Stošić, Dušan

Link to this page

Authority KeyName Variants
orcid::0000-0001-7949-3554
  • Stošić, Dušan (10)
Projects

Author's Bibliography

Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study

Bosnar, Sanja; Rac, Vladislav; Stošić, Dušan; Travert, Arnaud; Postole, Georgeta; Auroux, Aline; Škapin, Srečo; Damjanović-Vasilić, Ljiljana; Bronić, Josip; Du, Xuesen; Marković, Smilja; Pavlović, Vladimir; Rakić, Vesna

(Elsevier B.V., 2021)

TY  - JOUR
AU  - Bosnar, Sanja
AU  - Rac, Vladislav
AU  - Stošić, Dušan
AU  - Travert, Arnaud
AU  - Postole, Georgeta
AU  - Auroux, Aline
AU  - Škapin, Srečo
AU  - Damjanović-Vasilić, Ljiljana
AU  - Bronić, Josip
AU  - Du, Xuesen
AU  - Marković, Smilja
AU  - Pavlović, Vladimir
AU  - Rakić, Vesna
PY  - 2021
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5961
AB  - Dual templating approach, using hexadecyltrimethylammonium bromide (CTAB), was employed in an attempt to synthesize hierarchical ZSM-5 zeolite. Amount of mesoporogen and the duration of aging of the precursor were varied. Majority of the synthesis routes resulted in phase separation, yielding separate ZSM-5 and amorphous mesoporous material. The relative amounts of the two phases were dependent on the CTAB amount ratio and also significantly on the duration of precursor aging before CTAB addition. One particular combination of the two factors led to the formation of a homogeneous hierarchical form of ZSM-5 with leafy morphology, consisting of intergrown thin crystalline sheets which formed flower-like structures. The hierarchical ZSM-5 possessed significant microporous (≈95 m2/g) and highly developed mesoporous surface (≈470 m2/g), with a relatively broad distribution of mesopore sizes (<20 nm). The acidity of all samples was studied in detail. Isothermal microcalorimetry/volumetry of ammonia adsorption provided quantitative data on the number and distribution of strength of acidic sites. In situ FTIR of pyridine and collidine adsorption was used to quantify Brønsted and Lewis acid sites, and to provide information on their location - in the micropores or mesopores/external surface. The hierarchical ZSM-5 possessed both Lewis and Brønsted acidity, with Brønsted sites located mainly in the micropores. All samples were fully characterized using XRD, low temperature nitrogen adsorption, FESEM and EDS. The synthetic route used for obtaining the ZSM-5 zeolite with flower-like morphology is a simple strategy for preparing hierarchical ZSM-5 forms targeting enhanced diffusivity and accessibility of catalytically active sites.
PB  - Elsevier B.V.
T2  - Microporous and Mesoporous Materials
T1  - Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study
SP  - 111534
VL  - 329
DO  - 10.1016/j.micromeso.2021.111534
ER  - 
@article{
author = "Bosnar, Sanja and Rac, Vladislav and Stošić, Dušan and Travert, Arnaud and Postole, Georgeta and Auroux, Aline and Škapin, Srečo and Damjanović-Vasilić, Ljiljana and Bronić, Josip and Du, Xuesen and Marković, Smilja and Pavlović, Vladimir and Rakić, Vesna",
year = "2021",
abstract = "Dual templating approach, using hexadecyltrimethylammonium bromide (CTAB), was employed in an attempt to synthesize hierarchical ZSM-5 zeolite. Amount of mesoporogen and the duration of aging of the precursor were varied. Majority of the synthesis routes resulted in phase separation, yielding separate ZSM-5 and amorphous mesoporous material. The relative amounts of the two phases were dependent on the CTAB amount ratio and also significantly on the duration of precursor aging before CTAB addition. One particular combination of the two factors led to the formation of a homogeneous hierarchical form of ZSM-5 with leafy morphology, consisting of intergrown thin crystalline sheets which formed flower-like structures. The hierarchical ZSM-5 possessed significant microporous (≈95 m2/g) and highly developed mesoporous surface (≈470 m2/g), with a relatively broad distribution of mesopore sizes (<20 nm). The acidity of all samples was studied in detail. Isothermal microcalorimetry/volumetry of ammonia adsorption provided quantitative data on the number and distribution of strength of acidic sites. In situ FTIR of pyridine and collidine adsorption was used to quantify Brønsted and Lewis acid sites, and to provide information on their location - in the micropores or mesopores/external surface. The hierarchical ZSM-5 possessed both Lewis and Brønsted acidity, with Brønsted sites located mainly in the micropores. All samples were fully characterized using XRD, low temperature nitrogen adsorption, FESEM and EDS. The synthetic route used for obtaining the ZSM-5 zeolite with flower-like morphology is a simple strategy for preparing hierarchical ZSM-5 forms targeting enhanced diffusivity and accessibility of catalytically active sites.",
publisher = "Elsevier B.V.",
journal = "Microporous and Mesoporous Materials",
title = "Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study",
pages = "111534",
volume = "329",
doi = "10.1016/j.micromeso.2021.111534"
}
Bosnar, S., Rac, V., Stošić, D., Travert, A., Postole, G., Auroux, A., Škapin, S., Damjanović-Vasilić, L., Bronić, J., Du, X., Marković, S., Pavlović, V.,& Rakić, V.. (2021). Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study. in Microporous and Mesoporous Materials
Elsevier B.V.., 329, 111534.
https://doi.org/10.1016/j.micromeso.2021.111534
Bosnar S, Rac V, Stošić D, Travert A, Postole G, Auroux A, Škapin S, Damjanović-Vasilić L, Bronić J, Du X, Marković S, Pavlović V, Rakić V. Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study. in Microporous and Mesoporous Materials. 2021;329:111534.
doi:10.1016/j.micromeso.2021.111534 .
Bosnar, Sanja, Rac, Vladislav, Stošić, Dušan, Travert, Arnaud, Postole, Georgeta, Auroux, Aline, Škapin, Srečo, Damjanović-Vasilić, Ljiljana, Bronić, Josip, Du, Xuesen, Marković, Smilja, Pavlović, Vladimir, Rakić, Vesna, "Overcoming phase separation in dual templating: A homogeneous hierarchical ZSM-5 zeolite with flower-like morphology, synthesis and in-depth acidity study" in Microporous and Mesoporous Materials, 329 (2021):111534,
https://doi.org/10.1016/j.micromeso.2021.111534 . .
3
13
1
12

