Characterization of glycidyl methacrylate based magnetic nanocomposites
2019
Аутори
Marković, Bojana M.Spasojević, Vojislav V.
Dapcević, Aleksandra
Vuković, Zorica M.
Pavlović, Vladimir
Randjelović, Danijela, V
Nastasović, Aleksandra B.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the... polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.
Кључне речи:
glycidyl methacrylate / trimethylolpropane trimethacrylate / magnetic nanocomposite / diethylenetriamineИзвор:
HEMIJSKA INDUSTRIJA, 2019, 73, 1, 25-35Издавач:
- Savez hemijskih inženjera, Beograd
Финансирање / пројекти:
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Микро, нано-системи и сензори за примену у електропривреди, процесној индустрији и заштити животне средине (RS-MESTD-Technological Development (TD or TR)-32008)
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- 0-3D наноструктуре за примену у електроници и обновљивим изворима енергије: синтеза, карактеризација и процесирање (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
- Магнетни и радионуклидима обележени наноструктурни материјали за примене у медицини (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45015)
DOI: 10.2298/HEMIND181113006M
ISSN: 0367-598X
WoS: 000460129400003
Scopus: 2-s2.0-85064212602
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Marković, Bojana M. AU - Spasojević, Vojislav V. AU - Dapcević, Aleksandra AU - Vuković, Zorica M. AU - Pavlović, Vladimir AU - Randjelović, Danijela, V AU - Nastasović, Aleksandra B. PY - 2019 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5029 AB - Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer. PB - Savez hemijskih inženjera, Beograd T2 - HEMIJSKA INDUSTRIJA T1 - Characterization of glycidyl methacrylate based magnetic nanocomposites EP - 35 IS - 1 SP - 25 VL - 73 DO - 10.2298/HEMIND181113006M ER -
@article{ author = "Marković, Bojana M. and Spasojević, Vojislav V. and Dapcević, Aleksandra and Vuković, Zorica M. and Pavlović, Vladimir and Randjelović, Danijela, V and Nastasović, Aleksandra B.", year = "2019", abstract = "Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.", publisher = "Savez hemijskih inženjera, Beograd", journal = "HEMIJSKA INDUSTRIJA", title = "Characterization of glycidyl methacrylate based magnetic nanocomposites", pages = "35-25", number = "1", volume = "73", doi = "10.2298/HEMIND181113006M" }
Marković, B. M., Spasojević, V. V., Dapcević, A., Vuković, Z. M., Pavlović, V., Randjelović, D. V.,& Nastasović, A. B.. (2019). Characterization of glycidyl methacrylate based magnetic nanocomposites. in HEMIJSKA INDUSTRIJA Savez hemijskih inženjera, Beograd., 73(1), 25-35. https://doi.org/10.2298/HEMIND181113006M
Marković BM, Spasojević VV, Dapcević A, Vuković ZM, Pavlović V, Randjelović DV, Nastasović AB. Characterization of glycidyl methacrylate based magnetic nanocomposites. in HEMIJSKA INDUSTRIJA. 2019;73(1):25-35. doi:10.2298/HEMIND181113006M .
Marković, Bojana M., Spasojević, Vojislav V., Dapcević, Aleksandra, Vuković, Zorica M., Pavlović, Vladimir, Randjelović, Danijela, V, Nastasović, Aleksandra B., "Characterization of glycidyl methacrylate based magnetic nanocomposites" in HEMIJSKA INDUSTRIJA, 73, no. 1 (2019):25-35, https://doi.org/10.2298/HEMIND181113006M . .