TY  - JOUR
AU  - Stefanović, Ivan S.
AU  - Marković, Bojana M.
AU  - Nastasović, Aleksandra B.
AU  - Vuković, Zorica M.
AU  - Dapčević, Aleksandra
AU  - Pavlović, Vladimir B.
PY  - 2022
UR  - http://aspace.agrif.bg.ac.rs/handle/123456789/6117
AB  - The impact of the type and amounts of nanofiller on the features of the glycidyl methacrylate-co-ethylene glycol dimethacrylate (GMA-co-EGDMA)/organomodified montmorillonite (OMt) nanocomposites that were prepared by in situ radical suspension polymerization, was examined. Cloisite 30B and Cloisite 25A were used in this study as nanofillers, in amounts of 2 and 10 wt.%. The structure, morphology, thermal stability and porosity of the initial GMA-co-EGDMA copolymer and their nanocomposites were examined by ATR-FTIR analysis, wide angle X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), thermogravimetric analysis (TG) and mercury porosimetry. It has been established that both clay nanofillers were successfully incorporated into the structure of the initial copolymer, simultaneously on their surface and also on cross-sectional area. Prepared samples with 2 wt.% have predominantly exfoliated, while samples with 10 wt.% have some tactoids-aggregates structure of the OMt layers. Thermogravimetric analysis revealed that after ~ 30 % of degradation, all nanocomposites become more thermal stable than the initial copolymer. The obtained results indicate that porosity parameters can be easily modified with the addition of clay nanofillers and thus prepared nanocomposites adjusted to specific purposes. © 2022 Authors. Published by association for ETRAN Society.
T2  - Science of Sintering
T2  - Science of Sintering
T1  - Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites
EP  - 200
IS  - 2
SP  - 189
VL  - 54
DO  - 10.2298/SOS2202189S
ER  - 

@article{
author = "Stefanović, Ivan S. and Marković, Bojana M. and Nastasović, Aleksandra B. and Vuković, Zorica M. and Dapčević, Aleksandra and Pavlović, Vladimir B.",
year = "2022",
abstract = "The impact of the type and amounts of nanofiller on the features of the glycidyl methacrylate-co-ethylene glycol dimethacrylate (GMA-co-EGDMA)/organomodified montmorillonite (OMt) nanocomposites that were prepared by in situ radical suspension polymerization, was examined. Cloisite 30B and Cloisite 25A were used in this study as nanofillers, in amounts of 2 and 10 wt.%. The structure, morphology, thermal stability and porosity of the initial GMA-co-EGDMA copolymer and their nanocomposites were examined by ATR-FTIR analysis, wide angle X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), thermogravimetric analysis (TG) and mercury porosimetry. It has been established that both clay nanofillers were successfully incorporated into the structure of the initial copolymer, simultaneously on their surface and also on cross-sectional area. Prepared samples with 2 wt.% have predominantly exfoliated, while samples with 10 wt.% have some tactoids-aggregates structure of the OMt layers. Thermogravimetric analysis revealed that after ~ 30 % of degradation, all nanocomposites become more thermal stable than the initial copolymer. The obtained results indicate that porosity parameters can be easily modified with the addition of clay nanofillers and thus prepared nanocomposites adjusted to specific purposes. © 2022 Authors. Published by association for ETRAN Society.",
journal = "Science of Sintering, Science of Sintering",
title = "Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites",
pages = "200-189",
number = "2",
volume = "54",
doi = "10.2298/SOS2202189S"
}

Stefanović, I. S., Marković, B. M., Nastasović, A. B., Vuković, Z. M., Dapčević, A.,& Pavlović, V. B.. (2022). Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites. in Science of Sintering, 54(2), 189-200.
https://doi.org/10.2298/SOS2202189S

Stefanović IS, Marković BM, Nastasović AB, Vuković ZM, Dapčević A, Pavlović VB. Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites. in Science of Sintering. 2022;54(2):189-200.
doi:10.2298/SOS2202189S .

Stefanović, Ivan S., Marković, Bojana M., Nastasović, Aleksandra B., Vuković, Zorica M., Dapčević, Aleksandra, Pavlović, Vladimir B., "Preparation and Characterization of Novel Glycidyl Methacrylate/Clay Nanocomposites" in Science of Sintering, 54, no. 2 (2022):189-200,
https://doi.org/10.2298/SOS2202189S . .