Enhanced accessibility of active sites in hierarchical ZSM-5 zeolite for removal of pharmaceutically active substances: Adsorption and microcalorimetric study

Rac, Vladislav; Rakić, Vesna; Stošić, Dušan; Pavlović, Vladimir; Bosnar, Sanja; Auroux, Aline

(Elsevier, Amsterdam, 2020)

TY  - JOUR
AU  - Rac, Vladislav
AU  - Rakić, Vesna
AU  - Stošić, Dušan
AU  - Pavlović, Vladimir
AU  - Bosnar, Sanja
AU  - Auroux, Aline
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5365
AB  - The possibility of removal of pharmaceutically active substances, atenolol, diclofenac sodium and salicylic acid, from water solutions using hierarchical form of zeolite ZSM-5 is investigated in this paper. Mesopore formation in ZSM-5 was achieved using alkaline treatment. Zeolitic samples were characterized by X-ray diffraction, low temperature nitrogen adsorption, solid-state 27A1 MAS NMR, point of zero charge determination and microcalorimetry - volumetry of ammonia adsorption. Adsorption isotherms of pharmaceutically active substances were obtained and liquid calorimetric experiments were used to evaluate the strength of interactions. The capacity for salicylic acid adsorption measured for the mesoporous sample did not significantly differ from the results obtained for the parent ZSM-5. However, in the case of atenolol and diclofenac sodium, mesoporous ZSM-5 exhibited increased adsorption capacities. Calorimetric data revealed higher heats of atenolol adsorption on mesoporous ZSM-5, compared to the parent. Based on similar acidity and surface charge determined for the two samples, our results show that geometry and dimensions of both zeolite pores and adsorbing molecules play a crucial role in the studied adsorption processes and that tailoring ZSM-5 porosity by desilication can be used to expand its applicability in depollution processes.
PB  - Elsevier, Amsterdam
T2  - Arabian Journal of Chemistry
T1  - Enhanced accessibility of active sites in hierarchical ZSM-5 zeolite for removal of pharmaceutically active substances: Adsorption and microcalorimetric study
EP  - 1954
IS  - 1
SP  - 1945
VL  - 13
DO  - 10.1016/j.arabjc.2018.02.012
ER  - 
@article{
author = "Rac, Vladislav and Rakić, Vesna and Stošić, Dušan and Pavlović, Vladimir and Bosnar, Sanja and Auroux, Aline",
year = "2020",
abstract = "The possibility of removal of pharmaceutically active substances, atenolol, diclofenac sodium and salicylic acid, from water solutions using hierarchical form of zeolite ZSM-5 is investigated in this paper. Mesopore formation in ZSM-5 was achieved using alkaline treatment. Zeolitic samples were characterized by X-ray diffraction, low temperature nitrogen adsorption, solid-state 27A1 MAS NMR, point of zero charge determination and microcalorimetry - volumetry of ammonia adsorption. Adsorption isotherms of pharmaceutically active substances were obtained and liquid calorimetric experiments were used to evaluate the strength of interactions. The capacity for salicylic acid adsorption measured for the mesoporous sample did not significantly differ from the results obtained for the parent ZSM-5. However, in the case of atenolol and diclofenac sodium, mesoporous ZSM-5 exhibited increased adsorption capacities. Calorimetric data revealed higher heats of atenolol adsorption on mesoporous ZSM-5, compared to the parent. Based on similar acidity and surface charge determined for the two samples, our results show that geometry and dimensions of both zeolite pores and adsorbing molecules play a crucial role in the studied adsorption processes and that tailoring ZSM-5 porosity by desilication can be used to expand its applicability in depollution processes.",
publisher = "Elsevier, Amsterdam",
journal = "Arabian Journal of Chemistry",
title = "Enhanced accessibility of active sites in hierarchical ZSM-5 zeolite for removal of pharmaceutically active substances: Adsorption and microcalorimetric study",
pages = "1954-1945",
number = "1",
volume = "13",
doi = "10.1016/j.arabjc.2018.02.012"
}
Rac, V., Rakić, V., Stošić, D., Pavlović, V., Bosnar, S.,& Auroux, A.. (2020). Enhanced accessibility of active sites in hierarchical ZSM-5 zeolite for removal of pharmaceutically active substances: Adsorption and microcalorimetric study. in Arabian Journal of Chemistry
Elsevier, Amsterdam., 13(1), 1945-1954.
https://doi.org/10.1016/j.arabjc.2018.02.012
Rac V, Rakić V, Stošić D, Pavlović V, Bosnar S, Auroux A. Enhanced accessibility of active sites in hierarchical ZSM-5 zeolite for removal of pharmaceutically active substances: Adsorption and microcalorimetric study. in Arabian Journal of Chemistry. 2020;13(1):1945-1954.
doi:10.1016/j.arabjc.2018.02.012 .
Rac, Vladislav, Rakić, Vesna, Stošić, Dušan, Pavlović, Vladimir, Bosnar, Sanja, Auroux, Aline, "Enhanced accessibility of active sites in hierarchical ZSM-5 zeolite for removal of pharmaceutically active substances: Adsorption and microcalorimetric study" in Arabian Journal of Chemistry, 13, no. 1 (2020):1945-1954,
https://doi.org/10.1016/j.arabjc.2018.02.012 . .
17
8
17

Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction

Rac, Vladislav; Rakić, Vesna; Stošić, Dušan; Otman, Otman; Auroux, Aline

(Elsevier Science Bv, Amsterdam, 2014)

