Gajić-Kvascev, Maja D.

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Properties of humic acids from copper tailings 20 years after reclamation

Radmanović, Svjetlana; Marković, Mirjana M.; Jovanović, Uroš D.; Gajić-Kvascev, Maja D.; Čokeša, Djuro M.; Lilić, Jasmina A.

(Srpsko hemijsko društvo, Beograd, 2020)

TY  - JOUR
AU  - Radmanović, Svjetlana
AU  - Marković, Mirjana M.
AU  - Jovanović, Uroš D.
AU  - Gajić-Kvascev, Maja D.
AU  - Čokeša, Djuro M.
AU  - Lilić, Jasmina A.
PY  - 2020
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/5393
AB  - Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV-Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C >= aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.883.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7-26.8 nm range. Pronounced reaggregation (1462--5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids since the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.
PB  - Srpsko hemijsko društvo, Beograd
T2  - JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
T1  - Properties of humic acids from copper tailings 20 years after reclamation
EP  - 419
IS  - 3
SP  - 407
VL  - 85
DO  - 10.2298/JSC190717112R
ER  - 
@article{
author = "Radmanović, Svjetlana and Marković, Mirjana M. and Jovanović, Uroš D. and Gajić-Kvascev, Maja D. and Čokeša, Djuro M. and Lilić, Jasmina A.",
year = "2020",
abstract = "Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV-Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C >= aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.883.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7-26.8 nm range. Pronounced reaggregation (1462--5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids since the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "JOURNAL OF THE SERBIAN CHEMICAL SOCIETY",
title = "Properties of humic acids from copper tailings 20 years after reclamation",
pages = "419-407",
number = "3",
volume = "85",
doi = "10.2298/JSC190717112R"
}
Radmanović, S., Marković, M. M., Jovanović, U. D., Gajić-Kvascev, M. D., Čokeša, D. M.,& Lilić, J. A.. (2020). Properties of humic acids from copper tailings 20 years after reclamation. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
Srpsko hemijsko društvo, Beograd., 85(3), 407-419.
https://doi.org/10.2298/JSC190717112R
Radmanović S, Marković MM, Jovanović UD, Gajić-Kvascev MD, Čokeša DM, Lilić JA. Properties of humic acids from copper tailings 20 years after reclamation. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY. 2020;85(3):407-419.
doi:10.2298/JSC190717112R .
Radmanović, Svjetlana, Marković, Mirjana M., Jovanović, Uroš D., Gajić-Kvascev, Maja D., Čokeša, Djuro M., Lilić, Jasmina A., "Properties of humic acids from copper tailings 20 years after reclamation" in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 85, no. 3 (2020):407-419,
https://doi.org/10.2298/JSC190717112R . .