TY  - JOUR
AU  - Ristić, Predrag
AU  - Todorović, Tamara R.
AU  - Blagojević, Vladimir A.
AU  - Klisurić, Olivera
AU  - Marjanović, Ivana
AU  - Hollo, Berta Barta
AU  - Vulić, Predrag J.
AU  - Gulea, Mihaela
AU  - Donnard, Morgan
AU  - Monge, Miguel
AU  - Rodriguez-Castillo, Maria
AU  - Lopez-de-Luzuriaga, Jose M.
AU  - Filipović, Nenad
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5281
AB  - Four silver-based coordination polymers, {[Ag(L)(2)](BF4)}(infinity) (1), {[Ag(H2BTC)(L)]center dot(H3BTC)}(infinity) (2), {[Ag-2(H2BTEC)(L)(2)]..3.33H(2)O}(infinity) (3), and [Ag(H(25)SSA)(L)](infinity) (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H(35)SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036-0.056 min(-1) range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet-singlet electronic excitations to the fluorescence, indicating that metal- intraligand transitions are responsible for luminescence in both complexes.
PB  - Amer Chemical Soc, Washington
T2  - Crystal Growth & Design
T1  - 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study
EP  - 4478
IS  - 7
SP  - 4461
VL  - 20
DO  - 10.1021/acs.cgd.0c00287
ER  - 

@article{
author = "Ristić, Predrag and Todorović, Tamara R. and Blagojević, Vladimir A. and Klisurić, Olivera and Marjanović, Ivana and Hollo, Berta Barta and Vulić, Predrag J. and Gulea, Mihaela and Donnard, Morgan and Monge, Miguel and Rodriguez-Castillo, Maria and Lopez-de-Luzuriaga, Jose M. and Filipović, Nenad",
year = "2020",
abstract = "Four silver-based coordination polymers, {[Ag(L)(2)](BF4)}(infinity) (1), {[Ag(H2BTC)(L)]center dot(H3BTC)}(infinity) (2), {[Ag-2(H2BTEC)(L)(2)]..3.33H(2)O}(infinity) (3), and [Ag(H(25)SSA)(L)](infinity) (4), were synthesized using thiomorpholine-4-carbonitrile (L) as the primary ligand and three aromatic polyoxoacids as coligands: trimesic (H3BTC), pyromellitic (H4BTEC), and 5-sulfosalicylic acid (H(35)SSA). Compounds 1 and 3 are two-dimensional, while 2 and 4 are one-dimensional. L acts as a bis-monodentate ligand, while the Ag(I) ion is three-coordinated in 2 and four-coordinated in all of the other compounds. The tetrahedral coordination of Ag(I) in 3 leads to an almost complete absence of intermolecular interactions with the metal center. All compounds show reasonable photocatalytic activity for photocatalytic degradation of mordant blue 9 dye, with reaction rates in the 0.036-0.056 min(-1) range. Changes in the reaction rates can be correlated with the type and coordination of the coligand. Complex 3 exhibits photoluminescence at 77 K, while 4 exhibits photoluminescence at both room temperature and 77 K. Luminescence lifetimes indicate electronic transitions of singlet parentage, where transitions are allowed. A TD-DFT study determined the contributions of individual singlet-singlet electronic excitations to the fluorescence, indicating that metal- intraligand transitions are responsible for luminescence in both complexes.",
publisher = "Amer Chemical Soc, Washington",
journal = "Crystal Growth & Design",
title = "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study",
pages = "4478-4461",
number = "7",
volume = "20",
doi = "10.1021/acs.cgd.0c00287"
}

Ristić, P., Todorović, T. R., Blagojević, V. A., Klisurić, O., Marjanović, I., Hollo, B. B., Vulić, P. J., Gulea, M., Donnard, M., Monge, M., Rodriguez-Castillo, M., Lopez-de-Luzuriaga, J. M.,& Filipović, N.. (2020). 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design
Amer Chemical Soc, Washington., 20(7), 4461-4478.
https://doi.org/10.1021/acs.cgd.0c00287

Ristić P, Todorović TR, Blagojević VA, Klisurić O, Marjanović I, Hollo BB, Vulić PJ, Gulea M, Donnard M, Monge M, Rodriguez-Castillo M, Lopez-de-Luzuriaga JM, Filipović N. 1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study. in Crystal Growth & Design. 2020;20(7):4461-4478.
doi:10.1021/acs.cgd.0c00287 .

Ristić, Predrag, Todorović, Tamara R., Blagojević, Vladimir A., Klisurić, Olivera, Marjanović, Ivana, Hollo, Berta Barta, Vulić, Predrag J., Gulea, Mihaela, Donnard, Morgan, Monge, Miguel, Rodriguez-Castillo, Maria, Lopez-de-Luzuriaga, Jose M., Filipović, Nenad, "1D and 2D Silver-Based Coordination Polymers with Thiomorpholine-4-carbonitrile and Aromatic Polyoxoacids as Coligands: Structure, Photocatalysis, Photoluminescence, and TD-DFT Study" in Crystal Growth & Design, 20, no. 7 (2020):4461-4478,
https://doi.org/10.1021/acs.cgd.0c00287 . .