TY  - JOUR
AU  - Rac, Vladislav
AU  - Rakić, Vesna
AU  - Stošić, Dušan
AU  - Otman, Otman
AU  - Auroux, Aline
PY  - 2014
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3414
AB  - The acidity of hierarchical USY, Beta and ZSM-5 zeolites obtained by alkaline treatment was investigated. Samples were characterized by low temperature nitrogen adsorption, X ray diffraction and solid-state (27)AI MAS NMR. Acidity of parent and mesoporous samples was estimated through the adsorption of typical probe molecules - measurements were conducted in both gas phase (microcalorimetry/volumetry of ammonia adsorption, FTIR spectrometry of pyridine adsorption/desorption) and aqueous phase (calorimetry of phenylethylamine adsorption). Quantitative distributions in strength of the acid sites were determined, as well as acid sites concentrations. No significant changes in total acidity were detected for ZSM-5. Acid sites strength was decreased in modified Beta and USY zeolites. The samples were probed as catalysts for the dehydration of fructose. Higher selectivities towards 5-hydroxymethylfurfural were detected for all modified zeolites, compared to the parent ones.
PB  - Elsevier Science Bv, Amsterdam
T2  - Microporous and Mesoporous Materials
T1  - Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction
EP  - 134
SP  - 126
VL  - 194
DO  - 10.1016/j.micromeso.2014.04.003
ER  - 
@article{
author = "Rac, Vladislav and Rakić, Vesna and Stošić, Dušan and Otman, Otman and Auroux, Aline",
year = "2014",
abstract = "The acidity of hierarchical USY, Beta and ZSM-5 zeolites obtained by alkaline treatment was investigated. Samples were characterized by low temperature nitrogen adsorption, X ray diffraction and solid-state (27)AI MAS NMR. Acidity of parent and mesoporous samples was estimated through the adsorption of typical probe molecules - measurements were conducted in both gas phase (microcalorimetry/volumetry of ammonia adsorption, FTIR spectrometry of pyridine adsorption/desorption) and aqueous phase (calorimetry of phenylethylamine adsorption). Quantitative distributions in strength of the acid sites were determined, as well as acid sites concentrations. No significant changes in total acidity were detected for ZSM-5. Acid sites strength was decreased in modified Beta and USY zeolites. The samples were probed as catalysts for the dehydration of fructose. Higher selectivities towards 5-hydroxymethylfurfural were detected for all modified zeolites, compared to the parent ones.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Microporous and Mesoporous Materials",
title = "Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction",
pages = "134-126",
volume = "194",
doi = "10.1016/j.micromeso.2014.04.003"
}
Rac, V., Rakić, V., Stošić, D., Otman, O.,& Auroux, A.. (2014). Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction. in Microporous and Mesoporous Materials
Elsevier Science Bv, Amsterdam., 194, 126-134.
https://doi.org/10.1016/j.micromeso.2014.04.003
Rac V, Rakić V, Stošić D, Otman O, Auroux A. Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction. in Microporous and Mesoporous Materials. 2014;194:126-134.
doi:10.1016/j.micromeso.2014.04.003 .
Rac, Vladislav, Rakić, Vesna, Stošić, Dušan, Otman, Otman, Auroux, Aline, "Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction" in Microporous and Mesoporous Materials, 194 (2014):126-134,
https://doi.org/10.1016/j.micromeso.2014.04.003 . .
6
69
53
69

Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides

Stošić, Dušan; Bennici, Simona; Pavlović, Vladimir; Rakić, Vesna; Auroux, Aline

(Elsevier Science Sa, Lausanne, 2014)

TY  - JOUR
AU  - Stošić, Dušan
AU  - Bennici, Simona
AU  - Pavlović, Vladimir
AU  - Rakić, Vesna
AU  - Auroux, Aline
PY  - 2014
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3409
AB  - Mesoporous Nb2O5 MeO2 (Me = Ti, Zr, Ce) mixed oxides were successfully prepared using evaporation-induced self-assembly (EISA) method. The structural and textural properties of these materials have been fully characterized using appropriate techniques (low-temperature adsorption-desorption of nitrogen, thermogravimetric analysis, X-ray diffraction analysis (XRD) transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Raman spectroscopy). Acid-base properties were estimated by adsorption microcalorimetry of NH3 and SO2 molecules in order to determine the population, strength and strength distribution of acidic or basic sites. Formation of mesoporous structure was confirmed by the results of XRD, TEM and BET techniques. Results of adsorption microcalorimetry technique showed that the type of transition metal oxide added to niobia has a decisive role for acidic-basic character of investigated mixed oxides. Among the investigated mixed oxide formulations only Nb2O5-CeO2 was amphoteric, while the other samples showed prominent acidic character. All the investigated materials are catalytically active in fructose dehydration; conversion of fructose and selectivity to 5-hydroxymethylfurfural (5-HMF) and levulinic acid (LA) are proved to be dependant on the number of acidic sites on the surface of catalysts. Furthermore, presence of the basic sites on the surface of the catalyst decreases the activity in the fructose dehydration reaction, as in the case of Nb2O5-CeO2 sample.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Chemistry and Physics
T1  - Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides
EP  - 345
IS  - 3
SP  - 337
VL  - 146
DO  - 10.1016/j.matchemphys.2014.03.033
ER  - 
@article{
author = "Stošić, Dušan and Bennici, Simona and Pavlović, Vladimir and Rakić, Vesna and Auroux, Aline",
year = "2014",
abstract = "Mesoporous Nb2O5 MeO2 (Me = Ti, Zr, Ce) mixed oxides were successfully prepared using evaporation-induced self-assembly (EISA) method. The structural and textural properties of these materials have been fully characterized using appropriate techniques (low-temperature adsorption-desorption of nitrogen, thermogravimetric analysis, X-ray diffraction analysis (XRD) transmission electron microscopy (TEM), scanning electron microscopy (SEM) and Raman spectroscopy). Acid-base properties were estimated by adsorption microcalorimetry of NH3 and SO2 molecules in order to determine the population, strength and strength distribution of acidic or basic sites. Formation of mesoporous structure was confirmed by the results of XRD, TEM and BET techniques. Results of adsorption microcalorimetry technique showed that the type of transition metal oxide added to niobia has a decisive role for acidic-basic character of investigated mixed oxides. Among the investigated mixed oxide formulations only Nb2O5-CeO2 was amphoteric, while the other samples showed prominent acidic character. All the investigated materials are catalytically active in fructose dehydration; conversion of fructose and selectivity to 5-hydroxymethylfurfural (5-HMF) and levulinic acid (LA) are proved to be dependant on the number of acidic sites on the surface of catalysts. Furthermore, presence of the basic sites on the surface of the catalyst decreases the activity in the fructose dehydration reaction, as in the case of Nb2O5-CeO2 sample.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Chemistry and Physics",
title = "Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides",
pages = "345-337",
number = "3",
volume = "146",
doi = "10.1016/j.matchemphys.2014.03.033"
}
Stošić, D., Bennici, S., Pavlović, V., Rakić, V.,& Auroux, A.. (2014). Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides. in Materials Chemistry and Physics
Elsevier Science Sa, Lausanne., 146(3), 337-345.
https://doi.org/10.1016/j.matchemphys.2014.03.033
Stošić D, Bennici S, Pavlović V, Rakić V, Auroux A. Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides. in Materials Chemistry and Physics. 2014;146(3):337-345.
doi:10.1016/j.matchemphys.2014.03.033 .
Stošić, Dušan, Bennici, Simona, Pavlović, Vladimir, Rakić, Vesna, Auroux, Aline, "Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides" in Materials Chemistry and Physics, 146, no. 3 (2014):337-345,
https://doi.org/10.1016/j.matchemphys.2014.03.033 . .
36
24
34

