Efficient photocatalytic hydrogen production over titanate/titania nanostructures modified with nickel
Само за регистроване кориснике
2019
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Nickel-modified titanate/TiO2 catalysts were prepared by deposition of nickel ions onto hydrothermally prepared titanate supports, followed by hydrogen temperature-programmed reduction. Two different nickel precursors (hydroxide and carbonate) were used to tune reducibility and to vary the crystal phase structure of the final catalysts. The precursor reducibility and functional properties of the final catalysts were investigated systematically using various characterisation techniques. The results revealed a more facile reduction of the hydroxide precursor compared to its carbonate counterpart. Moreover, it was found that the formation of the anatase phase was favoured by the use of the hydroxide precipitation agent. The photocatalytic activity towards hydrogen production of the prepared catalysts was evaluated in the presence of 2-propanol under simulated solar light irradiation. A thorough study of the photocatalytic performance of the synthesised catalysts was conducted as a functio...n of the precipitation agent used and the reduction temperature applied. The catalyst with dominant anatase crystal phase displayed the highest photocatalytic activity with a maximum H-2 production rate of 1040 mu mol h(-1) g(-1), this being more than four times higher than that of its carbonate counterpart. The catalysts with titanate structure showed similar activity, independent of the precipitation method used. The nanotubular structure was found to be the dominant factor in the stability of photocatalysts under long-run working conditions.
Кључне речи:
Powders: chemical preparation / Nanocomposites / Titanium dioxide (TiO2) / Solar hydrogen productionИзвор:
Ceramics International, 2019, 45, 15, 19447-19455Издавач:
- Elsevier Sci Ltd, Oxford
Финансирање / пројекти:
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
- Усмерена синтеза, структура и својства мултифункционалних материјала (RS-MESTD-Basic Research (BR or ON)-172057)
DOI: 10.1016/j.ceramint.2019.06.200
ISSN: 0272-8842
WoS: 000483454200158
Scopus: 2-s2.0-85067699117
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Dostanić, Jasmina AU - Loncarević, Davor AU - Pavlović, Vladimir AU - Papan, Jelena AU - Nedeljković, Jovan M. PY - 2019 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4943 AB - Nickel-modified titanate/TiO2 catalysts were prepared by deposition of nickel ions onto hydrothermally prepared titanate supports, followed by hydrogen temperature-programmed reduction. Two different nickel precursors (hydroxide and carbonate) were used to tune reducibility and to vary the crystal phase structure of the final catalysts. The precursor reducibility and functional properties of the final catalysts were investigated systematically using various characterisation techniques. The results revealed a more facile reduction of the hydroxide precursor compared to its carbonate counterpart. Moreover, it was found that the formation of the anatase phase was favoured by the use of the hydroxide precipitation agent. The photocatalytic activity towards hydrogen production of the prepared catalysts was evaluated in the presence of 2-propanol under simulated solar light irradiation. A thorough study of the photocatalytic performance of the synthesised catalysts was conducted as a function of the precipitation agent used and the reduction temperature applied. The catalyst with dominant anatase crystal phase displayed the highest photocatalytic activity with a maximum H-2 production rate of 1040 mu mol h(-1) g(-1), this being more than four times higher than that of its carbonate counterpart. The catalysts with titanate structure showed similar activity, independent of the precipitation method used. The nanotubular structure was found to be the dominant factor in the stability of photocatalysts under long-run working conditions. PB - Elsevier Sci Ltd, Oxford T2 - Ceramics International T1 - Efficient photocatalytic hydrogen production over titanate/titania nanostructures modified with nickel EP - 19455 IS - 15 SP - 19447 VL - 45 DO - 10.1016/j.ceramint.2019.06.200 ER -
@article{ author = "Dostanić, Jasmina and Loncarević, Davor and Pavlović, Vladimir and Papan, Jelena and Nedeljković, Jovan M.", year = "2019", abstract = "Nickel-modified titanate/TiO2 catalysts were prepared by deposition of nickel ions onto hydrothermally prepared titanate supports, followed by hydrogen temperature-programmed reduction. Two different nickel precursors (hydroxide and carbonate) were used to tune reducibility and to vary the crystal phase structure of the final catalysts. The precursor reducibility and functional properties of the final catalysts were investigated systematically using various characterisation techniques. The results revealed a more facile reduction of the hydroxide precursor compared to its carbonate counterpart. Moreover, it was found that the formation of the anatase phase was favoured by the use of the hydroxide precipitation agent. The photocatalytic activity towards hydrogen production of the prepared catalysts was evaluated in the presence of 2-propanol under simulated solar light irradiation. A thorough study of the photocatalytic performance of the synthesised catalysts was conducted as a function of the precipitation agent used and the reduction temperature applied. The catalyst with dominant anatase crystal phase displayed the highest photocatalytic activity with a maximum H-2 production rate of 1040 mu mol h(-1) g(-1), this being more than four times higher than that of its carbonate counterpart. The catalysts with titanate structure showed similar activity, independent of the precipitation method used. The nanotubular structure was found to be the dominant factor in the stability of photocatalysts under long-run working conditions.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Ceramics International", title = "Efficient photocatalytic hydrogen production over titanate/titania nanostructures modified with nickel", pages = "19455-19447", number = "15", volume = "45", doi = "10.1016/j.ceramint.2019.06.200" }
Dostanić, J., Loncarević, D., Pavlović, V., Papan, J.,& Nedeljković, J. M.. (2019). Efficient photocatalytic hydrogen production over titanate/titania nanostructures modified with nickel. in Ceramics International Elsevier Sci Ltd, Oxford., 45(15), 19447-19455. https://doi.org/10.1016/j.ceramint.2019.06.200
Dostanić J, Loncarević D, Pavlović V, Papan J, Nedeljković JM. Efficient photocatalytic hydrogen production over titanate/titania nanostructures modified with nickel. in Ceramics International. 2019;45(15):19447-19455. doi:10.1016/j.ceramint.2019.06.200 .
Dostanić, Jasmina, Loncarević, Davor, Pavlović, Vladimir, Papan, Jelena, Nedeljković, Jovan M., "Efficient photocatalytic hydrogen production over titanate/titania nanostructures modified with nickel" in Ceramics International, 45, no. 15 (2019):19447-19455, https://doi.org/10.1016/j.ceramint.2019.06.200 . .