Voltammetric and Quantum Investigation of Selected Succinimides
2018
Autori
Božić, BojanLović, Jelena
Banjac, Nebojša
Vitnik, Željko J.
Vitnik, Vesna
Mijin, Dukin
Ušćumlić, Gordana
Avramov-Ivić, Milka L.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.
Ključne reči:
Diphenylsuccinimide / Threephenylsuccinimide / Voltammetry / Quantum chemical calculations / Reaction mechanismsIzvor:
International Journal of Electrochemical Science, 2018, 13, 5, 4285-4297Izdavač:
- Electrochemical Science Group, Beograd
Finansiranje / projekti:
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-Basic Research (BR or ON)-172013)
- Racionalni dizajn i sinteza biološki aktivnih i koordinacionih jedinjenja i funkcionalnih materijala, relevantnih u (bio)nanotehnologiji (RS-MESTD-Basic Research (BR or ON)-172035)
- Nov pristup dizajniranju materijala za konverziju i skladištenje energije (RS-MESTD-Basic Research (BR or ON)-172060)
DOI: 10.20964/2018.05.54
ISSN: 1452-3981
WoS: 000436257800020
Scopus: 2-s2.0-85046802281
Institucija/grupa
Poljoprivredni fakultetTY - JOUR AU - Božić, Bojan AU - Lović, Jelena AU - Banjac, Nebojša AU - Vitnik, Željko J. AU - Vitnik, Vesna AU - Mijin, Dukin AU - Ušćumlić, Gordana AU - Avramov-Ivić, Milka L. PY - 2018 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4765 AB - A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process. PB - Electrochemical Science Group, Beograd T2 - International Journal of Electrochemical Science T1 - Voltammetric and Quantum Investigation of Selected Succinimides EP - 4297 IS - 5 SP - 4285 VL - 13 DO - 10.20964/2018.05.54 ER -
@article{ author = "Božić, Bojan and Lović, Jelena and Banjac, Nebojša and Vitnik, Željko J. and Vitnik, Vesna and Mijin, Dukin and Ušćumlić, Gordana and Avramov-Ivić, Milka L.", year = "2018", abstract = "A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.", publisher = "Electrochemical Science Group, Beograd", journal = "International Journal of Electrochemical Science", title = "Voltammetric and Quantum Investigation of Selected Succinimides", pages = "4297-4285", number = "5", volume = "13", doi = "10.20964/2018.05.54" }
Božić, B., Lović, J., Banjac, N., Vitnik, Ž. J., Vitnik, V., Mijin, D., Ušćumlić, G.,& Avramov-Ivić, M. L.. (2018). Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science Electrochemical Science Group, Beograd., 13(5), 4285-4297. https://doi.org/10.20964/2018.05.54
Božić B, Lović J, Banjac N, Vitnik ŽJ, Vitnik V, Mijin D, Ušćumlić G, Avramov-Ivić ML. Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science. 2018;13(5):4285-4297. doi:10.20964/2018.05.54 .
Božić, Bojan, Lović, Jelena, Banjac, Nebojša, Vitnik, Željko J., Vitnik, Vesna, Mijin, Dukin, Ušćumlić, Gordana, Avramov-Ivić, Milka L., "Voltammetric and Quantum Investigation of Selected Succinimides" in International Journal of Electrochemical Science, 13, no. 5 (2018):4285-4297, https://doi.org/10.20964/2018.05.54 . .