Influence of the desilication process on the acidity of HZSM-5 zeolite

Rac, Vladislav; Rakić, Vesna; Miladinović, Zoran; Stošić, Dušan; Auroux, Aline

(Elsevier, Amsterdam, 2013)

TY  - JOUR
AU  - Rac, Vladislav
AU  - Rakić, Vesna
AU  - Miladinović, Zoran
AU  - Stošić, Dušan
AU  - Auroux, Aline
PY  - 2013
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/3289
AB  - The influence of the alkaline treatment on the acidity of zeolite ZSM-5 (SiO2/Al2O3 = 23, 50 and 80) modified by desilication was investigated. The samples were characterized by X-ray diffraction, low temperature adsorption of nitrogen and solid-state Al-27 MAS NMR. Acidity of the samples was investigated using microcalorimetry-volumetry of ammonia adsorption at 423 K. Acid sites accessibility and intracrystalline diffusion were estimated by the thermokinetic parameter. The desilication process was shown to be Si/Al ratio dependant. Relative enhancement of mesopore surface decreased in the following order of SiO2/Al2O3: 50 >80 >23. Pore size distribution broadened and mesopore sizes increased with increasing Si/Al ratio. For samples with SiO2/Al2O3 = 50 and 80 almost full preservation of acid sites strength and distribution was achieved. Significant alteration of the acidity was found for the mesoporous sample with SiO2/Al2O3 = 23. Thermokinetic parameter values indicate facilitated intracristalline diffusion for mesoporous samples.
PB  - Elsevier, Amsterdam
T2  - Thermochimica Acta
T1  - Influence of the desilication process on the acidity of HZSM-5 zeolite
EP  - 78
SP  - 73
VL  - 567
DO  - 10.1016/j.tca.2013.01.008
ER  - 
@article{
author = "Rac, Vladislav and Rakić, Vesna and Miladinović, Zoran and Stošić, Dušan and Auroux, Aline",
year = "2013",
abstract = "The influence of the alkaline treatment on the acidity of zeolite ZSM-5 (SiO2/Al2O3 = 23, 50 and 80) modified by desilication was investigated. The samples were characterized by X-ray diffraction, low temperature adsorption of nitrogen and solid-state Al-27 MAS NMR. Acidity of the samples was investigated using microcalorimetry-volumetry of ammonia adsorption at 423 K. Acid sites accessibility and intracrystalline diffusion were estimated by the thermokinetic parameter. The desilication process was shown to be Si/Al ratio dependant. Relative enhancement of mesopore surface decreased in the following order of SiO2/Al2O3: 50 >80 >23. Pore size distribution broadened and mesopore sizes increased with increasing Si/Al ratio. For samples with SiO2/Al2O3 = 50 and 80 almost full preservation of acid sites strength and distribution was achieved. Significant alteration of the acidity was found for the mesoporous sample with SiO2/Al2O3 = 23. Thermokinetic parameter values indicate facilitated intracristalline diffusion for mesoporous samples.",
publisher = "Elsevier, Amsterdam",
journal = "Thermochimica Acta",
title = "Influence of the desilication process on the acidity of HZSM-5 zeolite",
pages = "78-73",
volume = "567",
doi = "10.1016/j.tca.2013.01.008"
}
Rac, V., Rakić, V., Miladinović, Z., Stošić, D.,& Auroux, A.. (2013). Influence of the desilication process on the acidity of HZSM-5 zeolite. in Thermochimica Acta
Elsevier, Amsterdam., 567, 73-78.
https://doi.org/10.1016/j.tca.2013.01.008
Rac V, Rakić V, Miladinović Z, Stošić D, Auroux A. Influence of the desilication process on the acidity of HZSM-5 zeolite. in Thermochimica Acta. 2013;567:73-78.
doi:10.1016/j.tca.2013.01.008 .
Rac, Vladislav, Rakić, Vesna, Miladinović, Zoran, Stošić, Dušan, Auroux, Aline, "Influence of the desilication process on the acidity of HZSM-5 zeolite" in Thermochimica Acta, 567 (2013):73-78,
https://doi.org/10.1016/j.tca.2013.01.008 . .
27
16
25

CeO2-Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction

Stošić, Dušan; Bennici, Simona; Rakić, Vesna; Auroux, Aline

(Elsevier Science Bv, Amsterdam, 2012)

