, A.,& Pavlović, V.. (2012). Vertical distribution of natural radionuclides in soil: Assessment of external exposure of population in cultivated and undisturbed areas. in Science of the Total Environment
Elsevier, Amsterdam., 429, 309-316.
https://doi.org/10.1016/j.scitotenv.2012.04.054
Nenadović SS, Nenadović M, Kljajević LM, Vukanac IS, Poznanović M, Mihajlović-Radosavljević A, Pavlović V. Vertical distribution of natural radionuclides in soil: Assessment of external exposure of population in cultivated and undisturbed areas. in Science of the Total Environment. 2012;429:309-316.
doi:10.1016/j.scitotenv.2012.04.054 .
Nenadović, Snežana S., Nenadović, Miloš, Kljajević, Ljiljana M., Vukanac, Ivana S., Poznanović, Maja, Mihajlović-Radosavljević, Ana, Pavlović, Vladimir, "Vertical distribution of natural radionuclides in soil: Assessment of external exposure of population in cultivated and undisturbed areas" in Science of the Total Environment, 429 (2012):309-316,
https://doi.org/10.1016/j.scitotenv.2012.04.054 . .
18
19
25

Structure and composition of soils

Nenadović, Snežana S.; Nenadović, Miloš; Kljajević, Ljiljana M.; Pavlović, Vladimir; Djordjević, Aleksandar; Matović, Branko

(Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad, 2010)

TY  - JOUR
AU  - Nenadović, Snežana S.
AU  - Nenadović, Miloš
AU  - Kljajević, Ljiljana M.
AU  - Pavlović, Vladimir
AU  - Djordjević, Aleksandar
AU  - Matović, Branko
PY  - 2010
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/2349
AB  - This paper presents a study of soils structure and composition using up to date technique, such as scanning electronic microscopy, atomic force microscopy, X-ray diffraction, X-ray fluorescence, as well as some other characterization methods. It was shown that soil particles have porous structure and dimensions in the range from several millimeters to several hundreds of nanometers and consist of different minerals such as kaolin, quartz and feldspate.
PB  - Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad
T2  - Processing and Application of Ceramics
T1  - Structure and composition of soils
EP  - 263
IS  - 4
SP  - 259
VL  - 4
UR  - https://hdl.handle.net/21.15107/rcub_agrospace_2349
ER  - 
@article{
author = "Nenadović, Snežana S. and Nenadović, Miloš and Kljajević, Ljiljana M. and Pavlović, Vladimir and Djordjević, Aleksandar and Matović, Branko",
year = "2010",
abstract = "This paper presents a study of soils structure and composition using up to date technique, such as scanning electronic microscopy, atomic force microscopy, X-ray diffraction, X-ray fluorescence, as well as some other characterization methods. It was shown that soil particles have porous structure and dimensions in the range from several millimeters to several hundreds of nanometers and consist of different minerals such as kaolin, quartz and feldspate.",
publisher = "Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Structure and composition of soils",
pages = "263-259",
number = "4",
volume = "4",
url = "https://hdl.handle.net/21.15107/rcub_agrospace_2349"
}
Nenadović, S. S., Nenadović, M., Kljajević, L. M., Pavlović, V., Djordjević, A.,& Matović, B.. (2010). Structure and composition of soils. in Processing and Application of Ceramics
Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad., 4(4), 259-263.
https://hdl.handle.net/21.15107/rcub_agrospace_2349
Nenadović SS, Nenadović M, Kljajević LM, Pavlović V, Djordjević A, Matović B. Structure and composition of soils. in Processing and Application of Ceramics. 2010;4(4):259-263.
https://hdl.handle.net/21.15107/rcub_agrospace_2349 .
Nenadović, Snežana S., Nenadović, Miloš, Kljajević, Ljiljana M., Pavlović, Vladimir, Djordjević, Aleksandar, Matović, Branko, "Structure and composition of soils" in Processing and Application of Ceramics, 4, no. 4 (2010):259-263,
https://hdl.handle.net/21.15107/rcub_agrospace_2349 .