The effect of substituents on the surface modification of anatase nanoparticles with catecholate-type ligands: a combined DFT and experimental study
Само за регистроване кориснике
2014
Аутори
Savić, Tatjana D.Comor, Mirjana I.
Nedeljković, Jovan M.
Veljković, Dušan Z.
Zarić, Snežana D.
Rakić, Vesna
Janković, Ivana A.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The surface modification of nanocrystalline TiO2 particles (45 angstrom) with catecholate-type ligands having different electron donating/electron withdrawing substituent groups, specifically 3-methylcatechol, 4-methylcatechol, 3-methoxycatechol, 3,4-dihydroxybenzaldehyde and 4-nitrocatechol, was found to alter the optical properties of nanoparticles in a similar way to catechol. The formation of the inner-sphere charge-transfer (CT) complexes results in a red shift of the semiconductor absorption compared to unmodified nanocrystallites and a reduction of the effective band gap, being slightly less pronounced in the case of electron withdrawing substituents. The investigated ligands have the optimal geometry for binding to surface Ti atoms, resulting in ring coordination complexes of the catecholate type (binuclear bidentate binding-bridging) thus restoring six-coordinated octahedral geometry of surface Ti atoms. From the absorption measurements (Benesi-Hildebrand plot), the stability ...constants in methanol/water = 90/10 solutions at pH 2 in the order of 10(3) M-1 have been determined. The binding structures were investigated by using FTIR spectroscopy. Thermal stability of CT-complexes was investigated by using TG/DSC/MS analysis. Quantum chemical calculations on model systems using density functional theory (DFT) were performed to obtain the vibrational frequencies of charge transfer complexes, and the calculated values were compared with the experimental data.
Извор:
Physical Chemistry Chemical Physics, 2014, 16, 38, 20796-20805Издавач:
- Royal Soc Chemistry, Cambridge
Финансирање / пројекти:
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172056)
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
DOI: 10.1039/c4cp02197e
ISSN: 1463-9076
PubMed: 25166456
WoS: 000342072300062
Scopus: 2-s2.0-84907500581
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Savić, Tatjana D. AU - Comor, Mirjana I. AU - Nedeljković, Jovan M. AU - Veljković, Dušan Z. AU - Zarić, Snežana D. AU - Rakić, Vesna AU - Janković, Ivana A. PY - 2014 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/3458 AB - The surface modification of nanocrystalline TiO2 particles (45 angstrom) with catecholate-type ligands having different electron donating/electron withdrawing substituent groups, specifically 3-methylcatechol, 4-methylcatechol, 3-methoxycatechol, 3,4-dihydroxybenzaldehyde and 4-nitrocatechol, was found to alter the optical properties of nanoparticles in a similar way to catechol. The formation of the inner-sphere charge-transfer (CT) complexes results in a red shift of the semiconductor absorption compared to unmodified nanocrystallites and a reduction of the effective band gap, being slightly less pronounced in the case of electron withdrawing substituents. The investigated ligands have the optimal geometry for binding to surface Ti atoms, resulting in ring coordination complexes of the catecholate type (binuclear bidentate binding-bridging) thus restoring six-coordinated octahedral geometry of surface Ti atoms. From the absorption measurements (Benesi-Hildebrand plot), the stability constants in methanol/water = 90/10 solutions at pH 2 in the order of 10(3) M-1 have been determined. The binding structures were investigated by using FTIR spectroscopy. Thermal stability of CT-complexes was investigated by using TG/DSC/MS analysis. Quantum chemical calculations on model systems using density functional theory (DFT) were performed to obtain the vibrational frequencies of charge transfer complexes, and the calculated values were compared with the experimental data. PB - Royal Soc Chemistry, Cambridge T2 - Physical Chemistry Chemical Physics T1 - The effect of substituents on the surface modification of anatase nanoparticles with catecholate-type ligands: a combined DFT and experimental study EP - 20805 IS - 38 SP - 20796 VL - 16 DO - 10.1039/c4cp02197e ER -
@article{ author = "Savić, Tatjana D. and Comor, Mirjana I. and Nedeljković, Jovan M. and Veljković, Dušan Z. and Zarić, Snežana D. and Rakić, Vesna and Janković, Ivana A.", year = "2014", abstract = "The surface modification of nanocrystalline TiO2 particles (45 angstrom) with catecholate-type ligands having different electron donating/electron withdrawing substituent groups, specifically 3-methylcatechol, 4-methylcatechol, 3-methoxycatechol, 3,4-dihydroxybenzaldehyde and 4-nitrocatechol, was found to alter the optical properties of nanoparticles in a similar way to catechol. The formation of the inner-sphere charge-transfer (CT) complexes results in a red shift of the semiconductor absorption compared to unmodified nanocrystallites and a reduction of the effective band gap, being slightly less pronounced in the case of electron withdrawing substituents. The investigated ligands have the optimal geometry for binding to surface Ti atoms, resulting in ring coordination complexes of the catecholate type (binuclear bidentate binding-bridging) thus restoring six-coordinated octahedral geometry of surface Ti atoms. From the absorption measurements (Benesi-Hildebrand plot), the stability constants in methanol/water = 90/10 solutions at pH 2 in the order of 10(3) M-1 have been determined. The binding structures were investigated by using FTIR spectroscopy. Thermal stability of CT-complexes was investigated by using TG/DSC/MS analysis. Quantum chemical calculations on model systems using density functional theory (DFT) were performed to obtain the vibrational frequencies of charge transfer complexes, and the calculated values were compared with the experimental data.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Physical Chemistry Chemical Physics", title = "The effect of substituents on the surface modification of anatase nanoparticles with catecholate-type ligands: a combined DFT and experimental study", pages = "20805-20796", number = "38", volume = "16", doi = "10.1039/c4cp02197e" }
Savić, T. D., Comor, M. I., Nedeljković, J. M., Veljković, D. Z., Zarić, S. D., Rakić, V.,& Janković, I. A.. (2014). The effect of substituents on the surface modification of anatase nanoparticles with catecholate-type ligands: a combined DFT and experimental study. in Physical Chemistry Chemical Physics Royal Soc Chemistry, Cambridge., 16(38), 20796-20805. https://doi.org/10.1039/c4cp02197e
Savić TD, Comor MI, Nedeljković JM, Veljković DZ, Zarić SD, Rakić V, Janković IA. The effect of substituents on the surface modification of anatase nanoparticles with catecholate-type ligands: a combined DFT and experimental study. in Physical Chemistry Chemical Physics. 2014;16(38):20796-20805. doi:10.1039/c4cp02197e .
Savić, Tatjana D., Comor, Mirjana I., Nedeljković, Jovan M., Veljković, Dušan Z., Zarić, Snežana D., Rakić, Vesna, Janković, Ivana A., "The effect of substituents on the surface modification of anatase nanoparticles with catecholate-type ligands: a combined DFT and experimental study" in Physical Chemistry Chemical Physics, 16, no. 38 (2014):20796-20805, https://doi.org/10.1039/c4cp02197e . .