TY  - CONF
AU  - Stošić, Dušan
AU  - Bennici, Simona
AU  - Rakić, Vesna
AU  - Auroux, Aline
PY  - 2012
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/2987
AB  - In this work, ceria-niobia mixed oxides have been prepared by coprecipitation. The structural, textural, and surface properties of these materials have been fully characterized using appropriate techniques (low-temperature adsorption-desorption of nitrogen, thermogravimetric analysis, X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and temperature-programmed reduction/oxidation (TPR/O)). The acid-base properties were estimated by the adsorption of appropriate probe molecules - NH3 or SO2 were used to estimate the population, strength and strength distribution of acid or basic sites, by means of adsorption microcalorimetry. The nature of acidic sites was determined through the adsorption/desorption of pyridine, studied by infrared spectroscopy. New phases between the oxides were not formed, while there is evidence of interaction between them, as revealed by XRD and Raman spectroscopy. All investigated mixed oxide samples are amphoteric and possess red-ox centers on their surface. Both red-ox and acid-base properties are dependent on the ratio of ceria to niobia in the samples. Both Lewis and Brnsted acid sites are present on the surface of the mixed oxides. In order to check catalytic abilities of these materials, reaction of fructose dehydration has been performed. All the investigated materials are catalytically active in fructose dehydration; conversion of fructose and selectivity to 5-hydroxymethylfurfural (5-HMF) improved with increasing content of niobia in the samples.
PB  - Elsevier Science Bv, Amsterdam
C3  - Catalysis Today
T1  - CeO2-Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction
EP  - 168
IS  - 1
SP  - 160
VL  - 192
DO  - 10.1016/j.cattod.2011.10.040
ER  - 
@conference{
author = "Stošić, Dušan and Bennici, Simona and Rakić, Vesna and Auroux, Aline",
year = "2012",
abstract = "In this work, ceria-niobia mixed oxides have been prepared by coprecipitation. The structural, textural, and surface properties of these materials have been fully characterized using appropriate techniques (low-temperature adsorption-desorption of nitrogen, thermogravimetric analysis, X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and temperature-programmed reduction/oxidation (TPR/O)). The acid-base properties were estimated by the adsorption of appropriate probe molecules - NH3 or SO2 were used to estimate the population, strength and strength distribution of acid or basic sites, by means of adsorption microcalorimetry. The nature of acidic sites was determined through the adsorption/desorption of pyridine, studied by infrared spectroscopy. New phases between the oxides were not formed, while there is evidence of interaction between them, as revealed by XRD and Raman spectroscopy. All investigated mixed oxide samples are amphoteric and possess red-ox centers on their surface. Both red-ox and acid-base properties are dependent on the ratio of ceria to niobia in the samples. Both Lewis and Brnsted acid sites are present on the surface of the mixed oxides. In order to check catalytic abilities of these materials, reaction of fructose dehydration has been performed. All the investigated materials are catalytically active in fructose dehydration; conversion of fructose and selectivity to 5-hydroxymethylfurfural (5-HMF) improved with increasing content of niobia in the samples.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Catalysis Today",
title = "CeO2-Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction",
pages = "168-160",
number = "1",
volume = "192",
doi = "10.1016/j.cattod.2011.10.040"
}
Stošić, D., Bennici, S., Rakić, V.,& Auroux, A.. (2012). CeO2-Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction. in Catalysis Today
Elsevier Science Bv, Amsterdam., 192(1), 160-168.
https://doi.org/10.1016/j.cattod.2011.10.040
Stošić D, Bennici S, Rakić V, Auroux A. CeO2-Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction. in Catalysis Today. 2012;192(1):160-168.
doi:10.1016/j.cattod.2011.10.040 .
Stošić, Dušan, Bennici, Simona, Rakić, Vesna, Auroux, Aline, "CeO2-Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction" in Catalysis Today, 192, no. 1 (2012):160-168,
https://doi.org/10.1016/j.cattod.2011.10.040 . .
9
75
54
72

The adsorption of nicotine from aqueous solutions on different zeolite structures

Rakić, Vesna; Damjanović, Ljiljana; Rac, Vladislav; Stošić, Dušan; Dondur, Vera; Auroux, Aline

(Pergamon-Elsevier Science Ltd, Oxford, 2010)

TY  - JOUR
AU  - Rakić, Vesna
AU  - Damjanović, Ljiljana
AU  - Rac, Vladislav
AU  - Stošić, Dušan
AU  - Dondur, Vera
AU  - Auroux, Aline
PY  - 2010
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/2397
AB  - The present work is focused on the adsorption of nicotine from aqueous solutions. Based on the data available in the literature, serious concern is claimed regarding the appearance of nicotine in ground, surface and municipal wastewaters. In order to investigate the possibility of abatement by adsorption, three different types of zeolites (BEA, MFI and HEU) have been applied as adsorbents. In addition, the adsorption was per-formed on activated carbon, a solid customarily used for removal of pollutants from water. The adsorption of nicotine was studied by isothermal microcalorimetry, which provided the heats evolved as a result of adsorption. The values of these heats revealed that the investigated solids are energetically heterogeneous for the adsorption of nicotine from aqueous solution. Additionally, the amounts of adsorbed pollutant were determined and presented in the form of adsorption isotherms. The obtained adsorption isotherms were interpreted using Langmuir, Freundlich, and Sips equations; the latter was found to express high level of agreement with experimental data of nicotine adsorption on the investigated solids. The possibilities to regenerate the adsorbents were examined by means of thermogravimetry coupled with mass spectrometry. From all obtained results, it was possible to distinguish zeolite BEA as a material which possesses the capacity for adsorption of nicotine comparable to that of activated carbon.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Water Research
T1  - The adsorption of nicotine from aqueous solutions on different zeolite structures
EP  - 2057
IS  - 6
SP  - 2047
VL  - 44
DO  - 10.1016/j.watres.2009.12.019
ER  - 
@article{
author = "Rakić, Vesna and Damjanović, Ljiljana and Rac, Vladislav and Stošić, Dušan and Dondur, Vera and Auroux, Aline",
year = "2010",
abstract = "The present work is focused on the adsorption of nicotine from aqueous solutions. Based on the data available in the literature, serious concern is claimed regarding the appearance of nicotine in ground, surface and municipal wastewaters. In order to investigate the possibility of abatement by adsorption, three different types of zeolites (BEA, MFI and HEU) have been applied as adsorbents. In addition, the adsorption was per-formed on activated carbon, a solid customarily used for removal of pollutants from water. The adsorption of nicotine was studied by isothermal microcalorimetry, which provided the heats evolved as a result of adsorption. The values of these heats revealed that the investigated solids are energetically heterogeneous for the adsorption of nicotine from aqueous solution. Additionally, the amounts of adsorbed pollutant were determined and presented in the form of adsorption isotherms. The obtained adsorption isotherms were interpreted using Langmuir, Freundlich, and Sips equations; the latter was found to express high level of agreement with experimental data of nicotine adsorption on the investigated solids. The possibilities to regenerate the adsorbents were examined by means of thermogravimetry coupled with mass spectrometry. From all obtained results, it was possible to distinguish zeolite BEA as a material which possesses the capacity for adsorption of nicotine comparable to that of activated carbon.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Water Research",
title = "The adsorption of nicotine from aqueous solutions on different zeolite structures",
pages = "2057-2047",
number = "6",
volume = "44",
doi = "10.1016/j.watres.2009.12.019"
}
Rakić, V., Damjanović, L., Rac, V., Stošić, D., Dondur, V.,& Auroux, A.. (2010). The adsorption of nicotine from aqueous solutions on different zeolite structures. in Water Research
Pergamon-Elsevier Science Ltd, Oxford., 44(6), 2047-2057.
https://doi.org/10.1016/j.watres.2009.12.019
Rakić V, Damjanović L, Rac V, Stošić D, Dondur V, Auroux A. The adsorption of nicotine from aqueous solutions on different zeolite structures. in Water Research. 2010;44(6):2047-2057.
doi:10.1016/j.watres.2009.12.019 .
Rakić, Vesna, Damjanović, Ljiljana, Rac, Vladislav, Stošić, Dušan, Dondur, Vera, Auroux, Aline, "The adsorption of nicotine from aqueous solutions on different zeolite structures" in Water Research, 44, no. 6 (2010):2047-2057,
https://doi.org/10.1016/j.watres.2009.12.019 . .
3
58
47
60

