Ultrasound and shacking-assisted water-leaching of anions and cations from fly ash
2016
Аутори
Savić-Bisercić, MarjetkaPezo, Lato
Sredović-Ignjatović, Ivana
Ignjatović, Ljubiša M.
Savić, Andrija
Jovanović, Uroš D.
Andrić, Velibor
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Two mechanical extraction techniques were used for the extraction of environmentaly interesting components of coal fly ash: shaking, during which the extraction process lasted from 6 up to 24 h, and sonication that lasted from 15 up to 60 min, using water as extractant. The concentration of anions in fly ash extracts was determined by ion chromatography, while atomic absorption spectrometry was used for determination of: As, Pb, Cd, Ni, Cr, Zn, Cu, Fe, Mn and Al. The ultrasonication yielded slightly higher amounts of extracted anions as well as Pb, Al, Mn and Fe cations, while shaking-assisted extraction was more efficient for the Cr, As, Zn and Ni ions. The changes in pH value, particle size distribution within colloid solution, zeta potential and conductivity during ultrasound-assisted extraction were measured in order to explain changes that occur on the surface of fly ash particles contacting water and different processes (adsorption, ion exchange and flocculation) that develop und...er natural conditions. Principal Component Analysis was used for assessing the effect of observed process parameters. It is essential to evaluate quantity of these elements leachable from coal fly ash into the surface waters in natural conditions in order to prevent contamination of the environment.
Кључне речи:
fly ash / environmental impact / aqueous extractsИзвор:
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2016, 81, 7, 813-827Издавач:
- Srpsko hemijsko društvo, Beograd
Финансирање / пројекти:
- Примена унапређених оксидационих процеса и наноструктурисаних оксидних материјала за уклањање загађивача из животне средине, развој и оптимизација инструменталних техника за праћење ефикасности (RS-MESTD-Basic Research (BR or ON)-172030)
- Геохемијска испитивања седиментних стена - фосилна горива и загађивачи животне средине (RS-MESTD-Basic Research (BR or ON)-176006)
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
DOI: 10.2298/JSC151222027B
ISSN: 0352-5139
WoS: 000382175400008
Scopus: 2-s2.0-84980537309
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Savić-Bisercić, Marjetka AU - Pezo, Lato AU - Sredović-Ignjatović, Ivana AU - Ignjatović, Ljubiša M. AU - Savić, Andrija AU - Jovanović, Uroš D. AU - Andrić, Velibor PY - 2016 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/4030 AB - Two mechanical extraction techniques were used for the extraction of environmentaly interesting components of coal fly ash: shaking, during which the extraction process lasted from 6 up to 24 h, and sonication that lasted from 15 up to 60 min, using water as extractant. The concentration of anions in fly ash extracts was determined by ion chromatography, while atomic absorption spectrometry was used for determination of: As, Pb, Cd, Ni, Cr, Zn, Cu, Fe, Mn and Al. The ultrasonication yielded slightly higher amounts of extracted anions as well as Pb, Al, Mn and Fe cations, while shaking-assisted extraction was more efficient for the Cr, As, Zn and Ni ions. The changes in pH value, particle size distribution within colloid solution, zeta potential and conductivity during ultrasound-assisted extraction were measured in order to explain changes that occur on the surface of fly ash particles contacting water and different processes (adsorption, ion exchange and flocculation) that develop under natural conditions. Principal Component Analysis was used for assessing the effect of observed process parameters. It is essential to evaluate quantity of these elements leachable from coal fly ash into the surface waters in natural conditions in order to prevent contamination of the environment. PB - Srpsko hemijsko društvo, Beograd T2 - JOURNAL OF THE SERBIAN CHEMICAL SOCIETY T1 - Ultrasound and shacking-assisted water-leaching of anions and cations from fly ash EP - 827 IS - 7 SP - 813 VL - 81 DO - 10.2298/JSC151222027B ER -
@article{ author = "Savić-Bisercić, Marjetka and Pezo, Lato and Sredović-Ignjatović, Ivana and Ignjatović, Ljubiša M. and Savić, Andrija and Jovanović, Uroš D. and Andrić, Velibor", year = "2016", abstract = "Two mechanical extraction techniques were used for the extraction of environmentaly interesting components of coal fly ash: shaking, during which the extraction process lasted from 6 up to 24 h, and sonication that lasted from 15 up to 60 min, using water as extractant. The concentration of anions in fly ash extracts was determined by ion chromatography, while atomic absorption spectrometry was used for determination of: As, Pb, Cd, Ni, Cr, Zn, Cu, Fe, Mn and Al. The ultrasonication yielded slightly higher amounts of extracted anions as well as Pb, Al, Mn and Fe cations, while shaking-assisted extraction was more efficient for the Cr, As, Zn and Ni ions. The changes in pH value, particle size distribution within colloid solution, zeta potential and conductivity during ultrasound-assisted extraction were measured in order to explain changes that occur on the surface of fly ash particles contacting water and different processes (adsorption, ion exchange and flocculation) that develop under natural conditions. Principal Component Analysis was used for assessing the effect of observed process parameters. It is essential to evaluate quantity of these elements leachable from coal fly ash into the surface waters in natural conditions in order to prevent contamination of the environment.", publisher = "Srpsko hemijsko društvo, Beograd", journal = "JOURNAL OF THE SERBIAN CHEMICAL SOCIETY", title = "Ultrasound and shacking-assisted water-leaching of anions and cations from fly ash", pages = "827-813", number = "7", volume = "81", doi = "10.2298/JSC151222027B" }
Savić-Bisercić, M., Pezo, L., Sredović-Ignjatović, I., Ignjatović, L. M., Savić, A., Jovanović, U. D.,& Andrić, V.. (2016). Ultrasound and shacking-assisted water-leaching of anions and cations from fly ash. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY Srpsko hemijsko društvo, Beograd., 81(7), 813-827. https://doi.org/10.2298/JSC151222027B
Savić-Bisercić M, Pezo L, Sredović-Ignjatović I, Ignjatović LM, Savić A, Jovanović UD, Andrić V. Ultrasound and shacking-assisted water-leaching of anions and cations from fly ash. in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY. 2016;81(7):813-827. doi:10.2298/JSC151222027B .
Savić-Bisercić, Marjetka, Pezo, Lato, Sredović-Ignjatović, Ivana, Ignjatović, Ljubiša M., Savić, Andrija, Jovanović, Uroš D., Andrić, Velibor, "Ultrasound and shacking-assisted water-leaching of anions and cations from fly ash" in JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 81, no. 7 (2016):813-827, https://doi.org/10.2298/JSC151222027B . .