Room-temperature interaction of n-hexane with ZSM-5 zeolites - Microcalorimetric and temperature-programmed desorption studies
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2006
Konferencijski prilog (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
In this work, room temperature interaction of n-hexane with HZSM-5 (Si/Al=20) and ion-exchanged samples containing one (CuZSM-5, FeZSM-5 and MnZSM-5) or two transition-metal cations (Fe,CuZSM-5; Cu,MnZSM-5 and Fe,MnZSM-5) was studied by microcalorimetry and TPD methods. Both differential heats and the amounts of n-hexane adsorbed per one unit cell were quantitatively determined. Higher heats of adsorption and higher amounts of adsorbed gas were found for ion-exchanged samples than for HZSM-5. The experiments of n-hexane adsorption on hydrated samples were also performed. The amounts of n-hexane adsorbed on hydrated ZSM-5 were lower in comparison with dehydrated samples, while the energies of interaction were similar.
Ključne reči:
microcalorimetry / n-hexane / temperature-programmed desorption / ZSM-5Izvor:
Journal of Thermal Analysis and Calorimetry, 2006, 84, 1, 239-245Izdavač:
- Springer, Dordrecht
Finansiranje / projekti:
- Strukturne modifikacije i reakcije mikroporoznih i mezoporoznih materijala (RS-MESTD-MPN2006-2010-142055)
DOI: 10.1007/s10973-005-7164-z
ISSN: 1388-6150
WoS: 000238190700037
Scopus: 2-s2.0-33645920991
Institucija/grupa
Poljoprivredni fakultetTY - CONF AU - Rac, Vladislav AU - Rakić, Vesna AU - Gajinov, S. AU - Dondur, Vera AU - Auroux, Aline PY - 2006 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/1342 AB - In this work, room temperature interaction of n-hexane with HZSM-5 (Si/Al=20) and ion-exchanged samples containing one (CuZSM-5, FeZSM-5 and MnZSM-5) or two transition-metal cations (Fe,CuZSM-5; Cu,MnZSM-5 and Fe,MnZSM-5) was studied by microcalorimetry and TPD methods. Both differential heats and the amounts of n-hexane adsorbed per one unit cell were quantitatively determined. Higher heats of adsorption and higher amounts of adsorbed gas were found for ion-exchanged samples than for HZSM-5. The experiments of n-hexane adsorption on hydrated samples were also performed. The amounts of n-hexane adsorbed on hydrated ZSM-5 were lower in comparison with dehydrated samples, while the energies of interaction were similar. PB - Springer, Dordrecht C3 - Journal of Thermal Analysis and Calorimetry T1 - Room-temperature interaction of n-hexane with ZSM-5 zeolites - Microcalorimetric and temperature-programmed desorption studies EP - 245 IS - 1 SP - 239 VL - 84 DO - 10.1007/s10973-005-7164-z ER -
@conference{ author = "Rac, Vladislav and Rakić, Vesna and Gajinov, S. and Dondur, Vera and Auroux, Aline", year = "2006", abstract = "In this work, room temperature interaction of n-hexane with HZSM-5 (Si/Al=20) and ion-exchanged samples containing one (CuZSM-5, FeZSM-5 and MnZSM-5) or two transition-metal cations (Fe,CuZSM-5; Cu,MnZSM-5 and Fe,MnZSM-5) was studied by microcalorimetry and TPD methods. Both differential heats and the amounts of n-hexane adsorbed per one unit cell were quantitatively determined. Higher heats of adsorption and higher amounts of adsorbed gas were found for ion-exchanged samples than for HZSM-5. The experiments of n-hexane adsorption on hydrated samples were also performed. The amounts of n-hexane adsorbed on hydrated ZSM-5 were lower in comparison with dehydrated samples, while the energies of interaction were similar.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "Room-temperature interaction of n-hexane with ZSM-5 zeolites - Microcalorimetric and temperature-programmed desorption studies", pages = "245-239", number = "1", volume = "84", doi = "10.1007/s10973-005-7164-z" }
Rac, V., Rakić, V., Gajinov, S., Dondur, V.,& Auroux, A.. (2006). Room-temperature interaction of n-hexane with ZSM-5 zeolites - Microcalorimetric and temperature-programmed desorption studies. in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 84(1), 239-245. https://doi.org/10.1007/s10973-005-7164-z
Rac V, Rakić V, Gajinov S, Dondur V, Auroux A. Room-temperature interaction of n-hexane with ZSM-5 zeolites - Microcalorimetric and temperature-programmed desorption studies. in Journal of Thermal Analysis and Calorimetry. 2006;84(1):239-245. doi:10.1007/s10973-005-7164-z .
Rac, Vladislav, Rakić, Vesna, Gajinov, S., Dondur, Vera, Auroux, Aline, "Room-temperature interaction of n-hexane with ZSM-5 zeolites - Microcalorimetric and temperature-programmed desorption studies" in Journal of Thermal Analysis and Calorimetry, 84, no. 1 (2006):239-245, https://doi.org/10.1007/s10973-005-7164-z . .