Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)
Само за регистроване кориснике
2009
Аутори
Todorović, Tamara R.Rychlewska, Urszula
Warzajtis, Beata
Radanović, Dušanka
Filipović, Nenad
Pajić, Ivana A.
Sladić, Dušan M.
Andjelković, Katarina
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented.
Кључне речи:
Malonic acid dihydrazide derivative / Ni(II) and Zn(II) complexes / X-ray analysis / Antimicrobial activityИзвор:
Polyhedron, 2009, 28, 12, 2397-2402Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
- Интеракције природних производа и њихових аналога са протеинима и нуклеинским киселинама (RS-142026)
DOI: 10.1016/j.poly.2009.05.002
ISSN: 0277-5387
WoS: 000268994200014
Scopus: 2-s2.0-67650333161
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Todorović, Tamara R. AU - Rychlewska, Urszula AU - Warzajtis, Beata AU - Radanović, Dušanka AU - Filipović, Nenad AU - Pajić, Ivana A. AU - Sladić, Dušan M. AU - Andjelković, Katarina PY - 2009 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/2105 AB - The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II) EP - 2402 IS - 12 SP - 2397 VL - 28 DO - 10.1016/j.poly.2009.05.002 ER -
@article{ author = "Todorović, Tamara R. and Rychlewska, Urszula and Warzajtis, Beata and Radanović, Dušanka and Filipović, Nenad and Pajić, Ivana A. and Sladić, Dušan M. and Andjelković, Katarina", year = "2009", abstract = "The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)", pages = "2402-2397", number = "12", volume = "28", doi = "10.1016/j.poly.2009.05.002" }
Todorović, T. R., Rychlewska, U., Warzajtis, B., Radanović, D., Filipović, N., Pajić, I. A., Sladić, D. M.,& Andjelković, K.. (2009). Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II). in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 28(12), 2397-2402. https://doi.org/10.1016/j.poly.2009.05.002
Todorović TR, Rychlewska U, Warzajtis B, Radanović D, Filipović N, Pajić IA, Sladić DM, Andjelković K. Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II). in Polyhedron. 2009;28(12):2397-2402. doi:10.1016/j.poly.2009.05.002 .
Todorović, Tamara R., Rychlewska, Urszula, Warzajtis, Beata, Radanović, Dušanka, Filipović, Nenad, Pajić, Ivana A., Sladić, Dušan M., Andjelković, Katarina, "Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)" in Polyhedron, 28, no. 12 (2009):2397-2402, https://doi.org/10.1016/j.poly.2009.05.002 . .