The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents

Damjanović, Ljiljana; Rakić, Vesna; Rac, Vladislav; Stošić, Dušan; Auroux, Aline

(Elsevier, Amsterdam, 2010)

TY  - JOUR
AU  - Damjanović, Ljiljana
AU  - Rakić, Vesna
AU  - Rac, Vladislav
AU  - Stošić, Dušan
AU  - Auroux, Aline
PY  - 2010
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/2364
AB  - This work reports results on phenol adsorption from aqueous solutions on synthetic BEA (beta) and MFI (ZSM-5) zeolites, studied by heat-flow microcalorimetry. For the sake of comparison, the adsorption was performed on activated carbon, a solid customarily used for removal of phenol from water. The obtained values of heats evolved during phenol adsorption indicate the heterogeneity of active sites present on the investigated systems for the adsorption of phenol. In addition, the amounts of adsorbed pollutant were determined and presented in the form of adsorption isotherms, which were interpreted using Langmuir, Freundlich, Dubinin-Astakov and Sips' equations. The latter was found to express high level of agreement with experimental data. The results obtained in this work reveal that the adsorption of phenol on zeolites depends on both Si/Al ratio and on the pore size. Hydrophobic zeolites that possess higher contents of Si show higher affinities for phenol adsorption. Among investigated zeolites, zeolite beta possesses the highest capacity for adsorption of phenol. The possibility of regeneration of used adsorbents was investigated by thermal desorption technique. It has been shown that in the case of beta zeolite the majority of adsorbed phenol is easily released in the low temperature region.
PB  - Elsevier, Amsterdam
T2  - Journal of Hazardous Materials
T1  - The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents
EP  - 484
IS  - 1-3
SP  - 477
VL  - 184
DO  - 10.1016/j.jhazmat.2010.08.059
ER  - 
@article{
author = "Damjanović, Ljiljana and Rakić, Vesna and Rac, Vladislav and Stošić, Dušan and Auroux, Aline",
year = "2010",
abstract = "This work reports results on phenol adsorption from aqueous solutions on synthetic BEA (beta) and MFI (ZSM-5) zeolites, studied by heat-flow microcalorimetry. For the sake of comparison, the adsorption was performed on activated carbon, a solid customarily used for removal of phenol from water. The obtained values of heats evolved during phenol adsorption indicate the heterogeneity of active sites present on the investigated systems for the adsorption of phenol. In addition, the amounts of adsorbed pollutant were determined and presented in the form of adsorption isotherms, which were interpreted using Langmuir, Freundlich, Dubinin-Astakov and Sips' equations. The latter was found to express high level of agreement with experimental data. The results obtained in this work reveal that the adsorption of phenol on zeolites depends on both Si/Al ratio and on the pore size. Hydrophobic zeolites that possess higher contents of Si show higher affinities for phenol adsorption. Among investigated zeolites, zeolite beta possesses the highest capacity for adsorption of phenol. The possibility of regeneration of used adsorbents was investigated by thermal desorption technique. It has been shown that in the case of beta zeolite the majority of adsorbed phenol is easily released in the low temperature region.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Hazardous Materials",
title = "The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents",
pages = "484-477",
number = "1-3",
volume = "184",
doi = "10.1016/j.jhazmat.2010.08.059"
}
Damjanović, L., Rakić, V., Rac, V., Stošić, D.,& Auroux, A.. (2010). The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents. in Journal of Hazardous Materials
Elsevier, Amsterdam., 184(1-3), 477-484.
https://doi.org/10.1016/j.jhazmat.2010.08.059
Damjanović L, Rakić V, Rac V, Stošić D, Auroux A. The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents. in Journal of Hazardous Materials. 2010;184(1-3):477-484.
doi:10.1016/j.jhazmat.2010.08.059 .
Damjanović, Ljiljana, Rakić, Vesna, Rac, Vladislav, Stošić, Dušan, Auroux, Aline, "The investigation of phenol removal from aqueous solutions by zeolites as solid adsorbents" in Journal of Hazardous Materials, 184, no. 1-3 (2010):477-484,
https://doi.org/10.1016/j.jhazmat.2010.08.059 . .
115
99
125

The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials

Stošić, Dušan; Damjanović, Ljiljana; Hercigonja, Radmila; Dondur, Vera; Rac, Vladislav; Rakić, Vesna

(Savez hemijskih inženjera, Beograd, 2008)

