Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity
Samo za registrovane korisnike
2018
Autori
Kepić, Dejan P.Ristić, Ivan S.
Marinović-Cincović, Milena
Perusko, Davor
Spitalsky, Zdenko
Pavlović, Vladimir
Budimir, Milica D.
Siffalović, Peter
Dramicanin, Miroslav D.
Micusik, Matej
Kleinova, Angela
Janigova, Ivica
Marković, Zoran M.
Todorović-Marković, Biljana
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not... depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.
Ključne reči:
layered structures / electrical properties / microstructures / surface analysisIzvor:
Polymer International, 2018, 67, 8, 1118-1127Izdavač:
- Wiley, Hoboken
Finansiranje / projekti:
- bilateral project Serbia-Slovakia [SK-SRB-2016-0038]
- VEGAVedecka grantova agentura MSVVaS SR a SAV (VEGA) [2/0093/16]
- SASPRO Programme project [1237/02/02-b]
- SASPRO - Mobility Programme of Slovak Academy of Sciences: Supportive Fund for Excellent Scientists (EU-FP7-609427)
- Slovak Academy of Sciences
- Tanki slojevi jednoslojnih ugljeničnih nanotuba i grafena za primenu u elektronici (RS-MESTD-Basic Research (BR or ON)-172003)
- Višeskalno strukturiranje polimernih nanokompozita i funkcionalnih materijala primenom različitih prekursora (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45022)
- Uticaj veličine, oblika i strukture nanočestica na njihova svojstva i svojstva nanokompozita (RS-MESTD-Basic Research (BR or ON)-172056)
DOI: 10.1002/pi.5620
ISSN: 0959-8103
WoS: 000438218900018
Scopus: 2-s2.0-85049837334
Institucija/grupa
Poljoprivredni fakultetTY - JOUR AU - Kepić, Dejan P. AU - Ristić, Ivan S. AU - Marinović-Cincović, Milena AU - Perusko, Davor AU - Spitalsky, Zdenko AU - Pavlović, Vladimir AU - Budimir, Milica D. AU - Siffalović, Peter AU - Dramicanin, Miroslav D. AU - Micusik, Matej AU - Kleinova, Angela AU - Janigova, Ivica AU - Marković, Zoran M. AU - Todorović-Marković, Biljana PY - 2018 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4778 AB - This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene. PB - Wiley, Hoboken T2 - Polymer International T1 - Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity EP - 1127 IS - 8 SP - 1118 VL - 67 DO - 10.1002/pi.5620 ER -
@article{ author = "Kepić, Dejan P. and Ristić, Ivan S. and Marinović-Cincović, Milena and Perusko, Davor and Spitalsky, Zdenko and Pavlović, Vladimir and Budimir, Milica D. and Siffalović, Peter and Dramicanin, Miroslav D. and Micusik, Matej and Kleinova, Angela and Janigova, Ivica and Marković, Zoran M. and Todorović-Marković, Biljana", year = "2018", abstract = "This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.", publisher = "Wiley, Hoboken", journal = "Polymer International", title = "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity", pages = "1127-1118", number = "8", volume = "67", doi = "10.1002/pi.5620" }
Kepić, D. P., Ristić, I. S., Marinović-Cincović, M., Perusko, D., Spitalsky, Z., Pavlović, V., Budimir, M. D., Siffalović, P., Dramicanin, M. D., Micusik, M., Kleinova, A., Janigova, I., Marković, Z. M.,& Todorović-Marković, B.. (2018). Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International Wiley, Hoboken., 67(8), 1118-1127. https://doi.org/10.1002/pi.5620
Kepić DP, Ristić IS, Marinović-Cincović M, Perusko D, Spitalsky Z, Pavlović V, Budimir MD, Siffalović P, Dramicanin MD, Micusik M, Kleinova A, Janigova I, Marković ZM, Todorović-Marković B. Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International. 2018;67(8):1118-1127. doi:10.1002/pi.5620 .
Kepić, Dejan P., Ristić, Ivan S., Marinović-Cincović, Milena, Perusko, Davor, Spitalsky, Zdenko, Pavlović, Vladimir, Budimir, Milica D., Siffalović, Peter, Dramicanin, Miroslav D., Micusik, Matej, Kleinova, Angela, Janigova, Ivica, Marković, Zoran M., Todorović-Marković, Biljana, "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity" in Polymer International, 67, no. 8 (2018):1118-1127, https://doi.org/10.1002/pi.5620 . .