TY  - JOUR
AU  - Stošić, Dušan
AU  - Damjanović, Ljiljana
AU  - Hercigonja, Radmila
AU  - Dondur, Vera
AU  - Rac, Vladislav
AU  - Rakić, Vesna
PY  - 2008
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/1647
AB  - L-histidine, a naturally occurring amino acid, was incorporated inside the supercages of FAU type zeolite in a form of Me-complex entity (Me = Cu(II), Zn(II), Fe(III)). The preparation was done either by ion-exchange procedure, or previously prepared Me-histidine complex was incorporated into the a cages of Y zeolite by occlusion. The preparation procedure was found to be a very important factor, as well as the amount of metal complex loaded on the zeolite. The characterization of obtained samples was performed using Diffuse Reflectance Ultraviolet-Visible Spectroscopy (DRUV-Vis), 13C MAS NMR and Infrared Spectroscopy (FTIR). It was noticed that 1-hostidine interacted with the zeolitic framework, and with the extra-framework cation, as well. The results obtained by TG-DSC/MAS technique, revealed that the thermal stability of incorporated histidine was increased, in comparison with that one of pure histidine.
AB  - U ovom radu, Me-histidin (Me = Zn(II), Cu(II), Fe(III)) kompleksi ugrađivani su u strukturu Yzeolita, primenom dva različita postupka: (1) Me-histidin kompleksi su pravljeni u dejonizovanoj vodi i zatim mešani sa NaY zeolitom, (2) histidinje rastvoren u vodi i u rastvor su dodavani jonski izmenjeni Y zeoliti. UV-spektroskopijom tečne faze je utvrđeno da je proces imobilizacije izvršen za 24 h. Ovako dobijem čvrsti materijali su detaljno okarakterisani hemijski i metodama XRD, NMR, IR, DR UV-VIS, dok su njihove termalne stabilnosti ispitivane primenom TG-DSC/MAS tehnike. Dobijem rezultati omogućili su poređenje osobina sintetisanih uzoraka.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials
T1  - Ugradnja Me-histidin kompleksa u strukturu FAU zeolita - karakterizacija odbijenih materijala
EP  - 130
IS  - 3
SP  - 125
VL  - 62
DO  - 10.2298/HEMIND0803125S
ER  - 
@article{
author = "Stošić, Dušan and Damjanović, Ljiljana and Hercigonja, Radmila and Dondur, Vera and Rac, Vladislav and Rakić, Vesna",
year = "2008",
abstract = "L-histidine, a naturally occurring amino acid, was incorporated inside the supercages of FAU type zeolite in a form of Me-complex entity (Me = Cu(II), Zn(II), Fe(III)). The preparation was done either by ion-exchange procedure, or previously prepared Me-histidine complex was incorporated into the a cages of Y zeolite by occlusion. The preparation procedure was found to be a very important factor, as well as the amount of metal complex loaded on the zeolite. The characterization of obtained samples was performed using Diffuse Reflectance Ultraviolet-Visible Spectroscopy (DRUV-Vis), 13C MAS NMR and Infrared Spectroscopy (FTIR). It was noticed that 1-hostidine interacted with the zeolitic framework, and with the extra-framework cation, as well. The results obtained by TG-DSC/MAS technique, revealed that the thermal stability of incorporated histidine was increased, in comparison with that one of pure histidine., U ovom radu, Me-histidin (Me = Zn(II), Cu(II), Fe(III)) kompleksi ugrađivani su u strukturu Yzeolita, primenom dva različita postupka: (1) Me-histidin kompleksi su pravljeni u dejonizovanoj vodi i zatim mešani sa NaY zeolitom, (2) histidinje rastvoren u vodi i u rastvor su dodavani jonski izmenjeni Y zeoliti. UV-spektroskopijom tečne faze je utvrđeno da je proces imobilizacije izvršen za 24 h. Ovako dobijem čvrsti materijali su detaljno okarakterisani hemijski i metodama XRD, NMR, IR, DR UV-VIS, dok su njihove termalne stabilnosti ispitivane primenom TG-DSC/MAS tehnike. Dobijem rezultati omogućili su poređenje osobina sintetisanih uzoraka.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials, Ugradnja Me-histidin kompleksa u strukturu FAU zeolita - karakterizacija odbijenih materijala",
pages = "130-125",
number = "3",
volume = "62",
doi = "10.2298/HEMIND0803125S"
}
Stošić, D., Damjanović, L., Hercigonja, R., Dondur, V., Rac, V.,& Rakić, V.. (2008). The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 62(3), 125-130.
https://doi.org/10.2298/HEMIND0803125S
Stošić D, Damjanović L, Hercigonja R, Dondur V, Rac V, Rakić V. The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials. in Hemijska industrija. 2008;62(3):125-130.
doi:10.2298/HEMIND0803125S .
Stošić, Dušan, Damjanović, Ljiljana, Hercigonja, Radmila, Dondur, Vera, Rac, Vladislav, Rakić, Vesna, "The incorporation of Me-histidine complexes in the structure of FAU-type zeolite: Characterization of the obtained materials" in Hemijska industrija, 62, no. 3 (2008):125-130,
https://doi.org/10.2298/HEMIND0803125S . .

Adsorption of nicotine on different zeolite types, from aqueous solutions

Stošić, Dušan; Dondur, Vera; Rac, Vladislav; Rakić, Vesna; Zakrzewska, Joanna S.

(Savez hemijskih inženjera, Beograd, 2007)

TY  - JOUR
AU  - Stošić, Dušan
AU  - Dondur, Vera
AU  - Rac, Vladislav
AU  - Rakić, Vesna
AU  - Zakrzewska, Joanna S.
PY  - 2007
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/1418
AB  - The plant alkaloid, nicotine, is a strongly toxic heterocyclic compound: the lethal dose for an adult human being (40-60 mg) is importantly lower in comparison with the other known poisons such as arsenic or strychni­ne. Cigarettes represent "the most toxic and addictive form of nicotine". Besides the negative effects of nicotine on public health produced by self-administration, recently another potentially very dangerous effect has been recognized: because of its miscibility with water, nicotine can be found in industrial wastewaters, and consequently, in groundwater. Therefore, the problem of nicotine removal from aqueous solutions has became an interesting topic. In this work, the removal of nicotine has been probed by adsorption on solid materials. Adsorption of nicotine on different zeolites (clinoptilolite, ZSM-5 and beta zeolite) and on activated carbon was investigated from aqueous solutions, at 298 K. The obtained results are presented as adsorption isotherms: the amount of adsorbed nicotine as a function of equilibrium concentration. These data were obtained from the residual amount of nicotine in the aqueous phase, by the use of UV spectroscopy. The highest amounts of adsorbed nicotine was found for activated carbon and p zeolite (~ mmol·g-1). The attempt to modify the adsorption properties of ZSM-5 zeolite has been also done: ZSM-5 was modified by ion-exchange with VIII group metal (Cu2+ and Fe3+). In addition, the adsorption of nicotine on ZSM-5 zeolite with different Si/Al ratios has been done. It has been noticed that ion-exchange did not improve the adsorption possibilities, while the adsorption was importantly lower in the case of higher silicon content in ZMS-5 structure. 13C NMR spectra were collected for suspensions formed of solid adsorbent and aqueous solution of nicotine; in this way, the part of nicotine molecule which is most probably connected with the adsorbent was recognized.
AB  - U ovom radu ispitivana je adsorpcija nikotina iz vodenih rastvora na različitim zeolitima (klinoptilolitu, ZSM-5 i beta zeolitu) kao i na aktivnom uglju visoke specifične površine; na 298K. Dobijeni rezultati prikazani su u formi adsorpcionih izotermi: količina adsorbovanog nikotina u funkciji od ravnotežnih koncentracija nikotina. Ovi podaci dobijeni su iz određivanja količine nikotina preostale u vodenoj fazi, metodom UV spektroskopije. Najveće količine adsorbovanog nikotina utvrđene su na aktivnom uglju i beta zeolitu (~ mmol/g). Iz 13C NMR spektara snimljenih iz suspenzije: čvrsti adsorbent-vodeni rastvor nikotina, utvrđen je atom ugljenika preko koga se molekul nikotina najverovatnije vezuje sa površinama zeolita.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Adsorption of nicotine on different zeolite types, from aqueous solutions
T1  - Adsorpcija nikotina iz vodenih rastvora na različitim vrstama zeolita
EP  - 128
IS  - 3
SP  - 123
VL  - 61
DO  - 10.2298/HEMIND0703123S
ER  - 
@article{
author = "Stošić, Dušan and Dondur, Vera and Rac, Vladislav and Rakić, Vesna and Zakrzewska, Joanna S.",
year = "2007",
abstract = "The plant alkaloid, nicotine, is a strongly toxic heterocyclic compound: the lethal dose for an adult human being (40-60 mg) is importantly lower in comparison with the other known poisons such as arsenic or strychni­ne. Cigarettes represent "the most toxic and addictive form of nicotine". Besides the negative effects of nicotine on public health produced by self-administration, recently another potentially very dangerous effect has been recognized: because of its miscibility with water, nicotine can be found in industrial wastewaters, and consequently, in groundwater. Therefore, the problem of nicotine removal from aqueous solutions has became an interesting topic. In this work, the removal of nicotine has been probed by adsorption on solid materials. Adsorption of nicotine on different zeolites (clinoptilolite, ZSM-5 and beta zeolite) and on activated carbon was investigated from aqueous solutions, at 298 K. The obtained results are presented as adsorption isotherms: the amount of adsorbed nicotine as a function of equilibrium concentration. These data were obtained from the residual amount of nicotine in the aqueous phase, by the use of UV spectroscopy. The highest amounts of adsorbed nicotine was found for activated carbon and p zeolite (~ mmol·g-1). The attempt to modify the adsorption properties of ZSM-5 zeolite has been also done: ZSM-5 was modified by ion-exchange with VIII group metal (Cu2+ and Fe3+). In addition, the adsorption of nicotine on ZSM-5 zeolite with different Si/Al ratios has been done. It has been noticed that ion-exchange did not improve the adsorption possibilities, while the adsorption was importantly lower in the case of higher silicon content in ZMS-5 structure. 13C NMR spectra were collected for suspensions formed of solid adsorbent and aqueous solution of nicotine; in this way, the part of nicotine molecule which is most probably connected with the adsorbent was recognized., U ovom radu ispitivana je adsorpcija nikotina iz vodenih rastvora na različitim zeolitima (klinoptilolitu, ZSM-5 i beta zeolitu) kao i na aktivnom uglju visoke specifične površine; na 298K. Dobijeni rezultati prikazani su u formi adsorpcionih izotermi: količina adsorbovanog nikotina u funkciji od ravnotežnih koncentracija nikotina. Ovi podaci dobijeni su iz određivanja količine nikotina preostale u vodenoj fazi, metodom UV spektroskopije. Najveće količine adsorbovanog nikotina utvrđene su na aktivnom uglju i beta zeolitu (~ mmol/g). Iz 13C NMR spektara snimljenih iz suspenzije: čvrsti adsorbent-vodeni rastvor nikotina, utvrđen je atom ugljenika preko koga se molekul nikotina najverovatnije vezuje sa površinama zeolita.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Adsorption of nicotine on different zeolite types, from aqueous solutions, Adsorpcija nikotina iz vodenih rastvora na različitim vrstama zeolita",
pages = "128-123",
number = "3",
volume = "61",
doi = "10.2298/HEMIND0703123S"
}
Stošić, D., Dondur, V., Rac, V., Rakić, V.,& Zakrzewska, J. S.. (2007). Adsorption of nicotine on different zeolite types, from aqueous solutions. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 61(3), 123-128.
https://doi.org/10.2298/HEMIND0703123S
Stošić D, Dondur V, Rac V, Rakić V, Zakrzewska JS. Adsorption of nicotine on different zeolite types, from aqueous solutions. in Hemijska industrija. 2007;61(3):123-128.
doi:10.2298/HEMIND0703123S .
Stošić, Dušan, Dondur, Vera, Rac, Vladislav, Rakić, Vesna, Zakrzewska, Joanna S., "Adsorption of nicotine on different zeolite types, from aqueous solutions" in Hemijska industrija, 61, no. 3 (2007):123-128,
https://doi.org/10.2298/HEMIND0703123S . .
4
3